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Active and passive modulation of solar light transmittance in a uniquely multifunctional dual-band single molecule for smart window applications
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作者 Pooja V.Chavan Pramod V.Rathod +2 位作者 Joohyung Lee Sergei V.Kostjuk Hern Kim 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第1期293-305,I0007,共14页
Functional materials may change color by heat and electricity separately or simultaneously in smart windows.These materials have not only demonstrated remarkable potential in the modulation of solar radiation but are ... Functional materials may change color by heat and electricity separately or simultaneously in smart windows.These materials have not only demonstrated remarkable potential in the modulation of solar radiation but are also leading to the development of indoor environments that are more comfortable and conducive to improving individuals'quality of life.Unfortunately,dual-responsive materials have not received ample research attention due to economic and technological challenges.As a consequence,the broader utilization of smart windows faces hindrances.To address this new generational multistimulus responsive chromic materials,our group has adopted a developmental strategy to create a poly(NIPAM)n-HV as a switchable material by anchoring active viologen(HV)onto a phase-changing poly(NIPAM)n-based smart material for better utility and activity.These constructed smart windows facilitate individualistic reversible switching,from a highly transparent state to an opaque state(thermochromic)and a red state(electrochromic),as well as facilitate a simultaneous dual-stimuli response reversible switching from a clear transparent state to a fully opaque(thermochromic)and orange(electrochromic)states.Absolute privacy can be attained in smart windows designed for exclusive settings by achieving zero transmittance.Each unique chromic mode operates independently and modulates visible and near-infrared(NIR)light in a distinct manner.Hence,these smart windows with thermal and electric dual-stimuli responsiveness demonstrate remarkable heat regulation capabilities,rendering them highly attractive for applications in building facades,energy harvesting,privacy protection,and color display. 展开更多
关键词 Smart windows THERMOCHROMISM ELECTROCHROMISM Energy saving Dual-responsive material
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Learning Epipolar Line Window Attention for Stereo Image Super-Resolution Reconstruction
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作者 Xue Li Hongying Zhang +1 位作者 Zixun Ye Xiaoru 《Computers, Materials & Continua》 SCIE EI 2024年第2期2847-2864,共18页
Transformer-based stereo image super-resolution reconstruction(Stereo SR)methods have significantly improved image quality.However,existing methods have deficiencies in paying attention to detailed features and do not... Transformer-based stereo image super-resolution reconstruction(Stereo SR)methods have significantly improved image quality.However,existing methods have deficiencies in paying attention to detailed features and do not consider the offset of pixels along the epipolar lines in complementary views when integrating stereo information.To address these challenges,this paper introduces a novel epipolar line window attention stereo image super-resolution network(EWASSR).For detail feature restoration,we design a feature extractor based on Transformer and convolutional neural network(CNN),which consists of(shifted)window-based self-attention((S)W-MSA)and feature distillation and enhancement blocks(FDEB).This combination effectively solves the problem of global image perception and local feature attention and captures more discriminative high-frequency features of the image.Furthermore,to address the problem of offset of complementary pixels in stereo images,we propose an epipolar line window attention(EWA)mechanism,which divides windows along the epipolar direction to promote efficient matching of shifted pixels,even in pixel smooth areas.More accurate pixel matching can be achieved using adjacent pixels in the window as a reference.Extensive experiments demonstrate that our EWASSR can reconstruct more realistic detailed features.Comparative quantitative results show that in the experimental results of our EWASSR on the Middlebury and Flickr1024 data sets for 2×SR,compared with the recent network,the Peak signal-to-noise ratio(PSNR)increased by 0.37 dB and 0.34 dB,respectively. 展开更多
关键词 Stereo SR epipolar line window attention feature distillation
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Wideband low-scattering metasurface with an in-band reconfigurable transparent window
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作者 朱瑛 杨维旭 +4 位作者 段坤 姜田 赵俊明 陈克 冯一军 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第2期334-341,共8页
Active metasurfaces with dynamically reconfigurable functionalities are highly demanded in various practical applications.Here,we propose a wideband low-scattering metasurface that can realize an in-band reconfigurabl... Active metasurfaces with dynamically reconfigurable functionalities are highly demanded in various practical applications.Here,we propose a wideband low-scattering metasurface that can realize an in-band reconfigurable transparent window by altering the operation states of the PIN diodes loaded on the structures.The metasurface is composed of a band-pass frequency selective surface(FSS)sandwiched between two polarization conversion metasurfaces(PCMs).PIN diodes are integrated into the FSS to switch the transparent window,while a checkerboard configuration is applied in PCMs for the diffusive-reflective function.A sample with 20×20 elements is designed,fabricated,and experimentally verified.Both simulated and measured results show that the in-band functions can be dynamically switched between beam-splitting scattering and high transmission by controlling the biasing states of the diodes,while low backscattering can be attained outside the passband.Furthermore,the resonant structures of FSS also play the role of feeding lines,thus significantly eliminating extra interference compared with conventional feeding networks.We envision that the proposed metasurface may provide new possibilities for the development of an intelligent stealth platform and its antenna applications. 展开更多
关键词 metasurface reconfigurable transparent window radar cross section(RCS)reduction
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快速拓展Windows实时性!史上最小的PLC运动控制器发布
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《智慧工厂》 2024年第1期26-26,共1页
为了解决Windows系统下可视化界面友好、软件开发容易、兼容性好,但无法实现实时性控制;其它带有实时控制功能的系统存在软件平台搭建困难、开发难度高、兼容性差等问题。立迈胜研发了一种NIMC301-A微型运动控制器,可以做到开箱即用,极... 为了解决Windows系统下可视化界面友好、软件开发容易、兼容性好,但无法实现实时性控制;其它带有实时控制功能的系统存在软件平台搭建困难、开发难度高、兼容性差等问题。立迈胜研发了一种NIMC301-A微型运动控制器,可以做到开箱即用,极大地增加了用户的易用性。其自带CANopen主站,具备PLC控制功能,也可为WindoWs平台提供实时性拓展,而体积仅相当于“U盘”大小! 展开更多
关键词 windowS系统 可视化界面 软件开发 实时性控制 易用性 运动控制器 U盘 兼容性
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基于三次样条函数的加Blackman-harris窗插值FFT算法 被引量:15
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作者 许珉 刘凌波 《电力自动化设备》 EI CSCD 北大核心 2009年第2期59-63,共5页
使用加Blackman-harris窗插值快速傅里叶变换(FFT)算法计算电力系统谐波时,其频率修正系数公式和复振幅的插值修正函数过于复杂。提出利用三次样条函数逼近其频率修正系数的7次多项式和复振幅的修正函数,采用三次样条插值函数的有效形... 使用加Blackman-harris窗插值快速傅里叶变换(FFT)算法计算电力系统谐波时,其频率修正系数公式和复振幅的插值修正函数过于复杂。提出利用三次样条函数逼近其频率修正系数的7次多项式和复振幅的修正函数,采用三次样条插值函数的有效形式计算频率修正系数和复振幅的修正系数,将插值FFT算法的频率修正系数曲线分为10段,给定11个等间距插值点,并将复振幅修正系数曲线以频率修正系数间隔0.1分为10段,给定11个等间距插值点,分别构造出频率修正系数和复振幅修正系数的快速计算公式。公式简单,计算量小,程序实现方便,实时性好,并且在分段处连续,分段处的计算值为精确值。仿真结果表明,该算法计算所得幅值误差小于0.01%,频率误差小于0.003 Hz,相位误差小于1%。 展开更多
关键词 三次样条 blackman-harris 插值FFT算法 频谱泄漏 谐波 电力系统
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加Blackman-Harris窗插值算法仿真介损角测量 被引量:24
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作者 徐志钮 律方成 李和明 《高电压技术》 EI CAS CSCD 北大核心 2007年第3期104-108,共5页
为了更好地将加布莱克曼-哈里斯(Blackman-Harris)窗插值谐波分析法用于介损角测量,仿真分析了该算法及其在信号频率、3次谐波、直流分量、采样频率、A/D量化位数、采样时间长度、介损角真实值、白噪声及脉冲噪声变化时计算所得介损角... 为了更好地将加布莱克曼-哈里斯(Blackman-Harris)窗插值谐波分析法用于介损角测量,仿真分析了该算法及其在信号频率、3次谐波、直流分量、采样频率、A/D量化位数、采样时间长度、介损角真实值、白噪声及脉冲噪声变化时计算所得介损角误差的变化。仿真结果表明,频率波动时算法误差很小且稳定;算法随3次谐波分量的增加误差有很微小的增加;算法随直流分量的增加变化不显著;算法随A/D量化位数的增加误差减少,≥10位的量化位数能满足精度要求;随采样频率的增加误差稍有下降,但趋势不明显;随采样长度增加误差减少,0.1s的采样时间长度足够;介损角误差与真实值的关系不大;随白噪声和脉冲噪声含量的减少误差减少,对白噪声和脉冲噪声信噪比约80 dB能满足要求。 展开更多
关键词 介损角 傅立叶变换 非同步采样 布莱克曼-哈里斯窗 插值 仿真
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Blackman-Harris窗的插值FFT谐波分析与应用 被引量:23
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作者 周西峰 赵蓉 郭前岗 《电测与仪表》 北大核心 2014年第11期81-85,共5页
快速傅里叶变换在非同步采样和非整数周期截断的情况下存在较大的误差,无法得到准确的谐波参数。加窗插值快速傅里叶变换算法广泛用于电力系统谐波,可改善因非同步采样和非整数周期截断造成的频谱泄露,提高分析精度。文章分析了Blackman... 快速傅里叶变换在非同步采样和非整数周期截断的情况下存在较大的误差,无法得到准确的谐波参数。加窗插值快速傅里叶变换算法广泛用于电力系统谐波,可改善因非同步采样和非整数周期截断造成的频谱泄露,提高分析精度。文章分析了Blackman-Harris窗的频谱特性,提出了基于Blackman-Harris窗插值的分析算法,运用多项式拟合求出实用的插值修正公式。仿真结果表明,Blackman-Harris窗插值FFT方法设计实现灵活,抑制频谱泄露效果好。 展开更多
关键词 谐波分析 频谱泄露 Blackman—Harris窗 插值快速傅里叶变换
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基于Blackman-Harris相位差校正信号谐波分析方法 被引量:7
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作者 刘海升 付志红 +2 位作者 张淮清 李胜芳 侯兴哲 《数据采集与处理》 CSCD 北大核心 2011年第4期468-472,共5页
运用快速傅里叶变换(FFT)进行电力谐波分析时很难做到同步采样和整周期截断,造成的频谱泄漏将影响谐波分析精度。本文引入Blackman-Harris窗函数,分析其时域和频域特性,采用Blackman-Harris窗对谐波信号进行加权,结合相位差校正原理,用... 运用快速傅里叶变换(FFT)进行电力谐波分析时很难做到同步采样和整周期截断,造成的频谱泄漏将影响谐波分析精度。本文引入Blackman-Harris窗函数,分析其时域和频域特性,采用Blackman-Harris窗对谐波信号进行加权,结合相位差校正原理,用于谐波分析。推导了信号基波及各次谐波频率、幅值和初相角的计算式,对常规的频谱相位差校正方法进行了改进。仿真结果表明,应用Blackman-Harris窗相位差校正信号谐波分析法的运算时间与加其他余弦窗的运算时间相比没有明显增加,计算精度却显著提高。本文提出算法实现简单,精度高,通用性强,可应用于高精度电能计量和电能质量分析。 展开更多
关键词 电能计量 谐波分析 频谱泄漏 相位差校正 布莱克曼-哈里斯窗
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基于Blackman-Harris窗三谱线插值测试ADC信噪比的方法(英文) 被引量:2
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作者 虞致国 孙益洲 +2 位作者 黄朴 何芹 顾晓峰 《Journal of Measurement Science and Instrumentation》 CAS CSCD 2017年第4期321-327,共7页
利用快速傅里叶变换(FFT)测试模数转换器(ADC)的信噪比(SNR)必然存在非相干采样,导致测量结果会受频谱泄漏的影响。针对此问题,提出了一种利用Blackman-Harris窗三谱线插值测试高速ADC SNR的方法。基于MATLAB构建了验证平台,采用美国模... 利用快速傅里叶变换(FFT)测试模数转换器(ADC)的信噪比(SNR)必然存在非相干采样,导致测量结果会受频谱泄漏的影响。针对此问题,提出了一种利用Blackman-Harris窗三谱线插值测试高速ADC SNR的方法。基于MATLAB构建了验证平台,采用美国模拟器件公司(ADI)的AD9627等高速ADC产品的行为级动态模型进行了仿真验证。结果表明,在非相干程度最大的情况下,基于Blackman-Harris窗三谱线插值测试得到的SNR误差低于0.23dB,达到了ADI公司提供的测试标准,证明该法能很好地抑制频谱泄漏的影响,提高SNR测试精度。 展开更多
关键词 Blackman-Hars窗 信噪比 加窗插值 频谱泄漏 非相干采样
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基于相位差校正法的加Blackman-harris窗FFT算法与实现
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作者 李金锁 杜恒 《襄樊职业技术学院学报》 2010年第6期31-33,共3页
相位差校正法是连续两次加窗截断时域信号并进行两次FFT变换,然后利用其对应离散谱线的相位差校正出谱峰处的准确频率和相位的新校正方法,通过利用插值fft算法的窗谱函数公式还可以校正其幅值,用以解决离散频谱分析中由于不能做到同步... 相位差校正法是连续两次加窗截断时域信号并进行两次FFT变换,然后利用其对应离散谱线的相位差校正出谱峰处的准确频率和相位的新校正方法,通过利用插值fft算法的窗谱函数公式还可以校正其幅值,用以解决离散频谱分析中由于不能做到同步采样带来的较大误差。由于加Blackman-harris窗函数的频谱泄漏影响小、计算精度高,所以本文采用加Blackman-harris窗截断。 展开更多
关键词 相位差校正法 blackman-harris 插值FFT算法 频谱分析
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Teager-Kaiser能量算子Blackman-Harris窗三谱线插值的电压闪变参数检测 被引量:5
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作者 尹国明 陈克绪 +3 位作者 高云鹏 张韵琦 俞林刚 王英 《电测与仪表》 北大核心 2019年第4期8-14,共7页
针对电压闪变的检测,提出了一种基于Teager-Kaiser能量算子和Blackman-Harris窗三谱线插值的闪变参数测量方法。采用能量算子检测出电压波动信号,分析Blackman-Harris窗的旁瓣特性,将闪变包络进行Blackman-Harris窗三谱线插值FFT谱分析... 针对电压闪变的检测,提出了一种基于Teager-Kaiser能量算子和Blackman-Harris窗三谱线插值的闪变参数测量方法。采用能量算子检测出电压波动信号,分析Blackman-Harris窗的旁瓣特性,将闪变包络进行Blackman-Harris窗三谱线插值FFT谱分析与校正,对IEC标准推荐的检波方法进行简化,实现闪变参数的检测分析。通过大量仿真实验证明,在含有单一频率调制、多频率调制、电网基波频率发生偏移、含有谐波、间谐波和白噪声干扰时,文中的检测算法性能优良,相比传统检测方法,算法简单稳定、抗干扰性强,可实现电压闪变参数的在线检测。 展开更多
关键词 电压闪变 Teager-Kaiser能量算子 blackman-harris 三谱线插值 电能质量
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多媒体课件在Windows系统中的个性化创意设计
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作者 陈瑶 《数字通信世界》 2023年第2期109-111,共3页
文章从Windows桌面操作系统中图形界面应用出发,探讨通过个性化的设计方法创建自己的Windows Space,给用户创造出虚拟的桌面和软件界面应用,以多媒体课件的设计为实例,分析了多媒体课件界面设计的组成要素以及运用Flash和Dreamweaver进... 文章从Windows桌面操作系统中图形界面应用出发,探讨通过个性化的设计方法创建自己的Windows Space,给用户创造出虚拟的桌面和软件界面应用,以多媒体课件的设计为实例,分析了多媒体课件界面设计的组成要素以及运用Flash和Dreamweaver进行个性化创意设计的基本步骤。 展开更多
关键词 图形界面 多媒体课件 windowS系统 个性化创意
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基于强化学习的自动化Windows域渗透方法
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作者 占力戈 沙乐天 +2 位作者 肖甫 董建阔 张品昌 《网络与信息安全学报》 2023年第4期104-120,共17页
Windows域为用户之间的资源共享及信息交互提供统一的系统服务,在便利内网管理的同时带来了巨大的安全隐患。近年来,针对域控制器的各式攻击层出不穷,实现自动化渗透能够灵活检测Windows域中存在的漏洞威胁,保障办公网络安全稳定地持久... Windows域为用户之间的资源共享及信息交互提供统一的系统服务,在便利内网管理的同时带来了巨大的安全隐患。近年来,针对域控制器的各式攻击层出不穷,实现自动化渗透能够灵活检测Windows域中存在的漏洞威胁,保障办公网络安全稳定地持久运行,其核心是高效挖掘环境内可行的攻击路径。为此,将渗透测试过程进行强化学习建模,通过智能体与域环境的真实交互发现漏洞组合,进而验证有效的攻击序列;基于主机对渗透进程的贡献差异,减少强化学习模型中非必要的状态与动作,优化路径选择策略,提升实际攻击效率;使用状态动作删减、探索策略优化的Q学习算法筛选最优攻击路径,自动验证域环境中所有可能的安全隐患,为域管理员提供防护依据。实验针对典型内网业务场景展开测试,从生成的13种高效攻击路径中筛选最优路径,通过与相关研究成果对比,突出了所提方法在域控权限获取、主机权限获取、攻击步长、收敛性以及时间代价等方面的性能优化效果。 展开更多
关键词 windows域 渗透测试 强化学习 攻击路径
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An Electrochromic Nickel Phosphate Film for Large-Area Smart Window with Ultra-Large Optical Modulation 被引量:2
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作者 Pengyang Lei Jinhui Wang +6 位作者 Yi Gao Chengyu Hu Siyu Zhang Xingrui Tong Zhuanpei Wang Yuanhao Gao Guofa Cai 《Nano-Micro Letters》 SCIE EI CAS CSCD 2023年第3期35-47,共13页
Exploring materials with high electrochemical activity is of keen interest for electrochemistry-controlled optical and energy storage devices.However,it remains a great challenge for transition metal oxides to meet th... Exploring materials with high electrochemical activity is of keen interest for electrochemistry-controlled optical and energy storage devices.However,it remains a great challenge for transition metal oxides to meet this feature due to their low electron conductivity and insufficient reaction sites.Here,we propose a type of transition metal phosphate(NiHPO_(4)·3H_(2)O,NHP)by a facile and scalable electrodeposition method,which can achieve the capability of efficient ion accommodation and injection/extraction for electrochromic energy storage applications.Specifically,the NHP film with an ultra-high transmittance(approach to 100%)achieves a large optical modulation(90.8%at 500 nm),high coloration efficiency(75.4 cm^(2)C^(-1)at 500 nm),and a high specific capacity of 47.8 mAh g^(-1)at 0.4 A g^(-1).Furthermore,the transformation mechanism of NHP upon electrochemical reaction is systematically elucidated using in situ and ex situ techniques.Ultimately,a large-area electrochromic smart window with 100 cm^(2)is constructed based on the NHP electrode,displaying superior electrochromic energy storage performance in regulating natural light and storing electrical charges.Our findings may open up new strategies for developing advanced electrochromic energy storage materials and smart windows. 展开更多
关键词 ELECTROCHROMISM Transition metal phosphates Optical modulation Smart window Energy storage
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Effect of False Windows on Light Exposure and Sleep Quality in Hospitalized Patients
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作者 Hiroki Onodera Mitsuru Ida Masahiko Kawaguchi 《Health》 CAS 2023年第4期281-288,共8页
Purpose: We aimed to investigate the effects of installing false windows next to hospital beds without windows on the amount of light received by patients and their sleep quality. Methods: The study included patients ... Purpose: We aimed to investigate the effects of installing false windows next to hospital beds without windows on the amount of light received by patients and their sleep quality. Methods: The study included patients admitted to the Department of Neurology at our hospital between September 2020 and August 2021. An Actigraph device was fitted to patients’ wrist and their beds to measure the amount of light received and sleep quality. Patients were divided into three groups: bed with a window, aisle bed with a false window, and aisle bed without a window. Mean sleep efficiency (%), mean steps (per day), and the amount of light (lux) received by the patients and beds were measured. Results: Valid data were obtained for 48 participants (median age, 66.5 years). There were 23 patients in beds with a window, 13 patients in aisle beds without a false window, and 12 in aisle beds with a false window. No statistically significant differences were found in terms of mean sleep efficiency, number of steps taken, and the amount of light received by the patients (P > 0.05);however, difference in the mean amount of light received by the beds at the location of the bed was statistically significant (P Conclusion: The amount of light that the patient receives is not necessarily affected by the location of the bed or the presence of a false window. 展开更多
关键词 ACTIGRAPH False window Sleep Efficiency
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基于Windows服务器的网络安全问题研究
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作者 陈红娟 张曰花 刘婷婷 《黑龙江科学》 2023年第12期37-39,共3页
针对Windows服务器网络安全框架,分析了Windows服务器网络安全功能及应用,指出了Windows服务器网络安全的常见问题,包括操作系统漏洞、病毒攻击、恶意软件、黑客攻击、暴力破解及系统攻击等。提出了Windows服务器网络安全常用算法,包括W... 针对Windows服务器网络安全框架,分析了Windows服务器网络安全功能及应用,指出了Windows服务器网络安全的常见问题,包括操作系统漏洞、病毒攻击、恶意软件、黑客攻击、暴力破解及系统攻击等。提出了Windows服务器网络安全常用算法,包括Windows进程自动加载技术、端口隐藏、密码算法。分析了经典Windows服务器网络安全框架,需将网络监控系统放在同一个网络中,采用加密数据传输,以保证客户通信安全。 展开更多
关键词 windowS服务器 网络安全 通信
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基于Windows服务器终端的远程信息获取研究
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作者 刘婷婷 陈红娟 张曰花 《黑龙江科学》 2023年第10期129-130,133,共3页
分析了基于Windows服务器终端的远程信息获取技术,包括Microsoft Windows Server远程桌面服务、远程管理服务及网络管理服务。研究表明,使用Windows Server远程终端可实现信息获取与交互,通过套接字技术及TCP/IP等多种协议可完成Window... 分析了基于Windows服务器终端的远程信息获取技术,包括Microsoft Windows Server远程桌面服务、远程管理服务及网络管理服务。研究表明,使用Windows Server远程终端可实现信息获取与交互,通过套接字技术及TCP/IP等多种协议可完成Windows服务器终端通信,结合完成端口可搭建较为完成的系统框架。目前,搭建的系统框架能够满足客户的日常需求、服务器终端信息获取,采用加密技术可完成对隐私信息的网络保护。 展开更多
关键词 windowS服务器 通信 远程交互
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基于Windows平台的故障转移集群研究与应用
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作者 李永 《信息技术》 2023年第8期47-50,共4页
针对目前铁路客运营销辅助决策系统的资料库存在单点故障的问题,研究Microsoft SQL Server数据库。在Windows Server服务器上利用微软公司内置的故障转移集群功能来提高应用的稳定性和可用性;基于故障转移集群实现SQL Server的Always O... 针对目前铁路客运营销辅助决策系统的资料库存在单点故障的问题,研究Microsoft SQL Server数据库。在Windows Server服务器上利用微软公司内置的故障转移集群功能来提高应用的稳定性和可用性;基于故障转移集群实现SQL Server的Always On功能;通过研究集群相关技术,完成基于Windows Server 2016的无域控故障转移集群部署实践。实践表明,利用Windows故障转移特性,可以实现SQL Server数据库的高可用性及应用或服务的高可用性。 展开更多
关键词 windows Server 故障转移集群 高可用 无域
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Development of RF windows for 650 MHz multibeam klystron
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作者 Sheng-Chang Wang Zu-Sheng Zhou +5 位作者 Zhi-Jun Lu Zhi-Qing Liu Shigeki Fukuda Yu Liu Jing-Yi Li Wei-Ming Li 《Nuclear Science and Techniques》 SCIE EI CAS CSCD 2023年第9期58-68,共11页
Radio frequency windows are developed and evaluated for a 650 MHz continuous-wave multibeam klystron.Thin-pillbox windows with alumina and beryllia disks are designed with an average RF power of CW 400 kW.Results of a... Radio frequency windows are developed and evaluated for a 650 MHz continuous-wave multibeam klystron.Thin-pillbox windows with alumina and beryllia disks are designed with an average RF power of CW 400 kW.Results of a cold test and tuning procedures are described.The final measured S11 curves under the required bandwidth are less than-32.0 and-26.9 dB for alumina and beryllia windows,respectively.The windows are tested up to CW 143 kW for traveling waves and CW 110 kW for standing waves using a solid-state amplifier as an RF power source.Multipactor simulations for windows and benchmark studies for the thermal analysis of ceramic disks are introduced. 展开更多
关键词 RF window High-power test MBK
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A novel calculation strategy for optimized prediction of the reduction of electrochemical window at anode
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作者 孙国宸 高健 李泓 《Chinese Physics B》 SCIE EI CAS CSCD 2023年第7期191-198,共8页
The reduction of the electrochemical window(EW)of electrolytes plays a significant role in assessing their compatibility with the anode in lithium-ion batteries.However,the accurate calculation of the reduction of EW ... The reduction of the electrochemical window(EW)of electrolytes plays a significant role in assessing their compatibility with the anode in lithium-ion batteries.However,the accurate calculation of the reduction of EW is still challenging due to missing the solvation effects,condensation effects,kinetic factors,and the passivation on anodes.The theoretical prediction of the intrinsic and apparent EW is confirmed by a comprehensive experimental analysis of ethylene carbonatedimethyl carbonate(EC-DMC)electrolytes,combining linear sweep voltammetry(LSV)and gas chromatography-mass spectrometry(GC-MS).The proposed novel kinetic normal distribution theory model can quantitatively explain the current density from LSV and affirm acetaldehyde(MeCHO)as one of the primary reduction products of EC.The solvent effect restricts the intrinsic EW of EC-DMC without lithium salt to 2.6 V(vs.Li^(+)/Li)arising from the Marcus-Gerischer theory and the passivation of MeCHO on the anode broadens the apparent EW to 0.3 V(vs.Li^(+)/Li)arising from the normal distribution of the lowest unoccupied molecular orbital(LUMO)for MeCHO produced by thermal motion.In addition,the passivation on the anode depends intensively on the lithium salt,resulting in more complicated influences on the apparent EW. 展开更多
关键词 lithium battery ELECTROLYTE reduction kinetic electrochemical window
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