One-dimensional carbon nano-materials （ODCNMs） synthesized from ethanol flames exhibit various agglomerated morphologies, such as ＂chrysanthemum-like＂, ＂hairball-like＂ or ＂orange-peel-like＂, ＂vertically alig...One-dimensional carbon nano-materials （ODCNMs） synthesized from ethanol flames exhibit various agglomerated morphologies, such as ＂chrysanthemum-like＂, ＂hairball-like＂ or ＂orange-peel-like＂, ＂vertically aligned＂ and ＂wrinkling-pileup＂. The present work studied the agglomerating process and the growth mechanism by using scanning electron microscopy （SEM） and transmission electron microscopy （TEM）. It is thought that the size and distribution of the catalyst particles produced from pretreatment of the substrates play a key role during the formation of agglomerations. It is expected that the steady growth of ODCNMs in flames will be improved through the preparation of the catalysts.展开更多
A dynamic quasi-continuum model is presented to analyze free vibration of plate-type cubic crystal nano-materials.According to the Hamilton principle,fundamental governing equations in terms of displacement components...A dynamic quasi-continuum model is presented to analyze free vibration of plate-type cubic crystal nano-materials.According to the Hamilton principle,fundamental governing equations in terms of displacement components and angles of rotations are given.As an application of the model,the cylindrical bending deformation of the structure fixed at two ends is analyzed,and a theoretical formula evaluating the fundamental frequency is obtained by using Galerkin's method.Meanwhile,the solution for the classical continuous plate model is also derived,and the size-dependent elastic modulus and Poisson's ratio are taken in computation.The frequencies corresponding to different atomic layers are numerically presented for the plate-type NaC l nano-materials.Furthermore,a molecular dynamics(MD)simulation is conducted with the code LAMMPS.The comparison shows that the present quasi-continuum model is valid,and it may be used as an alternative model,which reflects scale effects in analyzing dynamic behaviors of such plate-type nano-materials.展开更多
On February 28th, 2005, AQSIQ (the General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China), and SAC (the Standardization Administration of P. R. China)jointly ho...On February 28th, 2005, AQSIQ (the General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China), and SAC (the Standardization Administration of P. R. China)jointly hosted the press conference on seven items of national standards on nano-materials in Beijing. The seven items of national standards were approved on Sept. 29th and Dec. 27th, 2004 respectively by SAC, and publicized in Jan. 2005. They will be formally put into practice from April 1st, 2005.展开更多
Colloidal CdSe quantum dots(QDs)are promising materials for solar cells because of their simple preparation pro-cess and compatibility with flexible substrates.The QD radiative recombination lifetime has attracted eno...Colloidal CdSe quantum dots(QDs)are promising materials for solar cells because of their simple preparation pro-cess and compatibility with flexible substrates.The QD radiative recombination lifetime has attracted enormous attention as it affects the probability of photogenerated charges leaving the QDs and being collected at the battery electrodes.However,the scaling law for the exciton radiative lifetime in CdSe QDs is still a puzzle.This article presents a novel explanation that recon-ciles this controversy.Our calculations agree with the experimental measurements of all three divergent trends in a broadened energy window.Further,we proved that the exciton radiative lifetime is a consequence of the thermal average of decays for all thermally accessible exciton states.Each of the contradictory size-dependent patterns reflects this trend in a specific size range.As the optical band gap increases,the radiative lifetime decreases in larger QDs,increases in smaller QDs,and is weakly depend-ent on size in the intermediate energy region.This study addresses the inconsistencies in the scaling law of the exciton life-time and gives a unified interpretation over a widened framework.Moreover,it provides valuable guidance for carrier separa-tion in the thin film solar cell of CdSe QDs.展开更多
基金Supported by the Scientific Research Foundationfor the Returned Overseas Chinese Scholars of Chinese Ministry Edu-cation (200233)
文摘One-dimensional carbon nano-materials （ODCNMs） synthesized from ethanol flames exhibit various agglomerated morphologies, such as ＂chrysanthemum-like＂, ＂hairball-like＂ or ＂orange-peel-like＂, ＂vertically aligned＂ and ＂wrinkling-pileup＂. The present work studied the agglomerating process and the growth mechanism by using scanning electron microscopy （SEM） and transmission electron microscopy （TEM）. It is thought that the size and distribution of the catalyst particles produced from pretreatment of the substrates play a key role during the formation of agglomerations. It is expected that the steady growth of ODCNMs in flames will be improved through the preparation of the catalysts.
文摘A dynamic quasi-continuum model is presented to analyze free vibration of plate-type cubic crystal nano-materials.According to the Hamilton principle,fundamental governing equations in terms of displacement components and angles of rotations are given.As an application of the model,the cylindrical bending deformation of the structure fixed at two ends is analyzed,and a theoretical formula evaluating the fundamental frequency is obtained by using Galerkin's method.Meanwhile,the solution for the classical continuous plate model is also derived,and the size-dependent elastic modulus and Poisson's ratio are taken in computation.The frequencies corresponding to different atomic layers are numerically presented for the plate-type NaC l nano-materials.Furthermore,a molecular dynamics(MD)simulation is conducted with the code LAMMPS.The comparison shows that the present quasi-continuum model is valid,and it may be used as an alternative model,which reflects scale effects in analyzing dynamic behaviors of such plate-type nano-materials.
文摘On February 28th, 2005, AQSIQ (the General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China), and SAC (the Standardization Administration of P. R. China)jointly hosted the press conference on seven items of national standards on nano-materials in Beijing. The seven items of national standards were approved on Sept. 29th and Dec. 27th, 2004 respectively by SAC, and publicized in Jan. 2005. They will be formally put into practice from April 1st, 2005.
基金supported by the National Key Research and Development Program of China under Grant No.2021YFB2800304.
文摘Colloidal CdSe quantum dots(QDs)are promising materials for solar cells because of their simple preparation pro-cess and compatibility with flexible substrates.The QD radiative recombination lifetime has attracted enormous attention as it affects the probability of photogenerated charges leaving the QDs and being collected at the battery electrodes.However,the scaling law for the exciton radiative lifetime in CdSe QDs is still a puzzle.This article presents a novel explanation that recon-ciles this controversy.Our calculations agree with the experimental measurements of all three divergent trends in a broadened energy window.Further,we proved that the exciton radiative lifetime is a consequence of the thermal average of decays for all thermally accessible exciton states.Each of the contradictory size-dependent patterns reflects this trend in a specific size range.As the optical band gap increases,the radiative lifetime decreases in larger QDs,increases in smaller QDs,and is weakly depend-ent on size in the intermediate energy region.This study addresses the inconsistencies in the scaling law of the exciton life-time and gives a unified interpretation over a widened framework.Moreover,it provides valuable guidance for carrier separa-tion in the thin film solar cell of CdSe QDs.
