Sulfated zirconia-lanthana （SO4^2-/ZrO2-La2O3） precursors were prepared by ultrasonic coprecipitation method and followed by aging at different temperature. The precursors were treated by 0.5 mol/L H2SO4. Samples of...Sulfated zirconia-lanthana （SO4^2-/ZrO2-La2O3） precursors were prepared by ultrasonic coprecipitation method and followed by aging at different temperature. The precursors were treated by 0.5 mol/L H2SO4. Samples of SO4^2-/ZrO2-La2O3 nano-crystalline catalysts were obtained by baking the treated precursors at different temperatures. The acidic properties of SO4^2-/ZrO2-La2O3 were tested by the Hammett indicator method. The phase composition, specific area, particle structure, and surface state were characterized by X-ray diffraction, BET, transmission electron microscopy, infrared spectrum, and X-ray photoelectron spec- troscopy. The catalytic activities were estimated by esterification of acetic acid with glycerin. It was shown that the catalyst prepared by ultrasonic stirring and low temperature （-15 ℃） exhibited highly active sites and high catalytic property.展开更多
The Bi_4Ti_3O_(12)/g-C_3N_4 composites with microsheet and nanosheet structure were prepared through facile ultrasonic-assisted method. The SEM and TEM results suggested that the nanosheets g-C_3N_4 were stacked on th...The Bi_4Ti_3O_(12)/g-C_3N_4 composites with microsheet and nanosheet structure were prepared through facile ultrasonic-assisted method. The SEM and TEM results suggested that the nanosheets g-C_3N_4 were stacked on the surface of regular Bi_4Ti_3O_(12) sheets. Comparing with pure Bi_4Ti_3O_(12) and g-C_3N_4, the Bi_4Ti_3O_(12)/g-C_3N_4 composites showed significant enhancement in photocatalytic efficiency for the degradation of RhB in solution. With the mass ratio of g-C_3N_4 increasing to 10 wt%, the Bi_4Ti_3O_(12)/g-C_3N_4-10% presented the best photocatalytic activity. Its photocatalysis reaction constant was approximately 2 times higher than the single component Bi_4Ti_3O_(12) or g-C_3N_4. Meanwhile, good stability and durability for the Bi_4Ti_3O_(12)/g-C_3N_4-10% were confirmed by the recycling experiment and FT-IR analysis. The possible mechanism for the improvements was the matched band positions and the effective separation of photo-excited electrons(e-) and holes(h+). Furthermore, based on the results of active species trapping, photo-generated holes(h+) and superoxide radical(·O2-) could be the main radicals in reaction.展开更多
Hypereutectic Al -27Si alloys were joined without flux by ultrasonic-assisted soldering at 420 ℃ in air using Zn -5Al the filler alloys, and Si particulate-reinforced Zn - Al based composites filler joints were obtai...Hypereutectic Al -27Si alloys were joined without flux by ultrasonic-assisted soldering at 420 ℃ in air using Zn -5Al the filler alloys, and Si particulate-reinforced Zn - Al based composites filler joints were obtained. The ultrasonic vibration introduced into soldering could influence the migration of Si particles and the microstructure of solidified Zn - Al based alloys. Both the distribution of Si particles and microstructure of the solidified Zn - Al based alloys affected the shear strength of joints. The shear strength increased with the ultrasonic vibration time. The highest average shear strength of joints reached to -68.5 MPa. Transcrystalline rupture mode was observed on the fracture surface.展开更多
The mechanism of ultrasonic vibration honing Nd-Fe-B has been briefly elaborated after the introduction of the strategic significance of processing Nd-Fe-B. Based on the formation principle of Scanning Electrtmic Micr...The mechanism of ultrasonic vibration honing Nd-Fe-B has been briefly elaborated after the introduction of the strategic significance of processing Nd-Fe-B. Based on the formation principle of Scanning Electrtmic Microscope （SEM）, and at the examination with the aid of SEM to the ultrasonic vibration honing Nd-Fe-B material＇s superficial microscopic topography, the paper discusses the new processing nechanism according to the SEM examination picture. The research indicates that as a result of supersonic high frequency vibration, the path of the abrasion extends at the same time, and the supersonic cavitation effect forms the intense shock-wave, knpacting Nd-Fe-B material＇s intemal surface, providing the supersonic energy for the superticial abrasive dust＇s dimination, which directly explain that the honing processing efficiency is enhanced, and the processing surface roughness is high.展开更多
A smart decontamination device is developed for small-size radioactive scrap metal(SSRSM)arisen from nuclear facilities.The abrasion pin in rotating magnetic field and ultrasonic wave cleaner are used for solving the ...A smart decontamination device is developed for small-size radioactive scrap metal(SSRSM)arisen from nuclear facilities.The abrasion pin in rotating magnetic field and ultrasonic wave cleaner are used for solving the problems of the second decontamination and high treatment cost.At first,the decontamination efficiency of each device is improved by upgrading the design.Optimal operating conditions are determined for each device.Next,both techniques are applied sequentially.Experimental results show that the efficiency of combined decontamination device is higher than that of each device.With the use of the developed device,the various SSRSMs are decontaminated for 15 min treatment in magnetic abrasion device and15 min treatment in ultrasonic cleaning device.Decontamination index ranges from18 to 56.Absolute values of all decontaminated samples are below the background value.展开更多
文摘Sulfated zirconia-lanthana （SO4^2-/ZrO2-La2O3） precursors were prepared by ultrasonic coprecipitation method and followed by aging at different temperature. The precursors were treated by 0.5 mol/L H2SO4. Samples of SO4^2-/ZrO2-La2O3 nano-crystalline catalysts were obtained by baking the treated precursors at different temperatures. The acidic properties of SO4^2-/ZrO2-La2O3 were tested by the Hammett indicator method. The phase composition, specific area, particle structure, and surface state were characterized by X-ray diffraction, BET, transmission electron microscopy, infrared spectrum, and X-ray photoelectron spec- troscopy. The catalytic activities were estimated by esterification of acetic acid with glycerin. It was shown that the catalyst prepared by ultrasonic stirring and low temperature （-15 ℃） exhibited highly active sites and high catalytic property.
基金Supported by the National Natural Science Foundation of China(51509220)the Natural Science Foundation of Zhejiang Province(LQ14E090003)+1 种基金Ningbo Science and Technology Plan Projects(2014C50007,2014C51003)Ningbo major social development projects(2017C510006)
文摘The Bi_4Ti_3O_(12)/g-C_3N_4 composites with microsheet and nanosheet structure were prepared through facile ultrasonic-assisted method. The SEM and TEM results suggested that the nanosheets g-C_3N_4 were stacked on the surface of regular Bi_4Ti_3O_(12) sheets. Comparing with pure Bi_4Ti_3O_(12) and g-C_3N_4, the Bi_4Ti_3O_(12)/g-C_3N_4 composites showed significant enhancement in photocatalytic efficiency for the degradation of RhB in solution. With the mass ratio of g-C_3N_4 increasing to 10 wt%, the Bi_4Ti_3O_(12)/g-C_3N_4-10% presented the best photocatalytic activity. Its photocatalysis reaction constant was approximately 2 times higher than the single component Bi_4Ti_3O_(12) or g-C_3N_4. Meanwhile, good stability and durability for the Bi_4Ti_3O_(12)/g-C_3N_4-10% were confirmed by the recycling experiment and FT-IR analysis. The possible mechanism for the improvements was the matched band positions and the effective separation of photo-excited electrons(e-) and holes(h+). Furthermore, based on the results of active species trapping, photo-generated holes(h+) and superoxide radical(·O2-) could be the main radicals in reaction.
基金sponsored by the National Natural Science Foundation of China(Grant No.51504165)the Project funded by the China Postdoctoral Science Foundation(Grant No.2016M601271)Tianjin Scince&Technology Project(Grant No.16JCQNJC02600)
文摘Hypereutectic Al -27Si alloys were joined without flux by ultrasonic-assisted soldering at 420 ℃ in air using Zn -5Al the filler alloys, and Si particulate-reinforced Zn - Al based composites filler joints were obtained. The ultrasonic vibration introduced into soldering could influence the migration of Si particles and the microstructure of solidified Zn - Al based alloys. Both the distribution of Si particles and microstructure of the solidified Zn - Al based alloys affected the shear strength of joints. The shear strength increased with the ultrasonic vibration time. The highest average shear strength of joints reached to -68.5 MPa. Transcrystalline rupture mode was observed on the fracture surface.
基金supported by The Natural Science Foundation of China(50975265)The Natural Science Foundation of Shanxi Province of China(2007011071)Program for the Top Young Academic Leaders of Higher Learning Institutions of Shanxi(20080205ZX)
文摘The mechanism of ultrasonic vibration honing Nd-Fe-B has been briefly elaborated after the introduction of the strategic significance of processing Nd-Fe-B. Based on the formation principle of Scanning Electrtmic Microscope （SEM）, and at the examination with the aid of SEM to the ultrasonic vibration honing Nd-Fe-B material＇s superficial microscopic topography, the paper discusses the new processing nechanism according to the SEM examination picture. The research indicates that as a result of supersonic high frequency vibration, the path of the abrasion extends at the same time, and the supersonic cavitation effect forms the intense shock-wave, knpacting Nd-Fe-B material＇s intemal surface, providing the supersonic energy for the superticial abrasive dust＇s dimination, which directly explain that the honing processing efficiency is enhanced, and the processing surface roughness is high.
基金The MKE(Ministry of Knowledge Economy),Korea,under the Convergence-ITRC(Convergence Information Technology Research Center)support program supervised by the NIPA(National IT Industry Promotion Agency)(NIPA-2012 C6150-1101-0004)
文摘A smart decontamination device is developed for small-size radioactive scrap metal(SSRSM)arisen from nuclear facilities.The abrasion pin in rotating magnetic field and ultrasonic wave cleaner are used for solving the problems of the second decontamination and high treatment cost.At first,the decontamination efficiency of each device is improved by upgrading the design.Optimal operating conditions are determined for each device.Next,both techniques are applied sequentially.Experimental results show that the efficiency of combined decontamination device is higher than that of each device.With the use of the developed device,the various SSRSMs are decontaminated for 15 min treatment in magnetic abrasion device and15 min treatment in ultrasonic cleaning device.Decontamination index ranges from18 to 56.Absolute values of all decontaminated samples are below the background value.
