The electronic structure of iron-pnictide compound superconductor Ba_2Ti_2Fe_2As_4O, which has metallic intermediate Ti_2O layers, is studied using angle-resolved photoemission spectroscopy. The Ti-related bands show ...The electronic structure of iron-pnictide compound superconductor Ba_2Ti_2Fe_2As_4O, which has metallic intermediate Ti_2O layers, is studied using angle-resolved photoemission spectroscopy. The Ti-related bands show a‘peak-dip-hump' line shape with two branches of dispersion associated with the polaronic states at temperatures below around 120 K. This change in the spectra occurs along with the resistivity anomaly that was not clearly understood in a previous study. Moreover, an energy gap induced by the superconducting proximity effect opens in the polaronic bands at temperatures below T_c(~21 K). Our study provides the spectroscopic evidence that superconductivity coexists with polarons in the same bands near the Fermi level, which provides a suitable platform to study interactions between charge, lattice and spin freedoms in a correlated system.展开更多
利用第一性原理密度泛函理论,计算了不同浓度Y掺杂Ba Ti O3的电子结构和光学性质.计算结果表明:掺杂Y元素后,体系的禁带宽度增大,能态密度向低能方向移动,费米能级进入导带,体现出n型半导体的特征,改善了Ba Ti O3的导电性.在光学性质上...利用第一性原理密度泛函理论,计算了不同浓度Y掺杂Ba Ti O3的电子结构和光学性质.计算结果表明:掺杂Y元素后,体系的禁带宽度增大,能态密度向低能方向移动,费米能级进入导带,体现出n型半导体的特征,改善了Ba Ti O3的导电性.在光学性质上,无入射光情况下的纯Ba Ti O3静态介电常数值为4.69,掺杂后静态介电常数改变比较大,尤其是高浓度掺杂后远远大于纯Ba Ti O3,这意味着其可能是一种新的介电材料.掺杂后,体系的能量损失峰明显向低能区移动,随着掺杂浓度的增大,能量损失强度也有所增加.展开更多
动力电池的荷电状态(state of charge,SOC)表示动力电池剩余电量情况,其估算的准确与否对于电动汽车进行整车控制优化以及续航里程估计具有重要意义。过去几年流行的天牛须算法(beetle antennae search,BAS)用于通过充分考虑环境温度、...动力电池的荷电状态(state of charge,SOC)表示动力电池剩余电量情况,其估算的准确与否对于电动汽车进行整车控制优化以及续航里程估计具有重要意义。过去几年流行的天牛须算法(beetle antennae search,BAS)用于通过充分考虑环境温度、电压和电流对电池的影响来估计SOC,选择天牛须算法改善BP神经网络的初始权重和阈值,实现有效地优化,进而提高动力电池SOC估算的准确性。实验结果表明,该方法克服了传统神经网络训练时间长、稳定性差等缺点,大大提高了估算的准确度。展开更多
基金Supported by the National Basic Research Program of China under Grant Nos 2013CB921700,2015CB921300 and2015CB921301the National Natural Science Foundation of China under Grant Nos 11234014,11622435,11274362,11674371 and11474340+1 种基金the National Key Research and Development Program of China under Grant Nos 2016YFA0300300,2016YFA0300600,2016YFA0401000 and 2016YFA0400902the Open Large Infrastructure Research of Chinese Academy of Sciences,and the Pioneer Hundred Talents Program(Type C)of Chinese Academy of Sciences
文摘The electronic structure of iron-pnictide compound superconductor Ba_2Ti_2Fe_2As_4O, which has metallic intermediate Ti_2O layers, is studied using angle-resolved photoemission spectroscopy. The Ti-related bands show a‘peak-dip-hump' line shape with two branches of dispersion associated with the polaronic states at temperatures below around 120 K. This change in the spectra occurs along with the resistivity anomaly that was not clearly understood in a previous study. Moreover, an energy gap induced by the superconducting proximity effect opens in the polaronic bands at temperatures below T_c(~21 K). Our study provides the spectroscopic evidence that superconductivity coexists with polarons in the same bands near the Fermi level, which provides a suitable platform to study interactions between charge, lattice and spin freedoms in a correlated system.
基金Supported by the National Natural Science Foundation of China(11204001,11174004)Anhui Provincial Natural Science Foundation(1208085QA07,1308085MA04)+2 种基金the Higher Educational Natural Science Foundation of Anhui Province(KJ2013A031)Anhui University Scientific Research Fund(201410357005,KYXL2013009)“211 Project”of Anhui University(SZJYKC2013020,XJGXKC1401)
文摘利用第一性原理密度泛函理论,计算了不同浓度Y掺杂Ba Ti O3的电子结构和光学性质.计算结果表明:掺杂Y元素后,体系的禁带宽度增大,能态密度向低能方向移动,费米能级进入导带,体现出n型半导体的特征,改善了Ba Ti O3的导电性.在光学性质上,无入射光情况下的纯Ba Ti O3静态介电常数值为4.69,掺杂后静态介电常数改变比较大,尤其是高浓度掺杂后远远大于纯Ba Ti O3,这意味着其可能是一种新的介电材料.掺杂后,体系的能量损失峰明显向低能区移动,随着掺杂浓度的增大,能量损失强度也有所增加.
文摘动力电池的荷电状态(state of charge,SOC)表示动力电池剩余电量情况,其估算的准确与否对于电动汽车进行整车控制优化以及续航里程估计具有重要意义。过去几年流行的天牛须算法(beetle antennae search,BAS)用于通过充分考虑环境温度、电压和电流对电池的影响来估计SOC,选择天牛须算法改善BP神经网络的初始权重和阈值,实现有效地优化,进而提高动力电池SOC估算的准确性。实验结果表明,该方法克服了传统神经网络训练时间长、稳定性差等缺点,大大提高了估算的准确度。