In the present investigation,Pt/Ru-modified bond coating consisted of 2 μm Pt+2 μm Ru was deposited on a nickel-based superalloy by electroplating method and followed by conventional Al pack cementation.The cyclic ...In the present investigation,Pt/Ru-modified bond coating consisted of 2 μm Pt+2 μm Ru was deposited on a nickel-based superalloy by electroplating method and followed by conventional Al pack cementation.The cyclic corrosion behavior of Pt/Ru-modified bond coating exposed to NaCl plus water vapor has been investigated under atmospheric pressure at 1050℃.The result shows that the cyclic corrosion life of Pt/Ru-modified bond coating is longer than that of the conventional Pt-modified aluminide coating in the presence of NaCl plus water vapor.The addition of Ru makes the coating possess the increased strength and suppress the rumpling behavior.The absence of rumpling may be responsible for the improved corrosion resistance of Pt/Ru-modified aluminide coating.展开更多
Thermal barrier coatings(TBCs) consisting ofLa_(2)Ce_(2)O_(7)(LCO) and Y_(2)O_(3)-stabilized-ZrO_(2)(YSZ) doubleceramic layer and Dy/Pt co-doped NiAl bond coat were produced by electron beam physical vapor deposition(...Thermal barrier coatings(TBCs) consisting ofLa_(2)Ce_(2)O_(7)(LCO) and Y_(2)O_(3)-stabilized-ZrO_(2)(YSZ) doubleceramic layer and Dy/Pt co-doped NiAl bond coat were produced by electron beam physical vapor deposition(EBPVD). Thermal cyclic performance of the TBCs was evaluated by flame shock testing at 1300 ℃. For comparison, the TBCs with a undoped NiAl bond coat were also studied. The microstructural evolution and failure mechanisms of the above TBCs during thermal cycling were investigated. Spallation failure of the TBCs with the undoped bond coat occurs after around 500 cycles by cracking at the interface between YSZ ceramic layer and thermally grown oxides(TGO) layer. The TBCs with Pt/Dy modified bond coat reveal improved interface bonding even after 1200 thermal cycles, whereas some delamination cracks are presented in the LCO layer. On the other hand,the Pt/Dy modified bond coat effectively suppresses the formation of the needle-like topologically closed packed phases(TCP) in the single crystal superalloy.展开更多
Objective To investigate the effect of multiple coatings of the one-step self-etching adhesive on immediate microtensile bond strength to primary dentin.Methods Twelve caries-free human primary molars were randomly di...Objective To investigate the effect of multiple coatings of the one-step self-etching adhesive on immediate microtensile bond strength to primary dentin.Methods Twelve caries-free human primary molars were randomly divided into 2 groups with 6 teeth each.In group 1,each tooth was hemisected into two halves.One half was assigned to control subgroup 1,which was bonded with a single-step self-etching adhesive according to the manufacturer's instructions;the other half was assigned to experimental subgroup 1 in which the adhesive was applied three times before light curing.In group 2,the teeth were also hemisected into two halves.One half was assigned to control subgroup 2,which was bonded with the single-step self-etching adhesive according to the manufacturer's instructions;the other half was assigned to experimental subgroup 2 in which three layers of adhesive were applied with light curing each successive layer.Microtensile bond strength was immediately tested after specimen preparation.Results When the adhesive was applied three times before light curing,the bond strength of the experimental subgroup 1(n=33,57.49±11.61 MPa) was higher than that of the control subgroup 1(n=31,49.71±11.43 MPa,P<0.05).When using the technique of applying multiple layers of adhesive with light curing each successive layer,no difference of immediate bond strength was observed between the control subgroup 2 and the experimental subgroup 2(P>0.05).Conclusion Multiple coatings of one-step self-etching adhesive can increase the immediate bond strength to primary dentin when using the technique of light-curing after applying three layers of adhesive.展开更多
On the basis of the alloying theory of bonding assistant coat (BAC), taking into account of the interaction of alloy elements, the regressive equation, which relates the wetting ability of bonding assistant coat wit...On the basis of the alloying theory of bonding assistant coat (BAC), taking into account of the interaction of alloy elements, the regressive equation, which relates the wetting ability of bonding assistant coat with the contents of Mn, Ni, Si, Sn, and B, was es- tablished by using quadratic regression orthogonal design of five factors. The influence of elements and their interaction on the wetting ability was analyzed. The ranges of alloy elements were optimized. The melting point of bonding assistant coat was measured by using differential thermal analysis. The results show that the interactions of Ni and Mn, Ni, and Sn can increase the wetting ability obviously and the melting point of bonding assistant coat has been decreased.展开更多
The Zr coating was deposited on titanium surface using the magnetron sputtering technique. Effects of Zr coating on microstructure and mechanical properties of porcelain fired to titanium have been investigated. The r...The Zr coating was deposited on titanium surface using the magnetron sputtering technique. Effects of Zr coating on microstructure and mechanical properties of porcelain fired to titanium have been investigated. The results show that interdiffusion of elements occurs during porcelain firing, and the Zr coating can effectively protect titanium surface from excess oxidation. The strength of bond zone with Zr coating deposited for 1 hour reaches 29. 7 MPa, which has increased by 26.4% as compared with that of bond zone without coating (23.5 MPa).展开更多
A novel technique combining electrophoretic deposition (EPD) and reaction bonding process (RBP) is developed to fabricate thick ZrO2/Al2O3 composite coatings. Mixed organic solvents are used here to make suspension co...A novel technique combining electrophoretic deposition (EPD) and reaction bonding process (RBP) is developed to fabricate thick ZrO2/Al2O3 composite coatings. Mixed organic solvents are used here to make suspension containing yttria stablised zirconia (YSZ) and aluminium (Al). The results show that densely packed green form coatings are deposited using a mixture of ethanol and acetylacetone as suspension medium and ball milling for 48 hours. On subsequent heat treatment, melting and oxidation of aluminium in the green forms promote densification during sintering. By these means, thick, uniform and crack-free ZrtVA^Oa composite coatings have been fabricated on metal substrate.展开更多
A novel test method of measuring the interface bond strength between a thermal sprayed coating and substrate is put forward first in this paper. The test method is simple and reliable, and exists no any inherent short...A novel test method of measuring the interface bond strength between a thermal sprayed coating and substrate is put forward first in this paper. The test method is simple and reliable, and exists no any inherent shortcoming and controversy. The interface bond strength obtained by the test method is completely the inherent property of the interface and depends only on coating material properties, spray conditions, and technique of depositing the coating. By extensive tests, it is shown that the test tesults are very tepeatable and reliable. Furthermore, from this test, the critical coating thickness under which the coating spall can not emerge is also obtained.展开更多
Self-propagating high-temperature synthesis (SHS) with reduction process was used to fabricate TiB2 powder from TiO2-B2O3-Mg system. The colloidal alumina-bonded TiB2 paste was prepared and coated on the cathode carbo...Self-propagating high-temperature synthesis (SHS) with reduction process was used to fabricate TiB2 powder from TiO2-B2O3-Mg system. The colloidal alumina-bonded TiB2 paste was prepared and coated on the cathode carbon blocks. Various properties of the baked paste such as the corrosive resistance, thermal expansion and wettability were tested. Experimental results showed that the colloidal alumina-bonded TiB2 coating could be well wetted by liquid aluminum; and the thermal expansion coefficient of the coated material was 5.8x10(-6) degreesC(-1) at 20-1000 degreesC, which was close to that of the traditional anthracite block cathode (4x10(-6) degreesC(-1)); the electrical resistivity was 8 mu Omega (.)m at 900 degreesC when the content of alumina in the coated material was about 9% in mass fraction. In addition, some other good results such as sodium resistance were also reported.展开更多
A WC-Co/NiCrBSi composite coating was made on 42CrMo steel through vacuum brazing technology. The effects of cobalt and WC-17Co content on the properties of the coating were analyzed. The abrasive wear resistance decr...A WC-Co/NiCrBSi composite coating was made on 42CrMo steel through vacuum brazing technology. The effects of cobalt and WC-17Co content on the properties of the coating were analyzed. The abrasive wear resistance decreased as the cobalt content increased. The tensile strength of the coating increased with the increase of the WC-17Co content and the maximum strength approaches to 184MPa. The abrusive property of the composite coating is better than that of the WC-17Co/NiCrBSi flame overlaying and CoCrW overlaying.展开更多
Fluororesin-based anti-corrosive coatings including graded FEP/PPS were prepared on carbon steel by melt powder coating, the bonding strength of all coating systems was determined by the pull-off test. It is found tha...Fluororesin-based anti-corrosive coatings including graded FEP/PPS were prepared on carbon steel by melt powder coating, the bonding strength of all coating systems was determined by the pull-off test. It is found that the poor adhesion of fluororesin coatings to metallic substrates is improved obviously by the graded coating structure of FEP/PPS, and the bonding strength reaches up to 11.8 MPa for the five-layer system. Examination by electron probe microanalysis (EPMA) verifies that the distribution of main components is graded in the five-layer system, which is responsible for the enhancement of the interfacial bonding.展开更多
The coating substrate bonding strengths under different intermixing processes were evaluated by scratch and spherical rolling contact fatigue methods. The results show that for low bombarding energy of N ions dynamic ...The coating substrate bonding strengths under different intermixing processes were evaluated by scratch and spherical rolling contact fatigue methods. The results show that for low bombarding energy of N ions dynamic recoiling at 10 keV and 20 keV, the coating layers are of excellent bonding strengths. The bonding strength of CrN coating with 40 keV static recoiling is higher than that of low energy(20 keV). On the other hand, the bonding strength of coating with 40 keV dynamic recoiling is much lower than that of static recoiling at the same energy and even less than that of dynamic recoiling intermixings at 10 keV and 20 keV energy. The results of scratch and spherical rolling contact fatigue methods exhibit the same trend for each group of recoiling methods, yet the results of the scratch and fatigue tests for two groups do not agree with each other.展开更多
Objective To investigate whether multiple coatings can improve the bond durability of one-step self-etching adhesive to primary dentin.Methods Twelve caries-free human primary molars were randomly divided into 2 group...Objective To investigate whether multiple coatings can improve the bond durability of one-step self-etching adhesive to primary dentin.Methods Twelve caries-free human primary molars were randomly divided into 2 groups.In group 1,each tooth was hemisected into 2 halves.One half was assigned to the control subgroup 1,which was bonded with a commercially available one-step self-etching adhesive according to the manufacturer's instructions;the other half was assigned to experimental subgroup 1,in which the adhesive was applied three times before light curing.In group 2,one split half tooth was bonded with a commercially available one-step self-etching adhesive according to the manufacturer's instructions;for the other half,three layers of adhesive were applied with each successive layer of light curing.Specimens were stored in 0.9% NaCl containing 0.02% sodium azide at 37℃ for 18 months and then were subjected to microtensile bond strength test and the fracture mode analysis.Results When the adhesive was applied three times before light curing,the bond strength of the experimental subgroup 1 was significantly higher than that of the control subgroup 1(47.46±13.91 vs.38.12±11.21 MPa,P<0.05).When using the technique of applying multiple layers of adhesive with each successive layer of light curing,no difference was observed in bond strength between the control subgroup and the experimental subgroup(39.40±8.87 vs.40.87±9.33 MPa,P>0.05).Conclusion Multiple coatings can improve the bond durability of one-step self-etching adhesive to primary dentin when using the technique of light-curing after applying 3 layers of adhesive.展开更多
PbO-ZnO-Na2O ceramic coating was fabricated on the AZ91D Mg-alloy substrate surface by using of evaporated pattern casting(EPC) process.The ceramic coating was characterized through scanning electron microscopy(SEM) o...PbO-ZnO-Na2O ceramic coating was fabricated on the AZ91D Mg-alloy substrate surface by using of evaporated pattern casting(EPC) process.The ceramic coating was characterized through scanning electron microscopy(SEM) observation,energy dispersive X-ray spectrometer(EDS) and so on.The research was emphasized on the formation process of ceramic coating and the interface bonding conditions between ceramic coating and the substrate.Results show that the glass powder(PbO-ZnO-Na2O) melts when contacts with the high temperature liquid metal,and solidifies on the surface of the substrate with the decrease of temperature.Therefore,the ceramic coating was successfully prepared with the formation of the bonding interface with the substrate.Beside the influence of coating layer thickness,the vacuum level was also investigated.Further analysis indicates that oxide inclusions and decomposition products of foam pattern had a significant effect on the bonding interface.To obtain a good bonding interface between the ceramic coating and the substrate,the metal liquid oxidation and inclusions must be decreased and the decomposition products of foam pattern should be exhausted from the EPC coating completely.展开更多
基金supported by the Program for Changjiang Scholars and Innovative Research Team in University(PCSIRT)(IRT0512)the Program for New Century Excellent Talents in University(NCET)+1 种基金the National Natural Science Foundation of China(Nos.50671002and50971013)the National Institute for Materials Science (NIMS) internship program
文摘In the present investigation,Pt/Ru-modified bond coating consisted of 2 μm Pt+2 μm Ru was deposited on a nickel-based superalloy by electroplating method and followed by conventional Al pack cementation.The cyclic corrosion behavior of Pt/Ru-modified bond coating exposed to NaCl plus water vapor has been investigated under atmospheric pressure at 1050℃.The result shows that the cyclic corrosion life of Pt/Ru-modified bond coating is longer than that of the conventional Pt-modified aluminide coating in the presence of NaCl plus water vapor.The addition of Ru makes the coating possess the increased strength and suppress the rumpling behavior.The absence of rumpling may be responsible for the improved corrosion resistance of Pt/Ru-modified aluminide coating.
基金financially sponsored by the National Natural Science Foundations of China(Nos.51590894,51425102 and 51231001)。
文摘Thermal barrier coatings(TBCs) consisting ofLa_(2)Ce_(2)O_(7)(LCO) and Y_(2)O_(3)-stabilized-ZrO_(2)(YSZ) doubleceramic layer and Dy/Pt co-doped NiAl bond coat were produced by electron beam physical vapor deposition(EBPVD). Thermal cyclic performance of the TBCs was evaluated by flame shock testing at 1300 ℃. For comparison, the TBCs with a undoped NiAl bond coat were also studied. The microstructural evolution and failure mechanisms of the above TBCs during thermal cycling were investigated. Spallation failure of the TBCs with the undoped bond coat occurs after around 500 cycles by cracking at the interface between YSZ ceramic layer and thermally grown oxides(TGO) layer. The TBCs with Pt/Dy modified bond coat reveal improved interface bonding even after 1200 thermal cycles, whereas some delamination cracks are presented in the LCO layer. On the other hand,the Pt/Dy modified bond coat effectively suppresses the formation of the needle-like topologically closed packed phases(TCP) in the single crystal superalloy.
文摘Objective To investigate the effect of multiple coatings of the one-step self-etching adhesive on immediate microtensile bond strength to primary dentin.Methods Twelve caries-free human primary molars were randomly divided into 2 groups with 6 teeth each.In group 1,each tooth was hemisected into two halves.One half was assigned to control subgroup 1,which was bonded with a single-step self-etching adhesive according to the manufacturer's instructions;the other half was assigned to experimental subgroup 1 in which the adhesive was applied three times before light curing.In group 2,the teeth were also hemisected into two halves.One half was assigned to control subgroup 2,which was bonded with the single-step self-etching adhesive according to the manufacturer's instructions;the other half was assigned to experimental subgroup 2 in which three layers of adhesive were applied with light curing each successive layer.Microtensile bond strength was immediately tested after specimen preparation.Results When the adhesive was applied three times before light curing,the bond strength of the experimental subgroup 1(n=33,57.49±11.61 MPa) was higher than that of the control subgroup 1(n=31,49.71±11.43 MPa,P<0.05).When using the technique of applying multiple layers of adhesive with light curing each successive layer,no difference of immediate bond strength was observed between the control subgroup 2 and the experimental subgroup 2(P>0.05).Conclusion Multiple coatings of one-step self-etching adhesive can increase the immediate bond strength to primary dentin when using the technique of light-curing after applying three layers of adhesive.
基金This work was financially supported by the National High-Tech Research and Development Program of China (863 Program) (No.2002AA334070).
文摘On the basis of the alloying theory of bonding assistant coat (BAC), taking into account of the interaction of alloy elements, the regressive equation, which relates the wetting ability of bonding assistant coat with the contents of Mn, Ni, Si, Sn, and B, was es- tablished by using quadratic regression orthogonal design of five factors. The influence of elements and their interaction on the wetting ability was analyzed. The ranges of alloy elements were optimized. The melting point of bonding assistant coat was measured by using differential thermal analysis. The results show that the interactions of Ni and Mn, Ni, and Sn can increase the wetting ability obviously and the melting point of bonding assistant coat has been decreased.
文摘The Zr coating was deposited on titanium surface using the magnetron sputtering technique. Effects of Zr coating on microstructure and mechanical properties of porcelain fired to titanium have been investigated. The results show that interdiffusion of elements occurs during porcelain firing, and the Zr coating can effectively protect titanium surface from excess oxidation. The strength of bond zone with Zr coating deposited for 1 hour reaches 29. 7 MPa, which has increased by 26.4% as compared with that of bond zone without coating (23.5 MPa).
文摘A novel technique combining electrophoretic deposition (EPD) and reaction bonding process (RBP) is developed to fabricate thick ZrO2/Al2O3 composite coatings. Mixed organic solvents are used here to make suspension containing yttria stablised zirconia (YSZ) and aluminium (Al). The results show that densely packed green form coatings are deposited using a mixture of ethanol and acetylacetone as suspension medium and ball milling for 48 hours. On subsequent heat treatment, melting and oxidation of aluminium in the green forms promote densification during sintering. By these means, thick, uniform and crack-free ZrtVA^Oa composite coatings have been fabricated on metal substrate.
文摘A novel test method of measuring the interface bond strength between a thermal sprayed coating and substrate is put forward first in this paper. The test method is simple and reliable, and exists no any inherent shortcoming and controversy. The interface bond strength obtained by the test method is completely the inherent property of the interface and depends only on coating material properties, spray conditions, and technique of depositing the coating. By extensive tests, it is shown that the test tesults are very tepeatable and reliable. Furthermore, from this test, the critical coating thickness under which the coating spall can not emerge is also obtained.
文摘Self-propagating high-temperature synthesis (SHS) with reduction process was used to fabricate TiB2 powder from TiO2-B2O3-Mg system. The colloidal alumina-bonded TiB2 paste was prepared and coated on the cathode carbon blocks. Various properties of the baked paste such as the corrosive resistance, thermal expansion and wettability were tested. Experimental results showed that the colloidal alumina-bonded TiB2 coating could be well wetted by liquid aluminum; and the thermal expansion coefficient of the coated material was 5.8x10(-6) degreesC(-1) at 20-1000 degreesC, which was close to that of the traditional anthracite block cathode (4x10(-6) degreesC(-1)); the electrical resistivity was 8 mu Omega (.)m at 900 degreesC when the content of alumina in the coated material was about 9% in mass fraction. In addition, some other good results such as sodium resistance were also reported.
文摘A WC-Co/NiCrBSi composite coating was made on 42CrMo steel through vacuum brazing technology. The effects of cobalt and WC-17Co content on the properties of the coating were analyzed. The abrasive wear resistance decreased as the cobalt content increased. The tensile strength of the coating increased with the increase of the WC-17Co content and the maximum strength approaches to 184MPa. The abrusive property of the composite coating is better than that of the WC-17Co/NiCrBSi flame overlaying and CoCrW overlaying.
文摘Fluororesin-based anti-corrosive coatings including graded FEP/PPS were prepared on carbon steel by melt powder coating, the bonding strength of all coating systems was determined by the pull-off test. It is found that the poor adhesion of fluororesin coatings to metallic substrates is improved obviously by the graded coating structure of FEP/PPS, and the bonding strength reaches up to 11.8 MPa for the five-layer system. Examination by electron probe microanalysis (EPMA) verifies that the distribution of main components is graded in the five-layer system, which is responsible for the enhancement of the interfacial bonding.
文摘The coating substrate bonding strengths under different intermixing processes were evaluated by scratch and spherical rolling contact fatigue methods. The results show that for low bombarding energy of N ions dynamic recoiling at 10 keV and 20 keV, the coating layers are of excellent bonding strengths. The bonding strength of CrN coating with 40 keV static recoiling is higher than that of low energy(20 keV). On the other hand, the bonding strength of coating with 40 keV dynamic recoiling is much lower than that of static recoiling at the same energy and even less than that of dynamic recoiling intermixings at 10 keV and 20 keV energy. The results of scratch and spherical rolling contact fatigue methods exhibit the same trend for each group of recoiling methods, yet the results of the scratch and fatigue tests for two groups do not agree with each other.
文摘Objective To investigate whether multiple coatings can improve the bond durability of one-step self-etching adhesive to primary dentin.Methods Twelve caries-free human primary molars were randomly divided into 2 groups.In group 1,each tooth was hemisected into 2 halves.One half was assigned to the control subgroup 1,which was bonded with a commercially available one-step self-etching adhesive according to the manufacturer's instructions;the other half was assigned to experimental subgroup 1,in which the adhesive was applied three times before light curing.In group 2,one split half tooth was bonded with a commercially available one-step self-etching adhesive according to the manufacturer's instructions;for the other half,three layers of adhesive were applied with each successive layer of light curing.Specimens were stored in 0.9% NaCl containing 0.02% sodium azide at 37℃ for 18 months and then were subjected to microtensile bond strength test and the fracture mode analysis.Results When the adhesive was applied three times before light curing,the bond strength of the experimental subgroup 1 was significantly higher than that of the control subgroup 1(47.46±13.91 vs.38.12±11.21 MPa,P<0.05).When using the technique of applying multiple layers of adhesive with each successive layer of light curing,no difference was observed in bond strength between the control subgroup and the experimental subgroup(39.40±8.87 vs.40.87±9.33 MPa,P>0.05).Conclusion Multiple coatings can improve the bond durability of one-step self-etching adhesive to primary dentin when using the technique of light-curing after applying 3 layers of adhesive.
基金supported by the National Natural Science Foundation of China (Grant No.50775085)
文摘PbO-ZnO-Na2O ceramic coating was fabricated on the AZ91D Mg-alloy substrate surface by using of evaporated pattern casting(EPC) process.The ceramic coating was characterized through scanning electron microscopy(SEM) observation,energy dispersive X-ray spectrometer(EDS) and so on.The research was emphasized on the formation process of ceramic coating and the interface bonding conditions between ceramic coating and the substrate.Results show that the glass powder(PbO-ZnO-Na2O) melts when contacts with the high temperature liquid metal,and solidifies on the surface of the substrate with the decrease of temperature.Therefore,the ceramic coating was successfully prepared with the formation of the bonding interface with the substrate.Beside the influence of coating layer thickness,the vacuum level was also investigated.Further analysis indicates that oxide inclusions and decomposition products of foam pattern had a significant effect on the bonding interface.To obtain a good bonding interface between the ceramic coating and the substrate,the metal liquid oxidation and inclusions must be decreased and the decomposition products of foam pattern should be exhausted from the EPC coating completely.