Carbide ceramic fibers are of significant importance for application in the high-tech areas of advanced aircraft engines,aerospace vehicles,and the nuclear industry due to their excellent properties,such as high tensi...Carbide ceramic fibers are of significant importance for application in the high-tech areas of advanced aircraft engines,aerospace vehicles,and the nuclear industry due to their excellent properties,such as high tensile strength and elastic modulus,excellent high-temperature resistance,and oxidation resistance.This paper reviews the preparation and application of different carbide ceramic fibers,including SiC fibers and transition metal carbide(e.g.,ZrC,HfC,and TaC)ceramic fibers.The preparation methods of carbide ceramic fibers are discussed in terms of different fiber diameters,represented by SiC fibers with variable weaving properties and functions due to their differences in diameter.Subsequently,the application of carbide ceramic fibers as high-temperature-resistant structural materials,catalyst carriers,sensors,and supercapacitors are summarized,and strategies for the future development of carbide ceramic fibers are proposed.This review aims to help researchers enhance their understanding of the preparation and utilization of carbide ceramic micro/nanofibers,advancing the development of high-performance carbide ceramic fibers.展开更多
In this work,pitch-based carbon fibers were utilized to reinforce silicon carbide(SiC)composites via reaction melting infiltration(RMI)method by controlling the reaction temperature and resin carbon content.Thermal co...In this work,pitch-based carbon fibers were utilized to reinforce silicon carbide(SiC)composites via reaction melting infiltration(RMI)method by controlling the reaction temperature and resin carbon content.Thermal conductivities and bending strengths of composites obtained under different preparation conditions were characterized by various analytical methods.Results showed the formation of SiC whiskers(SiC_(w))during RMI process according to vapor–solid(VS)mechanism.SiC_(w) played an important role in toughening the C_(pf)/SiC composites due to crack bridging,crack deflection,and SiC_(w) pull-out.Increase in reaction temperature during RMI process led to an initial increase in thermal conductivity along in-plane and thickness directions of composites,followed by a decline.At reaction temperature of 1600℃,thermal conductivities along the in-plane and thickness directions were estimated to be 203.00 and 39.59 W/(m×K),respectively.Under these conditions,bending strength was recorded as 186.15±3.95 MPa.Increase in resin carbon content before RMI process led to the generation of more SiC matrix.Thermal conductivities along in-plane and thickness directions remained stable with desirable values of 175.79 and 38.86 W/(m×K),respectively.By comparison,optimal bending strength improved to 244.62±3.07 MPa.In sum,these findings look promising for future application of pitch-based carbon fibers for reinforcement of SiC ceramic composites.展开更多
Using lower-cost lasers, 30% savings are possible for 10-Gb/s uncompensated metro transmission over NZDF, compared to G.652 fiber. We present WDM transmission results for a mixed plant of NZDF rings interconnected to ...Using lower-cost lasers, 30% savings are possible for 10-Gb/s uncompensated metro transmission over NZDF, compared to G.652 fiber. We present WDM transmission results for a mixed plant of NZDF rings interconnected to G.652.C-fiber access laterals.展开更多
Preparing antioxidant coatings to address the inherent oxidation sensitivity of carbon fiber-reinforced carbon aerogel(C/CA)composites is a feasible way to promote their application in oxidizing environments as therma...Preparing antioxidant coatings to address the inherent oxidation sensitivity of carbon fiber-reinforced carbon aerogel(C/CA)composites is a feasible way to promote their application in oxidizing environments as thermal insulation materials.However,preparing the coatings with excellent oxidation and ablation resistance while avoiding evident damage to the C/CA substrate still remains a challenge.Herein,a SiC@SiO_(2)nanowire-toughened ZrB2–SiC/SiC bilayer coating with a large thickness of 500μm was prepared on C/CA using a one-step low-temperature reaction sintering method,which simultaneously formed a sintered outer layer with even-distributed nanowires and a siliconized gradient inner layer.By courtesy of the synergic thermal response of the layers and the crack deflection induced by the nanowires,the resulting coating has moderate residual compressive stress of 0.08–1.22 GPa in the interface,high interfacial bonding strength of 6.02 MPa,and good fracture toughness of 4.36 MPa·m^(1/2).Benefited from the optimum components and improved structure,the coating shows excellent cyclic ablation resistance with linear ablation rates of 0.1μm/s at 1650℃for 1500 s(300 s×5 cycles)and 0.4μm/s at 1850℃for 900 s(300 s×3 cycles).The one-step preparation strategy contributes to little damage to the substrate,thus showing the well-preserved mechanical and thermal insulation properties.展开更多
Phospholipase C (PLC) are important regulatory enzymes involved in several lipid and Ca2+-dependent signaling pathways.Previous studies have elucidated the versatile roles of PLC genes in growth, development and stres...Phospholipase C (PLC) are important regulatory enzymes involved in several lipid and Ca2+-dependent signaling pathways.Previous studies have elucidated the versatile roles of PLC genes in growth, development and stress responses of many plants, however, the systematic analyses of PLC genes in the important fiber-producing plant, cotton, are still deficient. In this study,through genome-wide survey, we identified twelve phosphatidylinositol-specific PLC (PI-PLC) and nine non-specific PLC (NPC) genes in the allotetraploid upland cotton Gossypium hirsutum and nine PI-PLC and six NPC genes in two diploid cotton G. arboretum and G.raimondii, respectively. The PI-PLC and NPC genes of G. hirsutum showed close phylogenetic relationship with their homologous genes in the diploid cottons and Arabidopsis. Segmental and tandem duplication contributed greatly to the formation of the gene family. Expression profiling indicated that few of the PLC genes are constitutely expressed, whereas most of the PLC genes are preferentially expressed in specific tissues and abiotic stress conditions. Promoter analyses further implied that the expression of these PLC genes might be regulated by MYB transcription factors and different phytohormones.These results not only suggest an important role of phospholipase C members in cotton plant development and abiotic stress response but also provide good candidate targets for future molecular breeding of superior cotton cultivars.展开更多
The animal experiment of viscose carbon fiber based C/C composites applied in bone defection intramedullary fixation was carried out in New Zealand white rabbits.The histological observation on the 100th day after sur...The animal experiment of viscose carbon fiber based C/C composites applied in bone defection intramedullary fixation was carried out in New Zealand white rabbits.The histological observation on the 100th day after surgical operation indicated that the experimental animals recovered well and the bone defect area was reconstructed by new bone trabecula.Immunohistochemical observation of leukocyte common antigen and macrophage suggested that intramedullary fixation materials did not induct any chronic toxicity reactions such as inflammatory reactions,macrophage reactions and formation of granulation tissue.The tissue compatibility of this material was excellent.Meanwhile,the impurity element species and the biological toxic element content of viscose fiber based C/C composites were determined by atomic fluorescence analyzer and inductively coupled plasma atomic emission spectrometry.The results reveal that there are few biological toxic elements in the viscose fiber based C/C composites and it can satisfy the constituent demands of surgical implants.展开更多
Oxidation behaviors of carbon fiber reinforced SiC matrix composites(C/SiC)are one of the most noteworthy properties.For C/SiC,the oxidation behavior was controlled by matrix microcracks caused by the mismatch of coef...Oxidation behaviors of carbon fiber reinforced SiC matrix composites(C/SiC)are one of the most noteworthy properties.For C/SiC,the oxidation behavior was controlled by matrix microcracks caused by the mismatch of coefficients of thermal expansion(CTEs)and elastic modulus between carbon fiber and SiC matrix.In order to improve the oxidation resistance,multilayer SiC–Si_(3)N_(4) matrices were fabricated by chemical vapor infiltration(CVI)to alleviate the above two kinds of mismatch and change the local stress distribution.For the oxidation of C/SiC with multilayer matrices,matrix microcracks would be deflected at the transition layer between different layers of multilayer SiC–Si_(3)N_(4) matrix to lengthen the oxygen diffusion channels,thereby improving the oxidation resistance of C/SiC,especially at 800 and 1000℃.The strength retention ratio was increased from 61.9%(C/SiC–SiC/SiC)to 75.7%(C/SiC–Si_(3)N_(4)/SiC/SiC)and 67.8%(C/SiC–SiC/Si_(3)N_(4)/SiC)after oxidation at 800℃for 10 h.展开更多
We have given design of a very small residual dispersion fiber system consisting of a small dispersion fiber (SDF) with flat modal field and a corresponding dual core coaxial dispersion compensating fiber (DCF).
基金support from the National Natural Science Foundation of China(No.52272100)the Natural Science Foundation of Hunan Province(No.2022JJ30662)the Science and Technology on Advanced Ceramic Fibers and Composites Laboratory(No.WDZC20215250507).
文摘Carbide ceramic fibers are of significant importance for application in the high-tech areas of advanced aircraft engines,aerospace vehicles,and the nuclear industry due to their excellent properties,such as high tensile strength and elastic modulus,excellent high-temperature resistance,and oxidation resistance.This paper reviews the preparation and application of different carbide ceramic fibers,including SiC fibers and transition metal carbide(e.g.,ZrC,HfC,and TaC)ceramic fibers.The preparation methods of carbide ceramic fibers are discussed in terms of different fiber diameters,represented by SiC fibers with variable weaving properties and functions due to their differences in diameter.Subsequently,the application of carbide ceramic fibers as high-temperature-resistant structural materials,catalyst carriers,sensors,and supercapacitors are summarized,and strategies for the future development of carbide ceramic fibers are proposed.This review aims to help researchers enhance their understanding of the preparation and utilization of carbide ceramic micro/nanofibers,advancing the development of high-performance carbide ceramic fibers.
基金Supported by National Basic Research Program of China grant(to Zhu B),No.2011CB505201National Natural Science Foundation of China No.81130063 and No.81173345(to Zhu B and Gao X)
文摘AIM: To investigate the effect and mechanism of acupuncture at heterotopic acupoints on jejunal motility, particularly in pathological conditions.
基金This work is supported by the National Key R&D Program of China(No.2018YFB1106600)the National Natural Science Foundation of China(Nos.51602257,92060202,51872229,and 51972269)+2 种基金the State Key Laboratory of Advanced Technology for Materials Synthesis and Processing(Wuhan University of Technology,No.2021-KF-10)the Creative Research Foundation of the Science and Technology on Thermostructural Composite Materials Laboratory(No.JCKYS2020607001)the Shaanxi Province Foundation for Natural Science(No.2020JQ-169).
文摘In this work,pitch-based carbon fibers were utilized to reinforce silicon carbide(SiC)composites via reaction melting infiltration(RMI)method by controlling the reaction temperature and resin carbon content.Thermal conductivities and bending strengths of composites obtained under different preparation conditions were characterized by various analytical methods.Results showed the formation of SiC whiskers(SiC_(w))during RMI process according to vapor–solid(VS)mechanism.SiC_(w) played an important role in toughening the C_(pf)/SiC composites due to crack bridging,crack deflection,and SiC_(w) pull-out.Increase in reaction temperature during RMI process led to an initial increase in thermal conductivity along in-plane and thickness directions of composites,followed by a decline.At reaction temperature of 1600℃,thermal conductivities along the in-plane and thickness directions were estimated to be 203.00 and 39.59 W/(m×K),respectively.Under these conditions,bending strength was recorded as 186.15±3.95 MPa.Increase in resin carbon content before RMI process led to the generation of more SiC matrix.Thermal conductivities along in-plane and thickness directions remained stable with desirable values of 175.79 and 38.86 W/(m×K),respectively.By comparison,optimal bending strength improved to 244.62±3.07 MPa.In sum,these findings look promising for future application of pitch-based carbon fibers for reinforcement of SiC ceramic composites.
文摘Using lower-cost lasers, 30% savings are possible for 10-Gb/s uncompensated metro transmission over NZDF, compared to G.652 fiber. We present WDM transmission results for a mixed plant of NZDF rings interconnected to G.652.C-fiber access laterals.
基金the Defense Industrial Technology Development Program(No.JCKY2021130B007)the National Natural Science Foundation of China(Nos.52272075 and 52188101)+1 种基金the Research Fund of Youth Innovation Promotion Association of Chinese Academy of Sciences(No.2021190)the directional institutionalized scientific research platform relies on China Spallation Neutron Source of Chinese Academy of Sciences,and the National Key R&D Program of China(No.2021YFA1500804).
文摘Preparing antioxidant coatings to address the inherent oxidation sensitivity of carbon fiber-reinforced carbon aerogel(C/CA)composites is a feasible way to promote their application in oxidizing environments as thermal insulation materials.However,preparing the coatings with excellent oxidation and ablation resistance while avoiding evident damage to the C/CA substrate still remains a challenge.Herein,a SiC@SiO_(2)nanowire-toughened ZrB2–SiC/SiC bilayer coating with a large thickness of 500μm was prepared on C/CA using a one-step low-temperature reaction sintering method,which simultaneously formed a sintered outer layer with even-distributed nanowires and a siliconized gradient inner layer.By courtesy of the synergic thermal response of the layers and the crack deflection induced by the nanowires,the resulting coating has moderate residual compressive stress of 0.08–1.22 GPa in the interface,high interfacial bonding strength of 6.02 MPa,and good fracture toughness of 4.36 MPa·m^(1/2).Benefited from the optimum components and improved structure,the coating shows excellent cyclic ablation resistance with linear ablation rates of 0.1μm/s at 1650℃for 1500 s(300 s×5 cycles)and 0.4μm/s at 1850℃for 900 s(300 s×3 cycles).The one-step preparation strategy contributes to little damage to the substrate,thus showing the well-preserved mechanical and thermal insulation properties.
基金supported by the State Key Basic Research and Development Plan (2010CB126003)the National Transgenic Animals and Plants Research Project (2011ZX08005-003, 2011ZX08009-003)
文摘Phospholipase C (PLC) are important regulatory enzymes involved in several lipid and Ca2+-dependent signaling pathways.Previous studies have elucidated the versatile roles of PLC genes in growth, development and stress responses of many plants, however, the systematic analyses of PLC genes in the important fiber-producing plant, cotton, are still deficient. In this study,through genome-wide survey, we identified twelve phosphatidylinositol-specific PLC (PI-PLC) and nine non-specific PLC (NPC) genes in the allotetraploid upland cotton Gossypium hirsutum and nine PI-PLC and six NPC genes in two diploid cotton G. arboretum and G.raimondii, respectively. The PI-PLC and NPC genes of G. hirsutum showed close phylogenetic relationship with their homologous genes in the diploid cottons and Arabidopsis. Segmental and tandem duplication contributed greatly to the formation of the gene family. Expression profiling indicated that few of the PLC genes are constitutely expressed, whereas most of the PLC genes are preferentially expressed in specific tissues and abiotic stress conditions. Promoter analyses further implied that the expression of these PLC genes might be regulated by MYB transcription factors and different phytohormones.These results not only suggest an important role of phospholipase C members in cotton plant development and abiotic stress response but also provide good candidate targets for future molecular breeding of superior cotton cultivars.
基金the Fundamental Research Funds for the Central Universities of China(No.11CX04033A)the Postdoctoral Innovation Projection of Shandong Province(No.201103085)
文摘The animal experiment of viscose carbon fiber based C/C composites applied in bone defection intramedullary fixation was carried out in New Zealand white rabbits.The histological observation on the 100th day after surgical operation indicated that the experimental animals recovered well and the bone defect area was reconstructed by new bone trabecula.Immunohistochemical observation of leukocyte common antigen and macrophage suggested that intramedullary fixation materials did not induct any chronic toxicity reactions such as inflammatory reactions,macrophage reactions and formation of granulation tissue.The tissue compatibility of this material was excellent.Meanwhile,the impurity element species and the biological toxic element content of viscose fiber based C/C composites were determined by atomic fluorescence analyzer and inductively coupled plasma atomic emission spectrometry.The results reveal that there are few biological toxic elements in the viscose fiber based C/C composites and it can satisfy the constituent demands of surgical implants.
基金This work was supported by the National Natural Science Foundation of China(Nos.52072303 and 51821091)the National Science and Technology Major Project(No.J2019-VI-0014-0129)。
文摘Oxidation behaviors of carbon fiber reinforced SiC matrix composites(C/SiC)are one of the most noteworthy properties.For C/SiC,the oxidation behavior was controlled by matrix microcracks caused by the mismatch of coefficients of thermal expansion(CTEs)and elastic modulus between carbon fiber and SiC matrix.In order to improve the oxidation resistance,multilayer SiC–Si_(3)N_(4) matrices were fabricated by chemical vapor infiltration(CVI)to alleviate the above two kinds of mismatch and change the local stress distribution.For the oxidation of C/SiC with multilayer matrices,matrix microcracks would be deflected at the transition layer between different layers of multilayer SiC–Si_(3)N_(4) matrix to lengthen the oxygen diffusion channels,thereby improving the oxidation resistance of C/SiC,especially at 800 and 1000℃.The strength retention ratio was increased from 61.9%(C/SiC–SiC/SiC)to 75.7%(C/SiC–Si_(3)N_(4)/SiC/SiC)and 67.8%(C/SiC–SiC/Si_(3)N_(4)/SiC)after oxidation at 800℃for 10 h.
文摘We have given design of a very small residual dispersion fiber system consisting of a small dispersion fiber (SDF) with flat modal field and a corresponding dual core coaxial dispersion compensating fiber (DCF).