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Biological Decolorization of C.I. Basic Green 4 Solution by Chlorella sp.: Effect of Operational Parameters
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作者 Khataee A. R. Pourhassan M. Ayazloo M. 《应用与环境生物学报》 CAS CSCD 北大核心 2009年第1期110-114,共5页
In recent years, the ability of microorganisms to decolorize textile wastewater has received great attention due to the environmental persistence and toxicity of these pollutants. In this paper biological decolorizati... In recent years, the ability of microorganisms to decolorize textile wastewater has received great attention due to the environmental persistence and toxicity of these pollutants. In this paper biological decolorization of triphenylmethane dye, C.I. Basic Green 4 (BG 4), by Chlorella species was investigated. The effect of operational parameters (temperature, pH, initial dye concentration and algal concentration) on decolorization efficiency was examined. Results indicated that the desired initial pH was 9. The stability and efficiency of the algae in long-term repetitive operations were also examined. Michaelis–Menten kinetics was employed to describe the apparent correlation between the decolorization rate and dye concentration. The optimal kinetic parameters, νmax (specific decolorization rate) and Km (maximum specific decolorization rate) were 4.6 mg dye g cell-1 h-1 and 151.0 mg L-1, respectively. 展开更多
关键词 绿藻 植物 环境保护 水处理 生物技术
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Experimental Investigation of the Flame Propagation and Flashback Behavior of a Green Propellant Consisting of N2O and C2H4 被引量:6
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作者 Lukas Werling Felix Lauck +3 位作者 Dominic Freudenmann Nicole Rocke Helmut Ciezki Stefan Schlechtriem 《Journal of Energy and Power Engineering》 2017年第12期735-752,共18页
Regarding the research on alternatives for monopropellant hydrazine, several so called green propellants are currently under investigation or qualification. Aside others, the DLR Institute of Space Propulsion investig... Regarding the research on alternatives for monopropellant hydrazine, several so called green propellants are currently under investigation or qualification. Aside others, the DLR Institute of Space Propulsion investigates a N20/C2I-I4 premixed green propellant. During the research activities, flashback from the rocket combustion chamber into the feeding system has been identified as a major challenge when using the propellant mixture. This paper shows the results of ignition experiments conducted in a cylindrical, optical accessible ignition chamber. During the ignition and flame propagation process, pressure, temperature and high-speed video data were collected. The high speed video data were used to analyze the flame propagation speed. The obtained propagation speed was about 20 rn/s at ignition, while during further propagation of the flame speeds of up to 120 m/s were measured. Additionally, two different porous materials as flame arresting elements were tested: Porous stainless steel and porous bronze material. For both materials Peclet numbers for flashback were derived. The critical Peclet number for the sintered bronze material was around 20, while for the sintered stainless steel the critical Peclet number seems to be larger than 40. Due to the test results, sintered porous materials seem to be suitable as flashback arresters. 展开更多
关键词 green rocket propellants ignition flame flashback N2O C2H4 premixed gases flashback an'esters porous materials.
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氯硫共掺杂氮化碳的制备及其光催化性能
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作者 景张欣 宗刚 +2 位作者 高存 任敬 谢涛 《功能材料》 北大核心 2025年第1期1200-1208,共9页
以三聚氰胺为前驱体,氯化铵为Cl源,硫脲为S源,采用直接热聚合法制备了Cl、S共掺杂石墨相氮化碳(g-C3N4),考察了氯硫掺杂对g-C3N4结构和光催化性能的影响。利用X射线衍射(XRD)、傅里叶红外光谱(FTIR)、扫描电镜(SEM)、X射线光电子能谱(X... 以三聚氰胺为前驱体,氯化铵为Cl源,硫脲为S源,采用直接热聚合法制备了Cl、S共掺杂石墨相氮化碳(g-C3N4),考察了氯硫掺杂对g-C3N4结构和光催化性能的影响。利用X射线衍射(XRD)、傅里叶红外光谱(FTIR)、扫描电镜(SEM)、X射线光电子能谱(XPS)、比表面积和孔径分布(BET)、紫外-可见光(UV-Vis)等手段对样品进行了表征和分析,研究了催化剂投加量、PH以及底物浓度对光催化降解碱性红18(BR18)的影响。结果表明,当氯化铵掺入量为0.4 g,硫脲掺入量为1 g时,ClSCN2的光催化性能最优。催化剂投加量为40 mg,pH=10,底物浓度为5 mg/L时,在120 min内对BR 18的降解率达到92.6%。自由基捕获实验表明,光降解过程中主要的活性物质是·O-2和·OH。Cl和S两种杂原子的掺杂扩大了g-C3N4的比表面积,为光催化提供了更多的活性位点。同时Cl和S的掺杂代替了g-C3N4中的N,使之产生N缺陷,提高了光生电子和空穴的分离。 展开更多
关键词 石墨相氮化碳 氯硫共掺杂 光催化 碱性红18
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现代市场营销学的新发展 被引量:1
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作者 刘志超 《华南理工大学学报(自然科学版)》 EI CAS CSCD 北大核心 1997年第4期55-58,共4页
本文介绍了现代市场营销的4个发展方向:创造需求、大市场营销、4C营销和绿色营销。并分别就其与传统市场营销相比的特点、对现代市场营销的贡献进行了分析探讨和评价。
关键词 创造需求 大市场营销 4C营销 绿色营销
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The association between paired basic amino acid cleaving enz yme 4 gene haplotype and diastolic blood pressure 被引量:1
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作者 李建平 王晓滨 +5 位作者 陈常忠 徐新 洪雪梅 徐希平 高炜 霍勇 《Chinese Medical Journal》 SCIE CAS CSCD 2004年第3期382-388,共7页
Background In a previously identified locus linked to hypertension on chromosome 15q, we identified three blood pressure candidate genes: insulin-like growth factor 1 receptor gene (IGF1R), myocyte specific enhancer f... Background In a previously identified locus linked to hypertension on chromosome 15q, we identified three blood pressure candidate genes: insulin-like growth factor 1 receptor gene (IGF1R), myocyte specific enhancer factor 2A gene (MEF2A), and paired basic amino acid cleaving enzyme 4 gene (PACE4). In this study, we te sted their associations with hypertension using haplotype analysis.Methods A total of 288 unrelated individuals, including 163 high diastolic blood pressure (DBP) subjects and 125 normal DBP subjects were enrolled in this case-control study. Twenty single nucleotide polymorphisms (SNPs) in the three genes were genotyped using polymerase chain reaction followed by restriction enzyme digestion. Haplotype analysis was accomplished in the following stages: (1) pair-wise linkage disequilibrium test among SNPs on the same gene was performed to explore blocks in which recombination is very unlikely to happen; (2) Estimation-Maximization algorithm was applied to estimate haplotype frequencies in each block; (3) the chi-square test was used to examine the specific haplotype difference, and a permutation test was used to examine the overall haplotype profile difference between cases and controls in each block.Results An estimated haplotype “CCCCG” frequency in the haplotype block on the PACE4 gene was significantly higher in high DBP cases than in controls (P<0.01). The overall estimated haplotype profile in this block was also significantly different between the cases and the controls (P<0 .001). This association indicates. Conclusions This study for the first time demonstrated that PAC E4 gene may play an important role in the regulation of DBP. This association indicates that variations influencing DBP resides in or near this genomic region. 展开更多
关键词 hypertension · paired basic amino acid c leaving enzyme 4 · haplotypes
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碱性离子液体催化“一锅法”合成1,4-二氢吡喃并[2,3-c]吡唑 被引量:4
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作者 李晓君 郭红云 《有机化学》 SCIE CAS CSCD 北大核心 2012年第1期127-132,共6页
在碱性离子液体氢氧化1-丁基-3-甲基咪唑([bmim]OH)催化作用下,由芳香醛、丙二腈、苯甲酰乙酸乙酯和肼或苯肼"一锅法"合成了一系列1,4-二氢吡喃并[2,3-c]吡唑化合物.实验中考察了催化剂、反应温度、催化剂用量、溶剂对反应的... 在碱性离子液体氢氧化1-丁基-3-甲基咪唑([bmim]OH)催化作用下,由芳香醛、丙二腈、苯甲酰乙酸乙酯和肼或苯肼"一锅法"合成了一系列1,4-二氢吡喃并[2,3-c]吡唑化合物.实验中考察了催化剂、反应温度、催化剂用量、溶剂对反应的影响,确定了最优反应条件,给出了可能的反应机理.此外催化剂可以方便地收回,且循环使用四次其催化活性并没有显著降低.目标产物经过了1H NMR,IR,MS和元素分析确证.合成方法条件温和、反应时间短、产率高且对环境友好. 展开更多
关键词 碱性离子液体 一锅法 1 4-二氢吡喃并[2 3-c]吡唑化合物
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牛黄消炎片中孔雀石绿的检测方法研究 被引量:4
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作者 何风艳 何轶 +3 位作者 余新启 宿威 戴忠 鲁静 《药物分析杂志》 CAS CSCD 北大核心 2014年第4期698-701,共4页
目的:建立牛黄消炎片中孔雀石绿的检测方法。方法:采用HPLC法鉴别和定量,使用Phenomenon Gemini C18色谱柱(250mm×4.6mm,5μm),以乙腈-0.05mol·L^-1醋酸铵溶液(冰醋酸调pH4.5)(40:60)为流动相,流速1mL·m... 目的:建立牛黄消炎片中孔雀石绿的检测方法。方法:采用HPLC法鉴别和定量,使用Phenomenon Gemini C18色谱柱(250mm×4.6mm,5μm),以乙腈-0.05mol·L^-1醋酸铵溶液(冰醋酸调pH4.5)(40:60)为流动相,流速1mL·min^-1,检测波长618nm;采用HPLC—MS/MS法验证,以乙腈-5mmol·L^-1醋酸铵溶液(冰醋酸调pH4.5)(40:60)为流动相.电喷雾离子化源,正离子检测方式,对孔雀石绿的准分子离子峰m/z329[M—Cl]^+进行选择离子监测及二级全扫描质谱分析。结果:HPLC鉴别方法分离良好,检出限在0.03μg·mL^-1;阳性样品的选择离子监测图及二级全扫描质谱图与孔雀石绿对照品一致;含量测定方法在0.33~7.85μg·mL^-1线性关系良好,平均回收率为99.3%。结论:本方法专属性强,结果准确,可用于牛黄消炎片中孔雀石绿的定性、定量检测。 展开更多
关键词 牛黄消炎片 孔雀石绿 苯胺绿 碱性绿 化工染料 液相色谱法 液相色谱-质谱联用 染色检测 中成药质量控制
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