This paper investigates the luminescence characteristics of Eu2＋ activated Ca2SiO4, Sr2SiO4 and Ba2SiO4 phosphors. Two emission bands are assigned to the f-d transitions of Eu2＋ ions doped into two different cation ...This paper investigates the luminescence characteristics of Eu2＋ activated Ca2SiO4, Sr2SiO4 and Ba2SiO4 phosphors. Two emission bands are assigned to the f-d transitions of Eu2＋ ions doped into two different cation sites in host lattices, and show different emission colour variation caused by substituting M2＋ cations for smaller cations. This behaviour is discussed in terms of two competing factors of the crystal field strength and covalence. These phosphors with maximum excitation of around 370 nm can be applied as a colour-tunable phosphor for light-emitting diodes （LEDs） based on ultraviolet chip/phosphor technology.展开更多
A novel green phosphor,LiCaBO3:Tb3+,was synthesized by solid state reaction method,its luminescence characteristics were investigated,and the formation of phosphors were confirmed by X-ray powder diffraction(XRD).Its ...A novel green phosphor,LiCaBO3:Tb3+,was synthesized by solid state reaction method,its luminescence characteristics were investigated,and the formation of phosphors were confirmed by X-ray powder diffraction(XRD).Its excitation band extended from 220 to 400 nm,which was coupled well with the emission of UV LED(350-410 nm).It exhibited a strong green emission located at 544 nm with chromatic coordination(0.25,0.58).The emission intensities of LiCaBO3:Tb3+ phosphor were influenced by varying Tb3+ concentratio...展开更多
The phosphors of KY_(1-x)(MoO_(4))_(2-y)(WO_(4))y:xLn^(3+)(Ln^(3+)=Tm^(3+),Dy^(3+),Eu^(3+))were synthesized by using a sol-gel method.Then,the crystal structure,luminescence properties,energy transfer,and white emissi...The phosphors of KY_(1-x)(MoO_(4))_(2-y)(WO_(4))y:xLn^(3+)(Ln^(3+)=Tm^(3+),Dy^(3+),Eu^(3+))were synthesized by using a sol-gel method.Then,the crystal structure,luminescence properties,energy transfer,and white emission of the prepared materials were researched.The molar ratio of the anion group on the photoluminescence(PL)emission and excitation intensity were investigated,revealing that the optimum intensity could be obtained by using=3:1.The optimal Dy^(3+) doping concentration of KY(MoO_(4))1.5(WO4)0.5was obtained.In addition,the color-tunable emissions of Dy^(3+)/Eu^(3+)-codoped KY(MoO_(4))1.5(WO4)0.5phosphors were observed because of the effective energy transfer(ET)from Dy^(3+)to Eu^(3+)ions.Finally,by doping appropriate concentrations of Tm^(3+),Dy^(3+),and Eu^(3+)and different concentrations of(WO_(4))^(2-),white light emitting phosphors KY_(0.92)(WO_(4))2:0.01Tm^(3+),0.06Dy^(3+),0.01Eu^(3+)with excellent color-rending properties were obtained.The chromaticity coordinate was calculated as(x=0.3238,y=0.3173),closing to the artificial daylight(D65,x=0.313,y=0.329)illuminant,and which indicates the potential application of near ultraviolet White light-emitting diodes(WLEDs).展开更多
As the blue and yellow lights are complementary colors, a blue InGaN LED chip is coated hy a yellow phosphor film to generate white light based on luminescence conversion mechanism. The emitted light of a blue LED is ...As the blue and yellow lights are complementary colors, a blue InGaN LED chip is coated hy a yellow phosphor film to generate white light based on luminescence conversion mechanism. The emitted light of a blue LED is used as the primary source for exciting fluorescent material such as cerium doped yttrium aluminum garnet with the formula Y3Al2O12 ： Ce^3＋ （in short： YAG ： Ce^3＋ ）. The matching of the spectrum of the blue LED chips and the YAG ： Ce^3＋ yellow phosphor is studied to improve the conversion efficiency. The packaging methods and manufacturing processes for high power single chip-white LEDs are introduced. The uniformity of the output white light is investigated. Based on the characteristics of the high power white LEDs, some approaches and processes are suggested to improve the light uniformity when they are fabricated. The effectiveness of those approaches on the improvement of LEDs is discussed in detail and some interesting conclusions are also presented.展开更多
Much attention has been paid to white LEDs because of their potential applications in the illumination.The doping of rare earth ions plays an important role in the optical properties of yellow fluorescent powder.And m...Much attention has been paid to white LEDs because of their potential applications in the illumination.The doping of rare earth ions plays an important role in the optical properties of yellow fluorescent powder.And mainly aiming to raise the intensity and the luminous rate of the white LEDs and by photoluminescence and electroluminescence,the luminescence spectrum of yellow fluorescent powder bought from different places is measured.Furthermore, the luminous intensity in the normal direction and the angle distribution of half maximum power for the white LEDs packed with cylindrical Φ 5 epoxy on the same blue GaN chips are also measured under the same manufacture conditions. The results show that the yellow fluorescent powder bought from China mainland has higher optical output rate than that bought from China Taiwan and hence is more suitable to fabricate the white LEDs for practical use.展开更多
Hybrid white micro-pillar structure light emitting diodes(LEDs)have been manufacture utilizing blue micro-LEDs arrays integrated with 580 nm CIS((CuInS2-ZnS)/ZnS)core/shell quantum dots.The fabricated hybrid white mic...Hybrid white micro-pillar structure light emitting diodes(LEDs)have been manufacture utilizing blue micro-LEDs arrays integrated with 580 nm CIS((CuInS2-ZnS)/ZnS)core/shell quantum dots.The fabricated hybrid white micro-LEDs have good electrical properties,which are manifested in relatively low turn-on voltage and reverse leakage current.High-quality hybrid white light emission has been demonstrated by the hybrid white micro-LEDs after a systemic optimization,in which the corresponding color coordinates are calculated to be(0.3303,0.3501)and the calculated color temperature is 5596 K.This result indicates an effective way to achieve high-performance white LEDs and shows great promise in a large range of applications in the future including micro-displays,bioinstrumentation and visible light communication.展开更多
The Ba3Y2（BO3）4：Eu^3＋ phosphor was synthesized using a high temperature solid-state reaction method and the luminescent characteristics were investigated. The emission spectrum exhibited one strong red emission at...The Ba3Y2（BO3）4：Eu^3＋ phosphor was synthesized using a high temperature solid-state reaction method and the luminescent characteristics were investigated. The emission spectrum exhibited one strong red emission at 613 nm, corresponding to the electric dipole 5D0-TF2 transition of Eu^3＋, under 365 nm excitation. The excitation spectrum of 613 nm indicated that the Ba3Y2（BO3）n：Eu^3＋ phosphor was effectively excited by ultraviolet （UV） （254, 365 and 400 nm） and blue （470 nm） light. The effect of Eu^3＋ concentration on the 613 nm emission of the Ba3Y2（BO3）n：Eu^3＋ phosphor was measured. The results showed that the emission intensity increased with increasing Eu^3＋ concentration, and then decreased. The CIE color coordinates of Ba3Y2（BO3）4：Eu^3＋ phosphor were x=0.641 and y=0.359 at 15 mol.% Eu^3＋.展开更多
GaN-based irregular multiple quantum well （IMQW） structures assembled two different types of QWs emitting complementary wavelengths for dichromatic white light-emitting diodes （LEDs） are optimized in order to obta...GaN-based irregular multiple quantum well （IMQW） structures assembled two different types of QWs emitting complementary wavelengths for dichromatic white light-emitting diodes （LEDs） are optimized in order to obtain near white light emissions. The hole distributions and spontaneous emission spectra of the IMQW structures are analysed in detail by fully considering the effects of strain, well-coupling, valence band-mixing and polarization effect through employing a newly developed theoretical model from the k. p theory. Several structure parameters such as well material component, well width, layout of the wells and the thickness of harrier between different types of QWs are employed to analyse how these parameters together with the polarization effect influence the electronic and the optical properties of IMQW structure. Numerical results show that uniform hole distributions in different types of QWs are obtained when the number of the QWs emitting blue light is two, the number of the QWs emitting yellow light is one and the barrier between different types of QWs is 8nm in thickness. The near white light emission is realized using GaN-based IMQW structure with appropriate design parameters and injection level.展开更多
Most of the commercial white LED lamps use blue chip coated with yellow emitting phosphor. YAG:Ce3+ phosphor is coated on blue chip to obtain white light. Though this is commercially successful, there are several draw...Most of the commercial white LED lamps use blue chip coated with yellow emitting phosphor. YAG:Ce3+ phosphor is coated on blue chip to obtain white light. Though this is commercially successful, there are several drawbacks such as “halo effect”, poor colour rendition, etc. In recent years several efforts have been made to improve LED lamp performance. In this paper modifica-tion of YAG:Ce phosphor for improving CRI, by introducing Gd3+, Pr3+ or Tb3+ at Ce3+ site is reported.展开更多
A new optical wireless network based on white LED lights in home area is proposed. It is a duplex channel communication system utilizing signal emitters of white LED lights in the downlink and infrared devices in the ...A new optical wireless network based on white LED lights in home area is proposed. It is a duplex channel communication system utilizing signal emitters of white LED lights in the downlink and infrared devices in the uplink. Strategies for the system construction are given. Performance for users＇ mobile access of different kinds of optical concentrators is investigated. Indoor channel band-width is analyzed considering white LED light distribution, wall reflection, and receivers field of view （FOV）. Various modulation methods are discussed. A demo point-to-point system for surfing the net is constructed using a new line code of 4B6B which is developed to stabilize the optical output, and a peak data rate of 1 Mbps is achieved. This system is built into the lighting infrastructure, therefore decreasing the cost and offering a solution for wireless access in places which are sensitive to radio frequency like hospitals.展开更多
基金supported by Hebei Provincial Technology Development Foundation of China(Grant No 51215103b)Science Foundation of Hebei University of China(Grant No 2006Q06)
文摘This paper investigates the luminescence characteristics of Eu2＋ activated Ca2SiO4, Sr2SiO4 and Ba2SiO4 phosphors. Two emission bands are assigned to the f-d transitions of Eu2＋ ions doped into two different cation sites in host lattices, and show different emission colour variation caused by substituting M2＋ cations for smaller cations. This behaviour is discussed in terms of two competing factors of the crystal field strength and covalence. These phosphors with maximum excitation of around 370 nm can be applied as a colour-tunable phosphor for light-emitting diodes （LEDs） based on ultraviolet chip/phosphor technology.
基金supported by Natural Science Foundation of Hebei Province (E2009000209, F2009000217)Hebei Provincial Technology Development Foundation (51215103b)+1 种基金Science Foundation of Hebei University (2006Q06)National Natural Science Foundation of China (50902042)
文摘A novel green phosphor,LiCaBO3:Tb3+,was synthesized by solid state reaction method,its luminescence characteristics were investigated,and the formation of phosphors were confirmed by X-ray powder diffraction(XRD).Its excitation band extended from 220 to 400 nm,which was coupled well with the emission of UV LED(350-410 nm).It exhibited a strong green emission located at 544 nm with chromatic coordination(0.25,0.58).The emission intensities of LiCaBO3:Tb3+ phosphor were influenced by varying Tb3+ concentratio...
文摘The phosphors of KY_(1-x)(MoO_(4))_(2-y)(WO_(4))y:xLn^(3+)(Ln^(3+)=Tm^(3+),Dy^(3+),Eu^(3+))were synthesized by using a sol-gel method.Then,the crystal structure,luminescence properties,energy transfer,and white emission of the prepared materials were researched.The molar ratio of the anion group on the photoluminescence(PL)emission and excitation intensity were investigated,revealing that the optimum intensity could be obtained by using=3:1.The optimal Dy^(3+) doping concentration of KY(MoO_(4))1.5(WO4)0.5was obtained.In addition,the color-tunable emissions of Dy^(3+)/Eu^(3+)-codoped KY(MoO_(4))1.5(WO4)0.5phosphors were observed because of the effective energy transfer(ET)from Dy^(3+)to Eu^(3+)ions.Finally,by doping appropriate concentrations of Tm^(3+),Dy^(3+),and Eu^(3+)and different concentrations of(WO_(4))^(2-),white light emitting phosphors KY_(0.92)(WO_(4))2:0.01Tm^(3+),0.06Dy^(3+),0.01Eu^(3+)with excellent color-rending properties were obtained.The chromaticity coordinate was calculated as(x=0.3238,y=0.3173),closing to the artificial daylight(D65,x=0.313,y=0.329)illuminant,and which indicates the potential application of near ultraviolet White light-emitting diodes(WLEDs).
基金"863"Project from Ministry of Science & Technology of China(2006AA03A116)
文摘As the blue and yellow lights are complementary colors, a blue InGaN LED chip is coated hy a yellow phosphor film to generate white light based on luminescence conversion mechanism. The emitted light of a blue LED is used as the primary source for exciting fluorescent material such as cerium doped yttrium aluminum garnet with the formula Y3Al2O12 ： Ce^3＋ （in short： YAG ： Ce^3＋ ）. The matching of the spectrum of the blue LED chips and the YAG ： Ce^3＋ yellow phosphor is studied to improve the conversion efficiency. The packaging methods and manufacturing processes for high power single chip-white LEDs are introduced. The uniformity of the output white light is investigated. Based on the characteristics of the high power white LEDs, some approaches and processes are suggested to improve the light uniformity when they are fabricated. The effectiveness of those approaches on the improvement of LEDs is discussed in detail and some interesting conclusions are also presented.
文摘Much attention has been paid to white LEDs because of their potential applications in the illumination.The doping of rare earth ions plays an important role in the optical properties of yellow fluorescent powder.And mainly aiming to raise the intensity and the luminous rate of the white LEDs and by photoluminescence and electroluminescence,the luminescence spectrum of yellow fluorescent powder bought from different places is measured.Furthermore, the luminous intensity in the normal direction and the angle distribution of half maximum power for the white LEDs packed with cylindrical Φ 5 epoxy on the same blue GaN chips are also measured under the same manufacture conditions. The results show that the yellow fluorescent powder bought from China mainland has higher optical output rate than that bought from China Taiwan and hence is more suitable to fabricate the white LEDs for practical use.
基金supported by National Key R&D Program of China (2016YFB0400100)National Nature Science Foundation of China (61921005, 61674076, 61674081, 61605071, 61974062)+5 种基金Nature Science Foundation of Jiangsu Province (BY2013077, BK20141320, BE2015111)Six Talent Peaks Project of Jiangsu Province (XYDXX-081)Open Fund of the State Key Laboratory on Integrated Optoelectronics (IOSKL2017KF03)Innovation Project of Postgraduate Training in Jiangsu Province (KYCX18_0031)Fundamental Research Funds for the Central Universities (021014380096)Collaborative Innovation Center of Solid State Lighting and Energy-saving Electronics
文摘Hybrid white micro-pillar structure light emitting diodes(LEDs)have been manufacture utilizing blue micro-LEDs arrays integrated with 580 nm CIS((CuInS2-ZnS)/ZnS)core/shell quantum dots.The fabricated hybrid white micro-LEDs have good electrical properties,which are manifested in relatively low turn-on voltage and reverse leakage current.High-quality hybrid white light emission has been demonstrated by the hybrid white micro-LEDs after a systemic optimization,in which the corresponding color coordinates are calculated to be(0.3303,0.3501)and the calculated color temperature is 5596 K.This result indicates an effective way to achieve high-performance white LEDs and shows great promise in a large range of applications in the future including micro-displays,bioinstrumentation and visible light communication.
基金Project supported by the National High Technology Research and Development Program(863)of China(2006AA03A116)Application-based Research of Sichuan Province (2008JY0051)~~
基金Project supported by the Hebei Provincial Technology Development Foundation (51215103b)Science Foundation of Hebei University (2006Q06)
文摘The Ba3Y2（BO3）4：Eu^3＋ phosphor was synthesized using a high temperature solid-state reaction method and the luminescent characteristics were investigated. The emission spectrum exhibited one strong red emission at 613 nm, corresponding to the electric dipole 5D0-TF2 transition of Eu^3＋, under 365 nm excitation. The excitation spectrum of 613 nm indicated that the Ba3Y2（BO3）n：Eu^3＋ phosphor was effectively excited by ultraviolet （UV） （254, 365 and 400 nm） and blue （470 nm） light. The effect of Eu^3＋ concentration on the 613 nm emission of the Ba3Y2（BO3）n：Eu^3＋ phosphor was measured. The results showed that the emission intensity increased with increasing Eu^3＋ concentration, and then decreased. The CIE color coordinates of Ba3Y2（BO3）4：Eu^3＋ phosphor were x=0.641 and y=0.359 at 15 mol.% Eu^3＋.
基金supported by the National Natural Science Foundation of China (Grant No. 60777013)the Nature Science Foundation of Beijing,China (Grant No. 4082023)the Excellent Doctoral Science and Technology Innovation Foundation of Beijing Jiaotong University,China (Grant No. 141063522)
文摘GaN-based irregular multiple quantum well （IMQW） structures assembled two different types of QWs emitting complementary wavelengths for dichromatic white light-emitting diodes （LEDs） are optimized in order to obtain near white light emissions. The hole distributions and spontaneous emission spectra of the IMQW structures are analysed in detail by fully considering the effects of strain, well-coupling, valence band-mixing and polarization effect through employing a newly developed theoretical model from the k. p theory. Several structure parameters such as well material component, well width, layout of the wells and the thickness of harrier between different types of QWs are employed to analyse how these parameters together with the polarization effect influence the electronic and the optical properties of IMQW structure. Numerical results show that uniform hole distributions in different types of QWs are obtained when the number of the QWs emitting blue light is two, the number of the QWs emitting yellow light is one and the barrier between different types of QWs is 8nm in thickness. The near white light emission is realized using GaN-based IMQW structure with appropriate design parameters and injection level.
文摘Most of the commercial white LED lamps use blue chip coated with yellow emitting phosphor. YAG:Ce3+ phosphor is coated on blue chip to obtain white light. Though this is commercially successful, there are several drawbacks such as “halo effect”, poor colour rendition, etc. In recent years several efforts have been made to improve LED lamp performance. In this paper modifica-tion of YAG:Ce phosphor for improving CRI, by introducing Gd3+, Pr3+ or Tb3+ at Ce3+ site is reported.
文摘A new optical wireless network based on white LED lights in home area is proposed. It is a duplex channel communication system utilizing signal emitters of white LED lights in the downlink and infrared devices in the uplink. Strategies for the system construction are given. Performance for users＇ mobile access of different kinds of optical concentrators is investigated. Indoor channel band-width is analyzed considering white LED light distribution, wall reflection, and receivers field of view （FOV）. Various modulation methods are discussed. A demo point-to-point system for surfing the net is constructed using a new line code of 4B6B which is developed to stabilize the optical output, and a peak data rate of 1 Mbps is achieved. This system is built into the lighting infrastructure, therefore decreasing the cost and offering a solution for wireless access in places which are sensitive to radio frequency like hospitals.
