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Three-dimensional stability calculation method for high and large composite slopes formed by mining stope and inner dump in adjacent open pits
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作者 Zuchao Liang Dong Wang +4 位作者 Guanghe Li Guangyu Sun Mingyu Yu Dong Xia Chunjian Ding 《International Journal of Mining Science and Technology》 SCIE EI CAS CSCD 2024年第4期507-520,共14页
The 2D limit equilibrium method is widely used for slope stability analysis.However,with the advancement of dump engineering,composite slopes often exhibit significant 3D mechanical effects.Consequently,it is of signi... The 2D limit equilibrium method is widely used for slope stability analysis.However,with the advancement of dump engineering,composite slopes often exhibit significant 3D mechanical effects.Consequently,it is of significant importance to develop an effective 3D stability calculation method for composite slopes to enhance the design and stability control of open-pit slope engineering.Using the composite slope formed by the mining stope and inner dump in Baiyinhua No.1 and No.2 open-pit coal mine as a case study,this research investigates the failure mode of composite slopes and establishes spatial shape equations for the sliding mass.By integrating the shear resistance and sliding force of each row of microstrip columns onto the bottom surface of the strip corresponding to the main sliding surface,a novel 2D equivalent physical and mechanical parameters analysis method for the strips on the main sliding surface of 3D sliding masses is proposed.Subsequently,a comprehensive 3D stability calculation method for composite slopes is developed,and the quantitative relationship between the coordinated development distance and its 3D stability coefficients is examined.The analysis reveals that the failure mode of the composite slope is characterized by cutting-bedding sliding,with the arc serving as the side interface and the weak layer as the bottom interface,while the destabilization mechanism primarily involves shear failure.The spatial form equation of the sliding mass comprises an ellipsoid and weak plane equation.The analysis revealed that when the coordinated development distance is 1500 m,the error rate between the 3D stability calculation result and the 2D stability calculation result of the composite slope is less than 8%,thereby verifying the proposed analytical method of equivalent physical and mechanical parameters and the 3D stability calculation method for composite slopes.Furthermore,the3D stability coefficient of the composite slope exhibits an exponential correlation with the coordinated development distance,with the coefficient gradually decreasing as the coordinated development distance increases.These findings provide a theoretical guideline for designing similar slope shape parameters and conducting stability analysis. 展开更多
关键词 composite slope Destabilization mechanism 3D mechanical effect Three-dimensional stability Coordinated development distance
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Effects of dietary Clostridium butyricum and rumen protected fat on meat quality,oxidative stability,and chemical composition of finishing goats
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作者 Meimei Zhang Zhiyue Zhang +9 位作者 Xinlong Zhang Changming Lu Wenzhu Yang Xiaolai Xie Hangshu Xin Xiaotan Lu Mingbo Ni Xinyue Yang Xiaoyang Lv Peixin Jiao 《Journal of Animal Science and Biotechnology》 SCIE CAS CSCD 2024年第2期911-924,共14页
Background Clostridium butyricum(CB)is a probiotic that can regulate intestinal microbial composition and improve meat quality.Rumen protected fat(RPF)has been shown to increase the dietary energy density and provide ... Background Clostridium butyricum(CB)is a probiotic that can regulate intestinal microbial composition and improve meat quality.Rumen protected fat(RPF)has been shown to increase the dietary energy density and provide essential fatty acids.However,it is still unknown whether dietary supplementation with CB and RPF exerts beneficial effects on growth performance and nutritional value of goat meat.This study aimed to investigate the effects of dietary CB and RPF supplementation on growth performance,meat quality,oxidative stability,and meat nutritional value of finishing goats.Thirty-two goats(initial body weight,20.5±0.82 kg)were used in a completely randomized block design with a 2 RPF supplementation(0 vs.30 g/d)×2 CB supplementation(0 vs.1.0 g/d)factorial treatment arrangement.The experiment included a 14-d adaptation and 70-d data and sample collection period.The goats were fed a diet consisted of 400 g/kg peanut seedling and 600 g/kg corn-based concentrate(dry matter basis).Result Interaction between CB and RPF was rarely observed on the variables measured,except that shear force was reduced(P<0.05)by adding CB or RPF alone or their combination;the increased intramuscular fat(IMF)content with adding RPF was more pronounced(P<0.05)with CB than without CB addition.The pH24h(P=0.009),a*values(P=0.007),total antioxidant capacity(P=0.050),glutathione peroxidase activities(P=0.006),concentrations of 18:3(P<0.001),20:5(P=0.003)and total polyunsaturated fatty acids(P=0.048)were increased,whereas the L*values(P<0.001),shear force(P=0.050)and malondialdehyde content(P=0.044)were decreased by adding CB.Furthermore,CB supplementation increased essential amino acid(P=0.027),flavor amino acid(P=0.010)and total amino acid contents(P=0.024)as well as upregulated the expression of lipoprotein lipase(P=0.034)and peroxisome proliferator-activated receptorγ(PPARγ)(P=0.012),and downregulated the expression of stearoyl-CoA desaturase(SCD)(P=0.034).The RPF supplementation increased dry matter intake(P=0.005),averaged daily gain(trend,P=0.058),hot carcass weight(P=0.046),backfat thickness(P=0.006),concentrations of 16:0(P<0.001)and c9-18:1(P=0.002),and decreased the shear force(P<0.001),isoleucine(P=0.049)and lysine content(P=0.003)of meat.In addition,the expressions of acetyl-CoA carboxylase(P=0.003),fatty acid synthase(P=0.038),SCD(P<0.001)and PPARγ(P=0.022)were upregulated due to RPF supplementation,resulting in higher(P<0.001)content of IMF.Conclusions CB and RPF could be fed to goats for improving the growth performance,carcass traits and meat quality,and promote fat deposition by upregulating the expression of lipogenic genes of Longissimus thoracis muscle. 展开更多
关键词 Chemical composition Clostridium butyricum Goats Meat quality Oxidative stability Rumen protected fat
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Facile synthesis of composite polyferric magnesium-silicate-sulfate coagulant with enhanced performance in water and wastewater
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作者 Xiangtao Huo Rongxia Chai +2 位作者 Lizheng Gou Mei Zhang Min Guo 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2024年第3期574-584,共11页
The coagulation process is a widely applied technology in water and wastewater treatment.Novel composite polyferric mag-nesium-silicate-sulfate(PFMS)coagulants were synthesized using Na_(2)SiO_(3)·9H_(2)O,Fe_(2)(... The coagulation process is a widely applied technology in water and wastewater treatment.Novel composite polyferric mag-nesium-silicate-sulfate(PFMS)coagulants were synthesized using Na_(2)SiO_(3)·9H_(2)O,Fe_(2)(SO_(4))_(3),and MgSO_(4) as raw materials in this paper.The effects of aging time,Fe:Si:Mg,and OH:M molar ratios(M represents the metal ions)on the coagulation performance of the as-pre-pared PFMS were systematically investigated to obtain optimum coagulants.The results showed that PFMS coagulant exhibited good co-agulation properties in the treatment of simulated humic acid-kaolin surface water and reactive dye wastewater.When the molar ratio was controlled at Fe:Si:Mg=2:2:1 and OH:M=0.32,the obtained PFMS presented excellent stability and a high coagulation efficiency.The removal efficiency of ultraviolet UV254 was 99.81%,and the residual turbidity of the surface water reached 0.56 NTU at a dosage of 30 mg·L^(-1).After standing the coagulant for 120 d in the laboratory,the removal efficiency of UV254 and residual turbidity of the surface wa-ter were 88.12%and 0.68 NTU,respectively,which accord with the surface water treatment requirements.In addition,the coagulation performance in the treatment of reactive dye wastewater was greatly improved by combining the advantages of magnesium and iron salts.Compared with polyferric silicate-sulfate(PFS)and polymagnesium silicate-sulfate(PMS),the PFMS coagulant played a better decolor-ization role within the pH range of 7-13. 展开更多
关键词 polyferric-magnesium-silicate-sulfate composite coagulants water and wastewater excellent stability high coagulation ef-ficiency DECOLORIZATION
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Experimental and numerical interpretation on composite foundation consisting of soil-cement column within warm and ice-rich frozen soil
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作者 WANG Honglei ZHANG Jianming +2 位作者 WEI Shoucai SUN Zhizhong ZHANG Hu 《Journal of Mountain Science》 SCIE CSCD 2024年第1期313-321,共9页
Affected by climate warming and anthropogenic disturbances, the thermo-mechanical stability of warm and ice-rich frozen ground along the Qinghai-Tibet engineering corridor(QTEC) is continuously decreased, which may de... Affected by climate warming and anthropogenic disturbances, the thermo-mechanical stability of warm and ice-rich frozen ground along the Qinghai-Tibet engineering corridor(QTEC) is continuously decreased, which may delay the construction of major projects in the future. In this study, based on chemical stabilization of warm and icerich frozen ground, the soil-cement column(SCC) for ground improvement was recommended to reinforce the foundations in warm and ice-rich permafrost regions. To explore the validity of countermeasures mentioned above, both the original foundation and the composite foundation consisting of SCC with soil temperature of -1.0℃ were prepared in the laboratory, and then the plate loading tests were carried out. The laboratory investigations indicated that the bearing capacity of composite foundation consisting of SCC was higher than that of original foundation, and the total deformation of original foundation was greater than that of composite foundation, meaning that overall stability of foundation with warm and ice-rich frozen soil can be improved by SCC installation. Meanwhile, a numerical model considering the interface interaction between frozen soil and SCC was established for interpretating the bearing mechanism of composite foundation. The numerical investigations revealed that the SCC within composite foundation was responsible for the more applied load, and the applied load can be delivered to deeper zone in depth due to the SCC installation, which was favorable for improving the bearing characteristic of composite foundation. The investigations provide the valuable guideline for the choice of engineering supporting techniques to major projects within the QTEC. 展开更多
关键词 Chemical stabilization Ground improvement composite foundation Frozen soil engineering Qinghai-Tibet engineering corridor
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Double Layer Composite Electrode Strategy for Efficient Perovskite Solar Cells with Excellent Reverse-Bias Stability
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作者 Chaofan Jiang Junjie Zhou +6 位作者 Hang Li Liguo Tan Minghao Li Wolfgang Tress Liming Ding Michael Grätzel Chenyi Yi 《Nano-Micro Letters》 SCIE EI CAS CSCD 2023年第1期225-235,共11页
Perovskite solar cells(PSCs)have become the represent-atives of next generation of photovoltaics;nevertheless,their stability is insufficient for large scale deployment,particularly the reverse bias stability.Here,we ... Perovskite solar cells(PSCs)have become the represent-atives of next generation of photovoltaics;nevertheless,their stability is insufficient for large scale deployment,particularly the reverse bias stability.Here,we propose a transparent conducting oxide(TCO)and low-cost metal composite electrode to improve the stability of PSCs without sacrificing the efficiency.The TCO can block ion migrations and chemical reactions between the metal and perovskite,while the metal greatly enhances the conductivity of the composite electrode.As a result,composite electrode-PSCs achieved a power conversion efficiency(PCE)of 23.7%(certified 23.2%)and exhibited excellent stability,maintaining 95%of the initial PCE when applying a reverse bias of 4.0 V for 60 s and over 92%of the initial PCE after 1000 h continuous light soaking.This composite electrode strategy can be extended to different combinations of TCOs and metals.It opens a new avenue for improving the stability of PSCs. 展开更多
关键词 composite electrode Perovskite solar cells stabilITY Reverse bias Characterization
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Mechanical Behaviors of ZrO_2-Al_2O_3 Ceramic Composites with Y_2O_3 as Stabilizer 被引量:3
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作者 丘泰 王玉春 沈春英 《Journal of Rare Earths》 SCIE EI CAS CSCD 2005年第3期280-284,共5页
The ZrO2-Al2O3 ceramic composites were prepared by appropriate techniques with commercial ZrO2 and Al2O3 powders as raw materials and Y2O3 as stabilizer. The results indicate that with the introduction of Al2O3 into t... The ZrO2-Al2O3 ceramic composites were prepared by appropriate techniques with commercial ZrO2 and Al2O3 powders as raw materials and Y2O3 as stabilizer. The results indicate that with the introduction of Al2O3 into the ZrO2 matrix where the quantity of additive Y2O3 is 3.5% (mole fraction), the growth of ZrO2 grains is efficiently inhibited, which helps the ZrO2 grains exist in a metastable tetragonal manner; thus higher strength and toughness are acquired. When the content of alumina is 20% (mass fraction), the bending strength and fracture toughness of the composites are 676.7 MPa and 10 MPa·m1/2 respectively, the mechanical behaviors are close to those prepared with ZrO2 and Al2O3 powders synthesized through wet chemical approach. The mechanical behaviors of the composites are well improved owing to the dispersion toughening of alumina grains and phase transformation toughening of zirconia grains. 展开更多
关键词 inorganic non-metallic materials zirconia-alumina ceramic composites yttria stabilizer mechanical behaviors toughening mechanism rare earths
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Analysis of influence factors of unconfined compressive strength for composite soil stabilizer-stabilized gravel soil 被引量:1
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作者 Zhao Yulong Gao Ying +1 位作者 Zhang Yiluo Wang Yong 《Journal of Southeast University(English Edition)》 EI CAS 2017年第4期484-489,共6页
In order to investigate the effect o f some factors on the unconfined compressive strength(UCS)for composite soil stabilizer-stabilized gravel soil(CSSSGS),the orthogonal test is adopted to set up the experimental sch... In order to investigate the effect o f some factors on the unconfined compressive strength(UCS)for composite soil stabilizer-stabilized gravel soil(CSSSGS),the orthogonal test is adopted to set up the experimental scheme.Three levels o f each factor armconsidered to obtain the change laws o f UCS,in which the binder dosages are8%,10%,and12%;the curing times ae7,14and21d;the gradation nae0.3,0.35and0.4;and the degrees of compaction are95%,97%,and99%.The range analysis clearly indicates that the influence degree o f the four factors on UCS is in such an order:dosage,age,gradation,and degree o f compaction.The variance analysis shows that only the composite soil stabilizer dosage can significantly affect UCS.In road construction,the examination o f composite soil stabilizer dosage and base-course maintenance should be given much more attention to obtain satisfactory base-course strength,compared w ith gradation floating and the change of degree o f compaction. 展开更多
关键词 base course composite soil stabilizer gravel soil unconfined compressive strength orthogonal test
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Microstructure and interface thermal stability of C/Mo double-coated SiC fiber reinforced γ-TiAl matrix composites 被引量:5
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作者 罗贤 李超 +4 位作者 杨延清 许海嫚 李晓宇 刘帅 李鹏涛 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2016年第5期1317-1325,共9页
C/Mo duplex coating interfacially modified SiC fiber-reinforced γ-TiAl matrix composite (SiCf/C/Mo/γ-TiA1) was prepared by foil-fiber-foil method to investigate its interfacial modification effect. SiCf/C/TiAl com... C/Mo duplex coating interfacially modified SiC fiber-reinforced γ-TiAl matrix composite (SiCf/C/Mo/γ-TiA1) was prepared by foil-fiber-foil method to investigate its interfacial modification effect. SiCf/C/TiAl composites were also prepared under the same processing condition for comparision. Both kinds of the composites were thermally exposed in vacuum at 800 and 900℃ for different durations in order to study thermal stability of the interfacial zone. With the aids of scanning electron microscope (SEM) and energy dispersive spectrometer (EDS), the interracial microstructures of the composites were investigated. The results reveal that, although adding the Mo coating, the interfacial reaction product of the SiCf/C/Mo/TiAl composite is the same with that of the SiCf/C/TiA1 composite, which is TiC/Ti2AlC between the coating and the matrix. However, C/Mo duplex coating is more efficient in hindering interfacial reaction than C single coating at 900 ℃ and below. In addition, a new layer of interfacial reaction product was found between Ti2AlC and the matrix after 900 ℃, 200 h thermal exposure, which is rich in V and close to the chemical composition of B2 phase. 展开更多
关键词 Mo coating TiAl alloy SiC fiber titanium matrix composite interracial reaction thermal stability
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Microstructure stability of Ti_2Al N/Ti-48Al-2Cr-2Nb composite at 900 °C 被引量:1
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作者 刘懿文 胡锐 张铁邦 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2016年第2期423-430,共8页
Microstructure stability of in situ synthesized Ti2AlN/Ti-48Al-2Cr-2Nb composite during aging at 900 ℃ was investigated by XRD, OM and TEM, and the unreinforced Ti-48Al-2Cr-2Nb alloy was also examined for comparison.... Microstructure stability of in situ synthesized Ti2AlN/Ti-48Al-2Cr-2Nb composite during aging at 900 ℃ was investigated by XRD, OM and TEM, and the unreinforced Ti-48Al-2Cr-2Nb alloy was also examined for comparison. The result showed that in the TiAl alloy,α2 lamellae thinned and were broken down, and became discontinuous with increasing aging time. The decomposition ofα2 lamella toγ which was characterized by parallel decomposition and breakdown ofα2 lamellae led to the degradation of the lamellar structure. While in the composite, lamellar structure remained relatively stable even after aging at 900 ℃ for 100 h. No breakdown ofα2 lamellae except parallel decomposition and precipitation of fine nitride particles was observed. The better microstructural stability of the composite was mainly attributed to the precipitation of Ti2AlN particles at theα2/γ interface which played an important role in retarding the coarsening of lamellar microstructure in the matrix of composite. 展开更多
关键词 TiAl composite Ti2AlN microstructure stability lamellar structure PRECIPITATION
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Laminar Composite Solid Electrolyte with Poly(Ethylene Oxide)-Threaded Metal-Organic Framework Nanosheets for High-Performance All-Solid-State Lithium Battery 被引量:1
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作者 Na Peng Weijie Kou +3 位作者 Wenjia Wu Shiyuan Guo Yan Wang Jingtao Wang 《Energy & Environmental Materials》 SCIE EI CAS CSCD 2023年第1期264-273,共10页
Developing laminar composite solid electrolyte with ultrathin thickness and continuous conduction channels in vertical direction holds great promise for all-solid-state lithium batteries.Herein,a thin,laminar solid el... Developing laminar composite solid electrolyte with ultrathin thickness and continuous conduction channels in vertical direction holds great promise for all-solid-state lithium batteries.Herein,a thin,laminar solid electrolyte is synthesized by filtrating–NH 2 functionalized metal-organic framework nanosheets and then being threaded with poly(ethylene oxide)chains induced by the hydrogen-bonding interaction from–NH_(2) groups.It is demonstrated that the threaded poly(ethylene oxide)chains lock the adjacent metal-organic framework nanosheets,giving highly enhanced structural stability(Young’s modulus,1.3 GPa)to 7.5-μm-thick laminar composite solid electrolyte.Importantly,these poly(ethylene oxide)chains with stretching structure serve as continuous conduction pathways along the chains in pores.It makes the non-conduction laminar metal-organic framework electrolyte highly conductive:3.97×10^(−5) S cm^(−1) at 25℃,which is even over 25 times higher than that of pure poly(ethylene oxide)electrolyte.The assembled lithium cell,thus,acquires superior cycling stability,initial discharge capacity(148 mAh g^(−1) at 0.5 C and 60℃),and retention(94% after 150 cycles).Besides,the pore size of nanosheet is tailored(24.5–40.9˚A)to evaluate the mechanisms of chain conformation and ion transport in confined space.It shows that the confined pore only with proper size could facilitate the stretching of poly(ethylene oxide)chains,and meanwhile inhibit their disorder degree.Specifically,the pore size of 33.8˚A shows optimized confinement effect with trans-poly(ethylene oxide)and cis-poly(ethylene oxide)conformation,which offers great significance in ion conduction.Our design of poly(ethylene oxide)-threaded architecture provides a platform and paves a way to the rational design of next-generation high-performance porous electrolytes. 展开更多
关键词 all-solid-state lithium battery ion conduction laminar composite solid electrolyte poly(ethylene oxide)-threaded metal-organic framework nanosheet structural stability
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A high-power high-stability Q-switched green laser with intracavity frequency doubling using a diode-pumped composite ceramic Nd:YAG laser 被引量:7
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作者 王与烨 徐德刚 +2 位作者 刘长明 王卫鹏 姚建铨 《Chinese Physics B》 SCIE EI CAS CSCD 2012年第9期315-320,共6页
We successfully obtain a high-average-power high-stability Q-switched green laser based on diode-side-pumped composite ceramic Nd:YAG in a straight piano-concave cavity. The temperature distribution in composite cera... We successfully obtain a high-average-power high-stability Q-switched green laser based on diode-side-pumped composite ceramic Nd:YAG in a straight piano-concave cavity. The temperature distribution in composite ceramic Nd:YAG crystal is numerically analyzed and compared with that of conventional Nd:YAG crystal. By using a composite ceramic Nd:YAG rod and a type-II high gray track resistance KTP (HGTR-KTP) crystal, a green laser with an average output power of 165 W is obtained at a repetition rate of 25 kHz, with a diode-to-green optical conversion of 14.68%, and a pulse width of 162 ns. To the best of our knowledge, both the output power and optical-to-optical efficiency are the highest values for green laser systems with intracavity frequency doubling of this novel composite ceramic Nd:YAG laser to date. The power fluctuation at around 160 W is lower than 0.3% in 2.5 hours. 展开更多
关键词 high-average-power green laser high stability composite ceramic Nd:YAG rod
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The Controllability, Observability, and Stability Analysis of a Class of Composite Systems with Fractional Degree Generalized Frequency Variables 被引量:2
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作者 Cuihong Wang Yafei Zhao YangQuan Chen 《IEEE/CAA Journal of Automatica Sinica》 SCIE EI CSCD 2019年第3期859-864,共6页
This paper is concerned with fundamental properties of a class of composite systems with fractional degree generalized frequency variables, including controllability, observability and stability. Firstly, some necessa... This paper is concerned with fundamental properties of a class of composite systems with fractional degree generalized frequency variables, including controllability, observability and stability. Firstly, some necessary and sufficient conditions are given to guarantee controllability and observability of such composite systems. Then we prove that the stability problem of such composite systems can be reduced to judging whether a fractional degree polynomial is stable. Finally, the stability analysis result is applied in the supervisory control of fractional-order multi-agent systems, and an example is provided to illustrate the effectiveness of the proposed methods. 展开更多
关键词 composite SYSTEM CONTROLLABILITY fractionalorder SYSTEM OBSERVABILITY stability
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LiF and LiNO_(3) as synergistic additives for PEO-PVDF/LLZTO-based composite electrolyte towards high-voltage lithium batteries with dualinterfaces stability 被引量:7
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作者 Liansheng Li Yuanfu Deng +2 位作者 Huanhuan Duan Yunxian Qian Guohua Chen 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2022年第2期319-328,共10页
Solid electrolytes with desirable properties such as high ionic conductivity,wide electrochemical stable window,and suitable mechanical strength,and stable electrode-electrolyte interfaces on both cathode and anode si... Solid electrolytes with desirable properties such as high ionic conductivity,wide electrochemical stable window,and suitable mechanical strength,and stable electrode-electrolyte interfaces on both cathode and anode side are essential for high-voltage all-solid-state lithium batteries(ASSLBs)to achieve excellent cycle stability.In this work,a novel strategy of using LiF and LiNO_(3) as synergistic additives to boost the performance of PEO-PVDF/LLZTO-based composite solid electrolytes(CSEs)is developed,which also promotes the assembled high-voltage ASSLBs with dual-interfaces stability characteristic.Specifically,LiF as an inactive additive can increase the electrochemical stability of the CSE under high cut-off voltage,and improve the high-voltage compatibility between cathode and CSE,thus leading to a stable cathode/CSE interface.LiNO_(3) as an active additive can lead to an enhanced ionic conductivity of CSE due to the increased free-mobile Li+and ensure a stable CSE/Li interface by forming stable solid electrolyte interphase(SEI)on Li anode surface.Benefiting from the improved performance of CSE and stable dualinterfaces,the assembled NCM622/9[PEO_(15)-LiTFSI]-PVDF-15 LLZTO-2 LiF-3 LiNO_(3)/Li cell delivers a high rate capacity of 102.1 mAh g^(-1) at 1.0 C and a high capacity retention of 77.4%after 200 cycles at 0.5 C,which are much higher than those of the ASSLB assembled with additive-free CSE,with only 60.0 mAh g^(-1) and 52.0%,respectively.Furthermore,novel cycle test modes of resting for 5 h at different charge states after every 5 cycles are designed to investigate the high-voltage compatibility between cathode and CSE,and the results suggest that LiF additive can actually improve the high-voltage compatibility of cathode and CSE.All the obtained results confirm that the strategy of using synergistic additives in CSE is an effective way to achieve high-voltage ASSLBs with dual-interfaces stability. 展开更多
关键词 Synergistic additives composite solid electrolyte Dual-interfaces stability High-voltage cathode Lithium metal battery
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INVESTIGATION ON STABILITY OF PZT/EPOXY PIEZOCOMPOSITE WITH PRESSURE AND TEMPERATURE 被引量:2
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作者 Likun Wang Yuanyuan Wan +2 位作者 Li Li Lei Qin Yi Lu 《Acta Mechanica Solida Sinica》 SCIE EI 2009年第3期226-231,共6页
With the universal test machine and temperature test chamber, the effect of pressure and temperature on the behavior of 1-3 and 1-3-2 piezocomposites prepared with PZT/epoxy in our lab has been investigated through el... With the universal test machine and temperature test chamber, the effect of pressure and temperature on the behavior of 1-3 and 1-3-2 piezocomposites prepared with PZT/epoxy in our lab has been investigated through electrical impedance and dielectric analysis. The permittivity, resonant frequency and dielectric loss of the composites have been measured under vertical stress and temperature, and the variety of the material properties under pressure and temperature could also be obtained. The pressure and temperature stability of the composites have been assessed through experiments. The data of these two types of composites indicated that the stability of 1-342 composite with pressure was better than that of 1-3 composite, and two composites have almost the same dielectric stability with temperature. However, 1-3-2 composite showed slower frequency variation than 1-3 composite. 展开更多
关键词 piezoelectric composite directional pressure temperature stabilITY
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An upgraded polymeric composite with interparticle chemical bonding microstructure toward lithium-ion battery separators with enhanced safety and electrochemical performances
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作者 Qian Zhao Ling Ma +10 位作者 Ye Xu Xiulong Wu Shuai Jiang Qiaotian Zheng Guang Hong Bin He Chen Li Wanglai Cen Wenjun Zhou Yan Meng Dan Xiao 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2023年第9期402-413,共12页
A composite separator of SiC/PVDF-HFP was synthesized for lithium-ion batteries with high thermal and mechanical stabilities.Benefiting from the nanoscale,high hardness,and melting point of SiC,SiC/PVDFHFP with highly... A composite separator of SiC/PVDF-HFP was synthesized for lithium-ion batteries with high thermal and mechanical stabilities.Benefiting from the nanoscale,high hardness,and melting point of SiC,SiC/PVDFHFP with highly uniform microstructure was obtained.This polarization caused by barrier penetration was significantly restrained.Due to the Si-F bond between SiC and PVDF-HFP,the structural stability has been obviously enhanced,which could suppress the growth of lithium(Li) dendrite.Furthermore,some 3D reticulated Si nanowires are found on the surface of Li anode,which also greatly inhibit Li dendrites and result in irregular flakes of Li metal.Especially,the shrinkage of 6% SiC/PVDF-HFP at 150℃ is only 5%,which is notably lower than those of PVDF-HFP and Celgard2500.The commercial LiFePO_(4) cell assembled with 6% SiC/PVDF-HFP possesses a specific capacity of 157.8 mA h g^(-1) and coulomb efficiency of 98% at 80℃.In addition,the tensile strength and modulus of 6% SiC/PVDF-HFP could reach 14.6 and 562 MPa,respectively.And a small deformation(1000 nm) and strong deformation recovery are obtained under a high additional load(2.3 mN).Compared with PVDF-HFP and Celgard2500,the symmetric Li cell assembled with 6% SiC/PVDF-HFP has not polarized after 900 cycles due to its excellent mechanical stabilities.This strategy provides a feasible solution for the composite separator of high-safety batteries with a high temperature and impact resistance. 展开更多
关键词 SiC PVDF-HFP composite separator Thermal stability Mechanical stability High safety battery
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Stability analysis of radial inflation of incompressible compositerubber tubes 被引量:2
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作者 袁学刚 张文正 +1 位作者 张洪武 朱正佑 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI 2011年第3期301-308,共8页
The inflation mechanism is examined for a composite cylindrical tube composed of two incompressible rubber materials, and the inner surface of the tube is subjected to a suddenly applied radial pressure. The mathemati... The inflation mechanism is examined for a composite cylindrical tube composed of two incompressible rubber materials, and the inner surface of the tube is subjected to a suddenly applied radial pressure. The mathematical model of the problem is formulated, and the corresponding governing equation is reduced to a second-order ordinary differential equation by means of the incompressible condition of the material, the boundary conditions, and the continuity conditions of the radial displacement and the radial stress of the cylindrical tube. Moreover, the first integral of the equation is obtained. The qualitative analyses of static inflation and dynamic inflation of the tube are presented. Particularly, the effects of material parameters, structure parameters, and the radial pressure on radial inflation and nonlinearly periodic oscillation of the tube are discussed by combining numerical examples. 展开更多
关键词 composite rubber tube radial inflation stability nonlinearly periodic oscillation
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THEORY OF NONLINEAR DYNAMIC STABILITY FOR COMPOSITE LAMINATED PLATES 被引量:2
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作者 周承倜 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI 1991年第2期113-120,共8页
In this paper, the general equations of dynamic stability for composite laminated plates are derived hyHamilton principle. These general equations can he used to consider those different factors that affect the dynami... In this paper, the general equations of dynamic stability for composite laminated plates are derived hyHamilton principle. These general equations can he used to consider those different factors that affect the dynamic stability of laminated plates. The factors are transverse shear deformation, initial imperfections, longitudinal and rotational inertia, and ply-angle of the fiber, etc. The solutions of the fundamental equations show that some important characteristics of the dynamic instability can only be got by the consideration and analysis of those factors 展开更多
关键词 composite materials laminated plates dynamic stability
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Stabilization of ferric arsenate sludge with mechanochemically prepared FeS2/Fe composites 被引量:3
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作者 Xiao-bo MIN Tian-yu PENG +3 位作者 Yang-wen-jun LI Yong KE Yan-jie LIANG Xing-yu HE 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2019年第9期1983-1992,共10页
FeS2/Fe composites were mechanochemically prepared with iron powder and pyrite for the stabilization of ferrite arsenate sludge(FAS).The effects of preparation parameters on stabilization performance were investigated... FeS2/Fe composites were mechanochemically prepared with iron powder and pyrite for the stabilization of ferrite arsenate sludge(FAS).The effects of preparation parameters on stabilization performance were investigated.The results show that the optimum conditions are FeS2/Fe molar ratio of 5:5,milling time of 2 h,ball-to-material mass ratio of 15:1 and milling with stainless steel ball.Then,the composites were characterized by XRD,SEM,FTIR,etc.The physicochemical properties of FeS2/Fe mixture change dramatically,which is responsible for its excellent performance.Finally,the stabilization process of FAS was optimized.When the FAS is mixed with composites at mass ratio of 4:1 and milled for 30 min,the As leaching concentration of FAS can be reduced from 639.15 to 4.74 mg/L with the stabilization ratio of 99.2%. 展开更多
关键词 ARSENIC ferric arsenate sludge stabilIZATION mechanical milling FeS2/Fe composites
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Enhancing Structural Stability and Pervaporation Performance of Composite Membranes by Coating Gelatin onto Hydrophilically Modified Support Layer 被引量:2
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作者 吴洪 芦霞 +3 位作者 李宪实 李奕帆 赵翠红 姜忠义 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2014年第1期19-27,共9页
The interfacial compatibility of composite membrane is an important factor to its structural stability, andseparation performance. In this study, poly (ether sulfone) (PES) support layer was first hydrophilically ... The interfacial compatibility of composite membrane is an important factor to its structural stability, andseparation performance. In this study, poly (ether sulfone) (PES) support layer was first hydrophilically modified with poly(vinyl alcohol) (PVA) via surface segregation during the phase inversion process. Gelatin (GE) was then cast on the PVA-modified PES support layer as the active layer followed by crosslinking to fabricate composite membranes for ethanol dehydration. The enrichment of PVA on the surface of support layer improved interfacial compatibility of the as-prepared GE/PVA-PES composite membrane. The water contact angle measurement and X-ray photoelectron spectroscopy (XPS) data confirmed the surface segregation of PVA with a surface coverage density of -80%. T-peel test showed that the maxima/force to separate the support layer and the active layer was enhanced by 3 times compared with the GE/PES membrane. The effects of PVA content in the support layer, crosslinking of GE active layer and operating parameters on the pervaporative dehydration performance were investigated. The operational stability of the composite membrane was tested by immersing the membrane in ethanol aqueous solution for a period of time. Stable pervaporation performance for dehydration of 90% ethanol solution was obtained for GE/PVA-PES membrane with a separation factor of -60 and a permeation flux of -1910 g.m^-2.h1 without peeling over 28 days immersion. 展开更多
关键词 surface segregation composite membrane interfacial stability PERVAPORATION ethanol dehydration
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Enhanced ionic conductivity in a novel composite electrolyte based on Gd-doped SnO_(2) nanotubes for ultra-long-life all-solid-state lithium metal batteries
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作者 Lugang Zhang Nanping Deng +7 位作者 Junbao Kang Xiaoxiao Wang Hongjing Gao Yarong Liu Hao Wang Gang Wang Bowen Cheng Weimin Kang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2023年第2期326-337,I0009,共13页
All-solid-state electrolytes are exceedingly attractive because of the outstanding inherent safety and energy density compared to liquid electrolytes.Whereas,it is still formidable to simultaneously design solid elect... All-solid-state electrolytes are exceedingly attractive because of the outstanding inherent safety and energy density compared to liquid electrolytes.Whereas,it is still formidable to simultaneously design solid electrolytes with favorable electrode/electrolyte interface compatibility and high ionic conductivity in a simple and scalable manner.Hence,the oxygen-vacancy-rich Gd-doped SnO_(2) nanotubes(GDS NTs)are innovatively prepared and applied to the electrolyte of all-solid-state lithium metal batteries for the first time.The addition of GDS NTs can validly construct long-range co ntinuous ion transport networks in the poly(ethylene oxide)(PEO)-based system and greatly improve the mechanical properties of the electrolyte.Compared to the PEO-based electrolyte,the composite electrolyte displays a higher lithium ion conductivity of 2.41×10^(-4) S cm^(-1) at 30℃,a higher lithium ion transference number up to 0.62 and a wider electrochemical window of 5 V at 50℃.In addition,the composite electrolyte manifests outstanding compatibility with high-voltage LiNi_(0.8)Mn_(0.1)Co_(0.1)O_(2)(NMC811)cathode,LiFePO4 cathode and lithium metal anode.The assembled Li/Li symmetric battery exhibits stable Li plating/stripping cycling performance,which can cycle steadily for 1500 h at a capacity of 0.3 mA h cm^(-2).And Li/LiFePO4 battery still maintains a high capacity of 131.54 mA h g^(-1) at 0.5C after 800 cycles,which has a superior capacity retention rate of 93.2%.The obtained novel composite electrolyte has promising application prospects in the field of all-solid-state lithium metal cells. 展开更多
关键词 All-solid-state lithium metal batteries Gd-doped SnO2 nanotubes Interfacial stability Oxygen vacancies Solid-state composite electrolytes
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