The effect of inclusion-induced nucleation on hot-rolled steel base metal was evaluated in comparison with welding heataffected zone(HAZ).Microstructure and mechanical properties of hot-rolled low-carbon steel contain...The effect of inclusion-induced nucleation on hot-rolled steel base metal was evaluated in comparison with welding heataffected zone(HAZ).Microstructure and mechanical properties of hot-rolled low-carbon steel containing Ti–Ca oxide particles were studied.The results showed that inclusions in Ti–Ca deoxidized steel distributed dispersely and were effective for intragranular acicular ferrite nucleation.Under hot rolling and controlled cooling conditions,microstructure in steel base metal was significantly refined and mainly consisted of acicular ferrite and intragranular bainite,which exhibited higher strength and excellent toughness.The microstructural evolution behavior followed the process that acicular ferrite plates divided the austenite grain,intragranular bainite packets formed between interlocking acicular ferrite plates,and the remaining austenite decomposed into fine polygonal ferrite grains.The resultant complex microstructure improved the impact toughness significantly.By comparison,in HAZ microstructure,laminar grain boundary ferrite having similar crystallography orientation showed adverse effect on toughness.展开更多
The Ba-, La- and Ag-doped polycrystalline Ca2.9M0.1Co4O9 (M=Ca, Ba, La, Ag) thermoelectric bulk samples were pre- pared via citrate acid sol-gel synthesis method followed by spark plasma sintering technique. The bul...The Ba-, La- and Ag-doped polycrystalline Ca2.9M0.1Co4O9 (M=Ca, Ba, La, Ag) thermoelectric bulk samples were pre- pared via citrate acid sol-gel synthesis method followed by spark plasma sintering technique. The bulk samples were characterized and analyzed with regard to their phase compositions, grain orientations as well as microstructures. The high temperature thermoelec- tric transport properties of the bulk samples were studied in detail. All bulk samples were found to be single-phased with modified body texture. The electrical resistivity was modulated as a result of carrier concentration modification, however the carrier transport process was not influenced; the Seebeck coefficient was deteriorated simultaneously. The total thermal conductivity was remarkably reduced, on account of the decreasing of phonon thermal conductivity. The thermoelectric properties of the Ba-, La-, and Ag-doped bulk samples were optimized, and the Ba-doped Ca2.9Ba0.1Co4O9 system was found to have the highest dimensionless figure of merit ZT0.20 at 973 K, which was remarkably higher than that of the un-doped sample.展开更多
基金This work was supported by the National Natural Science Foundation of China(U1860201 and 51904070)China Postdoctoral Science Foundation(2018M631804)the Fundamental Research Funds for the Central Universities(N170703005).
文摘The effect of inclusion-induced nucleation on hot-rolled steel base metal was evaluated in comparison with welding heataffected zone(HAZ).Microstructure and mechanical properties of hot-rolled low-carbon steel containing Ti–Ca oxide particles were studied.The results showed that inclusions in Ti–Ca deoxidized steel distributed dispersely and were effective for intragranular acicular ferrite nucleation.Under hot rolling and controlled cooling conditions,microstructure in steel base metal was significantly refined and mainly consisted of acicular ferrite and intragranular bainite,which exhibited higher strength and excellent toughness.The microstructural evolution behavior followed the process that acicular ferrite plates divided the austenite grain,intragranular bainite packets formed between interlocking acicular ferrite plates,and the remaining austenite decomposed into fine polygonal ferrite grains.The resultant complex microstructure improved the impact toughness significantly.By comparison,in HAZ microstructure,laminar grain boundary ferrite having similar crystallography orientation showed adverse effect on toughness.
基金Foundation item: Project supported by National Natural Science Foundation of China (50801002), Beijing Municipal Natural Science Foundation (2112007) and the Education Department of Henan Province Science and Technology Research Projects (13B430895)
文摘The Ba-, La- and Ag-doped polycrystalline Ca2.9M0.1Co4O9 (M=Ca, Ba, La, Ag) thermoelectric bulk samples were pre- pared via citrate acid sol-gel synthesis method followed by spark plasma sintering technique. The bulk samples were characterized and analyzed with regard to their phase compositions, grain orientations as well as microstructures. The high temperature thermoelec- tric transport properties of the bulk samples were studied in detail. All bulk samples were found to be single-phased with modified body texture. The electrical resistivity was modulated as a result of carrier concentration modification, however the carrier transport process was not influenced; the Seebeck coefficient was deteriorated simultaneously. The total thermal conductivity was remarkably reduced, on account of the decreasing of phonon thermal conductivity. The thermoelectric properties of the Ba-, La-, and Ag-doped bulk samples were optimized, and the Ba-doped Ca2.9Ba0.1Co4O9 system was found to have the highest dimensionless figure of merit ZT0.20 at 973 K, which was remarkably higher than that of the un-doped sample.