以巢湖沉积物为研究对象,利用BCR(European Communities Bureau of Reference)连续提取法分析了沉积物样品中Zn、Cu、Pb、Cd、Mn赋存特征,分为可交换态及碳酸盐结合态、铁锰氧化物结合态、有机物及硫化物结合态和残渣态。结果表明:南淝...以巢湖沉积物为研究对象,利用BCR(European Communities Bureau of Reference)连续提取法分析了沉积物样品中Zn、Cu、Pb、Cd、Mn赋存特征,分为可交换态及碳酸盐结合态、铁锰氧化物结合态、有机物及硫化物结合态和残渣态。结果表明:南淝河入湖区S1采样点五种金属总量都达到最高,兆河入湖区S2采样点金属总量浓度最低。五种金属中锌和锰的质量较高,重金属回收率分别为:锌(93%),铜(92%),铅(90%),镉(92%),锰(93%)。Cu以残渣态为主(54.7%),Zn以铁锰氧化物结合态为主(40.5%),Pb以有机物、硫化物结合态为主(35.3%),Cd和Mn以可交换态及碳酸盐结合态为主,所占比例分布为41.9%、58.6%。研究表明,应用BCR连续提取法有助于确定沉积物中重金属的污染状况和潜在释放能力。展开更多
Surface sediments can integrate a wide variety of information of seawater in marginal seas, e.g., the Quaternary sedimentary shelf such as the East China Sea（ECS） and Yellow Sea（YS）. The Tessier and BCR sequential...Surface sediments can integrate a wide variety of information of seawater in marginal seas, e.g., the Quaternary sedimentary shelf such as the East China Sea（ECS） and Yellow Sea（YS）. The Tessier and BCR sequential extraction procedures（SEPs） have been widely applied for extraction of various geochemical phases from sediments. To choose a suitable SEP for phase extraction of sediments from the above Quaternary sedimentary shelf, efficiency and selectivity experiments were conducted on typical individual minerals and the applicability of each SEP was assessed for natural sediments（the natural sediment standard GSD-9 and three surface sediment samples）. The geochemical represented elements（Ca, Fe, Mn, Al, and Ti） were measured using both SEPs. Both SEPs have good dissolution efficiency and selectivity for the targeted geochemical phases; the optimized extractant volume for each fraction was determined. The Tessier SEP is particularly recommended for the study of adsorption-desorption process. The application of the Tessier SEP to surface sediments can furnish valuable information, including the productivity conditions（via the reducible fraction Mn） and sedimentary environments（via the carbonate fraction Ca）. These results confirm that the Tessier SEP is suitable for elemental fractionation in sediments from the Chinese continental shelf.展开更多
以新安江(屯溪段)沉积物为研究对象,采用BCR(European Communities Bureau of Reference)连续提取法分析了沉积物样品中Cu、Pb、Zn、Cd、Mn赋存特征。结果表明,老大桥上S1采样点锰、锌金属有效态与总量浓度最高,S2采样点重金属锰、镉总...以新安江(屯溪段)沉积物为研究对象,采用BCR(European Communities Bureau of Reference)连续提取法分析了沉积物样品中Cu、Pb、Zn、Cd、Mn赋存特征。结果表明,老大桥上S1采样点锰、锌金属有效态与总量浓度最高,S2采样点重金属锰、镉总量浓度最低。5种重金属中,锌和锰的BCR赋存形态质量浓度较高,重金属BCR态回收率均大于90%。Cu以有机物及硫化物结合态为主(38.16%);Zn、Mn、Pb、Cd以铁锰氧化物结合态为主,所占比例分布为63.33%、54.60%、81.92%、48.86%;可交换态及碳酸盐结合态(B1)比例较大为Cd和Mn,分别为36.39%、38.79%。研究结果表明,应用BCR连续提取法有助于确定沉积物中重金属的污染状况和潜在释放能力。展开更多
The soil pollution by heavy metals was characterized in the mine tailings and surrounding soils of an old Pb–Zn mine in Huize County. Three hundred and ninety-six samples of agricultural and non-agricultural soil wer...The soil pollution by heavy metals was characterized in the mine tailings and surrounding soils of an old Pb–Zn mine in Huize County. Three hundred and ninety-six samples of agricultural and non-agricultural soil were analyzed for the total metal concentration by acid digestion and sixty-eight selected soil samples were used to determine the chemical fractionation of heavy metals with the modified BCR sequential extraction method. The pollution index of the heavy metals indices for As, Cd, Cr, Cu,Hg, Pb and Zn of non-agricultural soil and agricultural soils in the study area indicated the spreading of heavy metal pollution. Sequential extraction showed that most of Cd existed in an exchangeable form(31.2 %). The available content of Pb, Cu and Zn was mainly distributed in acid extractable fractions and Fe/Mn oxide fractions(27.9, 30 and 27.2 %), and Hg, As and Cr were mainly associated with residual fractions(90.4, 72.9 and 76.8 %). The risks of heavy metals were also evaluated by the risk assessment code(RAC) and potential ecological risk index, respectively. The results of RAC showed a medium and high risk of Cd(45.6 and 54.4 %), medium risk of Zn(100 %), low and medium risk of Cu(41.2 and 58.8 %), largely no risk of Hg(97.1 %), and mainly low risk of As and Pb(92.6and 91.8 %). The range of the potential ecological risk of soil was 58.2–1839.3, revealing a considerably high ecological risk in the study area, most likely related to acid mine drainage and the mining complexes located in the area. The results can be used during the ecological risk screening stage, in conjunction with the total concentrations and metal fractionation values, to better estimate ecological risk.展开更多
文摘以巢湖沉积物为研究对象,利用BCR(European Communities Bureau of Reference)连续提取法分析了沉积物样品中Zn、Cu、Pb、Cd、Mn赋存特征,分为可交换态及碳酸盐结合态、铁锰氧化物结合态、有机物及硫化物结合态和残渣态。结果表明:南淝河入湖区S1采样点五种金属总量都达到最高,兆河入湖区S2采样点金属总量浓度最低。五种金属中锌和锰的质量较高,重金属回收率分别为:锌(93%),铜(92%),铅(90%),镉(92%),锰(93%)。Cu以残渣态为主(54.7%),Zn以铁锰氧化物结合态为主(40.5%),Pb以有机物、硫化物结合态为主(35.3%),Cd和Mn以可交换态及碳酸盐结合态为主,所占比例分布为41.9%、58.6%。研究表明,应用BCR连续提取法有助于确定沉积物中重金属的污染状况和潜在释放能力。
基金The National Natural Science Foundation of China under contract Nos 41530965,41276071 and 41003052the JSPS KAKENHI Grants under contract Nos JP26241009 and JP15H00973the Central Universities under contract Nos 201562008 and 201762031
文摘Surface sediments can integrate a wide variety of information of seawater in marginal seas, e.g., the Quaternary sedimentary shelf such as the East China Sea（ECS） and Yellow Sea（YS）. The Tessier and BCR sequential extraction procedures（SEPs） have been widely applied for extraction of various geochemical phases from sediments. To choose a suitable SEP for phase extraction of sediments from the above Quaternary sedimentary shelf, efficiency and selectivity experiments were conducted on typical individual minerals and the applicability of each SEP was assessed for natural sediments（the natural sediment standard GSD-9 and three surface sediment samples）. The geochemical represented elements（Ca, Fe, Mn, Al, and Ti） were measured using both SEPs. Both SEPs have good dissolution efficiency and selectivity for the targeted geochemical phases; the optimized extractant volume for each fraction was determined. The Tessier SEP is particularly recommended for the study of adsorption-desorption process. The application of the Tessier SEP to surface sediments can furnish valuable information, including the productivity conditions（via the reducible fraction Mn） and sedimentary environments（via the carbonate fraction Ca）. These results confirm that the Tessier SEP is suitable for elemental fractionation in sediments from the Chinese continental shelf.
文摘以新安江(屯溪段)沉积物为研究对象,采用BCR(European Communities Bureau of Reference)连续提取法分析了沉积物样品中Cu、Pb、Zn、Cd、Mn赋存特征。结果表明,老大桥上S1采样点锰、锌金属有效态与总量浓度最高,S2采样点重金属锰、镉总量浓度最低。5种重金属中,锌和锰的BCR赋存形态质量浓度较高,重金属BCR态回收率均大于90%。Cu以有机物及硫化物结合态为主(38.16%);Zn、Mn、Pb、Cd以铁锰氧化物结合态为主,所占比例分布为63.33%、54.60%、81.92%、48.86%;可交换态及碳酸盐结合态(B1)比例较大为Cd和Mn,分别为36.39%、38.79%。研究结果表明,应用BCR连续提取法有助于确定沉积物中重金属的污染状况和潜在释放能力。
基金funded by National Natural Science Foundation of China (No. 41303069)
文摘The soil pollution by heavy metals was characterized in the mine tailings and surrounding soils of an old Pb–Zn mine in Huize County. Three hundred and ninety-six samples of agricultural and non-agricultural soil were analyzed for the total metal concentration by acid digestion and sixty-eight selected soil samples were used to determine the chemical fractionation of heavy metals with the modified BCR sequential extraction method. The pollution index of the heavy metals indices for As, Cd, Cr, Cu,Hg, Pb and Zn of non-agricultural soil and agricultural soils in the study area indicated the spreading of heavy metal pollution. Sequential extraction showed that most of Cd existed in an exchangeable form(31.2 %). The available content of Pb, Cu and Zn was mainly distributed in acid extractable fractions and Fe/Mn oxide fractions(27.9, 30 and 27.2 %), and Hg, As and Cr were mainly associated with residual fractions(90.4, 72.9 and 76.8 %). The risks of heavy metals were also evaluated by the risk assessment code(RAC) and potential ecological risk index, respectively. The results of RAC showed a medium and high risk of Cd(45.6 and 54.4 %), medium risk of Zn(100 %), low and medium risk of Cu(41.2 and 58.8 %), largely no risk of Hg(97.1 %), and mainly low risk of As and Pb(92.6and 91.8 %). The range of the potential ecological risk of soil was 58.2–1839.3, revealing a considerably high ecological risk in the study area, most likely related to acid mine drainage and the mining complexes located in the area. The results can be used during the ecological risk screening stage, in conjunction with the total concentrations and metal fractionation values, to better estimate ecological risk.
