To rapidly determine the pollution extent of wastewater, the calibration models were established for deter-mination of Chemical Oxygen Demand and Biological Oxygen Demand in wastewater by partial least squares and nea...To rapidly determine the pollution extent of wastewater, the calibration models were established for deter-mination of Chemical Oxygen Demand and Biological Oxygen Demand in wastewater by partial least squares and near infrared spectrometry of 120 samples. Spectral data preprocessing and outliers’ diagnosis were also discussed. Correlation coefficients of the models were 0.9542 and 0.9652, and the root mean square error of prediction (RMSEP) were 25.24 mg?L-1 and 12.13 mg?L-1 in the predicted range of 28.40~528.0 mg?L-1 and 16.0~305.2 mg?L-1 for Chemical Oxygen Demand and Biological Oxygen Demand, respectively. By statistical significance test, the results of determination were compared with those of stan-dard methods with no significant difference at 0.05 level. The method has been applied to simultaneous de-termination of Chemical Oxygen Demand and Biological Oxygen Demand in wastewater with satisfactory results.展开更多
To improve the efficiency of backwashing in upflow biological aerated filter （BAF）, a novel backwashing process named air-water siphon backwashing （AWSB） was proposed and applied on laboratory scale. The effects o...To improve the efficiency of backwashing in upflow biological aerated filter （BAF）, a novel backwashing process named air-water siphon backwashing （AWSB） was proposed and applied on laboratory scale. The effects of backwashing on turbidity and suspended solid （SS） in backwashing efluent using this new backwashing process were compared with those of traditional backwashing process, namely air-water backwashing （AWB）. In AWB, the turbidity of backwashing efluent maintained 100 NUT when consumed 60 min and 10.5 L water. However, in AWSB, it declined to 44 NUT, consumed 40 min, and 7 L water. The COD removal of BAF after backwashing was also analyzed. The average removal rate of COD in the reactor backwashed by AWB and AWSB was 89.34% and 90.91%, respectively. Compared with AWB, the backwashing interval had been prolonged 35%. The volume of backwashing water in that AWSB was only 66.7% of that in AWB. The results demonstrated that AWSB required less water and took shorter backwashing timerelative to AWB to achieve the same turbidity of backwashing efluent, and AWSB was more effective in removing fouling than that of AWB. More significant advantage of AWSB was that the backwashing interval was effectively prolonged展开更多
A laboratory scale up-flow biological activated carbon(BAC) reactor was constructed for the advanced treatment of synthetic flotation wastewater. Biodegradation of a common collector(i.e., ethyl xanthate) for non-ferr...A laboratory scale up-flow biological activated carbon(BAC) reactor was constructed for the advanced treatment of synthetic flotation wastewater. Biodegradation of a common collector(i.e., ethyl xanthate) for non-ferrous metallic ore flotation was evaluated. The results show that the two stages of domestication can improve microbial degradation ability. The BAC reactor obtains a chemical oxygen demand(COD) reduction rate of 82.5% for ethyl xanthate and its effluent COD concentration lowers to below 20 mg/L. The kinetics equation of the BAC reactor proves that the activated carbon layers at the height of 0 mm to 70 mm play a key role in the removal of flotation reagents. Ultraviolet spectral analysis indicates that most of the ethyl xanthate are degraded by microorganisms after advanced treatment by the BAC reactor.展开更多
The implementation of the European WFD （water framework directive） requires IWRM （integrated water resource management）, an important tool in managing available water resources in the presence of emerging constrai...The implementation of the European WFD （water framework directive） requires IWRM （integrated water resource management）, an important tool in managing available water resources in the presence of emerging constraints. Pressures caused by variability in water supply cycles, droughts, pollution, industrialization, increasing domestic and commercial demand, inadequate infrastructure, intense urbanization and population growth, and decrepit distribution networks have led to the increasing exploitation of industrial wastewater. Most industrial process has some negative impacts on the environment especially on a catchment scale i.e. water, air and soil quality. In the context of water resources and environmental protection measures, the term ＂sustainable development＂, a development that is compatible with the future gains and environmental protection, is regulated more and more by law. To comply with these emission-based limit values, so-called ＂end-of-pipe-techniques＂ are used. Experimental results show CBT （continuous biological treatment） processes present secondary measures to purify highly contaminated industrial wastewater.展开更多
文摘To rapidly determine the pollution extent of wastewater, the calibration models were established for deter-mination of Chemical Oxygen Demand and Biological Oxygen Demand in wastewater by partial least squares and near infrared spectrometry of 120 samples. Spectral data preprocessing and outliers’ diagnosis were also discussed. Correlation coefficients of the models were 0.9542 and 0.9652, and the root mean square error of prediction (RMSEP) were 25.24 mg?L-1 and 12.13 mg?L-1 in the predicted range of 28.40~528.0 mg?L-1 and 16.0~305.2 mg?L-1 for Chemical Oxygen Demand and Biological Oxygen Demand, respectively. By statistical significance test, the results of determination were compared with those of stan-dard methods with no significant difference at 0.05 level. The method has been applied to simultaneous de-termination of Chemical Oxygen Demand and Biological Oxygen Demand in wastewater with satisfactory results.
基金supported by the National Natural Science Foundation of China (No. 30700010)the Eleventh Five-Year Plan National Key Technology R&D Program of China (No. 2006BAD07A01)+1 种基金the National Gongyixing Hangye Kejizhuanxiang (No. 200803033)the Special Program for Water Pollution Control of Taihu Lake in Jiangsu Province (No. BK2007741)
文摘To improve the efficiency of backwashing in upflow biological aerated filter （BAF）, a novel backwashing process named air-water siphon backwashing （AWSB） was proposed and applied on laboratory scale. The effects of backwashing on turbidity and suspended solid （SS） in backwashing efluent using this new backwashing process were compared with those of traditional backwashing process, namely air-water backwashing （AWB）. In AWB, the turbidity of backwashing efluent maintained 100 NUT when consumed 60 min and 10.5 L water. However, in AWSB, it declined to 44 NUT, consumed 40 min, and 7 L water. The COD removal of BAF after backwashing was also analyzed. The average removal rate of COD in the reactor backwashed by AWB and AWSB was 89.34% and 90.91%, respectively. Compared with AWB, the backwashing interval had been prolonged 35%. The volume of backwashing water in that AWSB was only 66.7% of that in AWB. The results demonstrated that AWSB required less water and took shorter backwashing timerelative to AWB to achieve the same turbidity of backwashing efluent, and AWSB was more effective in removing fouling than that of AWB. More significant advantage of AWSB was that the backwashing interval was effectively prolonged
基金Project(201209013)supported by Special Fund for Environmental Scientific Research in the Public Interest,China
文摘A laboratory scale up-flow biological activated carbon(BAC) reactor was constructed for the advanced treatment of synthetic flotation wastewater. Biodegradation of a common collector(i.e., ethyl xanthate) for non-ferrous metallic ore flotation was evaluated. The results show that the two stages of domestication can improve microbial degradation ability. The BAC reactor obtains a chemical oxygen demand(COD) reduction rate of 82.5% for ethyl xanthate and its effluent COD concentration lowers to below 20 mg/L. The kinetics equation of the BAC reactor proves that the activated carbon layers at the height of 0 mm to 70 mm play a key role in the removal of flotation reagents. Ultraviolet spectral analysis indicates that most of the ethyl xanthate are degraded by microorganisms after advanced treatment by the BAC reactor.
文摘The implementation of the European WFD （water framework directive） requires IWRM （integrated water resource management）, an important tool in managing available water resources in the presence of emerging constraints. Pressures caused by variability in water supply cycles, droughts, pollution, industrialization, increasing domestic and commercial demand, inadequate infrastructure, intense urbanization and population growth, and decrepit distribution networks have led to the increasing exploitation of industrial wastewater. Most industrial process has some negative impacts on the environment especially on a catchment scale i.e. water, air and soil quality. In the context of water resources and environmental protection measures, the term ＂sustainable development＂, a development that is compatible with the future gains and environmental protection, is regulated more and more by law. To comply with these emission-based limit values, so-called ＂end-of-pipe-techniques＂ are used. Experimental results show CBT （continuous biological treatment） processes present secondary measures to purify highly contaminated industrial wastewater.
文摘针对污水处理复杂系统中关键水质参数生化需氧量(biochemical oxygen demand,BOD)难以准确实时预测的问题,在分析污水处理过程相关影响因素的基础上,提出一种基于敏感度分析法的自组织随机权神经网络(selforganizing neural network with random weights,SONNRW)软测量方法.该方法首先通过机理分析选取原始辅助变量,经过数据预处理,之后采用主元分析法对辅助变量进行精选,作为SONNRW的输入变量进行污水处理关键水质参数BOD的预测.SONNRW算法利用隐含层节点输出及其权值向量计算该隐含层节点对于残差的敏感度,根据敏感度大小对网络隐含层节点进行排序,删除敏感度较低的隐含层节点即冗余点.仿真结果表明:该软测量方法对水质参数BOD的预测精度高、实时性好、模型结构稳定,能够用于污水水质的在线预测.
