To synthesize and study the relation between structure and characteristics of Co-Cbond of coenzym B<sub>12</sub> model compounds, it is an effective way to understand the fac-tors which can influence the s...To synthesize and study the relation between structure and characteristics of Co-Cbond of coenzym B<sub>12</sub> model compounds, it is an effective way to understand the fac-tors which can influence the stabilities of Co-C bond and the mechanism of mutasecatalyzed substrate rearrangement. Unfortunately knowledge about micro reaction mecha-nism of the model compounds is limited. W. N. Lipscomb calculated the展开更多
基金Project supported by the National Natural Science Foundation of China.
文摘To synthesize and study the relation between structure and characteristics of Co-Cbond of coenzym B<sub>12</sub> model compounds, it is an effective way to understand the fac-tors which can influence the stabilities of Co-C bond and the mechanism of mutasecatalyzed substrate rearrangement. Unfortunately knowledge about micro reaction mecha-nism of the model compounds is limited. W. N. Lipscomb calculated the