In this paper we investigate the influence of microstructure on the CH4 adsorption behavior of deep coal. The coal microstructure is characterized by N2 adsorption at 77 K, scanning electron microscopy （SEM）, Raman ...In this paper we investigate the influence of microstructure on the CH4 adsorption behavior of deep coal. The coal microstructure is characterized by N2 adsorption at 77 K, scanning electron microscopy （SEM）, Raman spectroscopy, and Fourier transform infrared spectroscopy （FT-IR）. The CH4 adsorptions are measured at 298 K at pressures up to 5.0 MPa by the the volumetric method and fitted by the Langmuir model. The results show that the Langmuir model fits well with the experimental data, and there is a positive correlation with surface area, pore volume, ID/IG, and CH4 adsorption capacity. The burial depth also affects the methane adsorption capacity of the samples.展开更多
基金Project supported by the National Basic Research Program of China (Grant No.2011CB201202)
文摘In this paper we investigate the influence of microstructure on the CH4 adsorption behavior of deep coal. The coal microstructure is characterized by N2 adsorption at 77 K, scanning electron microscopy （SEM）, Raman spectroscopy, and Fourier transform infrared spectroscopy （FT-IR）. The CH4 adsorptions are measured at 298 K at pressures up to 5.0 MPa by the the volumetric method and fitted by the Langmuir model. The results show that the Langmuir model fits well with the experimental data, and there is a positive correlation with surface area, pore volume, ID/IG, and CH4 adsorption capacity. The burial depth also affects the methane adsorption capacity of the samples.
