AC measurements of spray-deposited CdS:In thin films

Indium doped cadmium sulfide thin films （CdS：In） were produced by the spray pyrolysis technique on glass substrates. AC measurements were used to investigate the electrical properties of the films depending on Brick-layer model for polycrystalline materials. The measurements were performed at room temperature in the dark and room light in the frequency range from 20 Hz to 1 MHz using coplanar indium electrodes. The data were analyzed by using Bode plots for the impedance Z and dielectric loss tang with frequencyf It is found that the impedance has no dependence on frequency in the low frequency region but has 1/f dependence in the high frequency region. One dielectric loss peak is obtained, which means the presence of a single relaxation time, and hence the films are modeled by just one RC circuit which represents the grains. This means that there is just one conduction mechanism that is responsible for the conduction in the bulk, due to electronic transport through the grains. Real values of the impedance in the low frequency region and relaxation times for treated and as-deposited fihns were estimated.

PM Diagram of the Transfer Function and Its Use in the Design of Controllers

This paper presents an enhanced Root Locus diagram that consists of the representation of the phase and the magnitude of the transfer function G（s） of a system. The magnitude is represented in decibels and the phase is represented by colors. It also presents how to use it to calculate different kinds of controllers. An important characteristic of this diagram is that permits to read the phase and the gain margins directly and the imaginary axis cut represents the Bode diagram. It is also possible to put the grid with damping ratio ξ and frequency ωn.

On the notions of normality, locality, and operational stability in ADRC

Treating plant dynamics as an ideal integrator chain disturbed by the total disturbance is the hallmark of active disturbance rejection control(ADRC).To interpret its effectiveness and success,to explain why so many vastly different dynamic systems can be treated in this manner,and to answer why a detailed,accurate,and global mathematical model is unnecessary,is the target of this paper.Driven by a motivating example,the notions of normality and locality are introduced.Normality shows that,in ADRC,the plant is normalized to an integrator chain,which is called local nominal model and locally describes the plant’s frequency response in the neighborhood of the expected gain crossover frequency.Locality interprets why ADRC can design the controller only with the local information of the plant.With normality and locality,ADRC can be effective and robust,and obtain operational stability discussed by T.S.Tsien.Then viewing proportional-integral-derivative(PID)control as a low-frequency approximation of second-order linear ADRC,the above results are extended to PID control.A controller design framework is proposed to obtain the controller in three steps:(1)choose an integrator chain as the local nominal model of the plant;(2)select a controller family corresponding to the local nominal model;and(3)tune the controller to guarantee the gain crossover frequency specification.The second-order linear ADRC and the PID control are two special cases of the framework.

Electrochemical Impedance Spectroscopic Analysis of ZnS Nanorod Fabricated Using Butterfly Wings as Biotemplate

This article describes the growth of zinc sulfide（ZnS） nanorod on glass/aluminum foil by employing butterfly wings as biotemplate. Upon calcinating（at 400 °C）, the butterfly wings soaked in ZnS nanoparticle suspension, with uniform cage-like nanostructures in nanodimensions, were found on glass/aluminum surface. The transverse and longitudinal dimensions of the nanorods were evaluated from scanning electron microscopy micrographs as 132 and 159 nm,respectively. Purity of the ZnS nanorod found on the specimen was checked by recording XRD（28.877°, 48.038°, and57.174°） and Fourier transform infrared spectrometer spectra（663.7 and 551.68 cm^-1）. Luminescence natures of the nanorods were examined using photoluminescence spectral studies. The characteristic emission peak is shown in the visible region with strong intensity, while the excitation peak is shown at 267 nm. Electrochemical impedance spectroscopic analysis of ZnS nanorod exhibits double-layer capacitance value（Cdl= 6.7 nF）, and the Bode plot explains the stability of ZnS nanorod under the influence of electrical field.