目的制备毒性低,生物相容性好的新型半导体量子点。方法以还原型谷胱甘肽（GSH）为硫源和稳定剂,采用水热法合成Cd Te/Cd S QDs。结果制备的GSH包裹的Cd Te/Cd S QDs波长范围覆盖400~800 nm的区域,量子产率高达83.1%,平均粒径约为3 nm...目的制备毒性低,生物相容性好的新型半导体量子点。方法以还原型谷胱甘肽（GSH）为硫源和稳定剂,采用水热法合成Cd Te/Cd S QDs。结果制备的GSH包裹的Cd Te/Cd S QDs波长范围覆盖400~800 nm的区域,量子产率高达83.1%,平均粒径约为3 nm。结论该Cd Te/Cd S QDs制备方法简便,成本低,有效降低了量子点生物毒性。展开更多
采用简单液相沉积法制备了分级结构Cd S QDs/Bi OCl复合光催化剂,以XRD,SEM,TEM,HRTEM,XPS,EDS,UV-Vis DRS,PL等测试方法分别表征了样品的物相、形貌、组成、元素含量、光吸收性能以及光电特性,并以罗丹明B(Rh B)和苯酚为模型污染物,分...采用简单液相沉积法制备了分级结构Cd S QDs/Bi OCl复合光催化剂,以XRD,SEM,TEM,HRTEM,XPS,EDS,UV-Vis DRS,PL等测试方法分别表征了样品的物相、形貌、组成、元素含量、光吸收性能以及光电特性,并以罗丹明B(Rh B)和苯酚为模型污染物,分别在可见光和紫外光下评价Cd S QDs/Bi OCl复合光催化剂的催化性能。测试结果表明,粒径为5.5μm的Bi OCl微球由大量纳米片有序堆积而成,所负载的粒径为10~20 nm的Cd S QDs均匀分布在Bi OCl纳米片表面。与纯Bi OCl和Cd S QDs/Bi OCl相比,Cd S QDs/Bi OCl-3%表现出最佳的光催化性能,其对Rh B和苯酚的降解速率常数分别是纯Bi OCl的2.6倍和5.3倍。Cd S QDs/Bi OCl复合光催化剂性能的提高可归结于,分级结构Bi OCl有效防止了片层堆积,有助于Cd S QDs的负载,另外,Cd S QDs的负载拓展了复合光催化剂的光吸收性能,均匀分布的Cd S QDs与Bi OCl形成的异质结促进了光生电子-空穴对的有效分离。展开更多
In this paper, interface engineering via sputtering of CdO nanolayer at the buffer-CdS/CdTe-absorber interface is demonstrated as an efficient approach to improve the performance of solar cell device. The i-CdO interf...In this paper, interface engineering via sputtering of CdO nanolayer at the buffer-CdS/CdTe-absorber interface is demonstrated as an efficient approach to improve the performance of solar cell device. The i-CdO interfacial layer with various thicknesses from 5 nm to 35 nm was deposited by DC magnetron sputtering. Comparative studies on TCO/CdS/CdTe and TCO/CdS/CdO/CdTe interfaces have been conducted by current-voltage, capacitance-voltage and admittance spectroscopy measurements. The current-voltage characteristics of the devices with an area of 0.45 cm<sup>2</sup> under 100 mW/cm<sup>2</sup> illumination, at the optimum thickness of CdO intermediate layer in the proposed structures, show increases of the short circuit current density and the open circuit voltage by 5% and 25%, respectively. The efficiency improvement of 3.1% of p-i-n cell over p-n cell is observed. Results of the temperature-dependent current-voltage and admittance measurements revealed the removing of the deep level defect with the activation energy of 0.43 eV and the reducing of the ideality factor from 1.9 to 1.8 via buffer/absorber interfacial passivation method. Interface passivation appears to be critical to improve the short circuit current density and the open circuit voltage, and CdO thin film is clearly effective for this purpose.展开更多
首次将光电化学(PEC)传感应用于[Fe(CN)6]4-检测.合成了光电转换效率较高的TGA-Cd S QDs,并将Cd S QDs/Ti O2/ITO传感电极应用于食盐中抗结剂亚铁氰化钾的检测.实验结果表明:在最优条件下,该方法的线性范围为1.0~12.0μmol/L,线性方程为...首次将光电化学(PEC)传感应用于[Fe(CN)6]4-检测.合成了光电转换效率较高的TGA-Cd S QDs,并将Cd S QDs/Ti O2/ITO传感电极应用于食盐中抗结剂亚铁氰化钾的检测.实验结果表明:在最优条件下,该方法的线性范围为1.0~12.0μmol/L,线性方程为y=4.858x+31.46,相关系数R2=0.998 4,检测限为0.26μmol/L(S/σ=3,σ为10次空白试验的标准偏差).PEC传感策略在检测[Fe(CN)6]4-时,实验方法简单、成本低且检测效率高.展开更多
In this work,glutathione capped CdTe QDs(GSH-QDs)were prepared through a one-pot process and found to be quenched by Cr^3+,Ag^+and Cu^2+ions.Cr^3+and chromium(III)picolinate could be quantitatively measured after mask...In this work,glutathione capped CdTe QDs(GSH-QDs)were prepared through a one-pot process and found to be quenched by Cr^3+,Ag^+and Cu^2+ions.Cr^3+and chromium(III)picolinate could be quantitatively measured after masking Cu^2+and Ag+ions by sulfide.Under optimal conditions,linear quenching was observed for Cr^3+in the ranges of 0–2.0M and the limit of detection was 3.0 nM.The recoveries for Cr^3+in vitamin supplements obtained were from 92.5%to 106%.The determination results of chromium(III)picolinate in vitamin supplement samples were compared to that obtained using flame atomic absorption spectrometry(FAAS)method,and the result showed good reliability.展开更多
文摘目的制备毒性低,生物相容性好的新型半导体量子点。方法以还原型谷胱甘肽（GSH）为硫源和稳定剂,采用水热法合成Cd Te/Cd S QDs。结果制备的GSH包裹的Cd Te/Cd S QDs波长范围覆盖400~800 nm的区域,量子产率高达83.1%,平均粒径约为3 nm。结论该Cd Te/Cd S QDs制备方法简便,成本低,有效降低了量子点生物毒性。
文摘采用简单液相沉积法制备了分级结构Cd S QDs/Bi OCl复合光催化剂,以XRD,SEM,TEM,HRTEM,XPS,EDS,UV-Vis DRS,PL等测试方法分别表征了样品的物相、形貌、组成、元素含量、光吸收性能以及光电特性,并以罗丹明B(Rh B)和苯酚为模型污染物,分别在可见光和紫外光下评价Cd S QDs/Bi OCl复合光催化剂的催化性能。测试结果表明,粒径为5.5μm的Bi OCl微球由大量纳米片有序堆积而成,所负载的粒径为10~20 nm的Cd S QDs均匀分布在Bi OCl纳米片表面。与纯Bi OCl和Cd S QDs/Bi OCl相比,Cd S QDs/Bi OCl-3%表现出最佳的光催化性能,其对Rh B和苯酚的降解速率常数分别是纯Bi OCl的2.6倍和5.3倍。Cd S QDs/Bi OCl复合光催化剂性能的提高可归结于,分级结构Bi OCl有效防止了片层堆积,有助于Cd S QDs的负载,另外,Cd S QDs的负载拓展了复合光催化剂的光吸收性能,均匀分布的Cd S QDs与Bi OCl形成的异质结促进了光生电子-空穴对的有效分离。
文摘In this paper, interface engineering via sputtering of CdO nanolayer at the buffer-CdS/CdTe-absorber interface is demonstrated as an efficient approach to improve the performance of solar cell device. The i-CdO interfacial layer with various thicknesses from 5 nm to 35 nm was deposited by DC magnetron sputtering. Comparative studies on TCO/CdS/CdTe and TCO/CdS/CdO/CdTe interfaces have been conducted by current-voltage, capacitance-voltage and admittance spectroscopy measurements. The current-voltage characteristics of the devices with an area of 0.45 cm<sup>2</sup> under 100 mW/cm<sup>2</sup> illumination, at the optimum thickness of CdO intermediate layer in the proposed structures, show increases of the short circuit current density and the open circuit voltage by 5% and 25%, respectively. The efficiency improvement of 3.1% of p-i-n cell over p-n cell is observed. Results of the temperature-dependent current-voltage and admittance measurements revealed the removing of the deep level defect with the activation energy of 0.43 eV and the reducing of the ideality factor from 1.9 to 1.8 via buffer/absorber interfacial passivation method. Interface passivation appears to be critical to improve the short circuit current density and the open circuit voltage, and CdO thin film is clearly effective for this purpose.
文摘首次将光电化学(PEC)传感应用于[Fe(CN)6]4-检测.合成了光电转换效率较高的TGA-Cd S QDs,并将Cd S QDs/Ti O2/ITO传感电极应用于食盐中抗结剂亚铁氰化钾的检测.实验结果表明:在最优条件下,该方法的线性范围为1.0~12.0μmol/L,线性方程为y=4.858x+31.46,相关系数R2=0.998 4,检测限为0.26μmol/L(S/σ=3,σ为10次空白试验的标准偏差).PEC传感策略在检测[Fe(CN)6]4-时,实验方法简单、成本低且检测效率高.
基金The work was supported by the National Natural Science Foundation of China(31371767)the National S&T support program of China(2015BAD17B02)+1 种基金Jiangsu Entry-Exit Inspection and Quarantine Bureau China(2017KJ19)the National Engineering Research Center for Functional Food,Jiangnan University and the Collaborative Innovation Center of Food Safety and Quality Control in Jiangsu Province,Jiangnan University.
文摘In this work,glutathione capped CdTe QDs(GSH-QDs)were prepared through a one-pot process and found to be quenched by Cr^3+,Ag^+and Cu^2+ions.Cr^3+and chromium(III)picolinate could be quantitatively measured after masking Cu^2+and Ag+ions by sulfide.Under optimal conditions,linear quenching was observed for Cr^3+in the ranges of 0–2.0M and the limit of detection was 3.0 nM.The recoveries for Cr^3+in vitamin supplements obtained were from 92.5%to 106%.The determination results of chromium(III)picolinate in vitamin supplement samples were compared to that obtained using flame atomic absorption spectrometry(FAAS)method,and the result showed good reliability.
