A homogeneous better-dispersed ultrathin nanosheets（ca. 5 nm） of cobalt-nickel layered double hydroxides（LDH） supported on nickel foam scaffold was synthesized using controllable electrodeposition approach for hig...A homogeneous better-dispersed ultrathin nanosheets（ca. 5 nm） of cobalt-nickel layered double hydroxides（LDH） supported on nickel foam scaffold was synthesized using controllable electrodeposition approach for high efficiency electrode materials of new supercapacitor. The morphology and electrochemical performances of the samples can be controlled by adjusting the precursor ratio, i.e., Ni（OAc）2/Co（NO3）2 molar ratio in the electrodeposition approach. With the increase of this molar ratio, the electrochemical performances give a volcano trend. When the optimized molar ratio is 0.64/0.36, the hybrid delivered a high specific capacitance of 1587.5 F g-1 at a current density of 0.5 A g-1, with good rate capability（1155 F g-1 was retained even at 10 A g-1） and a robust recycle stability（remaining 91.5% after 1000 cycles at 5 A g-1）. The good performance could be attributed to the enlarged interlayer spacing, ultrathin nanosheets and synergistic effects between Co（OH）2 and Ni（OH）2. Furthermore, an asymmetric supercapacitor with a high energy density of 34.5 Wh kg-1 at 425 W kg-1 and excellent cycling stability of 85.4% after 5000 charge-discharge cycles at 2 A g-1 was fabricated. We believe that this fantabulous new electrode material would have encouraging applications in electrochemical energy storage and a wide readership.展开更多
The cobalt precursor affects the catalytic performance of Co/SiO_2 catalyst remarkably. The catalyst prepared from cobalt acetate exhibits excellent activity, stability and resistance to carbon deposition.
基金supported by the National Natural Science Foundation of China (21476145)
文摘A homogeneous better-dispersed ultrathin nanosheets（ca. 5 nm） of cobalt-nickel layered double hydroxides（LDH） supported on nickel foam scaffold was synthesized using controllable electrodeposition approach for high efficiency electrode materials of new supercapacitor. The morphology and electrochemical performances of the samples can be controlled by adjusting the precursor ratio, i.e., Ni（OAc）2/Co（NO3）2 molar ratio in the electrodeposition approach. With the increase of this molar ratio, the electrochemical performances give a volcano trend. When the optimized molar ratio is 0.64/0.36, the hybrid delivered a high specific capacitance of 1587.5 F g-1 at a current density of 0.5 A g-1, with good rate capability（1155 F g-1 was retained even at 10 A g-1） and a robust recycle stability（remaining 91.5% after 1000 cycles at 5 A g-1）. The good performance could be attributed to the enlarged interlayer spacing, ultrathin nanosheets and synergistic effects between Co（OH）2 and Ni（OH）2. Furthermore, an asymmetric supercapacitor with a high energy density of 34.5 Wh kg-1 at 425 W kg-1 and excellent cycling stability of 85.4% after 5000 charge-discharge cycles at 2 A g-1 was fabricated. We believe that this fantabulous new electrode material would have encouraging applications in electrochemical energy storage and a wide readership.
文摘The cobalt precursor affects the catalytic performance of Co/SiO_2 catalyst remarkably. The catalyst prepared from cobalt acetate exhibits excellent activity, stability and resistance to carbon deposition.
