A novel carbazole quaternary ammonium compound（abbreviated as T_2） had been synthesized and characterized by ~1H NMR, ^（13）C NMR and Mass spectrometry. The single-crystal structure has been determined by X-ray sin...A novel carbazole quaternary ammonium compound（abbreviated as T_2） had been synthesized and characterized by ~1H NMR, ^（13）C NMR and Mass spectrometry. The single-crystal structure has been determined by X-ray single-crystal diffraction. The electrochemical and two-photon absorption properties of T_2 were systematically studied by cyclic voltammetry and Z-scan determination methods, respectively. The results suggested that T_2 had a good oxidation-reduction and excellent nonlinear optical property. The two-photon absorption（TPA） value has a maximum corresponding to cross section σ = 7963.3 GM（Goeppert-Mayer units） at 700 nm, indicating potential applications in nonlinear optical materials. Furthermore, attributing to the excellent water solubility and low cytotoxicity, the compound was explored on its primary application in biological imaging.展开更多
Municipal solid waste(refuse) landfill stabilizes as the refuse degrades. After years of biodegradation, the refuse in the landfill becomes stabilized and aged, which may vary with the local climate, humidity, and com...Municipal solid waste(refuse) landfill stabilizes as the refuse degrades. After years of biodegradation, the refuse in the landfill becomes stabilized and aged, which may vary with the local climate, humidity, and composition of refuse placed. In this work, it is found that the refuse with an age of over 8 years at Shanghai Refuse Landfill has been significantly stabilized and sufficiently aged and is thus suitable for excavation. The 8 year old aged refuse is mechanically screened, and the fine fractions of refuse(aged refuse) with a diameter less than 2 cm are then used as a biological absorbent for removal of both inorganic and organic phosphorus in livestock wastewater and prepared aqueous solution. It is proved that the aged refuse is very effective for the quantitative removal of both types of phosphorus. The absorption mechanism is proposed. It is considered that phosphorus is firstly absorbed onto the surface of the aged refuse and then used as a substrate for the growth of microorganisms which ultimately leave the aged refuse as sludge.展开更多
基金Supported by the National Natural Science Foundation of China(21271004,51372003,21271003,51432001,21101001)the Natural Science Foundation of Anhui Province(1308085MB24)Scientific Innovation Team Foundation of Educational Commission of Anhui Province(KJ2012A025,2006KJ007TD)
文摘A novel carbazole quaternary ammonium compound（abbreviated as T_2） had been synthesized and characterized by ~1H NMR, ^（13）C NMR and Mass spectrometry. The single-crystal structure has been determined by X-ray single-crystal diffraction. The electrochemical and two-photon absorption properties of T_2 were systematically studied by cyclic voltammetry and Z-scan determination methods, respectively. The results suggested that T_2 had a good oxidation-reduction and excellent nonlinear optical property. The two-photon absorption（TPA） value has a maximum corresponding to cross section σ = 7963.3 GM（Goeppert-Mayer units） at 700 nm, indicating potential applications in nonlinear optical materials. Furthermore, attributing to the excellent water solubility and low cytotoxicity, the compound was explored on its primary application in biological imaging.
文摘Municipal solid waste(refuse) landfill stabilizes as the refuse degrades. After years of biodegradation, the refuse in the landfill becomes stabilized and aged, which may vary with the local climate, humidity, and composition of refuse placed. In this work, it is found that the refuse with an age of over 8 years at Shanghai Refuse Landfill has been significantly stabilized and sufficiently aged and is thus suitable for excavation. The 8 year old aged refuse is mechanically screened, and the fine fractions of refuse(aged refuse) with a diameter less than 2 cm are then used as a biological absorbent for removal of both inorganic and organic phosphorus in livestock wastewater and prepared aqueous solution. It is proved that the aged refuse is very effective for the quantitative removal of both types of phosphorus. The absorption mechanism is proposed. It is considered that phosphorus is firstly absorbed onto the surface of the aged refuse and then used as a substrate for the growth of microorganisms which ultimately leave the aged refuse as sludge.
