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Mitigative Effect of La on Glycine max seedlings under Pb-Cd Compound Pollution 被引量:10
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作者 周青 黄晓华 +1 位作者 曹玉华 张剑华 《Journal of Rare Earths》 SCIE EI CAS CSCD 1999年第4期303-307,共5页
Mitigative effect of La on Glycine max seedlings under combined Pb and Cd pollution was studied through pot culture experiment. The results show that the growth and metabolism of Glycine max seedlings are inhibited by... Mitigative effect of La on Glycine max seedlings under combined Pb and Cd pollution was studied through pot culture experiment. The results show that the growth and metabolism of Glycine max seedlings are inhibited by the solution with 500 mg.L-1 Pb + 100 mg.L-1 Cd. When 30 mg. L-1 LaCl3 is used to spray Glycine max seedlings once, the injury effect of combined Pb and Cd pollution is reduced. The experiment proves that the effect is related to La which can raise photosynthetic rate, chlorophyll content and activity of nitrate reductase, and reduce cell membrane permeability, content of Pb and Cd, and keep TTC reduction ability of Glycine max seedling. 展开更多
关键词 rare earths lanthanum Glycine max seedlings Pb-Cd compound pollution mitigative effect
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Compound pollution of Cd,Pb,Cu,Zn,As in plant-soil system and its prevention 被引量:3
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作者 Wu Yanyu Wang Xin Li Ying(Institute of Applied Ecology,Chinese Academy of Sciences,Shenyang 110015, China) 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 1996年第4期474-482,共9页
By means of both pot and field tests,this paper studied the contents of Cd,Pb,Cu,Zn and As and their ecological effects on plant-soil system.in tissues of crops and soil microorganisms.It was found that there exist sy... By means of both pot and field tests,this paper studied the contents of Cd,Pb,Cu,Zn and As and their ecological effects on plant-soil system.in tissues of crops and soil microorganisms.It was found that there exist synergistic effect among these five elements,especially for Cd in combination.The reclaniation of soil polluted by these elements in combination is rather difficult to be carried out.The distinctive ecological and chemical behaviors between Cd and As make various reclamation measures less applicable,and thus,further research measures are necessary. 展开更多
关键词 compound pollution plant-soil system heavy metals.
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Comparision of China's volatile organic compound pollution management:a computable general equilibrium approach 被引量:2
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作者 Yufei Wang Changxin Liu +2 位作者 Tong Wu Zhengping Hao Zheng Wang 《Chinese Journal of Population,Resources and Environment》 2016年第4期298-308,共11页
The public health and ecological impacts of volatile organic compound(VOCs) pollution have become a serious problem in China,arousing increasing attention to emissions control.In this context,this paper analyses the e... The public health and ecological impacts of volatile organic compound(VOCs) pollution have become a serious problem in China,arousing increasing attention to emissions control.In this context,this paper analyses the effectiveness of VOC reduction policies,namely pollution charges and environmental taxes at the national and industrial sector levels.It uses a computable general equilibrium model,which connects macroeconomic variables with VOC emissions inventory,to simulate the effects of policy scenarios(with 2007 as the reference year).This paper shows that VOC emissions are reduced by 2.2% when a pollution charge equal to the average cost of engineering reduction methods-the traditional approach to regulation in China-is applied.In order to achieve a similar reduction,an 8.9% indirect tax would have to be imposed.It concludes that an environmental tax should be the preferred method of VOC regulation due to its smaller footprint on the macroeconomy.Other policies,such as subsidies,should be used as supplements. 展开更多
关键词 Volatile organic compounds environmental tax pollution charge computable general equilibrium models
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Analysis of Micro Organic Compound Pollution in Major City River Reaches of the Main Stem of the Changjiang River
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作者 WANG Che-huaSenior Engineer, Changjiang River Water Environmental Monitoring Center, Wuhan 430051, China PENG BiaoSenior Engineer, Changjiang River Water Environmental Monitoring Center, Wuhan 430051, China 《人民长江》 北大核心 2002年第S1期63-68,共6页
It has become general for surface waters being polluted by micro organic compounds. In order to know the current pollution situation and the properties of micro organic compounds in the Changjiang River, a test was pe... It has become general for surface waters being polluted by micro organic compounds. In order to know the current pollution situation and the properties of micro organic compounds in the Changjiang River, a test was performed on micro organic compounds in the water, bottom material and fish bodies which were sampled from major city river reaches of the Changjiang River. Based on the test result, researchers described and analyzed the sorts, concentration level and distribution features of micro organic compounds. A comprehensive evaluation was conducted by adopting the method of MEG (Multimedia Environmental Goals). The study indicated that ① the water body of major city river reaches of the Changjiang River has been generally polluted. In the test, totally 12 types with 308 kinds of organic compounds were detected. The main pollutants were paraffins, PAHs and lipids; and ② micro organic pollutant content in fish bodies was generally higher than that in bottom material which is in turn higher than that in water; and ③ pollution is relatively severe in the river reaches of mid-to-large comprehensive industrial cities with fairly great TAS (Total Ambient Severity) of public health and ecological system. 展开更多
关键词 MICRO organic compounds content level distribution features water pollution situation MAJOR CITY RIVER reaches main stem of the CHANGJIANG RIVER
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Studies on Heavy Metal Pollution in Soil-Plant System:A Review 被引量:9
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作者 Wang Haiyan Sun XiangyangCollege of Soil and Water Conservation, Beijing Forestry University, Beijing 100083, P.R. China 《Forestry Studies in China》 CAS 2003年第1期55-62,共8页
Heavy metal pollution in soil-plant system is of major environmental concern on a world scale and in China in particular with the rapid development of industry. The heavy metal pollution status in soil-plant system in... Heavy metal pollution in soil-plant system is of major environmental concern on a world scale and in China in particular with the rapid development of industry. The heavy metal pollution status in soil-plant system in China, the research progress on the bioavailability of heavy metals (affecting factors, extraction methods, free-ion activity model, adsorption model, multivariate regression model, Q-I relationship, and compound pollution), and soil remediation are reviewed in the paper. Future research and monitoring is also discussed. 展开更多
关键词 heavy metal pollution soil-plant system BIOAVAILABILITY free-ion activity model adsorption model multivariate regression model compound pollution soil remediation
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Natural Gas and Indoor Air Pollution: A Comparison With Coal Gas and Liquefied Petroleum Gas
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作者 YUEZHANG BAO-SHENGCHEN +3 位作者 GUANG-QUANLIU JU-NINGWANG ZI-IEN-HUAZHAO LIAN-QINGLIN 《Biomedical and Environmental Sciences》 SCIE CAS CSCD 2003年第3期227-236,共10页
Objective The study was designed to compare the combustion products of coal gas, liquefied petroleum gas and natural gas in relation to indoor air pollution. Methods Regular pollutants including B(a)P were monitored a... Objective The study was designed to compare the combustion products of coal gas, liquefied petroleum gas and natural gas in relation to indoor air pollution. Methods Regular pollutants including B(a)P were monitored and 1-hydroxy pyrene were tested in urine of the enrolled subjects. Radon concentrations and their changes in four seasons were also monitored in the city natural gas from its source plant and transfer stations to final users. To analyze organic components of coal gas, liquefied petroleum gas and natural gas, a high-flow sampling device specially designed was used to collect their combustion products, and semi-volatile organic compounds contained in the particles were detected by gas chromatograph-mass spectrograph (GC/MS). Results Findings in the study showed that the regular indoor air pollutants particles and CO were all above the standard in winter when heating facilities were operated in the city, but they were lowest in kitchens using natural gas; furthermore, although NO2 and CO2 were slightly higher in natural gas, B(a)P concentration was lower in this group and 1-hydroxy pyrene was lowest in urine of the subjects exposed to natural gas. Organic compounds were more complicated in coal gas and liquefied petroleum gas than in natural gas. The concentration of radon in natural gas accounted for less than 1‰ of its effective dose contributing to indoor air pollution in Beijing households. Conclusion Compared to traditional fuels, gases are deemed as clean ones, and natural gas is shown to be cleaner than the other two gases. 展开更多
关键词 Natural gas Indoor air pollution Organic compounds RADON 1-hydroxy pyrene Environmental monitoring
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Review on the Effects of Combined Pollution of Lead and Chromium on Soil Microorganisms and Treatment Methods
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作者 Guangyao Yang Hongsheng Wu +5 位作者 Xiaoling Ma Yujie Tang Jia Li Yao Chai Chaomin Wang Haichao Yang 《Journal of Geoscience and Environment Protection》 2020年第9期140-150,共11页
Heavy metals—Pb and Cr are important causes of environmental pollution, and they often coexist in nature. At present, the effects of Pb and Cr toxicity on soil microorganisms have been less studied, in soil environme... Heavy metals—Pb and Cr are important causes of environmental pollution, and they often coexist in nature. At present, the effects of Pb and Cr toxicity on soil microorganisms have been less studied, in soil environment which is extremely complex. Simulating soil environment and studying microbial reaction under various heavy metal conditions are of great significance for revealing microbial tolerance to heavy metals. In this paper, firstly, the related concepts of soil rechecking pollution are discussed, and the physical and chemical properties and forms of lead and chromium are introduced accordingly. Secondly, the effects of combined pollution of lead and chromium on soil microbial biomass, soil microbial community structure and soil microbial activity were discussed. Finally, the relevant treatment methods of heavy metal contaminated soil were put forward. 展开更多
关键词 compound pollution Heavy Metals Soil Microorganisms
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Mercury pollution in the Chongqing part of the Three Gorges Reservoir area and its remediation and prevention
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作者 杨振宁 刘信安 《Journal of Chongqing University》 CAS 2008年第2期93-99,共7页
Mercury pollution in the Three Gorges Reservoir area of P.R.China merits special attention.We investigated into the current situation in the Chongqing part of the Reservoir area,identified the pollution sources and pr... Mercury pollution in the Three Gorges Reservoir area of P.R.China merits special attention.We investigated into the current situation in the Chongqing part of the Reservoir area,identified the pollution sources and proposed some suggestions for the remediation and prevention of mercury pollution in this area.Atmospheric mercury in Chongqing was mainly from coal burning and releases of mercury-containing products such as various types of lights and fever thermometers.Urban drainage in Chongqing and Changshou,and runoffs from the high mercury background area in the lower reaches of the Wujiang River contributed most of the mercury in the water of the Yangtze River.A majority of the blame should be laid on mercury and gold mining in the Wujiang valley.We suggested foresting sloping lands to relieve soil erosion and prevent mercury-bearing soil from running into rivers,educational activities to discourage use of mercury-containing products and improved infrastructure to collect mercury-containing wastes for reducing mercury releases,more facilities for treating wastewater and solid waste to accommodate increased requirements of discharge,and growing selected perennial plants in mercury-contaminated land to absorb the mercury in soil.We also suggested concerted operation of a dedicated water-quality monitoring system,reinforced legislation and an effective administrative mechanism to ensure lasting efforts are invested in curbing mercury releases and restoring mercury contaminated land and water in the Reservoir area. 展开更多
关键词 汞污染 环境保护 山峡水库 治理措施
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氧化钙活化过硫酸盐修复重金属-有机物复合污染土壤
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作者 程爱华 程岩 李晓军 《应用化工》 CAS CSCD 北大核心 2024年第2期322-326,共5页
采用氧化钙活化过硫酸盐氧化法修复重金属-有机物复合污染土壤,考察了过硫酸钠投加量、过硫酸钠与氧化钙投加比、水土比等对修复效果的影响,探讨了机理。结果表明,在过硫酸钠投加量2.5 mmol/g,氧化钙与过硫酸钠投加比2∶5,水土比3∶1的... 采用氧化钙活化过硫酸盐氧化法修复重金属-有机物复合污染土壤,考察了过硫酸钠投加量、过硫酸钠与氧化钙投加比、水土比等对修复效果的影响,探讨了机理。结果表明,在过硫酸钠投加量2.5 mmol/g,氧化钙与过硫酸钠投加比2∶5,水土比3∶1的条件下,汞、砷的钝化率分别为81%和83%,存在形态由弱酸提取态转化为更为稳定的残渣态,氯仿、苯、总石油烃和1,2,3-三氯丙烷的去除率分别为99%,98%,82%,80%。氧化钙一方面,催化过硫酸盐,产生硫酸根自由基和羟基自由基氧化重金属、降解有机污染物。另一方面,通过物理固封和吸附、络合、沉淀作用钝化汞、砷。研究为重金属-有机物复合污染土壤修复技术的实际应用奠定基础。 展开更多
关键词 土壤修复 重金属-有机物复合污染 氧化钙 过硫酸盐
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进口再生塑料颗粒中特征污染物的筛选及污染特征研究
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作者 白月娇 林晔 +3 位作者 岳波 孟棒棒 张颖 王超 《环境工程技术学报》 CAS CSCD 北大核心 2024年第3期769-777,共9页
为了掌握进口再生塑料颗粒中污染物的污染特性,选取5种不同类型的进口再生塑料颗粒,基于来源及再生利用过程分析其可能含有的污染物类型,筛选出重金属、双酚类化合物〔包括四溴双酚A(BPA)与四溴双酚S(BPS)〕和挥发性有机物(VOCs)3种特... 为了掌握进口再生塑料颗粒中污染物的污染特性,选取5种不同类型的进口再生塑料颗粒,基于来源及再生利用过程分析其可能含有的污染物类型,筛选出重金属、双酚类化合物〔包括四溴双酚A(BPA)与四溴双酚S(BPS)〕和挥发性有机物(VOCs)3种特征污染物进行污染特征分析。结果发现,5种再生塑料颗粒中检测出6种重金属,包括Cr、Mn、Pb、Cd、Cu、Hg,其中Cr、Mn、Pb的浓度相对较高;5种再生塑料颗粒中BPS的检出率达100%,BPA的检出率为20%~100%,且BPS浓度大于BPA,这可能与实际生产中使用BPS等代替BPA有关;5种再生塑料颗粒中检测出的VOCs中,除二氯甲烷外均为苯的同系物。研究结果可为塑料颗粒后续的再生利用提供基础数据支持,并有助于相关部门进一步规范进口再生塑料颗粒的管控。 展开更多
关键词 再生塑料颗粒 特征污染物 重金属 双酚类化合物 挥发性有机物
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上海西南某工业区夏季臭氧污染时期挥发性有机物特征及来源分析
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作者 曹想 李跃武 +6 位作者 赵梦飞 易家林 陈喆 黄蓓佳 段玉森 修光利 段炼 《环境污染与防治》 CAS CSCD 北大核心 2024年第6期796-802,共7页
于2020年8月1—31日在上海金山区省界工业区附近设置观测点,对空气中104种挥发性有机物(VOCs)、氮氧化物(NO_(x))和臭氧(O_(3))水平进行观测。观测期间,O_(3)小时质量浓度为17~262μg/m^(3),平均值为83μg/m^(3),期间出现两次O_(3)污染... 于2020年8月1—31日在上海金山区省界工业区附近设置观测点,对空气中104种挥发性有机物(VOCs)、氮氧化物(NO_(x))和臭氧(O_(3))水平进行观测。观测期间,O_(3)小时质量浓度为17~262μg/m^(3),平均值为83μg/m^(3),期间出现两次O_(3)污染时段,O_(3)时均值分别为119、110μg/m^(3);观测期间总VOCs(TVOCs)体积分数为66.67×10^(-9),VOCs呈白天低、夜间高的变化趋势,各VOCs组分的日变化趋势与TVOCs一致;VOCs的总臭氧生成潜势(OFP)为578.85μg/m^(3),烯烃对OFP的贡献最大;源解析结果表明,两个污染时期的VOCs均与机动车尾气排放及涂料溶剂使用有关,应加强两个VOCs来源的管控;后向轨迹聚类分析表明,两污染时期VOCs高值气团均来自于海上,除周边城市的区域输送外,海上排放源也需加强关注。 展开更多
关键词 挥发性有机物 臭氧污染 臭氧生成潜势 源解析
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陆上石油天然气开采过程中减污降碳协同管控
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作者 杜永亮 汪扬 +5 位作者 何少林 苑宏英 徐薇 宋阳 刘博 徐英俊 《环境工程技术学报》 CAS CSCD 北大核心 2024年第2期371-378,共8页
石油天然气行业是挥发性有机物(VOCs)排放的重要源头,也是甲烷(CH_(4))的最大工业释放源。在石油天然气开采中对VOCs与CH_(4)进行协同管控,实现减污降碳,对我国大气环境治理和“双碳”目标实现具有重要意义。石油天然气开采过程中大部分... 石油天然气行业是挥发性有机物(VOCs)排放的重要源头,也是甲烷(CH_(4))的最大工业释放源。在石油天然气开采中对VOCs与CH_(4)进行协同管控,实现减污降碳,对我国大气环境治理和“双碳”目标实现具有重要意义。石油天然气开采过程中大部分VOCs和CH_(4)释放源具有同根同源性,其中工艺有组织排放和火炬排放分别为最大的VOCs释放源和CH_(4)释放源;在加入新型网络化监测的协同管控路径基础上,选择适宜的管控措施,可提高污染物协同管控的效率;治理成本效益核算中多污染物成本效益法具有更高的经济效益,吸收法和吸附法是技术成熟度和经济性较高的VOCs治理技术,而减少压缩机和发动机启动次数是最经济的CH_(4)减排措施。 展开更多
关键词 石油天然气开采 VOCS CH_(4) 协同管控 减污降碳
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镉和扑草净污染对蚯蚓的急性毒性效应
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作者 李晓岚 吴珂 孙仕仙 《云南农业大学学报(自然科学版)》 CAS CSCD 北大核心 2024年第2期137-144,共8页
【目的】通过蚯蚓死亡率、体质量变化率等数据表征重金属镉和三嗪类农药扑草净单一及复合污染对蚯蚓造成的急性毒性效应,探讨污染物毒性及复合污染关系的变化。【方法】以赤子爱胜蚓(Eisenia fetida)为受试生物,镉和扑草净为受试材料,... 【目的】通过蚯蚓死亡率、体质量变化率等数据表征重金属镉和三嗪类农药扑草净单一及复合污染对蚯蚓造成的急性毒性效应,探讨污染物毒性及复合污染关系的变化。【方法】以赤子爱胜蚓(Eisenia fetida)为受试生物,镉和扑草净为受试材料,采用人工土壤法对比不同污染时间和不同污染物质量分数处理下蚯蚓生理指标的变化。【结果】单一污染时,镉对蚯蚓7和14 d的半致死浓度(LC50)分别为1101.00和543.30 mg/kg;扑草净对蚯蚓7和14 d的LC50分别为91.89和54.04 mg/kg。复合污染时,随着污染时间的增加,主效应因子由扑草净转为镉,污染物毒性也随之增强。【结论】扑草净单一污染的毒性大于镉,但镉在复合污染中的毒性更大。 展开更多
关键词 扑草净 蚯蚓 复合污染 毒性效应
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微塑料与重金属复合污染研究概述
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作者 李睿 卢杰 《现代农业研究》 2024年第6期1-6,共6页
微塑料和重金属污染已成为全球性环境问题,两者结合构成复合污染,对生态系统和人类健康构成潜在威胁。本文阐述了微塑料与重金属复合污染的概念,介绍了微塑料与重金属复合污染的研究方法,包括检测技术与方法和数据分析方法,揭示了微塑... 微塑料和重金属污染已成为全球性环境问题,两者结合构成复合污染,对生态系统和人类健康构成潜在威胁。本文阐述了微塑料与重金属复合污染的概念,介绍了微塑料与重金属复合污染的研究方法,包括检测技术与方法和数据分析方法,揭示了微塑料与重金属复合污染的特点,即复合污染物在环境中的稳定性、生物富集性与毒性,并从污染源控制与管理、修复技术和社会治理三个方面探讨了复合污染的相关防治措施。 展开更多
关键词 微塑料 重金属 复合污染 防治措施
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硅肥和磷矿粉复配对垃圾填埋场重金属污染土壤的修复
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作者 杨媛媛 马海关 +2 位作者 彭岗 黄国棣 黄丽 《华中农业大学学报》 CAS CSCD 北大核心 2024年第3期185-193,共9页
以四川省盐亭县云溪镇垃圾填埋场的紫色土为研究对象,将不同质量分数的硅肥(Si1:0.5%,Si2:1.0%)和磷矿粉(P1:0.2%,P2:0.4%,P3:1.0%)复配添加到土壤中培养90 d,研究钝化培养前后重金属Cd、Cu、Pb、Zn有效态含量的变化,并利用风险评价系数... 以四川省盐亭县云溪镇垃圾填埋场的紫色土为研究对象,将不同质量分数的硅肥(Si1:0.5%,Si2:1.0%)和磷矿粉(P1:0.2%,P2:0.4%,P3:1.0%)复配添加到土壤中培养90 d,研究钝化培养前后重金属Cd、Cu、Pb、Zn有效态含量的变化,并利用风险评价系数(risk assessment code,RAC)评价土壤修复效果。结果显示,高硅处理(Si2:1.0%)相比于低硅处理(Si1:0.5%)能显著降低重金属有效性,其中,Si2P3处理对Cd、Cu、Pb、Zn的钝化率最高,分别为30.79%、27.27%、27.13%、36.88%;Si2P1和Si2P2处理之间没有显著差异,而Si2P1处理可以显著降低重金属浸出毒性量和RAC。研究表明,复配钝化剂主要通过提高土壤pH和EC值,增强O-Si-O、Si-O-Si、H_(2)PO_(4)^(-)、PO4^(3-)等官能团的络合沉淀作用促使重金属由高活性的弱酸提取态、可还原态向低活性的可氧化态、残渣态转化。综合来看,Si2P1处理钝化剂施用量更低,更适合用于垃圾填埋场重金属污染土壤的修复。 展开更多
关键词 硅肥 磷矿粉 复配钝化剂 重金属污染 污染土壤 土壤修复
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外源Cd、Cd-Zn复合污染对绿豆苗的影响 被引量:1
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作者 陈坤 徐龙君 +2 位作者 袁智 李世贵 易俊 《安全与环境学报》 CAS CSCD 北大核心 2011年第5期11-14,共4页
采用盆栽试验,分别向磁器口土样(土壤1)、校园土样(土壤2)中添加不同质量比的Cd及不同质量比的Zn+Cd(20 mg/kg),研究不同质量比外源Cd及Zn+Cd(20mg/kg)复合污染对两种土壤中绿豆苗株高及绿豆苗吸收Cd的影响。结果表明:单一外源不同质量... 采用盆栽试验,分别向磁器口土样(土壤1)、校园土样(土壤2)中添加不同质量比的Cd及不同质量比的Zn+Cd(20 mg/kg),研究不同质量比外源Cd及Zn+Cd(20mg/kg)复合污染对两种土壤中绿豆苗株高及绿豆苗吸收Cd的影响。结果表明:单一外源不同质量比Cd污染绿豆苗时,生长期为7 d的绿豆苗株高较对照组有明显下降,随Cd污染加剧,绿豆苗生长受到抑制,随生长期延长而其危害加剧;随Cd污染的加剧,绿豆苗中Cd质量比增加,并呈正相关性,相同污染水平下,生长期为7 d的绿豆苗Cd质量比均大于生长期为3 d的;在不同污染水平下,土壤1的绿豆苗株高高于土壤2,其绿豆苗Cd质量比低于土壤2;Zn+Cd(20 mg/kg)复合污染时,株高较对照组矮,绿豆苗中Cd质量比随着Zn质量比增加而增加,呈正相关,表现为协同作用;对比土壤1和土壤2,土壤2的株高较低,但其绿豆苗中Cd质量比在不同水平下均高于土壤1。 展开更多
关键词 环境学 镉质量比 复合污染 协同作用
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VOC emitted by biopharmaceutical industries:Source profiles,health risks,and secondary pollution
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作者 Jiawei Ma Lin Li 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2024年第1期570-584,共15页
The biopharmaceutical industry contributes substantially to volatile organic compounds(VOCs)emissions,causing growing concerns and social developmental conflicts.This study conducted an on-site investigation of the pr... The biopharmaceutical industry contributes substantially to volatile organic compounds(VOCs)emissions,causing growing concerns and social developmental conflicts.This study conducted an on-site investigation of the process-based emission of VOCs from three biopharmaceutical enterprises.In the workshops of the three enterprises,26 VOCs were detected,which could be sorted into 4 classes:hydrocarbons,aromatic hydrocarbons,oxygen-containing compounds,and nitrogen-containing compounds.Ketones were the main components of waste gases,accounting for 44.13%-77.85%of the overall VOCs.Process-based source profiles were compiled for each process unit,with the fermentation and extraction units of tiamulin fumarate being the main source of VOC emissions.Dimethyl heptanone,vinyl acetate,diethylamine,propylene glycol methyl ether(PGME),and benzene were screened as priority pollutants through a fuzzy comprehensive evaluation system.Ground level concentration simulation results of the Gauss plume diffusion model demonstrated that the diffusivity of VOCs in the atmosphere was relatively high,indicating potential non-carcinogenic and carcinogenic risks 1.5-2 km downwind.Furthermore,the process-based formation potentials of ozone and secondary organic aerosols(SOAs)were determined and indicated that N-methyl-2-pyrrolidone,dimethyl heptanone,and PGME should be preferentially controlled to reduce the ozone formation potential,whereas the control of benzene and chlorobenzene should be prioritized to reduce the generation of SOAs.Our results provide a basis for understanding the characteristics of VOC emission by biopharmaceutical industries and their diffusion,potentially allowing the development of measures to reduce health risks and secondary pollution. 展开更多
关键词 BIOPHARMACEUTICAL Volatile organic compound Priority pollutant Exposure risk Secondary pollution
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华南地区典型食用鱼中4类卤代芳香化合物的污染特征和摄入风险
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作者 张莉娜 李会茹 +2 位作者 彭平安 刘明洋 胡建芳 《生态毒理学报》 CAS CSCD 北大核心 2024年第3期259-273,共15页
卤代芳香类化合物(HACs)具有环境普遍存在性、持久性、生物富集性和各种毒性,其污染和风险因此受到广泛关注。本研究对华南地区5种常见鱼肉中4类典型HACs进行了分析,结果表明,鱼肉中多氯代二苯并二噁英/呋喃(PCDD/Fs)、类二噁英多氯联苯... 卤代芳香类化合物(HACs)具有环境普遍存在性、持久性、生物富集性和各种毒性,其污染和风险因此受到广泛关注。本研究对华南地区5种常见鱼肉中4类典型HACs进行了分析,结果表明,鱼肉中多氯代二苯并二噁英/呋喃(PCDD/Fs)、类二噁英多氯联苯(DL-PCBs)、多溴代二苯并二噁英/呋喃(PBDD/Fs)和总二噁英类(dioxins)毒性当量(TEQ)的平均值±标准偏差(范围)分别为(0.0680±0.3230)pg·g^(-1)(0~2.21 pg·g^(-1))、(0.118±0.124)pg·g^(-1)(0.000451~0.528 pg·g^(-1))、(0.139±0.164)pg·g^(-1)(0.00882~0.917 pg·g^(-1))和(0.325±0.366)pg·g^(-1)(0.0409~2.30 pg·g^(-1))(以单位湿质量计),均低于欧盟规定的鱼肉中dioxins的TEQ限值;5种鱼中桂花鱼的总TEQ和摄入风险最高,其次是鳗鱼和鲶鱼,鲈鱼最低,但种类间并无显著差异。鱼肉中多溴联苯醚(PBDEs)的浓度(0.347±0.297)ng·g^(-1)(0.0191~1.40 ng·g^(-1))(以单位湿质量计)与国内外相比中等偏低,种类变化顺序为三文鱼>鳗鱼>鲈鱼>桂花鱼>鲶鱼。鱼肉中的PCDD/Fs以高氯代PCDDs为主,可能源于污染饲料和五氯酚/五氯酚钠的使用;DL-PCBs以PCB-118和PCB-105为主,主要源于其商业品和金属冶炼过程;PBDEs的来源包括其商业品和高溴PBDEs脱溴降解;PBDD/Fs以高溴PBDFs为主,其污染与PBDEs密切相关。华南地区居民通过膳食鱼肉摄入4类HACs的致癌和非致癌风险值分别为6.56×10-6~2.87×10-5和0.0314~0.114,其中儿童风险值高于青少年和成人。PBDD/Fs对总TEQ和摄入风险的贡献(平均45.6%)远高于其他HACs,其生物体污染和风险值得持续关注。 展开更多
关键词 卤代芳香化合物 持久性有机污染物 二噁英/呋喃 多氯联苯 多溴联苯醚 致癌风险
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焦化污染区春季VOCs的污染特征及其控制策略
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作者 李宏艳 张琰茹 +8 位作者 付国 黄时丹 李宏宇 崔阳 高雪莹 何秋生 白京霭 张国忠 温彪 《中国环境科学》 EI CAS CSCD 北大核心 2024年第3期1234-1243,共10页
在对介休焦化区和方山对照区春季大气挥发性有机化合物(VOCs)污染特征进行分析的基础上,利用等效丙烯浓度(PEC)法和最大增量反应活性(MIR)法量化了VOCs的臭氧生成潜势(OFP),利用分数气溶胶生成系数(FAC)法和二次有机气溶胶(SOAP)法计算... 在对介休焦化区和方山对照区春季大气挥发性有机化合物(VOCs)污染特征进行分析的基础上,利用等效丙烯浓度(PEC)法和最大增量反应活性(MIR)法量化了VOCs的臭氧生成潜势(OFP),利用分数气溶胶生成系数(FAC)法和二次有机气溶胶(SOAP)法计算了VOCs的二次有机气溶胶生成潜势(SOAFP),采用健康风险评价法对可能会威胁人体健康的VOCs组分进行了风险评估.在此基础上,结合熵值法和正定矩阵因子(PMF)源解析模型对VOCs的优先控制物种和优先控制污染源进行了判别.结果表明,介休焦化区VOCs污染严重,总VOCs(TVOCs)浓度是方山的2.7倍.介休焦化区VOCs组成具有明显的烷烃占比低而芳香烃和烯烃占比高的特点.介休的OFP、SOAFP与健康风险都远高于方山,分别是方山的3.0、8.9和8.8倍,对介休OFP、SOAFP和健康风险影响最大的物种分别为乙烯、甲苯和苯,削减烯烃和芳香烃的排放是控制介休二次生成与健康风险的有效途径.焦化源(32.4%)是介休VOCs的主要来源,其次为汽油型尾气源(29.0%)和溶剂使用源(16.9%),其中焦化源是介休一级控制污染物苯和乙烯的主要来源,贡献高达74.1%和98.9%,汽油型尾气源(52.0%)和溶剂使用源(31.3%)是一级控制污染物甲苯的主要来源. 展开更多
关键词 VOCS 焦化污染 熵值法 二次生成 健康风险 源解析
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杭州市一次持续性O_(3)污染过程成因分析
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作者 张特 许汇锋 +3 位作者 陈玲红 金嘉佳 沈建东 叶旭红 《环境污染与防治》 CAS CSCD 北大核心 2024年第6期810-815,共6页
明确O_(3)污染成因才能采取有效的O_(3)管控措施。针对杭州市2022年9月4—13日发生的一次持续性O_(3)污染过程,研究了污染发生前、污染暴发期、污染持续期以及污染消除期等不同阶段的气象条件、区域背景O_(3)浓度及前体物挥发性有机物(V... 明确O_(3)污染成因才能采取有效的O_(3)管控措施。针对杭州市2022年9月4—13日发生的一次持续性O_(3)污染过程,研究了污染发生前、污染暴发期、污染持续期以及污染消除期等不同阶段的气象条件、区域背景O_(3)浓度及前体物挥发性有机物(VOCs)等,基于正定矩阵因子模型并结合O_(3)生成潜势和后向轨迹模型,重点讨论了造成O_(3)污染的关键VOCs、VOCs排放源贡献及其主要来源。结果表明:高温(日最高温度>28.7℃)、低湿(日均湿度<70%)、静稳天气(风速<3 m/s)的气象条件是此次O_(3)污染的主要外因;乙烯、丙烯、1-丁烯、乙醛等为此次污染过程中生成O_(3)的关键VOCs组分,而关键VOCs载荷较高的排放源中,工艺过程源、机动车排放源和油气挥发源为O_(3)污染暴发的主要内因,石化排放源为O_(3)污染持续的主要内因。 展开更多
关键词 O_(3)污染 成因分析 挥发性有机物 正定矩阵因子模型
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