Chitosan is a good flocculant. The paper deals with the clarification of apple juice by means of chitosan. The results showed that the transmittance was over 97 % and soluble solid content was stable basically , under...Chitosan is a good flocculant. The paper deals with the clarification of apple juice by means of chitosan. The results showed that the transmittance was over 97 % and soluble solid content was stable basically , under the technological condition of chitosan of 0. 5 -1. 2 g L-1, temperature of 45 - 55℃ and pH 4.5. After the orthogonal trial, the optimum technological conditions of apple juice clarification by using chitosan were 0.3 g L-1 chitosan, 45℃ and pH 4. 5. The research of the apple juice clarification with chitosan made a basis of the application of chitosan and provided the theoretical basis for the clarification of apple juice with chitosan.展开更多
In this article, morphology, structure and size controllable chitosan microspheres with high mechanical strength were synthesized by microfluidic technology combining chemical crosslinking and used as an adsorbent for...In this article, morphology, structure and size controllable chitosan microspheres with high mechanical strength were synthesized by microfluidic technology combining chemical crosslinking and used as an adsorbent for methyl orange. The synthesized adsorbents were characterized using scanning electron microscopy(SEM),Fourier transform infrared spectroscopy(FTIR), and an Energy Dispersive Spectrometer(EDS). The effect of pH revealed that the adsorption process depended on pH and the pH variation of methyl orange solution after adsorption indicated that adsorption capacity was affected through the associated role of chitosan nature and pH variation. Experimental results suggested that the as-prepared chitosan microspheres were controlled within a narrow size distribution(coefficients of variation is 1.81%), whose adsorption capacity reached to 207 mg·g^(-1) and mechanical strength was suitable to resist forces. In addition, the adsorption isotherm was well fitted with the Langmuir model, and the adsorption kinetic was best described by the pseudo-second-order kinetic model.The high performance microfluidic-synthesized chitosan microspheres have promising potentials in the applications of removing dyes from wastewater.展开更多
An improved biosorbent of thiourea modified chitosan microsphere（TMCM） with high specific surface,favorable mechanical strength and excellent adsorption performance had been synthesized via microfluidic technology. ...An improved biosorbent of thiourea modified chitosan microsphere（TMCM） with high specific surface,favorable mechanical strength and excellent adsorption performance had been synthesized via microfluidic technology. Polyethylene glycol was used as a significant component added in aqueous solution of chitosan to produce such microspheres through droplets forming, chemical crosslinking and pores creating. For the improvement of adsorption capacity, thiourea was considered as an excellent choice in increasing amino functional group by graft modification. The SEM, FTIR and EDS were employed to detect distinct features of TMCM. Copper（Ⅱ） was used to test the adsorption performance of TMCM. The experimental results indicated that TMCM exhibited higher adsorption capacity（q_e= 60.6 mg g_（-1）） and faster adsorption rate than that non-modified chitosan microsphere（NMCM）.The adsorption kinetic was described well by the pseudo-second order kinetic model, which suggested that chemical adsorption along with electrons transferring was dominant in adsorption process.展开更多
以旋转正交组合试验分析了果酒的pH值、含糖量及壳聚糖用量和澄清温度对杨梅果酒澄清度的影响,建立澄清度与pH值、壳聚糖用量、含糖量试验因子间的回归方程;研究确定了杨梅干酒、甜酒酒体稳定时的澄清度和壳聚糖下胶量,并分析了果酒主...以旋转正交组合试验分析了果酒的pH值、含糖量及壳聚糖用量和澄清温度对杨梅果酒澄清度的影响,建立澄清度与pH值、壳聚糖用量、含糖量试验因子间的回归方程;研究确定了杨梅干酒、甜酒酒体稳定时的澄清度和壳聚糖下胶量,并分析了果酒主要理化成分的变化。试验结果表明:果酒的pH值、含糖量和壳聚糖用量对杨梅果酒澄清度的影响显著,温度的影响不显著;与以皂土澄清相比,以壳聚糖澄清杨梅果酒,澄清速度快,酒体稳定,对果酒的主要理化成分及氨基酸含量的影响较小;杨梅干酒和甜酒酒体稳定时的澄清度分别为91.4%和85.0%,适宜下胶量分别为50 m g/L和70 m g/L。展开更多
文摘Chitosan is a good flocculant. The paper deals with the clarification of apple juice by means of chitosan. The results showed that the transmittance was over 97 % and soluble solid content was stable basically , under the technological condition of chitosan of 0. 5 -1. 2 g L-1, temperature of 45 - 55℃ and pH 4.5. After the orthogonal trial, the optimum technological conditions of apple juice clarification by using chitosan were 0.3 g L-1 chitosan, 45℃ and pH 4. 5. The research of the apple juice clarification with chitosan made a basis of the application of chitosan and provided the theoretical basis for the clarification of apple juice with chitosan.
基金Supported by the National Basic Research Program of China(2014CB748500)the National Natural Science Foundation of China(51578239,51322805)
文摘In this article, morphology, structure and size controllable chitosan microspheres with high mechanical strength were synthesized by microfluidic technology combining chemical crosslinking and used as an adsorbent for methyl orange. The synthesized adsorbents were characterized using scanning electron microscopy(SEM),Fourier transform infrared spectroscopy(FTIR), and an Energy Dispersive Spectrometer(EDS). The effect of pH revealed that the adsorption process depended on pH and the pH variation of methyl orange solution after adsorption indicated that adsorption capacity was affected through the associated role of chitosan nature and pH variation. Experimental results suggested that the as-prepared chitosan microspheres were controlled within a narrow size distribution(coefficients of variation is 1.81%), whose adsorption capacity reached to 207 mg·g^(-1) and mechanical strength was suitable to resist forces. In addition, the adsorption isotherm was well fitted with the Langmuir model, and the adsorption kinetic was best described by the pseudo-second-order kinetic model.The high performance microfluidic-synthesized chitosan microspheres have promising potentials in the applications of removing dyes from wastewater.
基金support by National Basic Research Program of China(No.2014CB748500)National Natural Science Foundation of China(Nos.51578239,51322805)
文摘An improved biosorbent of thiourea modified chitosan microsphere（TMCM） with high specific surface,favorable mechanical strength and excellent adsorption performance had been synthesized via microfluidic technology. Polyethylene glycol was used as a significant component added in aqueous solution of chitosan to produce such microspheres through droplets forming, chemical crosslinking and pores creating. For the improvement of adsorption capacity, thiourea was considered as an excellent choice in increasing amino functional group by graft modification. The SEM, FTIR and EDS were employed to detect distinct features of TMCM. Copper（Ⅱ） was used to test the adsorption performance of TMCM. The experimental results indicated that TMCM exhibited higher adsorption capacity（q_e= 60.6 mg g_（-1）） and faster adsorption rate than that non-modified chitosan microsphere（NMCM）.The adsorption kinetic was described well by the pseudo-second order kinetic model, which suggested that chemical adsorption along with electrons transferring was dominant in adsorption process.
文摘以旋转正交组合试验分析了果酒的pH值、含糖量及壳聚糖用量和澄清温度对杨梅果酒澄清度的影响,建立澄清度与pH值、壳聚糖用量、含糖量试验因子间的回归方程;研究确定了杨梅干酒、甜酒酒体稳定时的澄清度和壳聚糖下胶量,并分析了果酒主要理化成分的变化。试验结果表明:果酒的pH值、含糖量和壳聚糖用量对杨梅果酒澄清度的影响显著,温度的影响不显著;与以皂土澄清相比,以壳聚糖澄清杨梅果酒,澄清速度快,酒体稳定,对果酒的主要理化成分及氨基酸含量的影响较小;杨梅干酒和甜酒酒体稳定时的澄清度分别为91.4%和85.0%,适宜下胶量分别为50 m g/L和70 m g/L。
