Carbon Fiber Breakage Mechanism in Aluminum(Al)/Carbon Fibers(CFs) Composite Sheet during Accumulative Roll Bonding(ARB) Process

We put forward a method of fabricating Aluminum(Al)/carbon fibers(CFs) composite sheets by the accumulative roll bonding(ARB) method. The finished Al/CFs composite sheet has CFs and pure Al sheets as sandwich and surface layers. After cross-section observation of the Al/CFs composite sheet, we found that the CFs discretely distributed within the sandwich layer. Besides, the tensile test showed that the contribution of the sandwich CFs layer to tensile strength was less than 11% compared with annealed pure Al sheet. With ex-situ observation of the CFs breakage evolution with-16%,-32%, and-45% rolling reduction during the ARB process, the plastic instability of the Al layer was found to bring shear damages to the CFs. At last, the bridging strengthening mechanism introduced by CFs was sacrificed. We provide new insight into and instruction on Al/CFs composite sheet preparation method and processing parameters.

CoS Nanosheets Coated with Dopamine-Derived Carbon Standing on Carbon Fiber Cloth as Binder-Free Anode for Li-ion Batteries

Cobalt sulphides attract much attention as anode materials for Li-ion batteries(LIBs).However,its poor conductivity,low initial column efficiency and large volume changes during cycling have hindered its further development.Herein,novel interlaced CoS nanosheets were firstly prepared on Carbon Fiber Cloth(CFC)by two hydrothermal reactions followed with carbon coating via carbonizing dopamine(CoS NS@C/CFC).As a freestanding anode,the nanosheet structure of CoS not only accommodates the volume variation,but also provides a large interface area to proceed the charge transfer reaction.In addition,CFC works as both a three-dimensional skeleton and an active substance which can further improve the areal capacity of the resulting electrode.Furthermore,the coated carbon combined with the CFC work as a 3D conductive network to facilitate the electron conduction.The obtained CoS NS@C/CFC,and the contrast sample prepared with the same procedure but without carbon coating(CoS NS/CFC),are characterized with XRD,SEM,TEM,XPS and electrochemical measurements.The results show that the CoS NS@C/CFC possesses much improved electrochemical performance due to the synergistic effect of nanosheet CoS,the coated carbon and the CFC substrate,exhibiting high initial columbic efficiency(~87%),high areal capacity(2.5 at 0.15 mA cm−2),excellent rate performance(1.6 at 2.73 mA cm−2)and improved cycle stability(87.5%capacity retention after 300 cycles).This work may provide a new route to explore freestanding anodes with high areal specific capacity for LIBs.

Small but mighty:Empowering sodium/potassium-ion battery performance with S-doped SnO_(2) quantum dots embedded in N,S codoped carbon fiber network

SnO_(2) has been extensively investigated as an anode material for sodium-ion batteries(SIBs)and potassium-ion batteries(PIBs)due to its high Na/K storage capacity,high abundance,and low toxicity.However,the sluggish reaction kinetics,low electronic conductivity,and large volume changes during charge and discharge hinder the practical applications of SnO_(2)-based electrodes for SIBs and PIBs.Engineering rational structures with fast charge/ion transfer and robust stability is important to overcoming these challenges.Herein,S-doped SnO_(2)(S-SnO_(2))quantum dots(QDs)(≈3 nm)encapsulated in an N,S codoped carbon fiber networks(S-SnO_(2)-CFN)are rationally fabricated using a sequential freeze-drying,calcination,and S-doping strategy.Experimental analysis and density functional theory calculations reveal that the integration of S-SnO_(2) QDs with N,S codoped carbon fiber network remarkably decreases the adsorption energies of Na/K atoms in the interlayer of SnO_(2)-CFN,and the S doping can increase the conductivity of SnO_(2),thereby enhancing the ion transfer kinetics.The synergistic interaction between S-SnO_(2) QDs and N,S codoped carbon fiber network results in a composite with fast Na+/K+storage and extraordinary long-term cyclability.Specifically,the S-SnO_(2)-CFN delivers high rate capacities of 141.0 mAh g^(−1) at 20 A g^(−1) in SIBs and 102.8 mAh g^(−1) at 10 A g^(−1) in PIBs.Impressively,it delivers ultra-stable sodium storage up to 10,000 cycles at 5 A g^(−1) and potassium storage up to 5000 cycles at 2 A g^(−1).This study provides insights into constructing metal oxide-based carbon fiber network structures for high-performance electrochemical energy storage and conversion devices.

Preparation and Analysis of Carbon Fiber-Silicon Carbide Thermally Conductive Asphalt Concrete

An experimental investigation into the thermal conductivity of CF-SiC two-phase composite asphalt concrete is presented.The main objective of this study was to verify the possibility of using SiC powder instead of mineral powder as the thermal conductive filler to prepare a new type of asphalt concrete and improve the efficiency of electrothermal snow and ice melting systems accordingly.The thermal conductivity of asphalt concrete prepared with different thermally conductive fillers was tested by a transient plane source method,and the related performances were measured.Then the temperature rise rate and surface temperature were studied through field heating tests.Finally,the actual ice melting efficiency of the thermally conductive asphalt concrete was evaluated using an effective electrothermal system.As shown by the experimental results,the composite made of SiC powder and carbon fiber has a high thermal conductivity.When SiC replaces mineral powder,the thermal conductivity of the asphalt mixture increases first and then decreases with the increase of carbon fiber content.In the present study,in particular,the thermal conductivity attained a peak when the carbon fiber content was 0.2%of the aggregate mass.

Study of damage behavior and repair effectiveness of patch repaired carbon fiber laminate under quasi-static indentation loading

Damage caused due to low-velocity impacts in composites leads to substantial deterioration in their residual strength and eventually provokes structural failure.This work presents an experimental investigation on the effects of different patch and parent laminate stacking sequences on the enhancement of impact strength of Carbon Fiber Reinforced Polymers(CFRP)composites by utilising the adhesively bonded external patch repair technique.Damage evolution study is also performed with the aid of Acoustic Emission(AE).Two different quasi-isotropic configurations were selected for the parent laminate,viz.,[45°/45°/0°/0°]s and[45°/0°/45°/0°]s.Quasi Static Indentation(QSI)test was performed on both the pristine laminates,and damage areas were detected by using the C-scan inspection technique.Damaged laminates were repaired by using a single-sided patch of two different configurations,viz.,[45°/45°/45°/45°]and[45°/0°/0°/45°],and employing a circular plug to fill the damaged hole.Four different combinations of repaired laminates with two configurations of each parent and patch laminate were produced,which were further subjected to the QSI test.The results reveal the effectiveness of the repair method,as all the repaired laminates show higher impact resistance compared to the respective pristine laminates.Patches of[45°/0°/0°/45°]configuration when repaired by taking[45°/45°/0°/0°]s and[45°/0°/45°/0°]s as parents exhibited 68%and 73%higher peak loads,respectively,than the respective pristine laminates.Furthermore,parent and patch of configuration[45°/0°/45°/0°]s and[45°/0°/0°/45°],respectively,attain the highest peak load,whereas[45°/45°/0°/0°]s and[45°/45°/45°/45°]combinations possess the most gradual decrease in the load.

Study of the Diffusion Behavior of Seawater Absorption in Multi-Walled Carbon Nanotubes/Halloysite Nanotubes Hybrid Nanofillers Modified Epoxy-Based Glass/Carbon Fiber Composites

In the maritime industry, cost-effective and lightweight Fiber Reinforced Polymer (FRP) composites offer excellent mechanical properties, design flexibility, and corrosion resistance. However, their reliability in harsh seawater conditions is a concern. Researchers address this by exploring three approaches: coating fiber surfaces, hybridizing fibers and matrices with or without nanofillers, and interply rearrangement. This study focuses on evaluating the synergistic effects of interply rearrangement of glass/carbon fibers and hybrid nanofillers, specifically Multi-walled carbon nanotubes (MWCNT) and Halloysite nanotubes (HNT). The aim is to enhance impact properties by minimizing moisture absorption. Hybrid nanocomposites with equal-weight proportions of two nanofillers: 0 wt.%, 1 wt.%, and 2 wt.% were exposed to seawater for 90 days. Experimental data was subjected to modelling through the application of Predictive Fick’s Law. The study found that the hybrid composite containing 2 wt.% hybrid nanofillers exhibited a 22.10% increase in impact performance compared to non-modified counterparts. After 90 days of seawater aging, the material exhibited enhanced resistance to moisture absorption (15.74%) and minimal reduction in impact strength (8.52%) compared to its dry strength, with lower diffusion coefficients.

Indirect Electroanalysis of 3-Methyl-4-Nitrophenol in Water Using Carbon Fiber Microelectrode Modified with Nickel Tetrasulfonated Phthalocyanine Complex

Electrochemical detection of 3-methyl-4-nitrophenol (MNP) in direct phenol oxidation occurs at high potentials and generally leads to progressive passivation of the electrochemical sensor. This study describes the use of a carbon fiber microelectrode modified with a tetrasulfonated nickel phthalocyanine complex for the detection of MNP at a lower potential than that of direct phenol oxidation. The MNP voltammogram showed the presence of an anodic peak at -0.11 V vs SCE, corresponding to the oxidation of the hydroxylamine group generated after the reduction of the nitro group. The effect of buffer pH on the peak current and SWV parameters such as frequency, scan increment, and pulse amplitude were studied and optimized to have better electrochemical response of the proposed sensor. With these optimal parameters, the calibration curve shows that the peak current varied linearly as a function of MNP concentration, leading to a limit of detection (LoD) of 1.1 μg/L. These results show an appreciable sensitivity of the sensor for detecting the MNP at relatively low potentials, making it possible to avoid passivation phenomena.

Strength,lightness,and more:Exploring the properties of carbon fiber

In today's world,where innovation reigns supreme,materials that push the boundaries of what's possible are constantly being developed.One such material is carbon fiber,a remarkable substance that has transformed countless industries.This article delves into the fascinating wo rld of carbon fiber,explo ringits key properties that make it a game-changer.

预应力CFRP布加固混凝土梁受弯试验

目的 研究不同加固方法下预应力碳纤维布加固混凝土梁的受弯性能,解决桥梁加固缺陷的问题。方法 制作了5根试验梁,其中一根为对比梁,不做任何加固处理,其余4根分别采用不同的锚固方式、不同的初始张拉力及不同的加固位置进行加固,通过控制变量,进行加载试验,分析其受弯性能的差异。结果 经加固后的试验梁承载能力与刚度明显增加,与对比梁相比,极限荷载分别提升了25%、22.06%、30.78%及36.76%;各试验梁达到屈服荷载时,经加固的试验梁挠度均小于对比梁产生的挠度,且模腔自锁式锚具锚固的试验梁挠度小于穿孔式自锁锚具锚固的试验梁挠度,相同锚固方法下初始张拉力较大的试验梁挠度要小于初始张拉力较小的试验梁挠度。结论 使用预应力碳纤维布加固混凝土梁能够有效提高混凝土梁的抗弯性能,提升效果与加固位置、锚固方式及初始张拉力大小有关。

单脉冲平顶激光清洗CFRP的多物理场特性研究

为探究平顶激光清洗碳纤维增强复合材料(CFRP)的作用机制,本研究考虑CFRP的组分对激光的吸收、反射特性差异显著,将激光载荷分层施加到CFRP的细观有限元模型上,引入热烧蚀-热应力双重作用效果,还原不同能量密度下单脉冲平顶激光清洗形貌,并完成了试验验证。结果表明:分层施加激光载荷较传统表面加载模式能够有效提升仿真精度,采用热烧蚀-热应力双重判据能够进一步提升形貌还原效果,本研究模型的仿真形貌长轴贴合度不低于96.64%,面积贴合度达到80.00%,并通过高精度模型瞬时温度场分布能够指导激光清洗CFRP表面树脂的实际工艺。

CFRP板纵向加固RC柱在水平低周循环荷载下的力学性能研究与应用

开发了一种纵向粘贴CFRP(Carbon Fiber Reinforced Polymer,碳纤维增强复合材料)板的RC(Reinforced Concrete,钢筋混凝土)柱抗弯加固系统,该加固系统由纵向粘贴在柱表面的预制CFRP板和防止柱底CFRP板脱粘的混凝土加厚层组成.为研究纵向粘贴CFRP板对RC柱的抗弯性能影响,设计并开展了5根足尺矩形RC柱的水平低周循环加载试验.研究结果表明:粘贴CFRP板加固能有效延缓柱的开裂;柱的破坏模式得到明显改善;相较于未加固柱子,粘贴1层CFRP板和2层CFRP板加固的RC柱极限承载力分别提高了15.1%和17.4%;加固后柱的抗弯承载力和刚度得到提高,但增加CFRP板的层数对极限强度和刚度没有显著影响,反而会降低柱的延性,相较于仅采用增大柱底截面的方式加固的对照柱,粘贴1层CFRP板和2层CFRP板加固的试验柱的延性系数分别降低16.2%和35.1%;试验过程中,由于柱与基础节点承载力的限制,CFRP的最大应变仅达到极限应变的24%,抗拉强度未得到充分发挥.该加固方法已在某医院加固工程中得到应用,跟踪研究表明,加固后柱子的抗弯承载力有明显提升,加固方法得到工程业界的认可.

CFRP-聚合物砂浆加固震损构造柱约束砖砌体墙试验研究

为研究斜向碳纤维布条带或斜向聚合物砂浆条带与外覆角钢组合的加固方式对震后砌体结构的加固效果,对模拟经过地震作用的三面带构造柱约束砌体墙片进行抗震加固,并进行拟静力试验。三面砌体墙均采用角钢外覆加固,面层采用不同方式处理。研究结果表明:采用碳纤维布-聚合物砂浆条带的加固方式能很好地恢复震损墙体的承载能力和变形能力;碳纤维布条带在限制裂缝开展以及提高震损结构延性方面有一定贡献;面层采用斜向聚合物砂浆条带加固的震损墙体延性和承载力均较低。工程实际应用中,建议考虑两种材料的复合加固形式。

弯-剪-扭复合受力CFRP布加固RC梁抗扭性能细观数值分析

为了研究弯-剪-扭复合受力条件下碳纤维增强复合材料(carbon fiber reinforced polymer, CFRP)布加固钢筋混凝土(reinforced concrete, RC)梁的抗扭性能,建立体现混凝土材料非均质性、钢筋-混凝土黏结滑移关系和CFRP布-混凝土相互作用关系的细观数值分析模型。由于缺乏CFRP布加固RC梁在弯-剪-扭复合受力作用下失效破坏的典型物理试验,采用复合对比验证法对数值模型的合理性进行验证,即分别与单独受剪、单独受扭以及受弯-扭复合作用下RC梁和CFRP布加固RC梁的试验结果进行对比验证。进而,基于建立的细观数值分析模型探究了配纤率和扭弯比对CFRP布加固RC梁在弯-剪-扭复合受力作用下抗扭力学性能的影响。结果表明:1)采用CFRP布加固能够显著提高RC梁的峰值扭矩;2)随配纤率增加,RC梁损伤分布范围逐渐变大,CFRP布应变逐渐减小,梁整体峰值扭矩增大,但其增大幅度减小;3)随扭弯比增加,RC梁裂缝分布愈加集中,裂缝与水平方向夹角逐渐减小,梁整体峰值扭矩增大,CFRP布应变减小。建立的考虑弯-剪-扭复合受力作用的数值模拟方法可为后续研究复杂应力状态下CFRP布加固RC梁尺寸效应行为等奠定基础。

侧向冲击荷载作用下CFRP型材-方钢管混凝土柱的动力响应

为了研究CFRP型材-方钢管混凝土固简柱的抗侧向冲击性能,采用水平撞击装置对3个CFRP型材-方钢管混凝土柱进行侧向冲击试验.根据柱的破坏模式、局部变形、整体变形及冲击力分析柱的动力响应,研究了CFRP型材、边界条件、冲击能量与冲击冲量对试件动力响应的影响规律.结果表明,CFRP型材-方钢管混凝土固简柱呈现弯曲破坏,具有良好的抗冲击性能,且随着支座约束能力的增大,抗侧向冲击性能增大.增加单位冲击冲量可使悬臂试件的峰值位移下降7%,而两端固支试件峰值位移仅变化1%.随着支座约束能力的下降,冲击冲量对试件变形的影响程度增大.在钢管混凝土固简试件中内置CFRP型材可使冲击位置处峰值位移下降9%,且降低程度随着支座约束能力的下降而增加.

超声振动辅助磨削CFRP复合材料薄管撕裂损伤研究

针对碳纤维增强复合材料(CFRP)薄管超声振动辅助磨削过程中存在撕裂损伤且形成原因不明确的问题,通过对M55J和T300复合材料薄管开展超声振动辅助磨削试验,探究了超声振幅、进给量及主轴转速对磨削力和撕裂尺寸的影响规律,通过对磨削过程的受力分析和对最大未变形切屑厚度的计算,分析了撕裂位置的形成原因和撕裂尺寸的变化规律。结果表明:磨削力随超声振幅的增大而减小,随进给量的增大而增大,与主轴转速的关联性较小;撕裂易出现于CFRP薄管内壁,其长度与高度随超声振幅的增大而减小,随进给量的增大而增大,随主轴转速的增大而减小。

"Three-in-One" Multi-Scale Structural Design of Carbon Fiber-Based Composites for Personal Electromagnetic Protection and Thermal Management

Wearable devices with efficient thermal management and electromagnetic interference(EMI) shielding are highly desirable for improving human comfort and safety. Herein, a multifunctional wearable carbon fibers(CF) @ polyaniline(PANI)/silver nanowires(Ag NWs) composites with a “branch-trunk” interlocked micro/nanostructure were achieved through "three-in-one" multi-scale design. The reasonable assembly of the three kinds of one-dimensional(1D) materials can fully exert their excellent properties i.e., the superior flexibility of CF, the robustness of PANI, and the splendid conductivity of Ag NWs. Consequently, the constructed flexible composite demonstrates enhanced mechanical properties with a tensile stress of 1.2 MPa, which was almost 6 times that of the original material. This is mainly attributed to the fact that the PNAI(branch) was firmly attached to the CF(trunk) through polydopamine(PDA), forming a robust interlocked structure. Meanwhile, the composite possesses excellent thermal insulation and heat preservation capacity owing to the synergistically low thermal conductivity and emissivity. More importantly, the conductive path of the composite established by the three 1D materials greatly improved its EMI shielding property and Joule heating performance at low applied voltage. This work paves the way for rational utilization of the intrinsic properties of 1D materials, as well as provides a promising strategy for designing wearable electromagnetic protection and thermal energy management devices.

新型CFRP网格-重组竹复合板力学试验研究

为提高重组竹的力学性能并减轻其各向异性缺陷,设计了一种新型CFRP网格-重组竹复合板(CBCP).分别对8组CBCP拉伸试样和18组CBCP拉拔试样进行单轴拉伸试验和拉拔试验,以分析其力学行为并评估复合方法的影响.选择3个相似的构成模型对拉拔试样的黏结应力-滑移曲线进行拟合,根据试验结果确定CFRP网格和重组竹的临界锚固长度及计算方法,并分析讨论了CFRP层数、横向CFRP束特性和锚固长度对CFRP网格与重组竹黏结性能的影响.结果表明,复合CFRP网格可使重组竹的顺纹和横纹抗拉强度分别提高35.77%和135.20%,从而改善了重组竹的各向异性缺陷.增加网格层数和间距可提高CBCP的拉伸性能.随着锚固长度的增加,平均界面黏结强度呈幂函数递减,而峰值载荷滑移则线性递减.

熔丝制造3D打印CFRP层内损伤破坏机理与模型研究

为将3D打印技术应用到桥梁工程中,以熔丝制造3D打印碳纤维复合材料锚环为研究对象,开展了材料层内损伤失效机理的基础性研究工作.首先,对锚环进行了张拉锚固破坏试验,明晰材料的损伤失效模式.其次,测试分析了材料的弹性参数及强度参数值,供后续仿真分析使用.最后,通过VUMAT子程序构建了材料的损伤失效本构关系,利用ABAQUS仿真分析软件模拟熔丝制造3D打印碳纤维复合材料锚环的渐进损伤失效全过程,分析其层内损伤失效机理.结果表明:熔丝制造3D打印碳纤维复合材料具有显著的层内损伤现象;选用Hashin损伤起始判据与刚度瞬间退化模型作为熔丝制造3D打印碳纤维复合材料损伤力学模型偏于安全,具有一定的可行性;锚环在高度方向产生纵向裂纹是由纤维拉伸失效导致的.

Boosting Capacitive Deionization Performance of Commercial Carbon Fibers Cloth via Structural Regulation Based on Catalytic-Etching Effect

Monolithic carbon electrodes with robust mechanical integrity and porous architecture are highly desired for capacitive deionization but remain challenging.Owing to the excellent mechanical strength and electroconductivity,commercial carbon fibers cloth demonstrates great potential as high-performance electrodes for ions storage.Despite this,its direct application on capacitive deionization is rarely reported in terms of limited pore structure and natural hydrophobicity.Herein,a powerful metal-organic framework-engaged structural regulation strategy is developed to boost the desalination properties of carbon fibers.The obtained porous carbon fibers features hierarchical porous structure and hydrophilic surface providing abundant ions-accessible sites,and continuous graphitized carbon core ensuring rapid electrons transport.The catalytic-etching mechanism involving oxidation of Co and subsequent carbonthermal reduction is proposed and highly relies on annealing temperature and holding time.When directly evaluated as a current collector-free capacitive deionization electrode,the porous carbon fibers demonstrates much superior desalination capability than pristine carbon fibers,and remarkable cyclic stability up to 20 h with negligible degeneration.Particularly,the PCF-1000 showcases the highest areal salt adsorption capacity of 0.037 mg cm^(−2) among carbon microfibers.Moreover,monolithic porous carbon fibers-carbon nanotubes with increased active sites and good structural integrity by in-situ growth of carbon nanotubes are further fabricated to enhance the desalination performance(0.051 mg cm^(−2)).This work demonstrates the great potential of carbon fibers in constructing high-efficient and robust monolithic electrode for capacitive deionization.

CFRP及EWSS复合加固震损双层高架桥框架式桥墩恢复力模型研究

为研究碳纤维布(Carbon Fiber Reinforced Polymer,CFRP)及外包型钢(Externally Wrapped Steel Section,EWSS)复合加固震损双层高架桥框架式桥墩的恢复力模型,对1榀原型对比试件、1榀无预损加固试件和2榀遭受不同地震损伤加固试件进行了低周往复加载破坏试验,获取了滞回曲线并提取骨架曲线,分析其滞回特性,提出一种弹性段和强化段为双折线、下降段为指数函数且考虑初始损伤的骨架曲线模型;采用试验数据回归拟合方法,定量描述了试件滞回曲线卸载刚度的退化规律,考虑了同级加载承载力退化和定点指向特征,建立了恢复力模型。研究结果表明:复合加固试件滞回曲线捏缩现象明显,呈倒S型,各滞回环分别相交于骨架曲线上正向、负向荷载为屈服荷载0.25倍的点,峰值荷载后EWSS产生包辛格效应;所提出的骨架曲线模型对中度震损和重度震损加固试件下降段指数函数的参数k建议取值分别为3.6和3.4;所建立的骨架曲线模型和恢复力模型计算结果与试验实测结果吻合较好,可为该类结构弹塑性地震反应分析提供依据。