Gedankenexperiment for Modified ZPE and Planck’s “Constant”, h, in the Beginning of Cosmological Expansion, Partly Due to NLED

We initially look at a non singular universe representation of entropy, based in part on what was brought up by Muller and Lousto. This is a gateway to bringing up information and computational steps (as defined by Seth Lloyd) as to what would be available initially due to a modified ZPE formalism. The ZPE formalism is modified as due to Matt Visser’s alternation of k (maximum) ~ 1/(Planck length), with a specific initial density giving rise to initial information content which may permit fixing the initial Planck’s constant, h, which is pivotal to the setting of physical law. The settings of these parameters depend upon NLED.

Stoichiometry and Stability Constant Values for Copper (II) Chelates with Ethylene Diamine in Deep Eutectic Solvents (DES) (Ethaline) Solutions

In this study we used the deep eutectic solvents (ionic liquids) to investigate the reaction between copper (II) with ethylene diamine (en). Two of the existing methods for analyzing spectrophotometric measurements have been applied for establishing, the stoichiometry and whenever possible, the stability constants of the chelates formed. The method of continuous variations was necessary to determine first whether, the metal ion and the ligand ethylene diamine form one or more than one chelate, when more than one chelate formed, the results obtained depend on the wavelength and for meaningful conclusions the wavelengths were carefully selected. The empirical formulae of the chelates were further substantiated by the molar ratio method. The effect of time and temperature on the formation and stability of these chelates in solution is also studied. The stability constants, K1 and K2 for the copper (II) chelates were calculated, though reliable, and are comparable to literature values.

Henry's Law constant for phosphine in seawater:determination and assessment of influencing factors

The Henry＇s Law constant （k） for phosphine in seawater was determined by multiple phase equilibration combined with headspace gas chromatography. The effects of pH, temperature, and salinity on k were studied. The k value for phosphine in natural seawater was 6.415 at room temperature （approximately 23℃）. This value increases with increases in temperature and salinity, but no obvious change was observed at different pH levels. At the same temperature, there was no significant difference between the k for phosphine in natural seawater and that in artificial seawater. This implies that temperature and salinity are major determining factors for k in marine environment. Double linear regression with Henry＇s Law constants for phosphine as a function of temperature and salinity confirmed our observations. These results provide a basis for the measurement of trace phosphine concentrations in seawater, and will be helpful for future research on the status of phosphine in the oceanic biogeochemical cycle of phosphorus.

Reinvestigation of the Henry's law constant for hydrogen peroxide with temperature and acidity variation

Hydrogen peroxide is not only an important oxidant in itself; it also serves as both sink and temporary reservoir for other important oxidants including HOx （OH and HO2） radicals and O3 in the atmosphere. Its partitioning between gas and aqueous phases in the atmosphere, usually described by its Henry＇s law constant （KH）, significantly influences its role in atmospheric processes. Large discrepancies between the KH values reported in previous work, however, have created uncertainty for atmospheric modelers. Based on our newly developed online instrumentation, we have re-determined the temperature and acidity dependence of KH for hydrogen peroxide at an air pressure of （0.960 ± 0.013） atm （1 atm = 1.01325 × 10^5 Pa）. The results indicated that the temperature dependence of KH for hydrogen peroxide fits to the Van＇t Hoff equation form, expressed as lnKH = a/T - b, and a = -△H/R, where KH is in M/atm （M is mol/L）, T is in degrees Kelvin, R is the ideal gas constant, and AH is the standard heat of solution. For acidity dependence, results demonstrated that the KH value of hydrogen peroxide appeared to have no obvious dependence on decreasing pH level （from pH 7 to pH 1）. Combining the dependence of both temperature and acidity, the obtained a and b were 7024 ± 138 and 11.97 ± 0.48, respectively, AH was （58.40 ± 1.15） kJ/（K.mol）, and the uncertainties represent σ. Our determined KH values for hydrogen peroxide will therefore be of great use in atmospheric models.

Physical interpretation of Planck's constant based on the Maxwell theory

The discovery of the Planck relation is generally regarded as the starting point of quantum physics.Planck＇s constant h is now regarded as one of the most important universal constants.The physical nature of h,however,has not been well understood.It was originally suggested as a fitting constant to explain the black-body radiation.Although Planck had proposed a theoretical justification of h,he was never satisfied with that.To solve this outstanding problem,we use the Maxwell theory to directly calculate the energy and momentum of a radiation wave packet.We find that the energy of the wave packet is indeed proportional to its oscillation frequency.This allows us to derive the value of Planck＇s constant.Furthermore,we show that the emission and transmission of a photon follows the all-or-none principle.The ＂strength＂ of the wave packet can be characterized by ζ,which represents the integrated strength of the vector potential along a transverse axis.We reason that ζ should have a fixed cut-off value for all photons.Our results suggest that a wave packet can behave like a particle.This offers a simple explanation to the recent satellite observations that the cosmic microwave background follows closely the black-body radiation as predicted by Planck＇s law.

ASYMPTOTIC EQUIVALENCE OF ALTERNATELY ADVANCED AND DELAYED DIFFERENTIAL SYSTEMS WITH PIECEWISE CONSTANT GENERALIZED ARGUMENTS

In this paper, we investigate the existence, uniqueness and the asymptotic equiv- alence of a linear system and a perturbed system of differential equations with piecewise alternately advanced and retarded argument of generalized type （DEPCAG）. This is based in the study of an equivalent integral equation with Cauchy and Green matrices type and in a solution of a DEPCAG integral inequality of Gronwall type. Several examples are also given to show the feasibility of results.

Stability constants of Sb^5+with Cl−and thermodynamics of Sb−S−Cl−H2O system involving complex behavior of Sb with Cl

The stability constants of Sb^5+with Cl−as well as thermodynamics of the Sb−S−Cl−H2O system were calculated.The stability constants of Sb5+with Cl−were obtained by theoretical calculations of the absorbance of a Sb5+-containing solution at different Cl^−concentrations,which was detected by spectrophotometric analysis at certain wavelengths of light(380 nm).The logarithmic values versus 10 of stability constants of Sb^5+with Cl−were 1.795,3.150,4.191,4.955,5.427 and 5.511,respectively,and partly filled the data gaps in the hydrometallurgy of antimony.The presence and distribution of pentavalent antimony compounds under different conditions were analyzed based on equilibrium calculations.Thermodynamic equilibrium calculations were performed for Sb−S−Cl−H2O system,which included the complex behavior of Sb with Cl,and the equilibrium equations of related reactions in this system were integrated into the potential−pH diagram.

Mass Constituents of a Flat Lattice Multiverse: Conclusion from Similarity between Two Universal Numbers, the Rocksalt-Type 2<i>D</i>Madelung Constant and the Golden Mean

In fairly good agreement with the consensus range of dark energy to matter this ratio of the critical density is suggested to be connected with the golden mean &phi;=0.6180339887, yielding for dark energy to matter mass fractions .?Assuming the baryonic matter to be only 4.432%, the ratio of matter to baryonic matter would be , and further the ratio of dark matter to baryonic one . If one subtracts from the dark matter a contribution of antimatter with the same mass of baryonic matter, according to the antigravity theories of Villata respectively Hajdukovic, the remaining mass ratio would yield . Replacing the “Madelung” constant α of Villata’s “lattice universe” by &phi;, one reaches again 1 + &phi;as the ratio of the repulsive mass contribution to the attractive one. Assuming instead of a 3D lattice a flat 2D one of rocksalt type, the numerical similarity between the Madelung constant and φ&minus;1 could not be just coincidence. The proposed scaling of the cosmological mass fractions with the square of the most irrational universal number &phi;may indicate that the chaotic cosmological processes have reached a quite stable equilibrium. This may be confirmed by another, but similar representation of the mass constituents by the Archimedes’ constant &pi;, giving for respectively for the dark components . However, the intimate connection of φ with its reciprocal may ignite the discussion whether our universe is intertwined with another universe or even part of a multiverse with the dark constituents contributed from there.

Prediction of Henry's constant in polymer solutions using PCOR equation of state coupled with an activity coefficient model

In this paper,the polymer chain of rotator(PCOR) equation of state(EOS) was used together with an EOS/G^E mixing rule(MHV1) and the Wilson's equation as an excess-Gibbs-energy model in the proposed approach to extend the capability and improve the accuracy of the PCOR EOS for predicting the Henry's constant of solutions containing polymers.The results of the proposed method compared with two equation of state(van der Waals and GC-Flory) and three activity coefficient models(UNIFAC,UNIFAC-FV and Entropic-FV) indicated that the PCOR EOS/Wilson's equation provided more accurate results.The interaction parameters of Wilson's equation were fitted with Henry's constant experimental data and the property parameters of PCOR,a and b,were fitted with experimental volume data(Tait equation).As a result,the present work provided a simple and useful model for prediction of Henry's constant for polymer solutions.

Values of Siva’s Constant “<i>K</i>” for All Fundamental Forces—A Review on Spin, Threshold Time and Quantum Entanglement

Siva’s constant “K” has been explained in brief. Its numerical values have been calculated for each fundamental force of nature. Spin of quantum mechanics has been interpreted in terms of Sivas constant “K”. Thus limitation to velocity of light and interrelation between relativity and quantum mechanics has been explained in a novel and profound way. Involvement of “physics of consciousness” in synchronizing relativity and quantum mechanics has been emphasized. Concept of “bio force” as fifth fundamental force in addition to other four fundamental forces, strong, weak, electromagnetic and gravitational forces also has been emphasized. Consciousness has been explained as entanglement between bio force particle named as “jeeton” and gravitational force particle “graviton”. Thus frequency mediated consciousness has been explained.

Experimental Evidence for Variability in Planck’s Constant

Annual variations of 1000 - 3000 ppm (peak-to-valley) have been observed in the decay rates of 8 radionuclides over a 20 year span by six organizations on three continents, including beta decay (weak interaction) and alpha decay (strong interaction). In searching for a common cause, we hypothesized that small variations in Planck’s constant might account for the observed synchronized variations in strong and weak decays. If so, then h would be a maximum around January-February of each year and a minimum around July-August of each year based on the 20 years of radioactive decay data. To test this hypothesis, a purely electromagnetic experiment was set up to search for the same annual variations. From Jun 14, 2011 to Jan 29, 2014 (941 days), annual variations in tunneling voltage through 5 parallel Esaki tunnel diodes were recorded. It found annual variations of 826 ppm peak-to-valley peaking around Jan 1. These variations lend support to the hypothesis that there is a gradient in h of about 21 ppm across the Earth’s orbit.

FLIP AND N-S BIFURCATION BEHAVIOR OF A PREDATOR-PREY MODEL WITH PIECEWISE CONSTANT ARGUMENTS AND TIME DELAY

In this paper, the stability and bifurcation behaviors of a predator-prey model with the piecewise constant arguments and time delay are investigated. Technical approach is fully based on Jury criterion and bifurcation theory. The interesting point is that the model will produce two different branches by limiting branch parameters of different intervals. Besides, image simulation is also given.

Newton Did Not Invent or Use the So-Called Newton’s Gravitational Constant;G, It Has Mainly Caused Confusion

Newton did not invent or use the so-called Newton’s gravitational constant G. Newton’s original gravity formula was and not . In this paper, we will show how a series of major gravity phenomena can be calculated and predicted without the gravitational constant. This is, to some degree, well known, at least for those that have studied a significant amount of the older literature on gravity. However, to understand gravity at a deeper level, still without G, one needs to trust Newton’s formula. It is when we first combine Newton’s assumptionn, that matter and light ultimately consist of hard indivisible particles, with new insight in atomism that we can truly begin to understand gravity at a deeper level. This leads to a quantum gravity theory that is unified with quantum mechanics and in which there is no need for G and not even a need for the Planck constant. We claim that two mistakes have been made in physics, which have held back progress towards a unified quantum gravity theory. First, it has been common practice to consider Newton’s gravitational constant as almost holy and untouchable. Thus, we have neglected to see an important aspect of mass;namely, the indivisible particle that Newton also held in high regard. Second, standard physics have built their quantum mechanics around the de Broglie wavelength, rather than the Compton wavelength. We claim the de Broglie wavelength is merely a mathematical derivative of the Compton wavelength, the true matter wavelength.

Determination of the Structural Constant of the Atom

The equations for energy, momentum, frequency, wavelength and also Schr?dinger equation of the electromagnetic wave in the atom are derived using the model of atom by analogy with the transmission line. The action constant A0 = (μ0/ε0)1/2s02e2 is a key term in the above mentioned equations. Besides the other well-known quantities, the only one unknown quantity in the last expression is a structural constant s0. Therefore, this article is dedicated to the calculation of the structural constant of the atoms on the basis of the above mentioned model. The structural constant of the atoms s0 = 8.277 56 shows up as a link between macroscopic and atomic world. After calculating this constant we get the theory of atoms based on Maxwell’s and Lorentz equations only. This theory does not require Planck constant h, which once was introduced empirically. Replacement for h is the action constant A0, which is here theoretically derived, while the replacement for fine structure constant α is 1/(2s02). In this way, the structural constant s0 replaces both constants, h and α. This paper also defines the stationary states of atoms and shows that the maximal atomic number is equal to 2s02 = 137.036, i.e., as integer should be Zmax=137. The presented model of the atoms covers three of the four fundamental interactions, namely the electromagnetic, weak and strong interactions.

The Kemeny’s Constant and Spanning Trees of Hexagonal Ring Network

Spanning tree(τ)has an enormous application in computer science and chemistry to determine the geometric and dynamics analysis of compact polymers.In the field of medicines,it is helpful to recognize the epidemiology of hepatitis C virus(HCV)infection.On the other hand,Kemeny’s constant(Ω)is a beneficial quantifier characterizing the universal average activities of a Markov chain.This network invariant infers the expressions of the expected number of time-steps required to trace a randomly selected terminus state since a fixed beginning state si.Levene and Loizou determined that the Kemeny’s constant can also be obtained through eigenvalues.Motivated by Levene and Loizou,we deduced the Kemeny’s constant and the number of spanning trees of hexagonal ring network by their normalized Laplacian eigenvalues and the coefficients of the characteristic polynomial.Based on the achieved results,entirely results are obtained for the M鯾ius hexagonal ring network.

Powell's optimal identification of material constants of thin-walled box girders based on Fibonacci series search method

A dynamic Bayesian error function of material constants of the structure is developed for thin-walled curve box girders. Combined with the automatic search scheme with an optimal step length for the one-dimensional Fibonacci series, Powell＇s optimization theory is used to perform the stochastic identification of material constants of the thin-walled curve box. Then, the steps in the parameter identification are presented. Powell＇s identification procedure for material constants of the thin-walled curve box is compiled, in which the mechanical analysis of the thin-walled curve box is completed based on the finite curve strip element （FCSE） method. Some classical examples show that Powell＇s identification is numerically stable and convergent, indicating that the present method and the compiled procedure are correct and reliable. During the parameter iterative processes, Powell＇s theory is irrelevant with the calculation of the FCSE partial differentiation, which proves the high computation efficiency of the studied methods. The stochastic performances of the system parameters and responses axe simultaneously considered in the dynamic Bayesian error function. The one-dimensional optimization problem of the optimal step length is solved by adopting the Fibonacci series search method without the need of determining the region, in which the optimized step length lies.

Determination of the Henry’s Law Constant of Hexane in High-Viscosity Polymer Systems

The Henry’s law constant of volatiles in polymer systems is a crucial parameter reflecting the gas-liquid equilibrium,which is very important for devolatilization.In this research,polyolefin elastomer(POE)-cyclohexane and polydimethylsiloxane(PDMS)-hexane systems were studied,and the Henry’s law constant was obtained by measuring the gas phase equilibrium partial pressure when polymer solutions containing different mass fractions of volatiles reached a saturated state.The effects of temperature,type of volatiles,and polymer viscosity on the gas phase equilibrium partial pressure and Henry’s law constant of the volatiles were investigated.The results indicate that,with the increase of temperature and polymer viscosity,the gas phase equilibrium partial pressure and Henry’s law constant of volatiles increase.As temperature increases,the solubility of gas in liquid decreases.The relationship between the Henry’s law constant and temperature is consistent with the Arrhenius law.In the PDMS-hexane system,the gas phase equilibrium partial pressure and Henry’s law constant of n-hexane are higher than those of cyclohexane.The obtained Henry’s law constants can be used as a reference for perfecting the devolatilization process and improving the devolatilization effect.

Unity Formulas for the Coupling Constants and the Dimensionless Physical Constants

In this paper in an elegant way will be presented the unity formulas for the coupling constants and the dimensionless physical constants. We reached the conclusion of the simple unification of the fundamental interactions. We will find the formulas for the Gravitational constant. It will be presented that the gravitational fine-structure constant is a simple analogy between atomic physics and cosmology. We will find the expression that connects the gravitational fine-structure constant with the four coupling constants. Perhaps the gravitational fine-structure constant is the coupling constant for the fifth force. Also will be presented the simple unification of atomic physics and cosmology. We will find the formulas for the cosmological constant and we will propose a possible solution for the cosmological parameters. Perhaps the shape of the universe is Poincare dodecahedral space. This article will be followed by the energy wave theory and the fractal space-time theory.

Plank Scale with Siva’s Constant “K”—A New Road to Grand Unification

Based on Vd = K equation and the consideration that maximum velocity is “velocity of light”, diameter of a space time for a particular fundamental force has been calculated. With Siva’s classical equation for space time, the quantity of fundamental force has been calculated in terms of relative energy with photon. This has been converted into relative force and the relative forces interpreted in terms of coupling constants of fundamental forces. All the fundamental forces are manifestation of space time material only. Space time will be different for different fundamental forces and their elementary force carrying particles. Specially, it has elaborated the difference between mass and energy for gravity space time. A generalized equation of space time and coupling constants has been derived. This equation can be used to calculate the space time parameters of other fundamental forces by knowing the coupling constant and vice versa. Space time parameters will be different for fundamental forces. In order to keep the parameters such as c,G,h,lp,tp and mp applicable to all other fundamental forces, a new parameter Siva’s constant “K” has been introduced. Thus all the observations are based on “K” and transformation is possible by a new additional parameter “K” such that c=h=G=K=1 instead of c=h=G=1. Ultimately, this paper may be a ground work to discuss lot of issues such as “consciousness” and “decoding of quantum information” in future.

Refining Black Hole Physics to Obtain Planck’s Constant from Information Shared from Cosmological Cycle to Cycle (Avoiding Super-Radiance)

Padmanabhan elucidated the concept of super radiance in black hole physics which would lead to loss mass of a black hole, and loss of angular momentum due to space-time infall of material into a black hole. As Padmanabhan explained it, to avoid super radiance, and probable break down of black holes, from in fall, one would need in fall material frequency, divided by mass of particles undergoing in fall in the black hole to be greater than the angular velocity of the black hole event horizon in question. We should keep in mind we bring this model up to improve the chance that Penrose’s conformal cyclic cosmology will allow for retention of enough information for preservation of Planck’s constant from cycle to cycle, as a counterpart to what we view as unacceptable reliance upon the LQG quantum bounce and its tetrad structure to preserve memory. In addition, we are presuming that at the time of z = 20 in red shift that there would be roughly about the same order of magnitude of entropy as number of operations in the electro weak era, and that the number of operations in the z = 20 case is close to the entropy at redshift z = 0. Finally, we have changed Λ with the result that after redshift = 20;there is a rapid collapse to the present-day vacuum energy value i.e. by z = 12 the value of the cosmological constant, Λ likely being the same, today, as for what it was when z = 12. And z = 12 is the redshift value about when Galaxies form.