Ti-V-based alloys are proved of huge potential in storing hydrogen,but the incomplete reversible hydrogen storage capacity caused by overstability of V hydride has limited the large-scale application.In this study,Ti_...Ti-V-based alloys are proved of huge potential in storing hydrogen,but the incomplete reversible hydrogen storage capacity caused by overstability of V hydride has limited the large-scale application.In this study,Ti_(32)V_(40+x)Fe_(23-x)Mn_(5)(x=0,4,8,12,at.%)alloys were designed,and the effects of V/Fe ratio on phase constitution and hydrogen storage properties were investigated.The main phase of the alloys is body-centered cubic(BCC)phase,and the lattice constants of the BCC phase decrease with the decrease of V/Fe ratio.Moreover,C14 Laves phase exists in alloys with a Fe content of 19at.%to 23at.%.For hydrogenation,the C14 Laves phase can accelerate the hydrogen absorption rate,but the hydrogen absorption capacity is reduced.With the decrease of V/Fe ratio,the hydride gradually destabilizes.Owing to its large lattice constant and high hydrogen absorption phase content,the Ti_(32)V_(52)Fe_(11)Mn_(5)alloy shows the most enhanced hydrogen storage properties with hydrogenation and dehydrogenation capacities of 3.588wt.%at 298 K and 1.688wt.%at 343 K,respectively.The hydrogen absorption capacity of this alloy can be reserved to 3.574wt.%after 20 cycles of hydrogen absorption and desorption.展开更多
全球气候模式BCC-CSM2-MR(Beijing Climate Center-Climate System Model version 2-Medium Resolution)由国家(北京)气候中心自主研发并参与了第六阶段国际耦合模式比较计划,该模式在BCC-CSM1.1m版本基础上对大气辐射传输、深对流过程...全球气候模式BCC-CSM2-MR(Beijing Climate Center-Climate System Model version 2-Medium Resolution)由国家(北京)气候中心自主研发并参与了第六阶段国际耦合模式比较计划,该模式在BCC-CSM1.1m版本基础上对大气辐射传输、深对流过程及重力波等方面进行了优化,因此,该模式对东亚地区降水和气温模拟能力的改进亟需进一步评估。本文主要基于不同格点观测数据集与中国区域站点观测数据,系统对比分析BCC-CSM2-MR、BCC-CSM1.1m两个模式版本对东亚地区季节平均降水(气温)和日极端降水(气温)的模拟能力。结果表明:(1)相比BCC-CSM1.1m,BCC-CSM2-MR改进了对东亚大部分区域季节平均降水的模拟能力,尤其是青藏高原地区夏季平均降水,明显提高了对中国东南地区、朝鲜半岛及日本降水月际变化的模拟性能;(2)BCC-CSM2-MR对东亚地区季节平均气温模拟能力改进不明显,且对东亚大部分区域气温月际变化的模拟误差大于BCC-CSM1.1m;(3)对日极端降水(气温),BCC-CSM2-MR的模拟能力优于BCC-CSM1.1m,明显提高了对中国东南地区日极端降水(气温)的模拟能力。总体而言,BCC-CSM2-MR在深对流过程参数方案中的改进有利于对东亚地区降水的模拟。展开更多
基金supported by the National Key Research and Development Program of China(2023YFB4005401)the National Natural Science Foundation of China(52425401,52204386)the Natural Science Foundation of Heilongjiang Province(JQ2023E003).
文摘Ti-V-based alloys are proved of huge potential in storing hydrogen,but the incomplete reversible hydrogen storage capacity caused by overstability of V hydride has limited the large-scale application.In this study,Ti_(32)V_(40+x)Fe_(23-x)Mn_(5)(x=0,4,8,12,at.%)alloys were designed,and the effects of V/Fe ratio on phase constitution and hydrogen storage properties were investigated.The main phase of the alloys is body-centered cubic(BCC)phase,and the lattice constants of the BCC phase decrease with the decrease of V/Fe ratio.Moreover,C14 Laves phase exists in alloys with a Fe content of 19at.%to 23at.%.For hydrogenation,the C14 Laves phase can accelerate the hydrogen absorption rate,but the hydrogen absorption capacity is reduced.With the decrease of V/Fe ratio,the hydride gradually destabilizes.Owing to its large lattice constant and high hydrogen absorption phase content,the Ti_(32)V_(52)Fe_(11)Mn_(5)alloy shows the most enhanced hydrogen storage properties with hydrogenation and dehydrogenation capacities of 3.588wt.%at 298 K and 1.688wt.%at 343 K,respectively.The hydrogen absorption capacity of this alloy can be reserved to 3.574wt.%after 20 cycles of hydrogen absorption and desorption.
文摘全球气候模式BCC-CSM2-MR(Beijing Climate Center-Climate System Model version 2-Medium Resolution)由国家(北京)气候中心自主研发并参与了第六阶段国际耦合模式比较计划,该模式在BCC-CSM1.1m版本基础上对大气辐射传输、深对流过程及重力波等方面进行了优化,因此,该模式对东亚地区降水和气温模拟能力的改进亟需进一步评估。本文主要基于不同格点观测数据集与中国区域站点观测数据,系统对比分析BCC-CSM2-MR、BCC-CSM1.1m两个模式版本对东亚地区季节平均降水(气温)和日极端降水(气温)的模拟能力。结果表明:(1)相比BCC-CSM1.1m,BCC-CSM2-MR改进了对东亚大部分区域季节平均降水的模拟能力,尤其是青藏高原地区夏季平均降水,明显提高了对中国东南地区、朝鲜半岛及日本降水月际变化的模拟性能;(2)BCC-CSM2-MR对东亚地区季节平均气温模拟能力改进不明显,且对东亚大部分区域气温月际变化的模拟误差大于BCC-CSM1.1m;(3)对日极端降水(气温),BCC-CSM2-MR的模拟能力优于BCC-CSM1.1m,明显提高了对中国东南地区日极端降水(气温)的模拟能力。总体而言,BCC-CSM2-MR在深对流过程参数方案中的改进有利于对东亚地区降水的模拟。
