Cold-junction compensation(CJC)and disconnection detection circuit design of various thermocouples(TC)and multi-channel TC interface circuits were designed.The CJC and disconnection detection circuit consists of a CJC...Cold-junction compensation(CJC)and disconnection detection circuit design of various thermocouples(TC)and multi-channel TC interface circuits were designed.The CJC and disconnection detection circuit consists of a CJC semiconductor device,an instrumentation amplifier(IA),two resistors,and a diode for disconnection detection.Based on the basic circuit,a multi-channel interface circuit was also implemented.The CJC was implemented using compensation semiconductor and IA,and disconnection detection was detected by using two resistors and a diode so that IA input voltage became-0.42 V.As a result of the experiment using R-type TC,the error of the designed circuit was reduced from 0.14 mV to 3μV after CJC in the temperature range of 0°C to 1400°C.In addition,it was confirmed that the output voltage of IA was saturated from 88 mV to-14.2 V when TC was disconnected from normal.The output voltage of the designed circuit was 0 V to 10 V in the temperature range of 0°C to 1400°C.The results of the 4-channel interface experiment using R-type TC were almost identical to the CJC and disconnection detection results for each channel.The implemented multi-channel interface has a feature that can be applied equally to E,J,K,T,R,and S-type TCs by changing the terminals of CJC semiconductor devices and adjusting the IA gain.展开更多
A new method was proposed, in which a high-power CO2 laser modulated by high frequency was used as the driv- ing source to heat up a surface-temperature sensor. The continual beam and the pulsed beam sent out by the s...A new method was proposed, in which a high-power CO2 laser modulated by high frequency was used as the driv- ing source to heat up a surface-temperature sensor. The continual beam and the pulsed beam sent out by the same laser could be used in the same system to carry on the static calibration of the radiation thermometer and the dynamic calibration of the temperature sensor to be checked. The frequency-response characteristics of high-speed radiation thermometer surpassed that of the temperature sensor, therefore it could be used as the reference value to calibrate the latter and let system error be cor- rected. Differences in the environment of the sensor installing and the error caused by the change of thermo-physical proper- ty could be avoided. Thus, the difficult problem of traceable dynamic calibration of temperature was solved. In experiment, to obtain the frequency characteristics of the thermocouple and the dynamic performance of the K type thermocouple, which could compensate the dynamic characteristics of the sensor, the sensor was dynamically corrected by using the method, and then the mathematical model was established.展开更多
The theory for measuring the time constant of thermocouple was introduced, and the method for measuring the time constant of NANMAC thermocouple by using dynamic calibration system of transient surface temperature sen...The theory for measuring the time constant of thermocouple was introduced, and the method for measuring the time constant of NANMAC thermocouple by using dynamic calibration system of transient surface temperature sensor was proposed. In this system, static and dynamic calibrations were conducted for infrared detectors and thermocouples, and then both temperature-time curves were obtained. Since the frequency response of infrared detector is superior to that of calibrat- ed thermocouple, the values measured by infrared detectors are taken as true values. Through dividing the values measured with thermocouples by those with infrared detectors, a normalized curve was obtained, based on which the time constant of thermocouple was measured. With this method, the experiments were carried out with NANMAC thermocouple to obtain its time constant. The results show that the method for measuring the time constant is feasible and the dynamic calibration of thermocouples can be achieved at microsecond and millisecond level. This research has a certain reference value for research and application of NANMAC thermocouple temperature sensor.展开更多
In high-speed cutting, natural thermocouple, artificial thermocouple and infrared radiation temperature measurement are usually adopted for measuring cutting temperature, but these methods have difficulty in measuring...In high-speed cutting, natural thermocouple, artificial thermocouple and infrared radiation temperature measurement are usually adopted for measuring cutting temperature, but these methods have difficulty in measuring transient temperature accurately of cutting area on account of low response speed and limited cutting condition. In this paper, NiCr/NiSi thin-film thermocouples（TFTCs） are fabricated according to temperature characteristic of cutting area in high-speed cutting by means of advanced twinned microwave electro cyclotron resonance（MW-ECR） plasma source enhanced radio frequency（RF） reaction non-balance magnetron sputtering technique, and can be used for transient cutting temperature measurement. The time constants of the TFTCs with different thermo-junction film width are measured at four kinds of sampling frequency by using Ultra-CFR short pulsed laser system that established. One-dimensional unsteady heat conduction model is constructed and the dynamic performance is analyzed theoretically. It can be seen from the analysis results that the NiCr/NiSi TFTCs are suitable for measuring transient temperature which varies quickly, the response speed of TFTCs can be obviously improved by reducing the thickness of thin-film, and the area of thermo-junction has little influence on dynamic response time. The dynamic calibration experiments are made on the constructed dynamic calibration system, and the experimental results confirm that sampling frequency should be larger than 50 kHz in dynamic measurement for stable response time, and the shortest response time is 0.042 ms. Measurement methods and devices of cutting heat and cutting temperature measurement are developed and improved by this research, which provide practical methods and instruments in monitoring cutting heat and cutting temperature for research and production in high-speed machining.展开更多
For the manufacture of S-type thermocouple the so-called thermocouple wire of platinum and platinum-rhodium alloy is used.One of the main technical requirements for the quality of the wire,according to State Standard ...For the manufacture of S-type thermocouple the so-called thermocouple wire of platinum and platinum-rhodium alloy is used.One of the main technical requirements for the quality of the wire,according to State Standard of Russia(GOST 10821),is the uniformity of its largest thermoelectric force(Thermo-emf) in the length different sections.It was found that a determining impact on the uniformity of the wire thermo-emf is the distribution of rhodium along the length of the wire.The impact of platinum-rhodium melt crystallization conditions on the inhomogeneity of wire manufactured from it.It was suggested that the chemical inhomogeneity of the wire is related to the liquation phase of platinum-rhodium alloy.展开更多
The electromotive force (EMF) changes in type K heavy gauge sheathed thermocouple cables was investigated. To cope with this discrepancy owing to EMF steep reduction and understand the difference between type K heavy ...The electromotive force (EMF) changes in type K heavy gauge sheathed thermocouple cables was investigated. To cope with this discrepancy owing to EMF steep reduction and understand the difference between type K heavy gauge sheathed thermocouple cables and small ones, the affects of EMF from sheath pipe, drawing times, annealing temperature, annealing time and annealing way were mainly studied and appropriately analyzed. The results show the change in the thermal EMF is related with the residual stress and crystal defects, which are imparted by cold work during manufacture. The affects of cold work can be removed by annealing. Finally, a feasible way of fabricating heavy gauge sheathed thermocouples was suggested according to practical situation.展开更多
There are large errors of linear measurement when the thermocouple measure temperature as temperature sensor.In order to improve the measurement precision,the sensor cold junction compensation and nonlinear compensati...There are large errors of linear measurement when the thermocouple measure temperature as temperature sensor.In order to improve the measurement precision,the sensor cold junction compensation and nonlinear compensation are usually needed.For the circumstances that the cold junction’s temperature is determinate,there is biggish nonlinear between thermoelectric power and temperature signals of the thermocouple sensor’s output.In order to solve the problem,this paper proposed a practical method of linear compensation,introduced the principle of linear compensation and gave the corresponding compensation circuit and circuit analysis.This circuit has the characteristic of simpleness,high reliability,small linear error and so on.展开更多
Aiming at high requirements of temperature measurement system in high temperature,high pressure,highly corrosive and other special environments,a temperature acquisition system based on field-programmable gate array(F...Aiming at high requirements of temperature measurement system in high temperature,high pressure,highly corrosive and other special environments,a temperature acquisition system based on field-programmable gate array(FPGA) which is the controller of the system is designed.Also a Flash memory is used as the memory and an erosion thermocouple is used as sensor of the system.Compared with the traditional system using complex programmable logic device(CPLD)and microcontroller unit(MCU)as the main body,this system has some advantages,such as short response time,small volume,no loss of data once power is off,high precision,stability and reliability.And the sensor of the system can be reused.In this paper,boiling water experiment is used to verify accuracy of the system.The millisecond level signal from firecrackers is for verifying the stability and fast response characteristics of the system.The results of experiment indicate that the temperature measurement system is more suitable for the field of explosion and other environments which have high requirements for the system.展开更多
A new simultaneous measurement method for the measurement of the three thermoelectric properties with a film-type thermocouple probe was proposed. Seebeck coefficient was measured using the steady-state condi-tion of ...A new simultaneous measurement method for the measurement of the three thermoelectric properties with a film-type thermocouple probe was proposed. Seebeck coefficient was measured using the steady-state condi-tion of the differential method. The electrical resistivity was measured us-ing the four-probe method and the thermal diffusivity is measured using the periodic heating method. The effectiveness of the proposed method was verified using constantan as a reference material. After describing the effectiveness of the method, the measurement of three thermoelectric properties of Bi0.3Sb1.7Te3, which is a thermoelectric material, was per-formed.展开更多
The thermodynamic re-assessment of Au-Pt binary system was carried out by using the Calphad method and based on the recent experimental data. The Gibbs energies of face-centred cubic and liquid phases were described b...The thermodynamic re-assessment of Au-Pt binary system was carried out by using the Calphad method and based on the recent experimental data. The Gibbs energies of face-centred cubic and liquid phases were described by a sub-regular solution model with the Redlich-Kister equation. Much effort was taken to reproduce the phase equilibrium results and thermodynamic properties of the solid phase, including the activity and mixing enthalpy. The constraint of the third law of thermodynamics was also considered in the assessment. According to the presently assessed results, the miscibility gap region in the Au-Pt system slightly shifts to the Au-rich side, and the critical !0oint of the miscibility gap is about 1200 ℃ and Au-56% Pt.展开更多
The Au-Pt alloy nanoparticles（Au-PtNPs） were electrochemically deposited on the surface of polyaniline nanotube（nanoPAN） and chitosan（CS） modified glassy carbon electrode（GCE）. The electrochemical behavior of ...The Au-Pt alloy nanoparticles（Au-PtNPs） were electrochemically deposited on the surface of polyaniline nanotube（nanoPAN） and chitosan（CS） modified glassy carbon electrode（GCE）. The electrochemical behavior of lincomycin at Au-PtNPs/nanoPAN/CS modified GCE was investigated by cyclic voltammetry, linear sweep voltammetry and chronocoulometry. Cyclic voltammetric experiments show that lincomycin at the nanocomposite membrane modified electrode exhibited a pair of quasi-reversible redox peaks in pH=6.0 PBS. The membrane could accelerate the electron transfer of lincomycin on the electrode and significantly enhance the peak current. In a range of 3.0-100.0 mg/L, the reductive peak current of lincomycin at 0.42 V was linearly related to its concentration and the linear regression equation was ip,c=0.2703ρ-0.0042（ip, c： μA; ρ： mg/L; r=0.998, n=7） with a detection limit of 1.0 mg/L（S/N =3）. Compared with other methods, this method exhibited many advantages such as high sensitivity, selectivity, wide linear range and low detection limit. The method was used to determine the content of lincomycin in injections commercially available with satisfactory results. Some electrochemical parameters involved in the redox reaction of lincomycin, such as parameter of kinetic ha, standard rate constant ks and the number of H^＋, were also calculated.展开更多
Objective To compare the long-term clinical effects of two kinds of crowns and bridges made of porcelain fused to Au-Pt alloy and Ni-Cr alloy. Methods A total of 131 teeth (64 patients) were rehabilitated using porcel...Objective To compare the long-term clinical effects of two kinds of crowns and bridges made of porcelain fused to Au-Pt alloy and Ni-Cr alloy. Methods A total of 131 teeth (64 patients) were rehabilitated using porcelain-fused-to-metal crowns, among which 59 were rehabilitated with Au-Pt alloy metal ceramic crown and 72 with Ni-Cr alloy metal ceramic crown. The porcelain fracture, shade, marginal adaptation, gingival discoloration, and gingival status after finishing restoration and 36 months of follow-up were evaluated. Results After 36 months of restoration, porcelain fused to Au-Pt alloy crown showed better clinical effects than porcelain fused to Ni-Cr alloy crown in shade, marginal adaptation, gingival discoloration, as well as gingival status (all P<0.05). Conclusion The Au-Pt alloy ceramic crown is superior to Ni-Cr alloy ceramic crown in long-term clinical effects.展开更多
同步辐射广泛使用Au薄膜作为反射镜膜层,降低Au薄膜的粗糙度以减小散射信号仍是难点。基于国内外对Au薄膜的研究,本文采用在Au薄膜中插入Pt间隔层的方法,制备了新型Au-Pt薄膜。原子力显微镜(Atomic Force Microscope,AFM)测试结果表明:...同步辐射广泛使用Au薄膜作为反射镜膜层,降低Au薄膜的粗糙度以减小散射信号仍是难点。基于国内外对Au薄膜的研究,本文采用在Au薄膜中插入Pt间隔层的方法,制备了新型Au-Pt薄膜。原子力显微镜(Atomic Force Microscope,AFM)测试结果表明:采用1 nm厚的Au膜层和1 nm厚的Pt间隔层交替制备的方法所获得的新型Au-Pt薄膜,粗糙度小于0.3 nm,明显小于传统Au薄膜的粗糙度;通过X射线衍射(X-ray Diffractometer,XRD)测试可以发现,Pt间隔层的插入能够有效抑制Au膜结晶。随着Pt间隔层插入间隔的减小,Au膜结晶程度显著降低。根据AFM测试结果,使用IMD软件计算了传统Au薄膜以及新型Au-Pt薄膜的反射率,发现新型Au-Pt薄膜反射率比传统Au薄膜略有提高,同时新型Au-Pt薄膜的表面粗糙度更小,降低了散射强度,提升了反射镜的实际性能。本文为用于同步辐射的高传输效率、高反射率的Au-Pt薄膜反射镜的制备提供了参考。展开更多
文摘Cold-junction compensation(CJC)and disconnection detection circuit design of various thermocouples(TC)and multi-channel TC interface circuits were designed.The CJC and disconnection detection circuit consists of a CJC semiconductor device,an instrumentation amplifier(IA),two resistors,and a diode for disconnection detection.Based on the basic circuit,a multi-channel interface circuit was also implemented.The CJC was implemented using compensation semiconductor and IA,and disconnection detection was detected by using two resistors and a diode so that IA input voltage became-0.42 V.As a result of the experiment using R-type TC,the error of the designed circuit was reduced from 0.14 mV to 3μV after CJC in the temperature range of 0°C to 1400°C.In addition,it was confirmed that the output voltage of IA was saturated from 88 mV to-14.2 V when TC was disconnected from normal.The output voltage of the designed circuit was 0 V to 10 V in the temperature range of 0°C to 1400°C.The results of the 4-channel interface experiment using R-type TC were almost identical to the CJC and disconnection detection results for each channel.The implemented multi-channel interface has a feature that can be applied equally to E,J,K,T,R,and S-type TCs by changing the terminals of CJC semiconductor devices and adjusting the IA gain.
基金Research Project Supported by Shanxi Scholarship Council of China(No.2012-068)Taiyuan Science and Technology Agency(No.120247-20)Surface-temperature Sensor Dynamic Measurement and Calibration Technology Research of National Defense Fundamental Scientific Research
文摘A new method was proposed, in which a high-power CO2 laser modulated by high frequency was used as the driv- ing source to heat up a surface-temperature sensor. The continual beam and the pulsed beam sent out by the same laser could be used in the same system to carry on the static calibration of the radiation thermometer and the dynamic calibration of the temperature sensor to be checked. The frequency-response characteristics of high-speed radiation thermometer surpassed that of the temperature sensor, therefore it could be used as the reference value to calibrate the latter and let system error be cor- rected. Differences in the environment of the sensor installing and the error caused by the change of thermo-physical proper- ty could be avoided. Thus, the difficult problem of traceable dynamic calibration of temperature was solved. In experiment, to obtain the frequency characteristics of the thermocouple and the dynamic performance of the K type thermocouple, which could compensate the dynamic characteristics of the sensor, the sensor was dynamically corrected by using the method, and then the mathematical model was established.
文摘The theory for measuring the time constant of thermocouple was introduced, and the method for measuring the time constant of NANMAC thermocouple by using dynamic calibration system of transient surface temperature sensor was proposed. In this system, static and dynamic calibrations were conducted for infrared detectors and thermocouples, and then both temperature-time curves were obtained. Since the frequency response of infrared detector is superior to that of calibrat- ed thermocouple, the values measured by infrared detectors are taken as true values. Through dividing the values measured with thermocouples by those with infrared detectors, a normalized curve was obtained, based on which the time constant of thermocouple was measured. With this method, the experiments were carried out with NANMAC thermocouple to obtain its time constant. The results show that the method for measuring the time constant is feasible and the dynamic calibration of thermocouples can be achieved at microsecond and millisecond level. This research has a certain reference value for research and application of NANMAC thermocouple temperature sensor.
基金supported by National Natural Science Foundation of China(Grant No.50775210)Liaoning Provincial Natural Science Foundation of China(Grant No.20062143)Liaoning Provincial Universities Science and Technology Program of China(Grant No.05L023)
文摘In high-speed cutting, natural thermocouple, artificial thermocouple and infrared radiation temperature measurement are usually adopted for measuring cutting temperature, but these methods have difficulty in measuring transient temperature accurately of cutting area on account of low response speed and limited cutting condition. In this paper, NiCr/NiSi thin-film thermocouples（TFTCs） are fabricated according to temperature characteristic of cutting area in high-speed cutting by means of advanced twinned microwave electro cyclotron resonance（MW-ECR） plasma source enhanced radio frequency（RF） reaction non-balance magnetron sputtering technique, and can be used for transient cutting temperature measurement. The time constants of the TFTCs with different thermo-junction film width are measured at four kinds of sampling frequency by using Ultra-CFR short pulsed laser system that established. One-dimensional unsteady heat conduction model is constructed and the dynamic performance is analyzed theoretically. It can be seen from the analysis results that the NiCr/NiSi TFTCs are suitable for measuring transient temperature which varies quickly, the response speed of TFTCs can be obviously improved by reducing the thickness of thin-film, and the area of thermo-junction has little influence on dynamic response time. The dynamic calibration experiments are made on the constructed dynamic calibration system, and the experimental results confirm that sampling frequency should be larger than 50 kHz in dynamic measurement for stable response time, and the shortest response time is 0.042 ms. Measurement methods and devices of cutting heat and cutting temperature measurement are developed and improved by this research, which provide practical methods and instruments in monitoring cutting heat and cutting temperature for research and production in high-speed machining.
文摘For the manufacture of S-type thermocouple the so-called thermocouple wire of platinum and platinum-rhodium alloy is used.One of the main technical requirements for the quality of the wire,according to State Standard of Russia(GOST 10821),is the uniformity of its largest thermoelectric force(Thermo-emf) in the length different sections.It was found that a determining impact on the uniformity of the wire thermo-emf is the distribution of rhodium along the length of the wire.The impact of platinum-rhodium melt crystallization conditions on the inhomogeneity of wire manufactured from it.It was suggested that the chemical inhomogeneity of the wire is related to the liquation phase of platinum-rhodium alloy.
文摘The electromotive force (EMF) changes in type K heavy gauge sheathed thermocouple cables was investigated. To cope with this discrepancy owing to EMF steep reduction and understand the difference between type K heavy gauge sheathed thermocouple cables and small ones, the affects of EMF from sheath pipe, drawing times, annealing temperature, annealing time and annealing way were mainly studied and appropriately analyzed. The results show the change in the thermal EMF is related with the residual stress and crystal defects, which are imparted by cold work during manufacture. The affects of cold work can be removed by annealing. Finally, a feasible way of fabricating heavy gauge sheathed thermocouples was suggested according to practical situation.
文摘There are large errors of linear measurement when the thermocouple measure temperature as temperature sensor.In order to improve the measurement precision,the sensor cold junction compensation and nonlinear compensation are usually needed.For the circumstances that the cold junction’s temperature is determinate,there is biggish nonlinear between thermoelectric power and temperature signals of the thermocouple sensor’s output.In order to solve the problem,this paper proposed a practical method of linear compensation,introduced the principle of linear compensation and gave the corresponding compensation circuit and circuit analysis.This circuit has the characteristic of simpleness,high reliability,small linear error and so on.
基金Natural Science Foundation of Shanxi Province(No. 2009011023)
文摘Aiming at high requirements of temperature measurement system in high temperature,high pressure,highly corrosive and other special environments,a temperature acquisition system based on field-programmable gate array(FPGA) which is the controller of the system is designed.Also a Flash memory is used as the memory and an erosion thermocouple is used as sensor of the system.Compared with the traditional system using complex programmable logic device(CPLD)and microcontroller unit(MCU)as the main body,this system has some advantages,such as short response time,small volume,no loss of data once power is off,high precision,stability and reliability.And the sensor of the system can be reused.In this paper,boiling water experiment is used to verify accuracy of the system.The millisecond level signal from firecrackers is for verifying the stability and fast response characteristics of the system.The results of experiment indicate that the temperature measurement system is more suitable for the field of explosion and other environments which have high requirements for the system.
文摘A new simultaneous measurement method for the measurement of the three thermoelectric properties with a film-type thermocouple probe was proposed. Seebeck coefficient was measured using the steady-state condi-tion of the differential method. The electrical resistivity was measured us-ing the four-probe method and the thermal diffusivity is measured using the periodic heating method. The effectiveness of the proposed method was verified using constantan as a reference material. After describing the effectiveness of the method, the measurement of three thermoelectric properties of Bi0.3Sb1.7Te3, which is a thermoelectric material, was per-formed.
基金Project (50871028) supported by the National Natural Science Foundation of ChinaProjects (N100702001,N090502002) supported by the Fundamental Research Funds for the Central Universities,China+1 种基金Project (NCET-09-0272) supported by the Program for New Century Excellent Talents in University of Ministry of Education, ChinaProject (200803) supported by Northeastern University Research Foundation for Doctor Candidates,China
文摘The thermodynamic re-assessment of Au-Pt binary system was carried out by using the Calphad method and based on the recent experimental data. The Gibbs energies of face-centred cubic and liquid phases were described by a sub-regular solution model with the Redlich-Kister equation. Much effort was taken to reproduce the phase equilibrium results and thermodynamic properties of the solid phase, including the activity and mixing enthalpy. The constraint of the third law of thermodynamics was also considered in the assessment. According to the presently assessed results, the miscibility gap region in the Au-Pt system slightly shifts to the Au-rich side, and the critical !0oint of the miscibility gap is about 1200 ℃ and Au-56% Pt.
基金Supported by the National Natural Science Foundation of China(Nos.20635020 and 20805025)Doctorial Foundation of the Ministry of Education of China(No.20060426001) Doctorial Fund of Qingdao University of Science and Technology, China(No.0022278)
文摘The Au-Pt alloy nanoparticles（Au-PtNPs） were electrochemically deposited on the surface of polyaniline nanotube（nanoPAN） and chitosan（CS） modified glassy carbon electrode（GCE）. The electrochemical behavior of lincomycin at Au-PtNPs/nanoPAN/CS modified GCE was investigated by cyclic voltammetry, linear sweep voltammetry and chronocoulometry. Cyclic voltammetric experiments show that lincomycin at the nanocomposite membrane modified electrode exhibited a pair of quasi-reversible redox peaks in pH=6.0 PBS. The membrane could accelerate the electron transfer of lincomycin on the electrode and significantly enhance the peak current. In a range of 3.0-100.0 mg/L, the reductive peak current of lincomycin at 0.42 V was linearly related to its concentration and the linear regression equation was ip,c=0.2703ρ-0.0042（ip, c： μA; ρ： mg/L; r=0.998, n=7） with a detection limit of 1.0 mg/L（S/N =3）. Compared with other methods, this method exhibited many advantages such as high sensitivity, selectivity, wide linear range and low detection limit. The method was used to determine the content of lincomycin in injections commercially available with satisfactory results. Some electrochemical parameters involved in the redox reaction of lincomycin, such as parameter of kinetic ha, standard rate constant ks and the number of H^＋, were also calculated.
文摘Objective To compare the long-term clinical effects of two kinds of crowns and bridges made of porcelain fused to Au-Pt alloy and Ni-Cr alloy. Methods A total of 131 teeth (64 patients) were rehabilitated using porcelain-fused-to-metal crowns, among which 59 were rehabilitated with Au-Pt alloy metal ceramic crown and 72 with Ni-Cr alloy metal ceramic crown. The porcelain fracture, shade, marginal adaptation, gingival discoloration, and gingival status after finishing restoration and 36 months of follow-up were evaluated. Results After 36 months of restoration, porcelain fused to Au-Pt alloy crown showed better clinical effects than porcelain fused to Ni-Cr alloy crown in shade, marginal adaptation, gingival discoloration, as well as gingival status (all P<0.05). Conclusion The Au-Pt alloy ceramic crown is superior to Ni-Cr alloy ceramic crown in long-term clinical effects.
