Effect of copper content on the pyrolysis process of organic components in waste printed circuit boards:Based on experimental and quantum chemical DFT simulations

In recent years,scientists have become increasingly concerned in recycling electronic trash,particularly waste printed circuit boards(WPCBs).Previous research has indicated that the presence of Cu impacts the pyrolysis of WPCBs.However,there may be errors in the experimental results,as printed circuit boards(PCBs)with copper and those without copper are produced differently.For this experiment,we blended copper powder with PCB nonmetallic resin powder in various ratios to create the samples.The apparent kinetics and pyrolysis properties of four resin powders with varying copper concentrations were compared using nonisothermal thermogravimetric analysis(TG)and thermal pyrolysis-gas chromatography mass spectrometry(Py-GC/MS).From the perspective of kinetics,the apparent activation energy of the resin powder in the pyrolysis reaction shows a rise(0.1<a<0.2)-stable(0.2<a<0.4)-accelerated increase(0.4<a<0.8)-decrease(0.8<a<0.9)process.After adding copper powder,the apparent activation energy changes more obviously when(0.2<a<0.4).In the early stage of the pyrolysis reaction(0.1<a<0.6),the apparent activation energy is reduced,but when a?0.8,it is much higher than that of the resin sample without copper.Additionally,it is discovered using thermogravimetric analysis and Py-GC/MS that copper shortens the temperature range of the primary pyrolysis reaction and prevents the creation of compounds containing bromine.This inhibition will raise the temperature at which compounds containing bromine first form,and it will keep rising as the copper level rises.The majority of the circuit board molecules have lower bond energies when copper is present,according to calculations performed using the Gaussian09 software,which promotes the pyrolysis reaction.

Effect of Low pH on Forming Process of Desulfurization Gypsum Composite Boards Strengthened by Melamine-formaldehyde Resin

Through exploring the effects of low pH on the composite system of desulfurization gypsum(DG)enhanced by melamine-formaldehyde resin(MF),it is found that the inducing of sulfate-ion,in contrast to chloride and oxalate ions,favors the longitudinal growth of the crystalline form of the hydration product,which was relatively simple and had the highest length to width(L/D)ratio.At the same time,MF can also improve L/D ratio of gypsum hydration products,which favors the formation of hydrated whiskers.Finally,in a composite system composed of hemihydrate gypsum,MF,and glass fibers,when dilute sulfuric acid was used to regulate pH=3-4,the tight binding formed among the components of the composite system compared to pH=5-6.The hydration product of gypsum adheres tightly to glass fiber surface and produces a good cross-linking and binding effect with MF.The flexural strength,compressive strength,elastic modulus,and water absorption of the desulphurized gypsum composite board is 22.7 MPa,39.8 MPa,5608 MPa,and 1.8%,respectively.

Protective benefits of HDPE board sand fences in an environment with variable wind directions on Gobi surfaces:wind tunnel study

The Golmud-Korla Railway in the Gobi area faces operational challenges due to sand hazards,caused by strong and variable winds.This study addresses these challenges by conducting wind tunnel tests to evaluate the protective benefits of High Density Polyethylene(HDPE)board sand fences,focusing on their orientation relative to various wind directions(referred to as'wind angle').This study found that the size of the low-velocity zone on the leeward side of the sand fences(LSF)expanded with an increase in the wind angle(WA).At 1H(the height of the sand fence)and 2H positions on the LSF,the wind speed profiles(WSP)exhibited a segmented logarithmic growth,constrained by Z=H at varying WAs.The efficacy of the sand fence in obstructing airflow escalated as WA increased.The size of the WA has a significant impact on the protective efficiency of HDPE board sand fences.Furthermore,compared to typical sandy surfaces,the rate of sand transport across the Gobi surface diminishes more slowly with height,attributed to the gravel's rebound effect.This phenomenon allows some sand particles to bypass the fences,rendering them less effective at blocking wind and trapping sand than in sandy environments.This paper offers scientific evidence supporting the practical use and enhancement of HDPE board sand fences in varied wind conditions.

Protective benefit of folded linear HDPE board sand fences along the Golmud-Korla Railway,China:Field observation and wind tunnel study

The Milan Gobi area of the Golmud-Korla Railway in northwest China is located in the lower dispersal area of the mountain pass and has strong winds with evident double wind direction characteristics.This study introduced a novel sand fence deployment technique,termed‘folded linear deployment',designed to position the sand fence orthogonally to the two predominant wind directions for optimal protection.This study used wind tunnel and field tests to evaluate the wind and sand flow characteristics,as well as the windproof and sandresistant performance of folded linear HDPE(Highdensity polyethylene)board sand fences.The results suggest that the airflow around the fence creates clear zoning characteristics.The deceleration area on the BSF(backwind side of the sand fence)is much larger than that on the DSF(downwind side of the sand fence).Thus,sand particles are primarily deposited on the BSF.At different wind speeds,the airflow at 2 and 5 h on the DSF is not disturbed.The WSP(wind speed profile)presents a logarithmic distribution.The airflow is disturbed at 1-20 h on the BSF,and the WSP gradually deviates from the logarithmic law.However,as the airflow moves away from the fence,the WSP gradually approaches a logarithmic distribution.Meanwhile,the WPE(windproof efficiency)and SRE(sand-resistant efficiency)of the sand fence exceed 80%.In addition,the results of wind tunnel tests are compared with those of field tests.The overall dispersion is good,and the best dispersion is found at z/H=2.00,indicating good agreement between the two test results.This study provides a scientific basis for the design of sand hazard control measures,similar to the railway project in the Gobi Gale area.

Women on Boards of Directors

This research aims to measure the current gender representation in membership of boards of directors,and to study the factors affecting the presence of women on boards.The results of the study will support the decision makers and policy makers at all levels by providing knowledge that contributes to bridging the current gap in participation of women boards.The methodology used in this research is the descriptive analytical approach,which relies on quantitative methods in the process of collecting and analyzing data.This study represents the boards of directors in the three sectors(public,private,and non-profit)in the Kingdom of Saudi Arabia,The study sample contained 350 targets,where a random sample of 150 people in the public sector,100 people in the private sector,and 100 people in the non-profit sector were selected.The research result found that the majority of the responses believe that the lack of experience and training,and social factors,are the most impact areas of explaining the reasons for the existence of a gap in women’s membership in boards of directors in the three sectors.And the most important reasons for the existence of a gender gap in board membership are:there is no statutory minimum percentage for women’s representation on boards of directors,and scarcity of female competencies in general,and the lack of women occupying leadership positions.

Development and Characterization of Particle Boards Based on Sorghum Husk

This study tackles current environmental challenges by developing innovative and eco-friendly particle boards utilizing sorghum husk, combined with recycled expanded polystyrene (EPS). This dual eco-responsible approach valorizes sorghum husk, often deemed agricultural waste, and repurposes EPS, a plastic waste, thus contributing to CO2 emission reduction and effective waste management. The manufacturing process involves dissolving recycled polystyrene within a solvent to create a binder, which is then mixed with sorghum husk and cold-pressed into composite boards. The study explores the impact of two particle sizes (fine and coarse) and two different concentrations of the recycled EPS binder. Results demonstrate significant variations in the boards’ mechanical properties, displaying a range of Modulus of Rupture (MOR) from 0.84 MPa to 3.85 MPa, and Modulus of Elasticity (MOE) spanning from 658.13 MPa to 1313.25 MPa, influenced by the binder concentration and particle size. These characteristics suggest that the boards can be effectively used in various construction applications, including interior decoration, false ceilings, and potentially for furniture and door manufacturing when combined with appropriate coatings. This study not only exemplifies the valorization of plastic and agricultural wastes but also offers a practical, localized solution to global climate change challenges by promoting sustainable construction materials.

Experimental study of polyurea-coated fiber-reinforced cement boards under gas explosions

Five types of polyurea elastomers were synthesized by changing the isocyanate component and the mechanical properties of polyurea materials were measured. Fiber-reinforced cement boards(FRCB)strengthened by polyurea with different formulations were processed, and a series of experiments were carried out on the specimens with gas explosion devices. The results showed that the conventional mechanical properties of different types of polyureas had their own advantages. Based on the gas explosion overpressure criterion, the blast resistances of reinforced plates were quantitatively evaluated,and the best polyurea was selected to guide the formulation design. The three typical failure modes of polyurea-reinforced FRCBs were flexural, shear, and flexural-shear failure. Dynamic thermodynamics and shock wave spectral analysis revealed that the polyurea did not undergo a glass transition in the gas explosion tests but retained its elastic properties, allowing it to effectively wrap the fragments formed by the brittle substrates.

Detection Algorithm of Surface Defect Word on Printed Circuit Board

For Printed Circuit Board(PCB)surface defect detection,traditional detection methods mostly focus on template matching-based reference method and manual detections,which have the disadvantages of low defect detection efficiency,large errors in defect identification and localization,and low versatility of detectionmethods.In order to furthermeet the requirements of high detection accuracy,real-time and interactivity required by the PCB industry in actual production life.In the current work,we improve the Youonly-look-once(YOLOv4)defect detection method to train and detect six types of PCB small target defects.Firstly,the original Cross Stage Partial Darknet53(CSPDarknet53)backbone network is preserved for PCB defect feature information extraction,and secondly,the original multi-layer cascade fusion method is changed to a single-layer feature layer structure to greatly avoid the problem of uneven distribution of priori anchor boxes size in PCB defect detection process.Then,the K-means++clustering method is used to accurately cluster the anchor boxes to obtain the required size requirements for the defect detection,which further improves the recognition and localization of small PCB defects.Finally,the improved YOLOv4 defect detection model is compared and analyzed on PCB dataset with multi-class algorithms.The experimental results show that the average detection accuracy value of the improved defect detection model reaches 99.34%,which has better detection capability,lower leakage rate and false detection rate for PCB defects in comparison with similar defect detection algorithms.

Internet of Things Supported Airport Boarding System and Evaluation with Fuzzy

The existing systems sustained with the investments made require more automation and digital transformation with the continuous advancement of tech-nology.The aviation industry is a sector that is open to more automation and digi-tal transformation,mainly because of the intense competition and the analysis of a large variety of data.The long duration of operations in current airline processes and some processflows cause customer dissatisfaction and cost increase.In this study,the boarding process,which is one of the operational processes of airline transportation and is open to improvement,was discussed.The classical boarding process has been redesigned using Internet of Things technology a model called Boarding 4.0 was created.With Boarding 4.0,it is aimed to design a process where passengers can take their time before boarding more efficiently.In the study,the sub-processes of the Boarding 4.0 model,other processes that the sub-processes interact with,their activities,and data exchange passenger move-ments during the activities are explained in detail.Compared to the classical boarding process and Boarding 4.0 with the fuzzy ahp technique,it has been shown that boarding 4.0 is more advantageous and passenger movement times can be reduced during boarding.As a result of the evaluation made with the fuzzy ahp,it was determined that boarding 4.0 is more advantageous than the classical boarding process.In addition,when the total time of the sub-activities in the board-ing process is calculated,boarding activities for a passenger take 50 min with the classic boarding process and 20 min with Boarding 4.0.Thus,when Boarding 4.0 is used,the passenger gains 30 min.Furthermore,when the calculation is made concerning the airport’s current capacity,two passengers are hosted with the clas-sical boarding process,whilefive passengers are hosted with Boarding 4.0.This acquisition is significant for airports in terms of efficient use of resources.

Modeling of Micropores Drilling Force for Printed Circuit Board Micro-holes Based on Energy Method

The quality of printed circuit board(PCB)micro-hole processing directly determines the stability of the inner and outer circuit connections.Micro-hole drilling technology is a typical method for PCB micro-hole processing.The problem of optimal control of its drilling force is one of the main factors affecting the quality of micro-hole machining.To address this problem,the thrust forces and torques in PCB drilling were first modeled and analyzed,and the corresponding prediction models were established.The drilling force analysis was carried out through the micro-hole drilling experiment,the specific cutting energy under different feed rates was calculated,the influence of the size effect was clarified,and the accuracy of the prediction model was verified.The result shows that during the drilling of glass fiber cloth,changes in the material removal mechanism are induced as the feed per revolution is varied.When the feed per revolution is less than the tool edge radius,the glass fiber is not cut by the main cutting edge,but is crushed and broken.When the feed per revolution is greater than the radius of the tool edge,the glass fiber is cut by the main cutting edge.At the same time,the established analytical model can accurately reflect the influence of the size effect on the drilling torque in PCB micro-hole drilling,and the error is within 10%.This method has certain practical application value in controlling PCB micro hole processing quality.

Experimental and numerical study regarding H-steel all-bolted connection steel frame with composite wall boards

H-steel all-bolted connection steel frame structures with heat preservation and decoration composite wall boards were investigated and the seismic performances of three scaled specimens were studied.The failure modes,hysteresis curves,bearing capacity,ductility,energy dissipation capacity,stiffness degradation and strain distribution were discussed.The calculation method of structural theoretical internal force was presented.The results showed that the overall structural seismic performance was better,and the structural ductility met the demands of elastic-plastic inter-story drift angle for seismic design.The H-steel weak-axis connection structure obtained better energy dissipation capacity,and its bearing capacity and stiffness were slightly different from the strong-axis connection.The heat preservation and decoration performance of composite wallboard and the all-bolted connection of the steel frame realized prefabrication during the whole construction period.The plastic hinge of the steel beam can be moved outwards because of the L-angles,which effectively avoids stress concentration in joint areas and expands the plastic hinge range.The errors between the theoretical structural capacity calculated by the plastic analysis method and the test results were within 2.44%.In addition,structural failure mechanisms and bearing capacities were verified by the finite element(FE)analysis,and the effects of the main parameters on the structures were investigated.The FE verification results were the same as in the test.The research results provide theoretical support and technical guidance for the application of thermal insulation and decorative composite wall panels in H-shaped steel all-bolted steel frames.

Industry-Oriented Detection Method of PCBA Defects Using Semantic Segmentation Models

Automated optical inspection(AOI)is a significant process in printed circuit board assembly(PCBA)production lines which aims to detect tiny defects in PCBAs.Existing AOI equipment has several deficiencies including low throughput,large computation cost,high latency,and poor flexibility,which limits the efficiency of online PCBA inspection.In this paper,a novel PCBA defect detection method based on a lightweight deep convolution neural network is proposed.In this method,the semantic segmentation model is combined with a rule-based defect recognition algorithm to build up a defect detection frame-work.To improve the performance of the model,extensive real PCBA images are collected from production lines as datasets.Some optimization methods have been applied in the model according to production demand and enable integration in lightweight computing devices.Experiment results show that the production line using our method realizes a throughput more than three times higher than traditional methods.Our method can be integrated into a lightweight inference system and pro-mote the flexibility of AOI.The proposed method builds up a general paradigm and excellent example for model design and optimization oriented towards industrial requirements.

A Single-Board Integrated Millimeter-Wave Asymmetric Full-Digital Beamforming Array for B5G/6G Applications

In this article,a single-board integrated millimeter-wave(mm-Wave)asymmetric full-digital beamforming(AFDBF)array is developed for beyond-fifth-generation(B5G)and sixth-generation(6G)communications.The proposed integrated array effectively addresses the challenge of arranging a large number of ports in a full-digital array by designing vertical connections in a three-dimensional space and successfully integrating full-digital transmitting(Tx)and receiving(Rx)arrays independently in a single board.Unlike the traditional symmetric array,the proposed asymmetric array is composed of an 8×8 Tx array arranged in a square shape and an 8+8 Rx array arranged in an L shape.The center-to-center distance between two adjacent elements is 0.54k0 for both the Tx and Rx arrays,where k0 is the free-space wavelength at 27 GHz.The proposed AFDBF array possesses a more compact structure and lower system hardware cost and power consumption compared with conventional brick-type full-digital arrays.In addition,the energy efficiency of the proposed AFDBF array outperforms that of a hybrid beamforming array.The measurement results indicate that the operating frequency band of the proposed array is 24.25–29.50 GHz.An eight-element linear array within the Tx array can achieve a scanning angle ranging from-47°to+47°in both the azimuth and the elevation planes,and the measured scanning range of each eight-element Rx array is–45°to+45°.The measured maximum effective isotropic radiated power(EIRP)of the eight-element Tx array is 43.2 dBm at 28.0 GHz(considering the saturation point).Furthermore,the measured error vector magnitude(EVM)is less than 3%when 64-quadrature amplitude modulation(QAM)waveforms are used.

Smaller & Smarter: Score-Driven Network Chaining of Smaller Language Models

With the continuous evolution and expanding applications of Large Language Models (LLMs), there has been a noticeable surge in the size of the emerging models. It is not solely the growth in model size, primarily measured by the number of parameters, but also the subsequent escalation in computational demands, hardware and software prerequisites for training, all culminating in a substantial financial investment as well. In this paper, we present novel techniques like supervision, parallelization, and scoring functions to get better results out of chains of smaller language models, rather than relying solely on scaling up model size. Firstly, we propose an approach to quantify the performance of a Smaller Language Models (SLM) by introducing a corresponding supervisor model that incrementally corrects the encountered errors. Secondly, we propose an approach to utilize two smaller language models (in a network) performing the same task and retrieving the best relevant output from the two, ensuring peak performance for a specific task. Experimental evaluations establish the quantitative accuracy improvements on financial reasoning and arithmetic calculation tasks from utilizing techniques like supervisor models (in a network of model scenario), threshold scoring and parallel processing over a baseline study.

BOB(Bosa On Board)设计研究

采用bosa on board的方式,将光通信电路直接铺设在PCB板上,替代传统的光模块独立器件,实现GPON/EPON产品的低成本高性能。

Experimental Study on Corrosion of Stainless Steel in Low Temperature Multi effect Seawater Desalination

Starting from the corrosion mechanism,this paper analyzes the characteristics of various types of stainless steel and selects the best performance composite plate composite plate stainless steel.Analyze and select the most suitable corrosion detection method based on specific practical multi working conditions,discuss the interference factors that affect metal corrosion during experimental simulation,and the advantages of newly developed sheet metal.The new development of composite board panels,with the substrate and composite materials applying their respective capabilities for MED,will bring breakthrough progress to the scientific research and engineering applica-tion of composite boards.

Preparation and characterization of high-strength calcium silicate boards from coal-fired industrial solid wastes

To realize the comprehensive utilization of coal-fired industrial solid wastes, a novel high-strength board was prepared from calcium silicate slag, fly ash, and flue gas desulfurization(FGD) gypsum. The changes in mineral phases, chemical structure, and morphology during hydration were investigated by X-ray diffraction(XRD), Fourier transform infrared spectroscopy(FTIR), and scanning electron microscopy(SEM). A traditional board made from quartz and lime was prepared as a reference. The novel board not only consumes a lot of solid wastes, but also meets the strength requirement of the class-five calcium silicate board according to the Chinese Standard JC/T 564.2—2008. Microanalysis showed that hydrated calcium silicate gel(C-S-H(I)), ettringite, tobermorite, and xonotlite were successively generated in the novel board by synergistic hydration of the mixed solid wastes. The board strength was improved by the formation of tobermorite and xonotlite but decreased by unhydrated quartz. It was demonstrated that quartz was not completely hydrated in the traditional board. As a result, the flexural strength of the traditional board was much lower than that of the novel board.

Hydration Characteristics and Humidity Control Performance of Calcium Silicate Board Prepared from Mine Tailing and Diatomite

The feasibility of utilizing molybdenum tailing and diatomite as siliceous materials to prepare calcium silicate board was explored.The influences of molybdenum tailing/diatomite proportion on hydration characteristics,thermal conductivity,water absorption,flexural strength and moisture adsorption-desorption property of calcium silicate board were investigated in detail.The experimental results reveal that molybdenum tailing is environmentally friendly to prepare building materials.The main hydration products in calcium silicate board under autoclaved condition are C-S-H with low crystallinity and tobermorite.Molybdenum tailing is favorable to the formation of tobermorite.The flexural strength and bulk density of the calcium silicate board gradually increase when the content of molybdenum tailing increases.Netlike C-S-H is formed with the increase of diatomite content during autoclaved curing process,resulting in the enhancement of moisture adsorptiondesorption performance and the reduction of thermal conductivity.The optimal content of molybdenum tailing is 20%,furthermore,the flexual strength and thermal conductivity of calcium silicate board at this content meet the Chinese standard JC/T564.1-2008.

Energy Absorption Diagrams of Multi-layer Corrugated Boards

Based on the static compression experiments, the compressive stress-strain curve of multi-layer corrugated boards is simplified into three sections of linear elasticity, sub-buckling going with local collapse and densification. By considering the structure factors of multi-layer corrugated boards, the energy absorption model is obtained and characterized by the structure factors of corrugated cell-wall. The model is standardized by the solid modulus and it is universal for corrugated structures of different basis material. In the liner-elastic section, with the increase of the load, the energy absorption per unit volume of multi-layer corrugated boards gradually increases; in the sub-buckling section going with local collapse, the compression resistance of multi-layer corrugated boards goes on under a nearly constant load, but the energy absorption per unit volume rapidly increases with the increase of the compression strain. It is shown as an ascending curve in the energy absorption diagram. In the densification section, the corrugated sandwich core has no energy absorption capability. A good consistency is achieved between theoretical and experimental energy absorption curves. In designing the cushioning package, the cushioning properties can be evaluated by the theoretical model without more experiments. The suggested method to develop the energy absorption diagram for corrugated boards can be used to characterize the cushioning properties and optimize the structures of corrugated sandwich structures.

Synthesis of Petri net supervisors enforcing general constraints

This paper deals with the synthesis of Petri net supervisor enforcing the more expressive constraints including marking terms, firing vector terms and Parikh vector terms. The method is developed to handle uncontrollable and unobservable transitions existing in the constraints. The “greater-than or equal” general constraints can also be transformed into “less-than or equal” Parikh constraints. An example is analyzed to show how the problem is solved. General constraint is first transformed into Parikh vector constraints, and Matrix-Transformation is proposed to obtain the admissible constraints without uncontrollable and unobservable transitions. Then the supervisor can be constructed based on constraints only consisting of Parikh vector terms. The method is proved to be more concise and effective than the method presented by Iordache and Moody especially when applied to large scale systems.