Reactions of bis-scandium bridged phosphinidene complex,[LSc(μ-PAr)]_(2)(L=MeC(NDIPP)CHC(Me)(NCH_(2)CH_(2)N(^(i)Pr)_(2)),DIPP=2,6-(^(i)Pr)_(2)C_(6)H_(3);Ar=2,6-Me_(2)C_(6)H_(3))(1),with pinacolborane,catecholborane,a...Reactions of bis-scandium bridged phosphinidene complex,[LSc(μ-PAr)]_(2)(L=MeC(NDIPP)CHC(Me)(NCH_(2)CH_(2)N(^(i)Pr)_(2)),DIPP=2,6-(^(i)Pr)_(2)C_(6)H_(3);Ar=2,6-Me_(2)C_(6)H_(3))(1),with pinacolborane,catecholborane,and 9-borabicyclo[3.3.1]nonane(9-BBN)are reported.Complex 1 reacts with pinacolborane and catecholborane to give scandium pinacolate(2)and catecholate(3),showing B-O bond cleavage.These two scandium complexes contain an unusual[P(Ar)B(H)P(Ar)]^(2−)dianion,which displays aμ-η^(2):η^(2) coordination model.On the other hand,reaction of complex 1 with 9-BBN affords the B-H bond cleavage product,1,3-diphospha-2,4-diboracyclobutane(4).展开更多
Novel conducting oligocatecholborane （OCOB） with electrical conductivity of 3.73 × 10^-2 S cm-1 was successfully synthesized by low-potential electropolymerization of catecholborane （COB） in boron trifluoride...Novel conducting oligocatecholborane （OCOB） with electrical conductivity of 3.73 × 10^-2 S cm-1 was successfully synthesized by low-potential electropolymerization of catecholborane （COB） in boron trifluoride diethyl etherate at 0.70 V versus Ag/AgC1. FT-IR and ^1H-NMR spectra, together with the computational results, proved that COB was polymerized through the coupling at C（4） and C（5} positions and the reactive B- H bond was stable during the electrochemical polymerization. The resulting product was mainly composed of oligomers with short chain lengths by GPC and mass spectral results. The as-formed OCOB film showed good electrochemistry in monomer-free electrolytes with the electrochromic property from opaque blue to sap green. Fluorescence studies indicated that soluble OCOB can emit bright blue light under excitation of 365 nm UV light with the maximum emission at 396 nm and a fluorescence quantum yield of 0.21. The deposited OCOB also exhibited favorable thermal stability and smooth and compact morphology even at high magnifications.展开更多
基金the National Natural Science Foundation of China(Nos.21325210,21132002 and 21121062)the State Key Basic Research&Development Program(No.2012CB821600).
文摘Reactions of bis-scandium bridged phosphinidene complex,[LSc(μ-PAr)]_(2)(L=MeC(NDIPP)CHC(Me)(NCH_(2)CH_(2)N(^(i)Pr)_(2)),DIPP=2,6-(^(i)Pr)_(2)C_(6)H_(3);Ar=2,6-Me_(2)C_(6)H_(3))(1),with pinacolborane,catecholborane,and 9-borabicyclo[3.3.1]nonane(9-BBN)are reported.Complex 1 reacts with pinacolborane and catecholborane to give scandium pinacolate(2)and catecholate(3),showing B-O bond cleavage.These two scandium complexes contain an unusual[P(Ar)B(H)P(Ar)]^(2−)dianion,which displays aμ-η^(2):η^(2) coordination model.On the other hand,reaction of complex 1 with 9-BBN affords the B-H bond cleavage product,1,3-diphospha-2,4-diboracyclobutane(4).
基金supported by the National Natural Science Foundation of China (Nos. 50963002 and 51073074)Jiangxi Provincial Department of Education (Nos. GJJ11590, GJJ10678 and GJJ12595)+1 种基金the Natural Science Foundation of Jiangxi Province (No. 2010GZH0041)Jiangxi Science & Technology Normal University (No. KY2010ZY13)
文摘Novel conducting oligocatecholborane （OCOB） with electrical conductivity of 3.73 × 10^-2 S cm-1 was successfully synthesized by low-potential electropolymerization of catecholborane （COB） in boron trifluoride diethyl etherate at 0.70 V versus Ag/AgC1. FT-IR and ^1H-NMR spectra, together with the computational results, proved that COB was polymerized through the coupling at C（4） and C（5} positions and the reactive B- H bond was stable during the electrochemical polymerization. The resulting product was mainly composed of oligomers with short chain lengths by GPC and mass spectral results. The as-formed OCOB film showed good electrochemistry in monomer-free electrolytes with the electrochromic property from opaque blue to sap green. Fluorescence studies indicated that soluble OCOB can emit bright blue light under excitation of 365 nm UV light with the maximum emission at 396 nm and a fluorescence quantum yield of 0.21. The deposited OCOB also exhibited favorable thermal stability and smooth and compact morphology even at high magnifications.
