Transfer Behavior of Carbendazim from Dried Yingshan Yunwu Tea Leaves into Tea Infusions

Tea infusion is the main route of human exposure to pollutants in tea,and it is vital to investigate the transfer rate of pollutants from tea leaves to infusion.Carbendazim is a commonly used systemic fungicide,the transfer behavior of which in Yingshan Yunwu tea is not clear.Hence,this study firstly established the analytical method for determination of carbendazim with great accuracy and precision via modified QuEChERS method and ultra-performance liquid chromatography-fluorescence detection(UPLC-FLD).Then,the transfer behavior of carbendazim from tea leaves and infusion was systematically investigated.Results indicated that water temperature and proportion of tea to water ration would obviously increase the transfer rate of carbendazim,but times of infusion repetition showed negative correlation with the transfer rate of carbendazim.In addition,brewing time seemed to have lesser impact on the transfer rate.This study will be helpful for the risk assessment of carbendazim residue and provide the guidance for tea brewing.

The element transfer behavior of gas pool coupled activating TIG welding

This paper deals with a novel dual shield TIG welding method named gas pool coupled activating TIG（ GPCA-TIG）welding. The welding method divides the shielding gas into two layers. Inert gas such as Ar is adopted as the inner layer gas to protect the tungsten electrode and the molten pool metal. Pure O;,N;or mixture of them are used as the outer layer gas to increase the weld penetration and improve the low temperature toughness of weld metal. Through analyzing the interaction between outer gas and arc and the distributions and existing forms of oxygen and nitrogen elements,the transfer behaviors of nitrogen and oxygen from arc to pool were investigated. The results show that,the interaction between the outer gas and arc plasma makes the arc slightly constrict. The incoming oxygen enriches on the molten pool surface and exists in the form of iron oxide,chromium oxide,manganese oxide and silicon oxygen compounds. The incoming nitrogen evenly distributes in the molten pool and exists in the form of nitrogen atom.

Development and application of inverse heat transfer model between liquid metal and shot sleeve in high pressure die casting process under non-shooting condition

To predict the heat transfer behavior of A380 alloy in a shot sleeve, a numerical approach(inverse method) is used and validated by high pressure die casting(HPDC) experiment under non-shooting condition. The maximum difference between the measured and calculated temperature profiles is smaller than 3 °C, which suggests that the inverse method can be used to predict the heat transfer behavior of alloys in a shot sleeve. Furthermore, the results indicate an increase in maximum interfacial heat flux density(q_(max)) and heat transfer coefficient(h_(max)) with an increase in sleeve filling ratio, especially at the pouring zone(S2 zone). In addition, the values of initial temperature(T_(IDS)) and maximum shot sleeve surface temperature(T_(simax)) at the two end zones(S2 and S10) are higher than those at the middle zone(S5). Moreover, in comparison with fluctuations in heat transfer coefficient(h) with time at the two end zones(S2 and S10), 2.4-6.5 kW ·m^(-2)·K^(-1), 3.5-12.5 kW ·m^(-2)·K^(-1), respectively, more fluctuations are found at S5 zone, 2.1-14.7 kW ·m^(-2)·K^(-1). These differences could theoretically explain the formation of the three zones: smooth pouring zone, un-smooth middle zone and smooth zone, with different morphologies in the metal log under the non-shot casting condition. Finally, our calculations also reveal that the values of q_(max) and h_(max) cast at 680 °C are smaller than those cast at 660 °C and at 700 °C.

A study of metal/die interfacial heat transfer behavior of vacuum die cast pure copper

High pressure die casting copper is used to produce rotors for induction motors to improve efficiency.Experiments were carried out for a special"step-shape"casting with different step thicknesses.Based on the measured temperature inside the die,the interfacial heat transfer coefficient(IHTC)at the metal/die interface during vacuum die casting was evaluated by solving the inverse problem.The IHTC peak value was 4.5×10^3-11×10^3 W·m^-2·K^-1 under the basic operation condition.The influences of casting pressure,fast shot speed,pouring temperature and initial die surface temperature on the IHTC peak values were investigated.Results show that a greater casting pressure and faster shot speed could only increase the IHTC peak values at the location close to the ingate.An increase of pouring temperature and/or initial die surface temperature significantly increases the IHTC peak values.

Evolution of interfacial heat transfer,contact behavior and microstructure during sub-rapid solidification of molten steel with different hydrogen contents

Typical Q235 low-carbon steel samples with different hydrogen contents(0.0004,0.0008,and 0.0013 wt.%)were prepared by adjusting the environment humidity and moisture.The effects of hydrogen on interfacial heat transfer,contact behavior,and microstructure evolution were investigated using a novel droplet solidification technique.The results revealed that when the hydrogen content increases from 0.0004 to 0.0013 wt.%,the maximum heat flux between the molten steel and cooling substrate decreases from 8.01 to 6.19 MW/m^(2),and the total heat removed in the initial 2 s reduces from 10.30 to 8.27 MJ/m^(2).Moreover,the final contact angle between the molten steel and substrate increases from 103.741°to 113.697°,and the number of pores on the droplet bottom surface increases significantly from 21 to 210 with the increase in hydrogen.The surface roughness of the droplet bottom surface increases from 20.902 to 49.181 pm.In addition,the average grain size of the droplet increases from 14.778 to 33.548 pm with the increase in the hydrogen content.The interfacial contact condition becomes worse due to the escape of hydrogen from the steel matrix during the cooling process,which leads to the reduction in the interfacial heat transfer and the increase in the grain size.

Heat transfer behaviors of some supercritical fluids: A review

Supercritical fluids(e.g.,hydrocarbon fuels,water,carbon dioxide,and organic working medium,etc)have been recognized as working media to improve thermal efficiencies in power cycles and energy conversion,and have been used or selected as the working fluids in engineering fields such as aerospace,nuclear power,solar energy,refrigeration,geothermal energy,chemical technology,and so on.To better understand the interesting characteristic or abnormal behaviors of supercritical fluids,most valuable research works(including experimental results and numerical studies)from domestic and abroad have been documented.As such,this paper presents a comprehensive review on heat transfer behaviors of some supercritical fluids in engineering applications.This review focuses on recently available articles published mainly from 2016 up to the present time.The common problems(i.e.,heat transfer enhancement and heat transfer deterioration particularly for the supercritical hydrocarbon fuels)in the supercritical field are summarized and some perspectives on future prospects are also included.

Determination of Interfacial Heat Transfer Behavior at the Metal/Shot Sleeve of High Pressure Die Casting Process of AZ91D Alloy

The interfacial heat transfer behavior at the metalJshot sleeve interface in the high pressure die casting （HPDC） process of AZ91D alloy is carefully investigated. Based on the temperature measurements along the shot sleeve, inverse method has been developed to determine the interfacial heat transfer coefficient in the shot sleeve. Under static condition, Interracial heat transfer coefficient （IHTC） peak values are 11.9, 7,3, 8.33kWm-2K-1 at pouring zone （S2）, middle zone （S5）, and end zone （510）, respectively. During the casting process, the IHTC curve displays a second peak of 6.1 kWm-2 K-1 at middle zone during the casting process at a slow speed of 0.3 ms 1 Subsequently, when the high speed started, the IHTC curve reached a second peal〈 of 12.9 kW m-2K-1 at end zone. Furthermore, under different slow casting speeds, both the calculated initial temperature （TIDs） and the maximum temperature （Tsimax） of shot sleeve surface first decrease from 0.1 ms-1 to 0.3 ms-1, but increase again from 0.3 ms-1 to 0.6 ms-1. This result agrees with the experimental results obtained in a series of ＂plate-shape＂ casting experiments under different slow speeds, which reveals that the amount of ESCs decreases to the minimum values at 0.3 m s-1 and increase again with the increasing casting slow speed.

Effect of Stress-Dependent Thermal Conductivity on Thermo-Mechanical Coupling Behavior in GaN-Based Nanofilm Under Pulse Heat Source

The thermal properties of a nanostructured semiconductor are affected by multi-physical fields,such as stress and electromagnetic fields,causing changes in temperature and strain distributions.In this work,the influence of stress-dependent thermal conductivity on the heat transfer behavior of a GaN-based nanofilm is investigated.The finite element method is adopted to simulate the temperature distribution in a prestressed nanofilm under heat pulses.Numerical results demonstrate the effect of stress field on the thermal conductivity of GaN-based nanofilm,namely,the prestress and the thermal stress lead to a change in the heat transfer behavior in the nanofilm.Under the same heat source,the peak temperature of the film with stress-dependent thermal conductivity is significantly lower than that of the film with a constant thermal conductivity and the maximum temperature difference can reach 8.2 K.These results could be useful for designing GaN-based semiconductor devices with higher reliability under multi-physical fields.

Phase behaviors of transfer functions in Vibrating systems

This paper investigates the applicabilitles of pole-zero model and wave propagation theory in estimating the phase characteristics of vibrating systems. The measured phase spectra are compared with the estlmated reverberant phase limit and wave propagation phase. The relations between transfer function phase and frequency, damping, and separation distance are described. The present results show that the pole-zero model provides a reasonable estimation of the reverberant phase limit in low frequency band below an identified transition frequency.The reverberant phase is linearly dependent on frequency in this band, but from the transition frequency and onwards the phase increases only with the square root of frequency. This behavior is characteristic for free propagating waves

Numerical investigation of mass transfer behavior of a gas-liquid two‐phase Taylor flow in a microchannel by a volume‐of‐fluid multiphase flow system

The microchannel reactor is the most commonly used microreaction technology,an innovative reaction system developed in recent years.This study investigates the mass transfer behavior of a gas-liquid two‐phase Taylor flow in a microchannel by coupling the volume‐of‐fluid model and the species transport model.The concentration distribution and the volumetric mass transfer coefficient of the gas solute are determined and discussed in detail.The simulation results reveal that the double‐circulation flow influences the concentration distribution in the liquid slug.The highest value is observed at the bubble's surface and decreases rapidly along the vertical direction of the bubble.The increase of bubble velocity leads to a more apparent decreasing trend.The gas-liquid interface renewal rate of the bubble is accelerated with increasing bubble velocity,resulting in an increase in the average mass transfer rate in all regions of the bubble surface with an increase in bubble velocity.The results also indicate that the liquid film area contributes the most to the mass transfer behavior due to the most significant proportion and average mass transfer rate of the liquid film among the bubble.