In the intricate network environment,the secure transmission of medical images faces challenges such as information leakage and malicious tampering,significantly impacting the accuracy of disease diagnoses by medical ...In the intricate network environment,the secure transmission of medical images faces challenges such as information leakage and malicious tampering,significantly impacting the accuracy of disease diagnoses by medical professionals.To address this problem,the authors propose a robust feature watermarking algorithm for encrypted medical images based on multi-stage discrete wavelet transform(DWT),Daisy descriptor,and discrete cosine transform(DCT).The algorithm initially encrypts the original medical image through DWT-DCT and Logistic mapping.Subsequently,a 3-stage DWT transformation is applied to the encrypted medical image,with the centre point of the LL3 sub-band within its low-frequency component serving as the sampling point.The Daisy descriptor matrix for this point is then computed.Finally,a DCT transformation is performed on the Daisy descriptor matrix,and the low-frequency portion is processed using the perceptual hashing algorithm to generate a 32-bit binary feature vector for the medical image.This scheme utilises cryptographic knowledge and zero-watermarking technique to embed watermarks without modifying medical images and can extract the watermark from test images without the original image,which meets the basic re-quirements of medical image watermarking.The embedding and extraction of water-marks are accomplished in a mere 0.160 and 0.411s,respectively,with minimal computational overhead.Simulation results demonstrate the robustness of the algorithm against both conventional attacks and geometric attacks,with a notable performance in resisting rotation attacks.展开更多
The catalytic descriptor with operational feasibility is highly desired towards rational design of high-performance catalyst especially the electrode/electrolyte solution interface working under mild conditions.Herein...The catalytic descriptor with operational feasibility is highly desired towards rational design of high-performance catalyst especially the electrode/electrolyte solution interface working under mild conditions.Herein,we demonstrate that the descriptorΩparameterized by readily accessible intrinsic properties of metal center and coordination is highly operational and efficient in rational design of single-atom catalyst(SAC)for driving electrochemical nitrogen reduction(NRR).Using twodimensional metal(M)-B_(x)P_(y)S_(z)N_m@C_(2)N as prototype SAC models,we reveal that^(*)N_(2)+(H~++e~-)→^(*)N_(2)H acts predominantly as the potential-limiting step(PLS)of NRR on M-B_(2)P_(2)S_(2)@C_(2)N and M-B_(1)P_(1)S_(1)N_(3)@C_(2)N regardless of the distinction in coordination microenvironment.Among the 28 screened M active sites,withΩvalues close to the optimal 4,M-B_(2)P_(2)S_(2)@C_(2)N(M=V(Ω=3.53),Mo(Ω=5.12),and W(Ω=3.92))and M-B_(1)P_(1)S_(1)N_(3)@C_(2)N(M=V(Ω=3.00),Mo(Ω=4.34),and W(Ω=3.32))yield the lowered limiting potential(U_(L))as-0.45,-0.54.-0.36,-0.58,-0.25,and-0.24 V,respectively,thus making them the promising NRR catalysts.More importantly,these SACs are located around the top of volcano-shape plot of U_(L) versusΩ,re-validatingΩas an effective descriptor for accurately predicting the high-activity NRR SACs even with complex coordination.Our study unravels the relationship between active-site structure and NRR performance via the descriptorΩ,which can be applied to other important sustainable electrocatalytic reactions involving activation of small molecules viaσ-donation andπ^(*)-backdonation mechanism.展开更多
To address the current issues of inaccurate segmentation and the limited applicability of segmentation methods for building facades in point clouds, we propose a facade segmentation algorithm based on optimal dual-sca...To address the current issues of inaccurate segmentation and the limited applicability of segmentation methods for building facades in point clouds, we propose a facade segmentation algorithm based on optimal dual-scale feature descriptors. First, we select the optimal dual-scale descriptors from a range of feature descriptors. Next, we segment the facade according to the threshold value of the chosen optimal dual-scale descriptors. Finally, we use RANSAC (Random Sample Consensus) to fit the segmented surface and optimize the fitting result. Experimental results show that, compared to commonly used facade segmentation algorithms, the proposed method yields more accurate segmentation results, providing a robust data foundation for subsequent 3D model reconstruction of buildings.展开更多
Graph theory plays a significant role in the applications of chemistry,pharmacy,communication,maps,and aeronautical fields.The molecules of chemical compounds are modelled as a graph to study the properties of the com...Graph theory plays a significant role in the applications of chemistry,pharmacy,communication,maps,and aeronautical fields.The molecules of chemical compounds are modelled as a graph to study the properties of the compounds.The geometric structure of the compound relates to a few physical properties such as boiling point,enthalpy,π-electron energy,andmolecular weight.The article aims to determine the practical application of graph theory by solving one of the interdisciplinary problems describing the structures of benzenoid hydrocarbons and graphenylene.The topological index is an invariant of a molecular graph associated with the chemical structure,which shows the correlation of chemical structures using many physical,chemical properties and biological activities.This study aims to introduce some novel degree-based entropy descriptors such as ENTSO,ENTGH,ENTHG,ENTSS,ENTNSO,ENTNReZ1,ENTNReZ2 and ENTNSS using the respective topological indices.Also,the above-mentioned entropy measures and physico-chemical properties of benzenoid hydrocarbons are fitted using linear regression models and calculated for graphenylene structure.展开更多
Electrocatalysis is undergoing a renaissance due to its central importance for a sustainable energy economy,relying on green(electro-)chemical processes to harvest,convert,and store energy.Theoretical considerations b...Electrocatalysis is undergoing a renaissance due to its central importance for a sustainable energy economy,relying on green(electro-)chemical processes to harvest,convert,and store energy.Theoretical considerations by electronic structure methods are key to identify potential material motifs for electrocatalytic processes at the solid/liquid interface.Most commonly,heuristic concepts in the realm of materials screening by the compilation of volcano plots are used,which rely on a plethora of simplifications and approximations of the complex electrochemical interface.While the investigation of the catalytic processes at the solid/liquid interface mainly relies on descriptor-based approaches,in the present future article it is discussed that the inclusion of the liquid part of the interface by mean-field models is crucial to elevate screening approaches to the next level.展开更多
Obtaining a 3D feature description with high descriptiveness and robustness under complicated nuisances is a significant and challenging task in 3D feature matching.This paper proposes a novel feature description cons...Obtaining a 3D feature description with high descriptiveness and robustness under complicated nuisances is a significant and challenging task in 3D feature matching.This paper proposes a novel feature description consisting of a stable local reference frame(LRF)and a feature descriptor based on local spatial voxels.First,an improved LRF was designed by incorporating distance weights into Z-and X-axis calculations.Subsequently,based on the LRF and voxel segmentation,a feature descriptor based on voxel homogenization was proposed.Moreover,uniform segmentation of cube voxels was performed,considering the eigenvalues of each voxel and its neighboring voxels,thereby enhancing the stability of the description.The performance of the descriptor was strictly tested and evaluated on three public datasets,which exhibited high descriptiveness,robustness,and superior performance compared with other current methods.Furthermore,the descriptor was applied to a 3D registration trial,and the results demonstrated the reliability of our approach.展开更多
Electrocatalytic nitrogen reduction reaction(NRR) is an efficient and green way to produce ammonia,which offers an alternative option to the conventional Haber-Bosch process.Unfortunately,the large-scale industrial ap...Electrocatalytic nitrogen reduction reaction(NRR) is an efficient and green way to produce ammonia,which offers an alternative option to the conventional Haber-Bosch process.Unfortunately,the large-scale industrial application of NRR processes is still hindered by poor Faraday efficiency and high overpotential,which need to be overcome urgently.Herein,combined with density functional theory and particle swarm optimization algorithm for the nitrogen carbide monolayer structural search(C_mN_(8-m),m=1-7),the surprising discovery is that single transition metal-atom-doped C_(4)N_(4) monolayers(TM@C_(4)N_(4)) could effectively accelerate nitrogen reduction reaction.TM@C_(4)N_(4)(TM=29 transition metals) as single-atom catalysts are evaluated via traditional multi-step screening method,and their structures,NRR activity,selectivity and solvation effect are investigated to evaluate their NRR performance,Through the screening steps,W@C_(4)N_(4) possesses the highest activity for NRR with a very low limiting potential of-0.29 V.Moreover,an intrinsic descriptor φ is proposed with machine learning,which shortens the screening process and provides a new idea for finding efficient SACs.This work not only offers promising catalysts W@C_(4)N_(4) for NRR process but also offers a new intrinsic and universal descriptor φ.展开更多
基金National Natural Science Foundation of China,Grant/Award Numbers:62063004,62350410483Key Research and Development Project of Hainan Province,Grant/Award Number:ZDYF2021SHFZ093Zhejiang Provincial Postdoctoral Science Foundation,Grant/Award Number:ZJ2021028。
文摘In the intricate network environment,the secure transmission of medical images faces challenges such as information leakage and malicious tampering,significantly impacting the accuracy of disease diagnoses by medical professionals.To address this problem,the authors propose a robust feature watermarking algorithm for encrypted medical images based on multi-stage discrete wavelet transform(DWT),Daisy descriptor,and discrete cosine transform(DCT).The algorithm initially encrypts the original medical image through DWT-DCT and Logistic mapping.Subsequently,a 3-stage DWT transformation is applied to the encrypted medical image,with the centre point of the LL3 sub-band within its low-frequency component serving as the sampling point.The Daisy descriptor matrix for this point is then computed.Finally,a DCT transformation is performed on the Daisy descriptor matrix,and the low-frequency portion is processed using the perceptual hashing algorithm to generate a 32-bit binary feature vector for the medical image.This scheme utilises cryptographic knowledge and zero-watermarking technique to embed watermarks without modifying medical images and can extract the watermark from test images without the original image,which meets the basic re-quirements of medical image watermarking.The embedding and extraction of water-marks are accomplished in a mere 0.160 and 0.411s,respectively,with minimal computational overhead.Simulation results demonstrate the robustness of the algorithm against both conventional attacks and geometric attacks,with a notable performance in resisting rotation attacks.
基金supported by the National Natural Science Foundation of China (21673137)。
文摘The catalytic descriptor with operational feasibility is highly desired towards rational design of high-performance catalyst especially the electrode/electrolyte solution interface working under mild conditions.Herein,we demonstrate that the descriptorΩparameterized by readily accessible intrinsic properties of metal center and coordination is highly operational and efficient in rational design of single-atom catalyst(SAC)for driving electrochemical nitrogen reduction(NRR).Using twodimensional metal(M)-B_(x)P_(y)S_(z)N_m@C_(2)N as prototype SAC models,we reveal that^(*)N_(2)+(H~++e~-)→^(*)N_(2)H acts predominantly as the potential-limiting step(PLS)of NRR on M-B_(2)P_(2)S_(2)@C_(2)N and M-B_(1)P_(1)S_(1)N_(3)@C_(2)N regardless of the distinction in coordination microenvironment.Among the 28 screened M active sites,withΩvalues close to the optimal 4,M-B_(2)P_(2)S_(2)@C_(2)N(M=V(Ω=3.53),Mo(Ω=5.12),and W(Ω=3.92))and M-B_(1)P_(1)S_(1)N_(3)@C_(2)N(M=V(Ω=3.00),Mo(Ω=4.34),and W(Ω=3.32))yield the lowered limiting potential(U_(L))as-0.45,-0.54.-0.36,-0.58,-0.25,and-0.24 V,respectively,thus making them the promising NRR catalysts.More importantly,these SACs are located around the top of volcano-shape plot of U_(L) versusΩ,re-validatingΩas an effective descriptor for accurately predicting the high-activity NRR SACs even with complex coordination.Our study unravels the relationship between active-site structure and NRR performance via the descriptorΩ,which can be applied to other important sustainable electrocatalytic reactions involving activation of small molecules viaσ-donation andπ^(*)-backdonation mechanism.
文摘To address the current issues of inaccurate segmentation and the limited applicability of segmentation methods for building facades in point clouds, we propose a facade segmentation algorithm based on optimal dual-scale feature descriptors. First, we select the optimal dual-scale descriptors from a range of feature descriptors. Next, we segment the facade according to the threshold value of the chosen optimal dual-scale descriptors. Finally, we use RANSAC (Random Sample Consensus) to fit the segmented surface and optimize the fitting result. Experimental results show that, compared to commonly used facade segmentation algorithms, the proposed method yields more accurate segmentation results, providing a robust data foundation for subsequent 3D model reconstruction of buildings.
文摘Graph theory plays a significant role in the applications of chemistry,pharmacy,communication,maps,and aeronautical fields.The molecules of chemical compounds are modelled as a graph to study the properties of the compounds.The geometric structure of the compound relates to a few physical properties such as boiling point,enthalpy,π-electron energy,andmolecular weight.The article aims to determine the practical application of graph theory by solving one of the interdisciplinary problems describing the structures of benzenoid hydrocarbons and graphenylene.The topological index is an invariant of a molecular graph associated with the chemical structure,which shows the correlation of chemical structures using many physical,chemical properties and biological activities.This study aims to introduce some novel degree-based entropy descriptors such as ENTSO,ENTGH,ENTHG,ENTSS,ENTNSO,ENTNReZ1,ENTNReZ2 and ENTNSS using the respective topological indices.Also,the above-mentioned entropy measures and physico-chemical properties of benzenoid hydrocarbons are fitted using linear regression models and calculated for graphenylene structure.
基金funding by the Ministry of Culture and Science of the Federal State of North Rhine-Westphalia(NRW Return Grant)funded by the CRC/TRR247:“Heterogeneous Oxidation Catalysis in the Liquid Phase”(Project number 388390466-TRR 247)+2 种基金the RESOLV Cluster of Excellence,funded by the Deutsche Forschungsgemeinschaft under Germany’s Excellence Strategy–EXC 2033–390677874–RESOLVthe Center for Nanointegration(CENIDE)supported by COST(European Cooperation in Science and Technology)。
文摘Electrocatalysis is undergoing a renaissance due to its central importance for a sustainable energy economy,relying on green(electro-)chemical processes to harvest,convert,and store energy.Theoretical considerations by electronic structure methods are key to identify potential material motifs for electrocatalytic processes at the solid/liquid interface.Most commonly,heuristic concepts in the realm of materials screening by the compilation of volcano plots are used,which rely on a plethora of simplifications and approximations of the complex electrochemical interface.While the investigation of the catalytic processes at the solid/liquid interface mainly relies on descriptor-based approaches,in the present future article it is discussed that the inclusion of the liquid part of the interface by mean-field models is crucial to elevate screening approaches to the next level.
基金the National Natural Science Foundation of China,No.51705469the Zhengzhou University Youth Talent Enterprise Cooperative Innovation Team Support Program Project(2021,2022).
文摘Obtaining a 3D feature description with high descriptiveness and robustness under complicated nuisances is a significant and challenging task in 3D feature matching.This paper proposes a novel feature description consisting of a stable local reference frame(LRF)and a feature descriptor based on local spatial voxels.First,an improved LRF was designed by incorporating distance weights into Z-and X-axis calculations.Subsequently,based on the LRF and voxel segmentation,a feature descriptor based on voxel homogenization was proposed.Moreover,uniform segmentation of cube voxels was performed,considering the eigenvalues of each voxel and its neighboring voxels,thereby enhancing the stability of the description.The performance of the descriptor was strictly tested and evaluated on three public datasets,which exhibited high descriptiveness,robustness,and superior performance compared with other current methods.Furthermore,the descriptor was applied to a 3D registration trial,and the results demonstrated the reliability of our approach.
基金supports by the National Natural Science Foundation of China (NSFC, Grant No. 52271113)the Natural Science Foundation of Shaanxi Province, China (2020JM-218)+1 种基金the Fundamental Research Funds for the Central Universities (CHD300102311405)HPC platform, Xi’an Jiaotong University。
文摘Electrocatalytic nitrogen reduction reaction(NRR) is an efficient and green way to produce ammonia,which offers an alternative option to the conventional Haber-Bosch process.Unfortunately,the large-scale industrial application of NRR processes is still hindered by poor Faraday efficiency and high overpotential,which need to be overcome urgently.Herein,combined with density functional theory and particle swarm optimization algorithm for the nitrogen carbide monolayer structural search(C_mN_(8-m),m=1-7),the surprising discovery is that single transition metal-atom-doped C_(4)N_(4) monolayers(TM@C_(4)N_(4)) could effectively accelerate nitrogen reduction reaction.TM@C_(4)N_(4)(TM=29 transition metals) as single-atom catalysts are evaluated via traditional multi-step screening method,and their structures,NRR activity,selectivity and solvation effect are investigated to evaluate their NRR performance,Through the screening steps,W@C_(4)N_(4) possesses the highest activity for NRR with a very low limiting potential of-0.29 V.Moreover,an intrinsic descriptor φ is proposed with machine learning,which shortens the screening process and provides a new idea for finding efficient SACs.This work not only offers promising catalysts W@C_(4)N_(4) for NRR process but also offers a new intrinsic and universal descriptor φ.