The Qiangtang Basin(QB), located in the central Tibetan Plateau, is a Jurassic marine basin and one of the most important prospective salt resource belts in China. In recent decades, many outcrops of gypsiferous bed...The Qiangtang Basin(QB), located in the central Tibetan Plateau, is a Jurassic marine basin and one of the most important prospective salt resource belts in China. In recent decades, many outcrops of gypsiferous bed have been found in the Jurassic marine strata in the basin. Salt springs with abnormally high sodium(Na-+) contents had been identified in the Late Jurassic Xiali Formation(Fm.) in the basin in the last years. However, to date, no potash or halite deposits have been identified in the QB. Gypsum outcrops and salt springs are very important signs in the investigation of halite and potash deposits. Therefore, the Xiali Fm. is a potentially valuable layer to evaluate for the possible presence of halite and potash deposits in the basin. However, few studies have explored the formation conditions of evaporites in the unit. Here, we present detailed geochemical records from the Yanshiping section related to the study of the formation conditions of evaporites in the Xiali Fm. of the QB. Climate proxies based on the obviously increased anion concentrations of SO4(2-) and Cl-- and the significant correlation coefficients of Ca2+-SO42-(R = 0.985) and Na-+-Cl--(R = 0.8974) reveal that the upper member of the Xiali Fm.(the upper Xiali Fm.) formed under an arid climate and evolved into the sulfate phase or early chloride phase. Provenance proxies based on the obviously increased K-+ and Na-+ ion concentrations and the significant correlation coefficient of Na-+-Cl--(R = 0.8974) suggest that the upper Xiali Fm. featured optimal provenance conditions for the possible formation of halite deposits. The regression and the semi-closed tidal flat environment in the upper Xiali Fm. were favorable for the formation of potash and halite deposits. The low Mg-(2+) /Ca-(2+) values(mean value = 1.82) and significant Na-+-Cl-- correlation coefficient(R = 0.8974) also suggest that the upper Xiali Fm. is the layer most likely to contain potential halite deposits. In addition, the macroscopic correlations of tectonism, provenance, paleoclimate, saliferous strata and sedimentary environment between the QB and the adjoining Amu Darya Basin in Central Asia reveal that the two basins shared similar geologic settings that were favorable for the formation of evaporites during the Late Jurassic. Therefore, the upper Xiali Fm. is a valuable layer to explore for halite deposit and may be potentially valuable in the future exploration for potash deposits in the QB.展开更多
The presence of shale gas has been confirmed in almost every marine shale distribution area in North America.Formation conditions of shale gas in China are the most favorable for marine,organic-rich shale as well.But ...The presence of shale gas has been confirmed in almost every marine shale distribution area in North America.Formation conditions of shale gas in China are the most favorable for marine,organic-rich shale as well.But there has been little research focusing on shale gas in Qiangtang Basin,Qinghai-Tibet Plateau,where a lot of Mesozoic marine shale formations developed.Based on the survey results of petroleum geology and comprehensive test analysis data for Qinghai-Tibet Plateau,for the first time,this paper discusses characteristics of sedimentary development,thickness distribution,geochemistry,reservoir and burial depth of organic-rich shale,and geological conditions for shale gas formation in Qiangtang Basin.There are four sets of marine shale strata in Qiangtang Basin including Upper Triassic Xiaochaka Formation (T3x),Middle Jurassic Buqu Formation (J2b),Xiali Formation (J2x) and Upper Jurassic Suowa Formation (J3s),the sedimentary types of which are mainly bathyal-basin facies,open platform-platform margin slope facies,lagoon and tidal-fiat facies,as well as delta facies.By comparing it with the indicators of gas shale in the main U.S.basins,it was found that the four marine shale formations in Qiangtang Basin constitute a multi-layer distribution of organic-rich shale,featuring a high degree of thickness and low abundance of organic matter,high thermal evolution maturity,many kinds of brittle minerals,an equivalent content of quartz and clay minerals,a high content of feldspar and low porosity,which provide basic conditions for an accumulation of shale gas resources.Xiaochaka Formation shale is widely distributed,with big thickness and the best gas generating indicators.It is the main gas source layer.Xiali Formation shale is of intermediate thickness and coverage area,with relatively good gas generating indicators and moderate gas formation potential.Buqu Formation shale and Suowa Formation shale are of relatively large thickness,and covering a small area,with poor gas generating indicators,and limited gas formation potential.The shale gas geological resources and technically recoverable resources were estimated by using geologic analogy method,and the prospective areas and potentially favorable areas for Mesozoic marine shale gas in Qiangtang Basin are forecast and analyzed.It is relatively favorable in a tectonic setting and indication of oil and gas,shale maturity,sedimentary thickness and gypsum-salt beds,and in terms of mineral association for shale gas accumulation.But the challenge lies in overcoming the harsh natural conditions which contributes to great difficulties in ground engineering and exploration,and high exploration costs.展开更多
The Qiangtang Basin of the Tibetan Plateau,located in the eastern Tethys tectonic domain,is the largest new marine petroliferous region for exploration in China.The scientific drilling project consisting primarily of ...The Qiangtang Basin of the Tibetan Plateau,located in the eastern Tethys tectonic domain,is the largest new marine petroliferous region for exploration in China.The scientific drilling project consisting primarily of well QK-1 and its supporting shallow boreholes for geological surveys(also referred to as the Project)completed in recent years contributes to a series of new discoveries and insights into the oil and gas preservation conditions and source rock evaluation of the Qiangtang Basin.These findings differ from previous views that the Qiangtang Basin has poor oil and gas preservation conditions and lacks high-quality source rocks.As revealed by well QK-1 and its supporting shallow boreholes in the Project,the Qiangtang Basin hosts two sets of high-quality regional seals,namely an anhydrite layer in the Quemo Co Formation and the gypsum-bearing mudstones in the Xiali Formation.Moreover,the Qiangtang Basin has favorable oil and gas preservation conditions,as verified by the comprehensive study of the sealing capacity of seals,basin structure,tectonic uplift,magmatic activity,and groundwater motion.Furthermore,the shallow boreholes have also revealed that the Qiangtang Basin has high-quality hydrocarbon source rocks in the Upper Triassic Bagong Formation,which are thick and widely distributed according to the geological and geophysical data.In addition,the petroleum geological conditions,such as the type,abundance,and thermal evolution of organic matter,indicate that the Qiangtang Basin has great hydrocarbon-generating potential.展开更多
Mesozoic marine shale oil was found in the Qiangtang Basin by a large number of hydrocarbon geological surveys and shallow drilling sampling.Based on systematic observation and experimental analysis of outcrop and cor...Mesozoic marine shale oil was found in the Qiangtang Basin by a large number of hydrocarbon geological surveys and shallow drilling sampling.Based on systematic observation and experimental analysis of outcrop and core samples,the deposition and development conditions and characteristics of marine shale are revealed,the geochemical and reservoir characteristics of marine shale are evaluated,and the layers of marine shale oil in the Mesozoic are determined.The following geological understandings are obtained.First,there are two sets of marine organic-rich shales,the Lower Jurassic Quse Formation and the Upper Triassic Bagong Formation,in the Qiangtang Basin.They are mainly composed of laminated shale with massive mudstone.The laminated organic-rich shale of the Quse Formation is located in the lower part of the stratum,with a thickness of 50–75 m,and mainly distributed in southern Qiangtang Basin and the central-west of northern Qiangtang Basin.The laminated organic-rich shale of the Bagong Formation is located in the middle of the stratum,with a thickness of 250–350 m,and distributed in both northern and southern Qiangtang Basin.Second,the two sets of laminated organic-rich shales develop foliation,and various types of micropores and microfractures.The average content of brittle minerals is 70%,implying a high fracturability.The average porosity is 5.89%,indicating good reservoir physical properties to the level of moderate–good shale oil reservoirs.Third,the organic-rich shale of the Quse Formation contains organic matters of types II1 and II2,with the average TOC of 8.34%,the average content of chloroform bitumen'A'of 0.66%,the average residual hydrocarbon generation potential(S1+S2)of 29.93 mg/g,and the Ro value of 0.9%–1.3%,meeting the standard of high-quality source rock.The organic-rich shale of the Bagong Formation contains mixed organic matters,with the TOC of 0.65%–3.10%and the Ro value of 1.17%–1.59%,meeting the standard of moderate source rock.Fourth,four shallow wells(depth of 50–250 m)with oil shows have been found in the organic shales at 50–90 m in the lower part of the Bagong Formation and 30–75 m in the middle part of the Quse Formation.The crude oil contains a high content of saturated hydrocarbon.Analysis and testing of outcrop and shallow well samples confirm the presence of marine shale oil in the Bagong Formation and the Quse Formation.Good shale oil intervals in the Bagong Formation are observed in layers 18–20 in the lower part of the section,where the shales with(S0+S1)higher than 1 mg/g are 206.7 m thick,with the maximum and average(S0+S1)of 1.92 mg/g and 1.81 mg/g,respectively.Good shale oil intervals in the Quse Formation are found in layers 4–8 in the lower part of the section,where the shales with(S0+S1)higher than 1 mg/g are 58.8 m thick,with the maximum and average(S0+S1)of 6.46 mg/g and 2.23 mg/g,respectively.展开更多
The largest Mesozoic northward transgression in Qangtang Basin of Qinghai-Xizang (Tibet) Plateau occurred during the Buqu Stage, Middle Jurassic. Mainly filled with carbonate rocks, the whole basin is composed of tran...The largest Mesozoic northward transgression in Qangtang Basin of Qinghai-Xizang (Tibet) Plateau occurred during the Buqu Stage, Middle Jurassic. Mainly filled with carbonate rocks, the whole basin is composed of transgression-regression sedimentary cycle. Field outcrops and indoor analysis revealed 8 types of sedimentary facies markers in this region. 4 types of sedimentary facies have been recognized: platform facies, platform marginal facies, foreslope facies and basin facies. Influenced by the northern Lazhuglung-Jinshajiang suture zone, central uplift region and southern Bangongco-Nujiang suture zone, these facies belts extended east-west. The sedimentary model was established based on observed depositional features. From their biological features and sedimentary characteristics, it is suggested that the paleoclimate was warm and humid at that time. The Buqu Formation is a promising target for oil and gas exploration in Shuanghu-Duoyong area in future.展开更多
探讨羌塘盆地南部古油气藏中侏罗统布曲组白云岩的成因机制。通过对布曲组岩心观察、岩石学研究及微区C、O、Sr同位素分析,确定布曲组白云岩包括保留先驱灰岩原始组构白云岩、晶粒白云岩和白云石充填物。其中保留先驱灰岩原始组构的白云...探讨羌塘盆地南部古油气藏中侏罗统布曲组白云岩的成因机制。通过对布曲组岩心观察、岩石学研究及微区C、O、Sr同位素分析,确定布曲组白云岩包括保留先驱灰岩原始组构白云岩、晶粒白云岩和白云石充填物。其中保留先驱灰岩原始组构的白云岩Sr同位素值与同期海水相似,C-O同位素值较同期灰岩偏正,属于准同生阶段高位体系域晚期局限环境中蒸发的咸化海水,高度过饱和的白云石化流体快速通过有利于原始组构的保存。晶粒白云石中分别由细晶自形白云石和细晶半自形白云石构成的白云岩Sr同位素值与同期海水相似,C-O同位素值较同期灰岩偏正,较保留先驱灰岩原始组构白云岩负偏,为浅埋藏阶段、高位体系域晚期局限环境中因蒸发咸化的海水回流或下渗扩散交代先驱灰岩而来,过度白云石化是形成细晶半自形白云石的主要原因。由中-粗晶他形白云石构成的白云岩形成于中-深埋藏阶段,Sr同位素值与同期海水相似;但O同位素值较前几种白云岩负偏,可能为早期白云石重结晶的结果;部分样品C同位素值与灰岩相似,可能为不彻底交代灰岩的结果;较高的成岩温度是晶体发生曲面化的主要原因。细-中晶自形-半自形白云石充填形成于浅埋藏阶段末期到中-深埋藏阶段初期,是化学沉淀或结晶作用的产物。鞍形白云石充填物Sr同位素值普遍高于同期海水,C同位素分布范围较宽,O同位素值比中-粗晶他形白云岩偏负,可能与早白垩世末期的剪切背景造成大气淡水下渗及64~78 Ma B.P.的构造热事件有关。展开更多
基金supported by the National Basic Research Program of China (Grant Nos.2011CB403003 and 2013CB956403)"Strategic Priority Research Program" of the Chinese Academy of Sciences (Grant No.XDB03020402)+1 种基金the National Natural Science Foundation of China (Grant No.41272128)the College Research Program of Gansu Province (Grant No.2016A-123)
文摘The Qiangtang Basin(QB), located in the central Tibetan Plateau, is a Jurassic marine basin and one of the most important prospective salt resource belts in China. In recent decades, many outcrops of gypsiferous bed have been found in the Jurassic marine strata in the basin. Salt springs with abnormally high sodium(Na-+) contents had been identified in the Late Jurassic Xiali Formation(Fm.) in the basin in the last years. However, to date, no potash or halite deposits have been identified in the QB. Gypsum outcrops and salt springs are very important signs in the investigation of halite and potash deposits. Therefore, the Xiali Fm. is a potentially valuable layer to evaluate for the possible presence of halite and potash deposits in the basin. However, few studies have explored the formation conditions of evaporites in the unit. Here, we present detailed geochemical records from the Yanshiping section related to the study of the formation conditions of evaporites in the Xiali Fm. of the QB. Climate proxies based on the obviously increased anion concentrations of SO4(2-) and Cl-- and the significant correlation coefficients of Ca2+-SO42-(R = 0.985) and Na-+-Cl--(R = 0.8974) reveal that the upper member of the Xiali Fm.(the upper Xiali Fm.) formed under an arid climate and evolved into the sulfate phase or early chloride phase. Provenance proxies based on the obviously increased K-+ and Na-+ ion concentrations and the significant correlation coefficient of Na-+-Cl--(R = 0.8974) suggest that the upper Xiali Fm. featured optimal provenance conditions for the possible formation of halite deposits. The regression and the semi-closed tidal flat environment in the upper Xiali Fm. were favorable for the formation of potash and halite deposits. The low Mg-(2+) /Ca-(2+) values(mean value = 1.82) and significant Na-+-Cl-- correlation coefficient(R = 0.8974) also suggest that the upper Xiali Fm. is the layer most likely to contain potential halite deposits. In addition, the macroscopic correlations of tectonism, provenance, paleoclimate, saliferous strata and sedimentary environment between the QB and the adjoining Amu Darya Basin in Central Asia reveal that the two basins shared similar geologic settings that were favorable for the formation of evaporites during the Late Jurassic. Therefore, the upper Xiali Fm. is a valuable layer to explore for halite deposit and may be potentially valuable in the future exploration for potash deposits in the QB.
基金co-funded by National Science and Technology Major Special Project (Grant No.2011ZX05018-001 and 2011ZX05028-002)PetroChina Co. Ltd. Project (Grant No.2011D-5002-02, 2014E-050202)
文摘The presence of shale gas has been confirmed in almost every marine shale distribution area in North America.Formation conditions of shale gas in China are the most favorable for marine,organic-rich shale as well.But there has been little research focusing on shale gas in Qiangtang Basin,Qinghai-Tibet Plateau,where a lot of Mesozoic marine shale formations developed.Based on the survey results of petroleum geology and comprehensive test analysis data for Qinghai-Tibet Plateau,for the first time,this paper discusses characteristics of sedimentary development,thickness distribution,geochemistry,reservoir and burial depth of organic-rich shale,and geological conditions for shale gas formation in Qiangtang Basin.There are four sets of marine shale strata in Qiangtang Basin including Upper Triassic Xiaochaka Formation (T3x),Middle Jurassic Buqu Formation (J2b),Xiali Formation (J2x) and Upper Jurassic Suowa Formation (J3s),the sedimentary types of which are mainly bathyal-basin facies,open platform-platform margin slope facies,lagoon and tidal-fiat facies,as well as delta facies.By comparing it with the indicators of gas shale in the main U.S.basins,it was found that the four marine shale formations in Qiangtang Basin constitute a multi-layer distribution of organic-rich shale,featuring a high degree of thickness and low abundance of organic matter,high thermal evolution maturity,many kinds of brittle minerals,an equivalent content of quartz and clay minerals,a high content of feldspar and low porosity,which provide basic conditions for an accumulation of shale gas resources.Xiaochaka Formation shale is widely distributed,with big thickness and the best gas generating indicators.It is the main gas source layer.Xiali Formation shale is of intermediate thickness and coverage area,with relatively good gas generating indicators and moderate gas formation potential.Buqu Formation shale and Suowa Formation shale are of relatively large thickness,and covering a small area,with poor gas generating indicators,and limited gas formation potential.The shale gas geological resources and technically recoverable resources were estimated by using geologic analogy method,and the prospective areas and potentially favorable areas for Mesozoic marine shale gas in Qiangtang Basin are forecast and analyzed.It is relatively favorable in a tectonic setting and indication of oil and gas,shale maturity,sedimentary thickness and gypsum-salt beds,and in terms of mineral association for shale gas accumulation.But the challenge lies in overcoming the harsh natural conditions which contributes to great difficulties in ground engineering and exploration,and high exploration costs.
基金funded by projects of the National Natural Science Foundation of China(91955204,42241202)the Second Tibetan Plateau Scientific Expedition and Research(2019QZKK080301)a project entitled Tectonics,Sedimentation,Evolution,and Basic Petroleum Geology of the Qiangtang Basin(2021DJ0801)of the Forward-looking Basic Subjects of PetroChina’s 14th Five-Year Plan.
文摘The Qiangtang Basin of the Tibetan Plateau,located in the eastern Tethys tectonic domain,is the largest new marine petroliferous region for exploration in China.The scientific drilling project consisting primarily of well QK-1 and its supporting shallow boreholes for geological surveys(also referred to as the Project)completed in recent years contributes to a series of new discoveries and insights into the oil and gas preservation conditions and source rock evaluation of the Qiangtang Basin.These findings differ from previous views that the Qiangtang Basin has poor oil and gas preservation conditions and lacks high-quality source rocks.As revealed by well QK-1 and its supporting shallow boreholes in the Project,the Qiangtang Basin hosts two sets of high-quality regional seals,namely an anhydrite layer in the Quemo Co Formation and the gypsum-bearing mudstones in the Xiali Formation.Moreover,the Qiangtang Basin has favorable oil and gas preservation conditions,as verified by the comprehensive study of the sealing capacity of seals,basin structure,tectonic uplift,magmatic activity,and groundwater motion.Furthermore,the shallow boreholes have also revealed that the Qiangtang Basin has high-quality hydrocarbon source rocks in the Upper Triassic Bagong Formation,which are thick and widely distributed according to the geological and geophysical data.In addition,the petroleum geological conditions,such as the type,abundance,and thermal evolution of organic matter,indicate that the Qiangtang Basin has great hydrocarbon-generating potential.
基金Supported by the PetroChina Science and Technology Major Project(2021DJ08)National Natural Science Foundation of China(42241203).
文摘Mesozoic marine shale oil was found in the Qiangtang Basin by a large number of hydrocarbon geological surveys and shallow drilling sampling.Based on systematic observation and experimental analysis of outcrop and core samples,the deposition and development conditions and characteristics of marine shale are revealed,the geochemical and reservoir characteristics of marine shale are evaluated,and the layers of marine shale oil in the Mesozoic are determined.The following geological understandings are obtained.First,there are two sets of marine organic-rich shales,the Lower Jurassic Quse Formation and the Upper Triassic Bagong Formation,in the Qiangtang Basin.They are mainly composed of laminated shale with massive mudstone.The laminated organic-rich shale of the Quse Formation is located in the lower part of the stratum,with a thickness of 50–75 m,and mainly distributed in southern Qiangtang Basin and the central-west of northern Qiangtang Basin.The laminated organic-rich shale of the Bagong Formation is located in the middle of the stratum,with a thickness of 250–350 m,and distributed in both northern and southern Qiangtang Basin.Second,the two sets of laminated organic-rich shales develop foliation,and various types of micropores and microfractures.The average content of brittle minerals is 70%,implying a high fracturability.The average porosity is 5.89%,indicating good reservoir physical properties to the level of moderate–good shale oil reservoirs.Third,the organic-rich shale of the Quse Formation contains organic matters of types II1 and II2,with the average TOC of 8.34%,the average content of chloroform bitumen'A'of 0.66%,the average residual hydrocarbon generation potential(S1+S2)of 29.93 mg/g,and the Ro value of 0.9%–1.3%,meeting the standard of high-quality source rock.The organic-rich shale of the Bagong Formation contains mixed organic matters,with the TOC of 0.65%–3.10%and the Ro value of 1.17%–1.59%,meeting the standard of moderate source rock.Fourth,four shallow wells(depth of 50–250 m)with oil shows have been found in the organic shales at 50–90 m in the lower part of the Bagong Formation and 30–75 m in the middle part of the Quse Formation.The crude oil contains a high content of saturated hydrocarbon.Analysis and testing of outcrop and shallow well samples confirm the presence of marine shale oil in the Bagong Formation and the Quse Formation.Good shale oil intervals in the Bagong Formation are observed in layers 18–20 in the lower part of the section,where the shales with(S0+S1)higher than 1 mg/g are 206.7 m thick,with the maximum and average(S0+S1)of 1.92 mg/g and 1.81 mg/g,respectively.Good shale oil intervals in the Quse Formation are found in layers 4–8 in the lower part of the section,where the shales with(S0+S1)higher than 1 mg/g are 58.8 m thick,with the maximum and average(S0+S1)of 6.46 mg/g and 2.23 mg/g,respectively.
基金Sponsored by National Ninth Five Year Plan Science and Technology Project (970204-01-01).
文摘The largest Mesozoic northward transgression in Qangtang Basin of Qinghai-Xizang (Tibet) Plateau occurred during the Buqu Stage, Middle Jurassic. Mainly filled with carbonate rocks, the whole basin is composed of transgression-regression sedimentary cycle. Field outcrops and indoor analysis revealed 8 types of sedimentary facies markers in this region. 4 types of sedimentary facies have been recognized: platform facies, platform marginal facies, foreslope facies and basin facies. Influenced by the northern Lazhuglung-Jinshajiang suture zone, central uplift region and southern Bangongco-Nujiang suture zone, these facies belts extended east-west. The sedimentary model was established based on observed depositional features. From their biological features and sedimentary characteristics, it is suggested that the paleoclimate was warm and humid at that time. The Buqu Formation is a promising target for oil and gas exploration in Shuanghu-Duoyong area in future.
文摘探讨羌塘盆地南部古油气藏中侏罗统布曲组白云岩的成因机制。通过对布曲组岩心观察、岩石学研究及微区C、O、Sr同位素分析,确定布曲组白云岩包括保留先驱灰岩原始组构白云岩、晶粒白云岩和白云石充填物。其中保留先驱灰岩原始组构的白云岩Sr同位素值与同期海水相似,C-O同位素值较同期灰岩偏正,属于准同生阶段高位体系域晚期局限环境中蒸发的咸化海水,高度过饱和的白云石化流体快速通过有利于原始组构的保存。晶粒白云石中分别由细晶自形白云石和细晶半自形白云石构成的白云岩Sr同位素值与同期海水相似,C-O同位素值较同期灰岩偏正,较保留先驱灰岩原始组构白云岩负偏,为浅埋藏阶段、高位体系域晚期局限环境中因蒸发咸化的海水回流或下渗扩散交代先驱灰岩而来,过度白云石化是形成细晶半自形白云石的主要原因。由中-粗晶他形白云石构成的白云岩形成于中-深埋藏阶段,Sr同位素值与同期海水相似;但O同位素值较前几种白云岩负偏,可能为早期白云石重结晶的结果;部分样品C同位素值与灰岩相似,可能为不彻底交代灰岩的结果;较高的成岩温度是晶体发生曲面化的主要原因。细-中晶自形-半自形白云石充填形成于浅埋藏阶段末期到中-深埋藏阶段初期,是化学沉淀或结晶作用的产物。鞍形白云石充填物Sr同位素值普遍高于同期海水,C同位素分布范围较宽,O同位素值比中-粗晶他形白云岩偏负,可能与早白垩世末期的剪切背景造成大气淡水下渗及64~78 Ma B.P.的构造热事件有关。