Effects of oil contamination and bioremediation on geotechnical properties of highly plastic clayey soil

Leakage of oil and its derivatives into the soil can change the engineering behavior of soil as well as cause environmental disasters.Also,recovering the contaminated sites into their natural condition and making contaminated materials as both environmentally and geotechnically suitable construction materials need the employment of remediation techniques.Bioremediation,as an efficient,low cost and environmentalfriendly approach,was used in the case of highly plastic clayey soils.To better understand the change in geotechnical properties of highly plastic fine-grained soil due to crude oil contamination and bioremediation,Atterberg limits,compaction,unconfined compression,direct shear,and consolidation tests were conducted on natural,contaminated,and bioremediated soil samples to investigate the effects of contamination and remediation on fine-grained soil properties.Oil contamination reduced maximum dry density(MDD),optimum moisture content(OMC),unconfined compressive strength(UCS),shear strength,swelling pressure,and coefficient of consolidation of soil.In addition,contamination increased the compression and swelling indices and compressibility of soil.Bioremediation reduced soil contamination by about 50%.Moreover,in comparison with contaminated soil,bioremediation reduced the MDD,UCS,swelling index,free swelling and swelling pressure of soil,and also increased OMC,shear strength,cohesion,internal friction angle,failure strain,porosity,compression index,and settlement.Microstructural analyses showed that oil contamination does not alter the soil structure in terms of chemical compounds,elements,and constituent minerals.While it decreased the specific surface area of the soil,and the bioremediation significantly increased the mentioned parameters.Bioremediation resulted in the formation of quasi-fibrous textures and porous and agglomerated structures.As a result,oil contamination affected the mechanical properties of soil negatively,but bioremediation improved these properties.

Paleo-environmental conditions,paleoclimatic significance and effects of weathering on clay deposits in the Lower Benue Trough,Nigeria.Mineralogical approach

Combined methods for mineralogical identifications were used to characterise the clay deposits within the Lower Benue Trough of Nigeria to interpret paleo-environmental conditions,the paleoclimatic significance of the trough,and effects of weathering on the minerals as factors that favour its deposition/accumulation within the trough which host other important industrial minerals like coal,barite,limestone etc.Bulk-sample random-powder XRD data and data for clay fractions deposited onto zero-background quartz plates were measured.The samples contained kaolinite,vermiculite,and traces of smectite,and the non-clay phases included quartz,microcline,and muscovite.All samples were unaffected after glycolation,confirming the absence of significant smectite.Muscovite was characterized by the nature of its 10Åbasal peak with a width of<0.10°2θ,which was very sharp.DTA/TGA results support the presence of kaolinite,and the characteristic kaolinite O-H,Al-OH,Si-OH and Si-O-Al FTIR bands also confirmed its presence.Vermicular and book-like morphologies were observed under the SEM,typical of kaolinitic clay from in situ alteration.High kaolinite abundance in these sediments is consistent with intense weathering of parent rocks rich in Al under wet/tropical paleo-climatic conditions with fresh and/or brackish water conditions in a continental setting.The variety of observed morphologies suggests that the deposits suffered more of chemical weathering.The clay deposits in Lower Benue Trough are quartz-rich,kaolinitic and derived from the chemical weathering of Al-rich source rocks.

Clay Mineralogical and Geochemical Studies of Detrital Rocks of the Upper Cretaceous Salt-bearing Strata,Simao Basin,SW China:Implication for Provenance and Source Weathering

1 Introduction Geological studies established on several sections in Lanping-Simao basin have shown that the salt-bearing strata of Mengyejing formation(Yunlong Fm.in Lanping basin)are constituted by an alternation of salt layers and interbedded facies.The latter consists mainly of mudstones,and mudstone-rich conglomerate.The mineralogy and geochemistry of salt-bearing beds and

Soil Genesis of Four Alfisols Established in Oak Hickory Forests along Drainages into the Mississippi River in Southeastern Missouri, USA

Alfisols in USA taxonomy are “deciduous forest” soils having an argillic horizon with a base saturation in the control section greater than 35%. Alfisols are geographically extensive and support productive agriculture and deciduous forest ecosystems. Understanding Alfisol genesis, including the presence and intensity of the dominant soil processes, facilitates best management practices that provide stewardship for these soil resources and improves forest and agriculture productivity. Four Alfisols, presently having mature forest settings and located in the central United States along the Mississippi River, were selected for soil and landscape description, classification, and delineation of the dominant soil forming processes. Excavated soils were described and routinely sampled for subsequent physical, chemical, and mineralogical analysis. An aqua regia digestion protocol provided elemental analysis for identifying and inferring the intensity of soil forming processes. The dominant soil forming factors include 1) organic matter accumulation, 2) clay eluviation-illuviation, 3) acidification, 4) base cation accumulation in the A horizons by the forest vegetation, 5) Fe-oxyhydroxide formation, and 6) clay mineral synthesis. Two soils were developed entirely in Peoria loess and two soils were developed in Peoria Loess overlying Ordovician limestone residuum. Ecological site descriptions provide land managers information for evaluating land suitability and the capability to implement different management activities without ecosystem disturbance. Best management practices for the described landforms and based on their Ecological Site Descriptions are presented.

Kinetics of Soil Potassium Release Under Long-Term Imbalanced Fertilization in Calcareous Soils

Knowledge on potassium ion(K^+) release from soils makes K fertilizer recommendation more efficient and profitable.Kinetics of K^+release under continuous fertilization of no fertilizer(CK), urea(N), triple superphosphate(P), and urea + triple superphosphate(NP) without K fertilizer was investigated in calcareous(chloritic and kaolinitic) soils on the Miandarband Plain in Kermanshah Province of Iran.The results showed that the kinetics of K^+release included an initial reaction and a slow reaction.The phosphateand NH_4^+-induced K^+release followed the same rate process during the rapid(2–192 h) and slow release periods(192–1 090 h).There were no significant differences in the cumulative K^+released from the chloritic and kaolinitic soils among all the treatments.The cumulative K^+released was positively correlated with P adsorption capacity for the chloritic(r = 0.461, P < 0.05) and kaolinitic soils(r = 0.625, P < 0.01), and negatively correlated with K fixation potential for the chloritic(r = 0.720, P < 0.01) and kaolinitic soils(r =-0.513, P < 0.01).There was a significant(P < 0.001) interactive effect of K fixation potential × P adsorption capacity on the cumulative K^+released for both soil groups.The initial release rate(IRR) index(a·b, where a and b are the rate coefficients of the power function equation) for the chloritic soils was significantly(P < 0.05) higher under applications of P and NP than N and CK.The IRR index values among different fertilization treatments were in the order of NP = P > N = CK for the chloritic soils, and N =P > NP > CK for the kaolinitic soils.This study showed that K fixation potential and P adsorption capacities controlled K^+release from soils.This information will be helpful for precise fertilizer recommendations for the studied soils.