Optimization of Channel Structure of Alkaline Water Electrolyzer by Using an Expanded Mesh as a Bipolar Plate

Alkaline water electrolysis(AWE)is the most mature technology for hydrogen production by water electrolysis.Alkaline water electrolyzer consists of multiple electrolysis cells,and a single cell consists of a diaphragm,electrodes,bipolar plates and end plates,etc.The existing industrial bipolar plate channel is concave-convex structure,which is manufactured by complicated and high-cost mold punching.This structure still results in uneven electrolyte flow and low current density in the electrolytic cell,further increasing in energy consumption and cost of AWE.Thereby,in this article,the electrochemical and flow model is firstly constructed,based on the existing industrial concave and convex flow channel structure of bipolar plate,to study the current density,electrolyte flow and bubble distribution in the electrolysis cell.The reliability of the model was verified by comparison with experimental data in literature.Among which,the electrochemical current density affects the bubble yield,on the other hand,the generated bubbles cover the electrode surface,affecting the active specific surface area and ohmic resistance,which in turn affects the electrochemical reaction.The result indicates that the flow velocity near the bottom of the concave ball approaches zero,while the flow velocity on the convex ball surface is significantly higher.Additionally,vortices are observed within the flow channel structure,leading to an uneven distribution of electrolyte.Next,modelling is used to optimize the bipolar plate structure of AWE by simulating the electrochemistry and fluid flow performances of four kinds of structures,namely,concave and convex,rhombus,wedge and expanded mesh,in the bipolar plate of alkaline water electrolyzer.The results show that the expanded mesh channel structure has the largest current density of 3330 A/m^(2)and electrolyte flow velocity of 0.507 m/s in the electrolytic cell.Under the same current density,the electrolytic cell with the expanded mesh runner structure has the smallest potential and energy consumption.This work provides a useful guide for the comprehensive understanding and optimization of channel structures,and a theoretical basis for the design of large-scale electrolyzer.

Study about the Asymmetry Competing Channel Structure under Bargaining Power

On the problem of competing channel structure, we present asymmetry competing channel structure models under bargaining power, analyze the evolving process of channel structure under different bargaining power and product nature, find different bargaining power and product nature important role for channel structure, and also present equilibrium result. Furthermore, the academic proof for channel structure choice is presented.

Study Competition Channel Structure Based on the Differences of Cost and Products

The purpose of this paper is to expand Trivedi’s study on the influence of channel structure ,which based on product difference, to cost difference; and analyze the evolution course of channel structure under different conditions. We find that like product difference, cost difference have important influence on the choice of channel structure. This paper has improved the present result and provided proof for the choice of channel structure under different environments.

Study about the Competing Channel Structure under Bargaining Power

From the bargaining process, competing channel structure models are presented. The evolving process of channel structure under different bargaining power is analyzed The important role of different bargaining power is discussed and the equilibrium result is found. Also the theoretical evidences for competing channel structure choice are given.

Heat Transfer and Friction Characteristics of Printed Circuit Heat Exchangers with Different Channel Structures for S-CO_(2) Power System

Printed circuit heat exchanger(PCHE)has been widely used in supercritical carbon dioxide(S-CO_(2))power systems because of its high heat transfer efficiency and good compactness.However,due to the large variety of PCHE configurations,channel selection in practical applications lacks a basis.Therefore,this paper discussed the heat transfer and friction characteristics and the synergy of three fields in the channel under the guidance of the field synergy principle for four typical PCHE channels.Additionally,the comprehensive performance of four channels was compared.Finally,the heat transfer and friction factor correlations for S-CO_(2)in four channels were established.The findings demonstrate that the synergy of velocity and pressure fields of the straight channel PCHE is better(β≈180°),so its resistance loss is relatively small.The zigzag and sinusoidal wavy channels and the airfoil fins can reduce the angle a between the temperature gradient and velocity,thus enhancing the heat transfer.The sinusoidal wavy channel can reduce flow resistance compared to the zigzag channel due to the rounded corners.The streamlined airfoil structure can guide the flow and reduce backflow,thus reducing resistance losses.In the range of Re studied in this paper,the maximum error of the proposed heat transfer and friction factor correlations of PCHE is 7.0%,which shows good fitting accuracy.The research in this paper can provide a reference for the selection and design of PCHE with different channel configurations.

A Novel Layered Complex with Rhomboidal Channels:Hydrothermal Synthesis,Crystal Structure,and Properties of Cu(4,4'-bipy)_2(H_2PO_4)_2(H_2O)_2 (bipy=bipyridine)

The combination of both 4,4′-bipyridine(4,4′-bipy) and dihydrogen phosphate anion ligands with copper(Ⅱ) results in the formation of a novel layered compound Cu(4,4′-bipy)_2(H_2PO_4)_2(H_2O)_2. The crystal structure comprises discrete neutral Cu(4,4′-bipy)_2(H_2PO_4)_2(H_2O)_2 units. The copper atom,located on the crystallographic twofold axis,is coordinated with two nitrogen atoms of terminal 4,4′-bipy ligands and two water molecules at the equatorial positions,and two dihydrogen phosphate oxygen atoms at the axial positions,forming an elongated octahedron. The complex is a two-dimensional distorted rhomboidal network possessing two kinds of rhomboids with dimensions of ca . 1.6792 nm×0.3203 nm and 1.2778 nm×0.3198 nm,respectively. The two-dimensional networks are stacked parallelly on each other along c -axis to give an extended three-dimensional channel network with an interlayer distance of ca . 0.5030 nm. Crystal data: triclinic,space group P -_1,a =1.0253(2) nm,b =1.4501(3) nm,c =0.79715(16) nm, α =97.91(3)°,β = 90.99(3)° ,γ =85.54(3)°,V =1.1703(4) nm 3,Z =2,R =0.0892,wR =0.2451.

Theoretical and Experimental Optimization of InGaAs Channels in GaAs PHEMT Structure

The ground-state energy level （GEL） and electron distribution of GaAs pseudomorphic high-electron-mobility transistors （PHEMTs） are analyzed by a self-consistent solution to the Schrodinger-Poisson equations. The indium composition and thickness of the InGaAs channel are optimized according to the GEL position. The GEL position is not in direct proportion to 1/d^2 （d is the channel thickness） by considering the influence of electron distribution in the InGaAs channel. Indium composition 0.22 and channel thickness 9 nm are obtained by considering the mismatch between InGaAs and AlGaAs. Several PHEMT samples are grown according to the theoretical results and mobility 6300 cm^2 /V.s is achieved.

Helix-like structure formation of a semi-flexible chain confined in a cylinder channel

Molecular dynamics method is used to study the conformation behavior of a semi-flexible polymer chain confined in a cylinder channel.A novel helix-like structure is found to form during the simulation.Moreover,the detailed characteristic parameters and formation probability of these helix-like structures under moderate conditions are investigated.We find that the structure is not a perfect helix,but a bundle of elliptical turns.In addition,we conduct a statistical analysis for the chain monomer distribution along the radial direction.This research contributes to our understanding of the microscopic conformation of polymer chains in confined environments filled with a solvent.

Voltage-gated Sodium Channels and Blockers:An Overview and Where Will They Go?

Voltage-gated sodium(Nav)channels are critical players in the generation and propagation of action potentials by triggering membrane depolarization.Mutations in Nav channels are associated with a variety of channelopathies,which makes them relevant targets for pharmaceutical intervention.Sofar,the cryoelectron microscopic structure of the human Nav 1.2,Nav 1.4,and Nav 1.7 has been reported,which sheds light on the molecular basis of functional mechanism of Nav channels and provides a path toward structure-based drug discovery.In this review,we focus on the recent advances in the structure,molecular mechanism and modulation of Nav channels,and state updated sodium channel blockers for the treatment of pathophysiology disorders and briefly discuss where the blockers may be developed in the future.

Pore structure characteristics of the relative water-resisting layer on the top of the Ordovician in Longgu Coal Mine

In order to study the permeability and water-resisting ability of the strata on the top of the Ordovician in Longgu Coal Mine, this paper tested the permeability and porosity of the strata, investigated the fracture and pore structure features of the strata, and identified the main channels which govern the permeability and water-resisting ability of the strata. The permeability of the upper, central and lower strata shows as 2.0504 × 10^-3-2.782762× 10^-3, 4.1092 × 10^-3 -7.3387 × 10^-3 and 2.0891 ×10^-3-3.2705 × 10-3 μm^2, respectively, and porosity of that is 0.6786-0.9197%, 0.3109-0.3951% and 0.9829-1.8655%, respectively. The results indicate that： （I） the main channels of the relative water-resisting layer are the pore throats with a diameter more than 6 μm; （2） the major proportion of pore throats in the vertical flow channel and the permeability first increases and then sharply decreases; （3） the fractures occurring from the top to 20 m in depth of the strata were filled and there occurred almost no fracture under the depth of 40 m; and （4） the ratio of turning point of the main flow channel in the strata on top of Ordovician can be used to confirm the thickness of filled water-resisting lavers.

Biofabrication of aligned structures that guide cell orientation and applications in tissue engineering

The organized alignment of cells in various tissues plays a significant role in the maintenance of specific functions.To induce such an alignment,ideal scaffolds should simulate the characteristics and morphologies of natural tissues.Aligned structures that guide cell orientation are used to facilitate tissue regeneration and repair.We here review how various aligned structures are fabricated,including aligned electrospun nanofibers,aligned porous or channeled structures,micropatterns and combinations thereof,and their application in nerve,skeletal muscle,tendon,and tubular dentin regeneration.The future use of aligned structures in tissue engineering is also discussed.

Research on Multichannel Supply Chain Pricing Under Different Dominance

In a multichannel supply chain comprising of dual-channel retailers with both physical and online channels as well as single-channel e-tailers with online channels,a multichannel demand model for e-commerce is constructed based on customer channel preferences,and a Stackerberg game model with price competition dominated by dual-channel retailers and single-channel e-tailers as well as a Bertrand game model with equal rights are established to analyze the impact of different channel rights structures on the price,demand,and profit of the two retailers.The results show that the single-channel e-tailer under the dual-channel retailer-dominated game has the highest profit,and the dual-channel retailer xmder the single-channel e-tailer-dominated game has the highest profit;thus,both retailers should accept the other's dominant channel rights for profit maximization.

The influence of upstream slope on the local scour at drop structure

The drop structure will fail as a result of local scoring downstream.This paper discusses the influence of a drop structures' upstream slope to local scour.Empirical equations of the scour hole were developed by laboratory experiment,theoretical assumptions,and regression analysis.These equations include the maximum scour depth and length during the scouring period,the maximum equilibrium scour depth and length,and the unit width scour rate.The four channel slopes(0%,2%,4%,and 6%) before the drop structure has been included in the analysis.A series of laboratory experiments were conducted to obtain 48 groups of experiments and 419 scour hole profiles during the scouring period.The material used in the scour section is uniform non-cohesive and with a median diameter of d50 = 0.5 mm.The results have been used to develop empirical equations via regression analysis to determine the coefficients of theoretical equations.The high correlation coefficient indicates that the equations developed in this study are suitable for verifying the characteristics of a scour hole at drop structure in the sloped channel.The semi-empirical equation is more accurate than the empirical equation.Compared to a horizontal channel,a sloped channel tends to cause a greater equilibriummaximum scour length,shorter equilibrium maximum scour depth,and faster unit-wide scour rate.

In Situ Polymer Gel Electrolyte in Boosting Scalable Fibre Lithium Battery Applications

The poor interfacial stability not only deteriorates fibre lithium-ion batteries(FLBs)performance but also impacts their scalable applications.To efficiently address these challenges,Prof.Huisheng Peng team proposed a generalized channel structures strategy with optimized in situ polymerization technology in their recent study.The resultant FLBs can be woven into different-sized powering textiles,providing a high energy density output of 128 Wh kg^(-1) and simultaneously demonstrating good durability even under harsh conditions.Such a promising strategy expands the horizon in developing FLB with particular polymer gel electrolytes,and significantly ever-deepening understanding of the scaled wearable energy textile system toward a sustainable future.

Sufficiently diffused attachment of nitrogen arc by gasdynamic action

For realizing diffused anode attachment in pure nitrogen arcs, a special arc plasma generator was designed and combined with suitable working parameters such as gas flow rate and arc current. The anode has a flow-restrictor channel of 2.8 mm diameter and downstream expansion half-angle of 8°, with the purpose of creating a dispersed nitrogen-arc column by strong gasdynamic expansion effect. Results show that, when thermal blocking condition existed in the flow restrictor and the cathode cavity pressure was higher than that in the exit chamber by at least 9 kPa, the action due to gasdynamic expansion could be much stronger than the self-magnetic contraction effect of the arc and the nitrogen arc column could be effectively dispersed to form a sufficiently diffused attachment on the water-cooled anode surface.

Secure Model of Medical Data Sharing for Complex Scenarios

In order to secure the massive heterogeneous medical data for the complex scenarios and improve the information sharing efficiency in healthcare system,a distributed medical data ledger model(DMDL)is proposed in this paper.This DMDL model has adopted the blockchain technology including the function decoupling,the distributed consensus,smart contract as well as multi-channel communication structure of consortium blockchain.The DMDL model not only has high adaptability,but also meets the requirements of the medical treatment processes which generally involve multientities,highly private information and secure transaction.The steps for processing the medical data are also introduced.Additionally,the methods for the definition and application of the DMDL model are presented for three specific medical scenarios,i.e.,the management of the heterogeneous data,copyright protection for medical data and the secure utilization of sensitive data.The advantage of the proposed DMDL model is demonstrated by comparing with the models which are being currently adopted in healthcare system.

Structural ensemble dynamics based closure model for wall-bounded turbulent flow

Wall-bounded turbulent flow involves the development of multi-scale turbulent eddies, as well as a sharply varying boundary layer. Its theoretical descriptions are yet phenomenological. We present here a new framework called structural ensemble dynamics （SED）, which aims at using systematically all relevant statistical properties of turbulent structures for a quantitative description of ensemble means. A new set of closure equations based on the SED approach for a turbulent channel flow is presented. SED order functions are defined, and numerically determined from data of direct numerical simulations （DNS）. Computational results show that the new closure model reproduces accurately the solution of the original Navier-Stokes simulation, including the mean velocity profile, the kinetic energy of the streamwise velocity component, and every term in the energy budget equation. It is suggested that the SED-based studies of turbulent structure builds a bridge between the studies of physical mechanisms of turbulence and the development of accurate model equations for engineering predictions.

Distributed Differences Structures Underlie Gating between the Kin Channel KAT1 and the Kout Channel SKOR

The family of voltage-gated （Shaker-like） potassium channels in plants includes both inward-rectifying （Kin） channels that allow plant cells to accumulate K＋ and outward-rectifying （Kout） channels that mediate K＋ efflux. Despite their dose structural similarities, Kin and Kout channels differ in their gating sensitivity towards voltage and the extracellular K＋ concentration. We have carried out a systematic program of domain swapping between the Kout channel SKOR and the Kin channel KAT1 to examine the impacts on gating of the pore regions, the S4, S5, and the S6 helices. We found that, in particular, the N-terminal part of the S5 played a critical role in KAT1 and SKOR gating. Our findings were supported by molecular dynamics of KAT1 and SKOR homology models. In silico analysis revealed that during channel opening and closing, displacement of certain residues, especially in the S5 and S6 segments, is more pronounced in KAT1 than in SKOR. From our analysis of the S4-S6 region, we conclude that gating （and K＋-sensing in SKOR） depend on a number of structural elements that are dispersed over this -145-residue sequence and that these place additional constraints on configurational rearrangement of the channels during gating.

Compressed sensing-based structured joint channel estimation in a multi-user massive MIMO system

Acquisition of accurate channel state information （CSI） at transmitters results in a huge pilot overhead in massive multiple input multiple output （MIMO） systems due to the large number of antennas in the base station （BS）. To reduce the overwhelming pilot overhead in such systems, a structured joint channel estimation scheme employing compressed sensing （CS） theory is proposed. Specifically, the channel sparsity in the angular domain due to the practical scattering environment is analyzed, where common sparsity and individual sparsity structures among geographically neighboring users exist in multi-user massive MIMO systems. Then, by equipping each user with multiple antennas, the pilot overhead can be alleviated in the framework of CS and the channel estimation quality can be improved. Moreover, a structured joint matching pursuit （SJMP） algorithm at the BS is proposed to jointly estimate the channel of users with reduced pilot overhead. Furthermore, the probability upper bound of common support recovery and the upper bound of channel estimation quality using the proposed SJMP algorithm are derived. Simulation results demonstrate that the proposed SJMP algorithm can achieve a higher system performance than those of existing algorithms in terms of pilot overhead and achievable rate.

Structure of an ATP-sensitive potassium channel(K_(ATP))

Subject Code:C05 With the support by the National Natural Science Foundation of China,the collaborative research team led by Prof.Chen Lei(陈雷)at the State Key Laboratory of Membrane Biology,Institute of Molecular Medicine,Peking-Tsinghua Center for Life Sciences,Beijing Key Laboratory of Cardiometabolic