The title complex {[%n%|Bu-2SnO-2CCH(CS-2NEt-2)-2]-2O}-2 was synthesized and characterized by elemental analysis, IR, NMR and X|ray single crystal diffraction. The results show that the complex belongs to a monoclinic...The title complex {[%n%|Bu-2SnO-2CCH(CS-2NEt-2)-2]-2O}-2 was synthesized and characterized by elemental analysis, IR, NMR and X|ray single crystal diffraction. The results show that the complex belongs to a monoclinic system with space group %C2/c%, and unit cell dimensions: %a%=2.848(5) nm, {%b%=1.381(2) nm}, %c%=3.239(6) nm, %β%=111.11(2)°, %Z=4, V%=11.884(35) nm+3, %D%-c=1.329 g/cm+3, {%F%(000)}=4 912, %S=0.991, R-1=0.053 5, wR-2=0.116 6.% The complex has a centrosymmetric dimer structure mode with a four|membered central %endo%|cyclic Sn-2O-2 unit. The %endo%|cyclic tin atoms are six|coordination and have coordition geometry of distorted octahedron. The %exo%|cyclic tin atoms are five|coordination and have coordination geometry of distorted trigonal bipyramid. This complex was tested %in vitro% against human tumour cell lines, MCF-7 and WiDr, and displayed the higher activity.展开更多
The Co(II) complex I and ammonium salt II were synthesized from the direct reaction of 1,2-ethylenediamine and cobaltous acetate tetrahydrate and manganese acetate tetrahydrate in anhydrous ethanol. Treatment of N,N...The Co(II) complex I and ammonium salt II were synthesized from the direct reaction of 1,2-ethylenediamine and cobaltous acetate tetrahydrate and manganese acetate tetrahydrate in anhydrous ethanol. Treatment of N,N'-bis(salicylidene)ethylenediamine with Cu(OAc)2·H2O results in the formation of Cu(II) complex III. C14H37CoNaO8 (I): triclinic, space group P1, a = 8.6296(12), b = 12.0291(17), c = 12.1108(17) A, α = 75.335(2), β = 69.991(2), γ = 72.248(2)°, V= 1109.4(3) A3, Z = 2, ρcaloa = 1.342 g/cm3, the final R= 0.0342 for 4817 observed reflections with I 〉 2σ(I) and Rw = 0.1263 for all data. C6H16N204 (II): space group P1, a = 5.5513(10), b = 5.5589(11), c = 7.4437(14) A, α = 94.332(4), β = 104.497(4), γ = 103.487(4)°,V= 214.06(7) A3, Z = 1, ρcalcd = 1.398 g/cm3, the final R = 0.0431 for 829 observed reflections with I〉 2σ(I) and Rw = 0.1263 for all data. C14H37CuN40 (III), space group P21/n, a = 9.050(9), b = 18.434(17), c = 11.659(11) A, β = 107.134(19)°, V= 1859(3) A3, Z = 4, ρcalcd =1.443 g/cm3, the final R = 0.0616 for 3308 observed reflections (O 〉 2σ(I)) and Rw = 0.1229 for all data. Their structures were all determined by X-ray diffraction, elemental analysis and IR.展开更多
文摘The title complex {[%n%|Bu-2SnO-2CCH(CS-2NEt-2)-2]-2O}-2 was synthesized and characterized by elemental analysis, IR, NMR and X|ray single crystal diffraction. The results show that the complex belongs to a monoclinic system with space group %C2/c%, and unit cell dimensions: %a%=2.848(5) nm, {%b%=1.381(2) nm}, %c%=3.239(6) nm, %β%=111.11(2)°, %Z=4, V%=11.884(35) nm+3, %D%-c=1.329 g/cm+3, {%F%(000)}=4 912, %S=0.991, R-1=0.053 5, wR-2=0.116 6.% The complex has a centrosymmetric dimer structure mode with a four|membered central %endo%|cyclic Sn-2O-2 unit. The %endo%|cyclic tin atoms are six|coordination and have coordition geometry of distorted octahedron. The %exo%|cyclic tin atoms are five|coordination and have coordination geometry of distorted trigonal bipyramid. This complex was tested %in vitro% against human tumour cell lines, MCF-7 and WiDr, and displayed the higher activity.
文摘The Co(II) complex I and ammonium salt II were synthesized from the direct reaction of 1,2-ethylenediamine and cobaltous acetate tetrahydrate and manganese acetate tetrahydrate in anhydrous ethanol. Treatment of N,N'-bis(salicylidene)ethylenediamine with Cu(OAc)2·H2O results in the formation of Cu(II) complex III. C14H37CoNaO8 (I): triclinic, space group P1, a = 8.6296(12), b = 12.0291(17), c = 12.1108(17) A, α = 75.335(2), β = 69.991(2), γ = 72.248(2)°, V= 1109.4(3) A3, Z = 2, ρcaloa = 1.342 g/cm3, the final R= 0.0342 for 4817 observed reflections with I 〉 2σ(I) and Rw = 0.1263 for all data. C6H16N204 (II): space group P1, a = 5.5513(10), b = 5.5589(11), c = 7.4437(14) A, α = 94.332(4), β = 104.497(4), γ = 103.487(4)°,V= 214.06(7) A3, Z = 1, ρcalcd = 1.398 g/cm3, the final R = 0.0431 for 829 observed reflections with I〉 2σ(I) and Rw = 0.1263 for all data. C14H37CuN40 (III), space group P21/n, a = 9.050(9), b = 18.434(17), c = 11.659(11) A, β = 107.134(19)°, V= 1859(3) A3, Z = 4, ρcalcd =1.443 g/cm3, the final R = 0.0616 for 3308 observed reflections (O 〉 2σ(I)) and Rw = 0.1229 for all data. Their structures were all determined by X-ray diffraction, elemental analysis and IR.