Change Color Effect and Spectral Properties of Gold Nanoparticle-cationic Surfactants System

The change color effect of gold nanoparticle solutions was studied by means of resonance scattering and absorption spectrometry and scan electron microscopy. The red Au nanoparticles with a size of 10 nm exhibit a resonance absorption peak and a resonance scattering peak all at 525 nm. After some inorganic electrolyte was added to a red Au nanoparticles solution, the color of the solution became blue and the absorbance at (600_700) nm was significantly increased. The ratio of the concentration of monovalent cations, at which the resonance scattering of the system at 525 nm is maximal to that of divalent cations, is in the range of 100∶1_100∶1.8. It is in good agreement with the Schulze-Hardy rule of the coagulation value of electrolyte. After adding some cationic surfactants to the above solution, the color of the solution is in deep blue, with two resonance absorption peaks at 550 and 680 nm, and a greatly enhanced resonance scattering peak at 525 nm. The experiments demonstrate that the stronger the hydrophobicity of the cationic surfactant is, the stronger the change color effect of the Au nanoparticle solution promoted by cationic surfactant is. The change color effect of Au nanoparticle solution is resulted from the increased diameter of Au nanoparticles, and the changes of resonance absorption peak and resonance scattering.

The magnetic properties and magnetocaloric effects in binary R-T(R = Pr,Gd,Tb,Dy,Ho,Er,Tm;T = Ga,Ni,Co,Cu)intermetallic compounds

In this paper, we review the magnetic properties and magnetocaloric effects（MCE） of binary R–T（R = Pr, Gd, Tb,Dy, Ho, Er, Tm; T = Ga, Ni, Co, Cu） intermetallic compounds（including RGa series, RNi series, R_（12）Co_7 series, R_3 Co series and RCu_2series）, which have been investigated in detail in the past several years. The R–T compounds are studied by means of magnetic measurements, heat capacity measurements, magnetoresistance measurements and neutron powder diffraction measurements. The R–T compounds show complex magnetic transitions and interesting magnetic properties.The types of magnetic transitions are investigated and confirmed in detail by multiple approaches. Especially, most of the R–T compounds undergo more than one magnetic transition, which has significant impact on the magnetocaloric effect of R–T compounds. The MCE of R–T compounds are calculated by different ways and the special shapes of MCE peaks for different compounds are investigated and discussed in detail. To improve the MCE performance of R–T compounds,atoms with large spin（S） and atoms with large total angular momentum（J） are introduced to substitute the related rare earth atoms. With the atom substitution, the maximum of magnetic entropy change（？SM）, refrigerant temperature width（Twidth）or refrigerant capacity（RC） is enlarged for some R–T compounds. In the low temperature range, binary R–T（R = Pr, Gd,Tb, Dy, Ho, Er, Tm; T = Ga, Ni, Co, Cu） intermetallic compounds（including RGa series, RNi series,R_（12）Co_7 series, R_3 Co series and RCu_2series） show excellent performance of MCE, indicating the potential application for gas liquefaction in the future.

Effects of Land Use Change on Eco-environment in Hilly Area of Central Sichuan Basin——A Case Study of Yanting County, Sichuan Province

With the artificial alder and cypress mixed forest being planted, there has been a marked land use change since 1970s' in Hilly Area of Central Sichuan Basin, China. Data from meteorological observations or posts operated over long time, measurement and calculation of NPP (net primary production) and biomass of biological community, and analysis of soil organic matter content show that the artificial alder and cypress mixed forest has outstanding eco-environmental effect: adjusting local climate, raising soil fertility, alleviating menace of drought, and raising NPP and biomass of biological community. It is very beneficial for improving ecological environment to afforest artificial alder and cypress mixed forest in populous Hilly Area of Central Sichuan Basin, China. Key Words: land use/land cover change (LUCC); eco-environmental effect; Hilly Area of Central Sichuan Basin; the artificial alder and cypress mixed forest

Characteristics of gravity signal and loading effect in China

The complex geographical environment in China makes its gravity signals miscellaneous.This work gives a comprehensive representation and explanation in secular trend of gravity change in different regions,the key features of which include positive trend in inner Tibet Plateau and South China and negative trend in North China plain and high mountain Asia（HMA）.We also present the patterns of amplitudes and phases of annual and semiannual change.The mechanism underlying the semiannual period is explicitly discussed.The displacement in three directions expressed in terms of geo-potential spherical coefficients and load Love numbers are given.A case study applied with these equations is presented.The results show that Global Positioning System（GPS） observations can be used to compare with Gravity Recovery and Climate Experiment（GRACE） derived displacement and the vertical direction has a signal-noise-ratio of about one order of magnitude larger than the horizontal directions.

Numerical Experiments of the Effects of Initial Desert Moisture on the Climate Change

A numerical model with the p-sigma incorporated coordinate system and primitive equations is used to simulate the effect of initial soil moisture in desert areas on the climate change. The results show that the present deserts have a tendency to expand. When the initial soil moisture in the desert regions increases,the desert areas will shrink but can not disappear. The small deserts may not remain any longer when there are sources of water vapour around. Both the land-sea contrast and the topography are the background conditions of the present desert distribution through the mechanism of the downdrafts and the rare precipitation over the desert regions. The increase of the initial desert soil moisture will weaken the summer monsoon circulation and, consequently, the monsoonal precipitation.

Observation of giant magnetocaloric effect under low magnetic fields in EuTi_(1-x)Co_xO_3

The magnetic properties and magnetocaloric effect（MCE） in EuTi1-xCoxO3（x = 0, 0.025, 0.05, 0.075, 0.1） compounds have been investigated. When the Ti^4＋ ions were substituted by Co2＋ions, the delicate balance was changed between antiferromagnetic（AFM） and ferromagnetic（FM） phases in the EuTiO3 compound. In EuTi1-xCoxO3 system, a giant reversible MCE and large refrigerant capacity（RC） were observed without hysteresis. The values of -△SM^max were evaluated to be around 10 J·kg^-1·K^-1 for EuTi0.95Co0.05O3 under a magnetic field change of 10 kOe. The giant reversible MCE and large RC suggests that EuTi1-xCoxO3 series could be considered as good candidate materials for low-temperature and low-field magnetic refrigerant.

Influence of Ni/Mn ratio on magnetostructural transformation and magnetocaloric effect in Ni48-xCo2Mn38+xSn12(x=0,1.0,1.5,2.0,and 2.5)ferromagnetic shape memory alloys

An investigation on the magnetostructural transformation and magnetocaloric properties of Ni48-xCo2Mn38＋xSn12（x = 0, 1.0, 1.5, 2.0, and 2.5） ferromagnetic shape memory alloys is carried out. With the partial replacement of Ni by Mn in the Ni_（48）Co2Mn38Sn12 alloy, the electron concentration decreases. As a result, the martensitic transformation temperature is decreased into the temperature window between the Curie-temperatures of austenite and martensite. Thus, the samples with x = 1.5 and 2.0 exhibit the magnetostructural transformation between the weak-magnetization martensite and ferromagnetic austenite at room temperature. The structural transformation can be induced not only by the temperature,but also by the magnetic field. Accompanied by the magnetic-field-induced magnetostructural transformation, a considerable magnetocaloric effect is observed. With the increase of x, the maximum entropy change decreases, but the effective magnetic cooling capacity increases.

Assessing the Effect of Natural Controls and Land Use Change on Sediment Yield in a Major Andean River:The Magdalena Drainage Basin,Colombia

马格达莱纳河是哥伦比亚安第斯山区的一个世界级的河流网络，该河流年产沙量约为150Mt，是全世界10大主要产沙河流之一。在本研究中，我们探讨主要自然因子和人类活动对马格达莱纳河流域产沙模式的影响，重建该区森林砍伐和农业活动时空模式，探讨土地利用变化与产沙趋势的关系。我们的研究结果表明，整个马格达莱纳河流域的产沙量可以用自然变量（包括径流量和最大河水流量）来解释。这两个因子解释了产沙量58％的变化。含沙率和土地利用的时间分析表明，在过去10～20年里流域侵蚀呈现增加的趋势。许多人类活动的影响，包括森林覆被在20年里减小了近40％．农业和牧场增加了65％、土壤保持差、开矿活动，以及城市化的加速，都促进了该地区域尺度上产沙量的增加。

The neural butterfly effect The injury to peripheral nerves changes the brain

Regeneration of damaged innervations in the peripheral nervous system （PNS） has been well documented in both animals and human. After injury, the damaged neurite swells and undergoes retrograde degeneration. Once the debris is cleared, it begins to sprout and restore damaged connections. Damaged axons are able to regrow as long as the perikarya are intact and have made contact with the Schwann cells in the endoneurial channel[2]. Under appropriate conditions,

Modulating effects of survivin antisense oligonucleotide on changes of apoptosis and cell cycle of human hepatocellular carcinoma cell line SMMC-7721

To investigate the modulating effects of survivn antisense oligonucletode (ASODN) on the cell cycle and apoptosis of human hepatocellular carcinoma (HCC) cell line SMMC-7721 and explore its mechanism.Methods Survivin ASODN was transfected into SMMC-7721 cells mediated by DOTAP liposomal reagent.Electron microscopy,flow cytometry and RT-PCR were used to detect the changes in cell ultrastructure,apoptosis,cell cycle and the expression of cyclinB1 mRNA,respectively.Results After transfection of survivin ASODN,the expression of cyclinB1 mRNA in the cells significantly increased and increase in G2-M arrest and apoptosis appeared.Meanwhile,the cell ultrastructure had apoptotic changes such as chromatin condensation and apoptotic body formation.Conclusion Survivin ASODN can induce the expression of cyclinB1 that may result in G2-M arrest.Consequently,apoptosis is triggered.Survivin ASODN transfection might be an improtant new treatment for HCC.14 refs,2 figs,1 tab.

THE CURATIVE EFFECT OF HIGH EFFICIENCY HEMODIALYSIS AND THE GRADIENT CHANGE OF PLASMA OSMOTIC PRESSURE(Report of 27 Cases)

ＴＨＥＣＵＲＡＴＩＶＥＥＦＦＥＣＴＯＦＨＩＧＨＥＦＦＩＣＩＥＮＣＹＨＥＭＯＤＩＡＬＹＳＩＳＡＮＤＴＨＥＧＲＡＤＩＥＮＴＣＨＡＮＧＥＯＦＰＬＡＳＭＡＯＳＭＯＴＩＣＰＲＥＳＳＵＲＥ（Ｒｅｐｏｒｔｏｆ２７Ｃａｓｅｓ）ＣｈｅｎＨｕａｊｉ（ＣｅｎｔｒａｌＨｏｓ...

Effects of changing cognitive factors on the quality of life in patients with functional dyspepsia

Objective To explore the effects of cognitive intervention on the quality of life in patients with functional dyspepsia(FD).Methods From May 2013 to February2015,a total of 412 patients with FD were enrolled,cognition of the disease and the quality of life were assessed by disease cognitive simple questionnaire(B-IPQ)and Nepean dyspepsia index(NDI).The patients also re-

Adaptation Strategies to Mitigate Impact of Climate Change on Food Crops Farming in Oyo State,Nigeria

The research investigated the adaptation strategies to mitigate consequence of climate change on food crops farming in Oyo State.120 respondents were selected for this study using multi-stage sampling procedures.Primary data was collected through interview schedule and analyzed using both descriptive and inferential statistics.Available results indicated that 84.2% of the respondents were male,93.3% of them were married and maize(45.8%),cassava(37.5%)are the mainly crops cultivated.Results also revealed that 70.0% of the respondents have knowledge of climate change with majority(84.17%)of them regularly accessed information on climate change through radio and 88.3%of them claimed to adopt planting crops favorable for the present weather condition as an adaptation techniques to mitigate the consequences of climate change more frequently.Chi-square and Correlation results revealed a significant relationship existed between farmers educational levels(X2=4.861;p=0.003);household size(r=-0.089;p=0.002);knowledge(r=-0.157;p=0.002),and adaptation strategies to reduce the consequences of climate change on the food crops farming.It was recommended that food crop farmers should be provided with better education and sensitized in order for them to be acquainted with adaptation techniques and coping mechanisms that are currently been offered by research.

Climatic change: Causal correlations over the last 240 Ma

The climate of the Earth has been oscillating between mega warm periods and mega cold periods for 3,000 Ma. Each mega cold period included alternating major warm and cold events. The present mega cold period commenced about 44 Ma in the polar re- gions as the seas cooled following the loss of the circum-equatorial ocean. Before then, a mega warm period lasted for more than 200 Ma. The frequency of the major cold events within the present mega cold period is increasing, with each continent being un- der the influence of a different set of climatic controls. There are many causes of these shifts in climate, ranging from fluctuating meridional ocean currents, rearrangement of tectonic plates, and changes in ocean gateways. These are enhanced by a combination of Milankovitch cycles and many other medium to small oscillations and cyclic controls that cause the daily, monthly, and season- al fluctuations in weather. Examples are given of how these can cause a change from cold to warm events, or vice versa, at pre- sent-day or mega scales, aided by eustatic changes in sea levels and changes in the distribution of air masses, sea ice, and snow.

Coupling the 4M crop model with national geo-databases for assessing the effects of climate change on agro-ecological characteristics of Hungary

The 4M crop model was used to investigate the prospective effects of climate change on the agro-ecological characteristics of Hungary.The model was coupled with a detailed meteorological database and spatial soil information systems covering the whole territory of Hungary.Plant-specific model parameters were determined by inverse modeling.Future meteorological data were produced from the present meteorological data by combining a climate change scenario and a stochastic weather generator.Using the available and the generated data,the present and the prospective agro-ecological characteristics of Hungary were determined.According to the simulation results,average yields will decrease considerably(-30%)due to climate change.The rate of nitrate leaching will prospectively decrease as well.The fluctuations of both the yields and the annual nitrate leaching rates will most likely increase approaching the end of the twenty-first century.On the basis of the simulation results,the role of autumn crops is likely to become more significant in Hungary.The achieved results can be generalized for more extended regions based on the concept of spatial(geographical)analogy.

Effect of proportion change of aluminum and silicon on magnetic entropy change and magnetic properties in La0.8Ce0.2Fe11.5Al1.5-xSix compounds

The microstructure, magnetic entropy changes, hysteresis and magnetic properties of La_（0.8）Ce_（0.2）Fe_（11.5）Al_（1.5–x）Si_x（x=0.4, 0.5, 0.6, 0.7） compounds were studied by X-ray diffraction（XRD） and a superconducting quantum interference device magnetometer（SQUID）. The results showed that all the compounds presented cubic Na Zn13-type structure. Their Curie temperatures changed complicatedly with decreasing Al content due to changes of antiferromagnetic and ferromagnetic interaction. Under a field change from 0 to 2 T, the maximum magnetic entropy change for La_（0.8）Ce_（0.2）Fe_（11.5）Al_（1.1）Si_（0.4）, La_（0.8）Ce_（0.2）Fe_（11.5）Al_（1.0）Si_（0.5）, La_（0.8）Ce_（0.2）Fe_（11.5）Al_（0.9）Si_（0.6） and La_（0.8）Ce_（0.2）Fe_（11.5）Al_（0.8）Si_（0.7） were found to be –9.6, –4.8, –5.8 and –11.7 J/（kg·K）, respectively. Moreover, their hysteresis losses were 1.13 J/（kg·K） or less. The large magnetic entropy changed and small hysteresis losses made them potential candidates for practical magnetic refrigeration application.

Effects of manganese doping on magnetocaloric effect in Ge-rich Gd_5Ge_(2.05)Si_(1.95) alloy

The structure, magnetic and magnetocaloric properties of the Ge-rich Gd5Ge2.05-xSi1.95-xMn2x （x=0.01 and 0.03） alloys were investigated by scanning electron microscopy, X-ray powder diffraction, differential scanning calorimeter （DSC） and magnetization measurements. The results of energy dispersive X-ray analysis （EDX） and X-ray diffraction analyses showed that the composition and crystal structure of the alloys were desired. DSC measurements were performed to determine the transformation temperatures for each alloy. Both alloys exhibited the first order phase transition around room temperature. The alloys showed an anti-ferromagnetic transition around 60 K. The isothermal magnetic entropy changes of the alloys were determined from the isothermal magnetization measurements by using the Maxwell relation. The maximum values of isothermal magnetic entropy change of the Gd5Ge2.05-xSi1.95-xMn2x alloy with x=0.01 was found to be -12.1 and -19.8 J/（kg·K） using Maxwell equation around 268 K in applied fields of 2 and 5 T, respectively.

Effect of the change of ghrelin and its receptor on accelerating diabetic encephalopathy by blood glucose fluctuation in GK rats

Objective To explore the the effect of the changes of ghrelin and its receptor(GHSR1a)on accelerating diabetic encephalopathy by blood glucose fluctuation in GK rats.Methods Eight male wistar rats were set as normal control group(NC).16 male GK rats were randomly divided into sustained hyperglycemia group(MS)and blood glucose fluctuation group(MF).MF group

A new broom sweeps clean:is there a Chinese-style political business cycle?

Politics is an important cause of economic growth and fluctuations.We present a new Political Business Cycle(PBC)Theory based on the background of recent Chinese economic transformation and government behaviors,explore the economic impact of the National Congress of the Communist Party of China(CPC),the National People’s Congress(NPC)and Chinese People’s Political Consultive Conference(CPPCC)and how they shape and influence the behaviors of local government officials.Based on 1994-2012 inter-provincial panel data of China and using SYS-GMM and LSDVC,we find that there are significant effects in China of PBC and government administration change.Changes in government administration influence the economic behaviors of local governments,which in turn influence local economic development through fiscal decentralization and political promotion tournament.These effects are sustained and robust.In this paper we offer an economic explanation for the Chinese proverb“a new broom sweeps clean,”and try to verify the Chinese-style Political Business Cycle(CPBC).We provide new ideas for further improving the functions of government,optimizing macroeconomic control,and preventing personnel changes in the government from overheating the economy.

Mass production of magnetocaloric LaFeMnSiB alloys with hydrogenation

LaFe_（11.39）Mn_（0.35）Si_（1.26）B_（0.1）Hxalloys were prepared by hydrogenation.Samples were annealed at 1343Kfor30-90 hto form the NaZn13 phase.La-rich andα-Fe secondary phases were also detected.Saturated hydrogenation at 553 Kand 0.15 MPa of H_2 pressure for 5hwas employed to improve the Curie temperature of the alloys to 279 K.The maximum magnetic entropy change,relative cooling power,and adiabatic temperature change of LaFe_（11.39）Mn_（0.35）Si_（1.26）B_（0.1）H_x annealed at 1343 Kfor 90hafter hydrogen absorption are 6.38J/（kg·K）（magnetic changesμ0ΔH =1.65T）,100.1J/kg（μ0ΔH =1.65T）,and 2.2 K（μ0ΔH =1.48T）,respectively.Although the maximum magnetic entropy change of the LaFe_（11.39）Mn_（0.35）Si_（1.26）B_（0.1）H_x alloys is lower than those of similar alloys with high purity raw materials,the relative cooling power is nearly the same.The effect of impurities of the raw materials used was also discussed.It is assumed that the impurity of 0.2wt.% Al is responsible for the reduced entropy change of the resulted alloys.The LaFe_（11.39）Mn_（0.35）Si_（1.26）B_（0.1）H_x alloys prepared by this method could be a low cost alternative material for room temperature magnetic cooling applications.