The adsorption behavior and mechanism of Bi（Ⅲ） ions on the rutile-water interface were investigated through micro-flotation, Zeta potential measurement, adsorption amount measurement and X-ray photoelectron spectro...The adsorption behavior and mechanism of Bi（Ⅲ） ions on the rutile-water interface were investigated through micro-flotation, Zeta potential measurement, adsorption amount measurement and X-ray photoelectron spectroscopy（XPS）. According to the results of micro-flotation, Bi（Ⅲ） ions could largely improve the rutile flotation recovery（from 62% to 91%）, and they could increase the activating sites and reduce the competitive adsorption between nonyl hydroxamic acid negative ions and OH-ions, which determined that Bi（Ⅲ） ions were capable of activating rutile flotation. The adsorption of Bi（Ⅲ） ions onto the rutile surface led to the shift of Zeta potential into the positive direction, which was good for the adsorption of nonyl hydroxamic acid anions. In addition, the results of XPS indicated that the chemical environment around Ti atom had not changed before and after the adsorption of Bi（Ⅲ） ions. Based on the adsorption mechanism of Bi（Ⅲ） ions, it was deduced that firstly Bi（Ⅲ） ions occupied the vacancies of the original Ca^2＋, Mg^2＋ and Fe^2＋ ions on the rutile surface; secondly Bi（Ⅲ） ions covered on the rutile surface in the form of hydroxides.展开更多
The polargraphic behavior of Bi(Ⅲ)-NOTP complex has been investigated inaqueous solution. It was found that under the conditions of pH 3.0 and of 0.02 mol/L NH_4Cl, theBi(Ⅲ)-NOTP system gives a sensitive second orde...The polargraphic behavior of Bi(Ⅲ)-NOTP complex has been investigated inaqueous solution. It was found that under the conditions of pH 3.0 and of 0.02 mol/L NH_4Cl, theBi(Ⅲ)-NOTP system gives a sensitive second order derivative wave at -0.340 V(vs SCE), which isproved to be an adsorptive complex wave. The composition of the complex is Bi(Ⅲ):NOTP. Furthermore,the peak current is linear to the concentration of Bi(Ⅲ) in the range from 3.0x10^(-8) to5.0x10^(-6) mol/L. Artificial and practical samples have been detected with high sensitivity andreceptivity.展开更多
基金Project(51474254)supported by the National Natural Science Foundation of ChinaProject(2013M531813)supported by the China Postdoctoral Science Foundation+1 种基金Project(2016zzts111)supported by the Independent Exploration and Innovation Program of Central South University,ChinaProject(CSUZC201715)supported by Open-End Fund for the Valuable and Precision Instruments of Central South University,China
文摘The adsorption behavior and mechanism of Bi（Ⅲ） ions on the rutile-water interface were investigated through micro-flotation, Zeta potential measurement, adsorption amount measurement and X-ray photoelectron spectroscopy（XPS）. According to the results of micro-flotation, Bi（Ⅲ） ions could largely improve the rutile flotation recovery（from 62% to 91%）, and they could increase the activating sites and reduce the competitive adsorption between nonyl hydroxamic acid negative ions and OH-ions, which determined that Bi（Ⅲ） ions were capable of activating rutile flotation. The adsorption of Bi（Ⅲ） ions onto the rutile surface led to the shift of Zeta potential into the positive direction, which was good for the adsorption of nonyl hydroxamic acid anions. In addition, the results of XPS indicated that the chemical environment around Ti atom had not changed before and after the adsorption of Bi（Ⅲ） ions. Based on the adsorption mechanism of Bi（Ⅲ） ions, it was deduced that firstly Bi（Ⅲ） ions occupied the vacancies of the original Ca^2＋, Mg^2＋ and Fe^2＋ ions on the rutile surface; secondly Bi（Ⅲ） ions covered on the rutile surface in the form of hydroxides.
基金This project is financially supported by the National Natural Science Foundation of China (No.29575207) KJCXGC-01 of Northwest Normal University
文摘The polargraphic behavior of Bi(Ⅲ)-NOTP complex has been investigated inaqueous solution. It was found that under the conditions of pH 3.0 and of 0.02 mol/L NH_4Cl, theBi(Ⅲ)-NOTP system gives a sensitive second order derivative wave at -0.340 V(vs SCE), which isproved to be an adsorptive complex wave. The composition of the complex is Bi(Ⅲ):NOTP. Furthermore,the peak current is linear to the concentration of Bi(Ⅲ) in the range from 3.0x10^(-8) to5.0x10^(-6) mol/L. Artificial and practical samples have been detected with high sensitivity andreceptivity.
