Facing increasingly strict environmental regulations on transportation fuels, China National Petroleum Corporation （CNPC）, the second largest supplier of petroleum products in China, needs to upgrade its transportat...Facing increasingly strict environmental regulations on transportation fuels, China National Petroleum Corporation （CNPC）, the second largest supplier of petroleum products in China, needs to upgrade its transportation fuels. Using the scenario-based analysis method, this paper analyzes how the output and emission related properties, including cetane number, and sulfur and aromatics contents of diesel produced by CNPC, will vary with changes in the configuration of diesel production units in the next 5-10 years. The results showed that, to upgrade its diesel, CNPC needs to adjust its diesel pool by decreasing the share of fluid catalytic cracking （FCC） diesel and increasing the shares of hydrocracking （HDC） and hydrotreating （HDT） diesel. Furthermore, to produce ultra-low-sulfur diesel, straight-run diesel as well as poor diesel blendstocks such as FCC diesel and coker diesel should be hydrotreated before being blended into finished diesel. Developing highly efficient HDC and HDT catalysts and corresponding processes is the key to CNPC economically producing more and cleaner diesel.展开更多
Abstract： This article introduces the development and application of the medium-pressure hydro-upgrading （MHUG） tech- nology developed by the Research Institute of Petroleum Processing （RIPP）. The MHUG technology...Abstract： This article introduces the development and application of the medium-pressure hydro-upgrading （MHUG） tech- nology developed by the Research Institute of Petroleum Processing （RIPP）. The MHUG technology based on the chemistry of diesel hydro-upgrading reactions has the advantages of flexible product slate and excellent product quality that can in- crease the cetane rating of diesel fuel up to more than 15 units. The hydrotreating and hydro-upgrading catalysts associated with the MHUG technology have outstanding performance to meet the demand of MHUG technology for hydro-saturation and selective ring-opening of aromatic rings. New MHUG process flow scheme can further increase the yield and selectivity of target products. Commercial application of multiple MHUG units has revealed that the MHUG technology designated for clean diesel production features good feedstock adaptability and operating stability.展开更多
The catalytic performance of perovskite composite oxide catalyst La0.9 K0.1 CoO3 coated on catalyst supports by traditional solid state reaction method and sol-gel method were investigated by a series of experiments....The catalytic performance of perovskite composite oxide catalyst La0.9 K0.1 CoO3 coated on catalyst supports by traditional solid state reaction method and sol-gel method were investigated by a series of experiments. The restdt shows that the catalytic performance of the La0.9 K0.1 CoO3 perovskite composite oxide catalyst synthesized by sol-gel method is superior to that synthesized by solid state reaction method, having lower ignition temperature of the diesel soot particulates, lower start temperature of NOx treatment, and lower concentration of byproduct CO.展开更多
柴油车是城市氮氧化物和颗粒物污染的主要来源之一。以一种新型的发动机前端空气净化技术(warp air clean,WAC)为研究对象,研究其对7辆柴油货车在怠速和自由加速阶段的减排效果。结果表明:WAC对柴油货车一氧化碳(CO)、氮氧化物(NO_(x))...柴油车是城市氮氧化物和颗粒物污染的主要来源之一。以一种新型的发动机前端空气净化技术(warp air clean,WAC)为研究对象,研究其对7辆柴油货车在怠速和自由加速阶段的减排效果。结果表明:WAC对柴油货车一氧化碳(CO)、氮氧化物(NO_(x))、碳氢化合物(HC)和颗粒物数量(particulate number,PN)的平均减排率分别为12.2%、2.9%、3.9%和11.3%;不同排放标准下,WAC对国Ⅲ车辆的净化效果更佳。同一排放标准下,轻型柴油车的减排效果要优于重型柴油车;怠速(空挡)阶段,WAC对使用年限长、排放标准低的车辆净化效果更佳;自由加速阶段,WAC对CO、NO_(x)和HC的净化作用主要表现为降低车辆加速过程中气体污染物排放的峰值,最高分别可达70.6%、50.0%和38.6%。展开更多
Ultra-Clean Micronized Coal Water Slurry (UCMCWS ) as a form or coal-based fuel can be used in place of oil in diesel engine, gas turbine and clean combustion. In laboratory UCMCWS has been made from ultra-clean coal ...Ultra-Clean Micronized Coal Water Slurry (UCMCWS ) as a form or coal-based fuel can be used in place of oil in diesel engine, gas turbine and clean combustion. In laboratory UCMCWS has been made from ultra-clean coal with ash less than 0. 8%, with concentration of UCMCWS less than 55%, and with viscosity less than 600 mPa. s. A test rig of atomization with diesel oil nozzle has been made. A preliminary conclusion is that UCMCWS can be atomized as good as diesel oil in the working condition of diesel engine.展开更多
Urban smog issue has become more and more heated topic in China in recent years.Vehicle pollution is one of the main reasons for smog and haze in most large and medium-sized cities in the country.Maybe it is not surpr...Urban smog issue has become more and more heated topic in China in recent years.Vehicle pollution is one of the main reasons for smog and haze in most large and medium-sized cities in the country.Maybe it is not surprising now that the nation drives 95 million cars,second only to the United States with 240 million.Therefore,China has released a series of policies to alleviate the increasingly severe urban smog issues and accelerate upgrading of oil products quality.展开更多
文摘Facing increasingly strict environmental regulations on transportation fuels, China National Petroleum Corporation （CNPC）, the second largest supplier of petroleum products in China, needs to upgrade its transportation fuels. Using the scenario-based analysis method, this paper analyzes how the output and emission related properties, including cetane number, and sulfur and aromatics contents of diesel produced by CNPC, will vary with changes in the configuration of diesel production units in the next 5-10 years. The results showed that, to upgrade its diesel, CNPC needs to adjust its diesel pool by decreasing the share of fluid catalytic cracking （FCC） diesel and increasing the shares of hydrocracking （HDC） and hydrotreating （HDT） diesel. Furthermore, to produce ultra-low-sulfur diesel, straight-run diesel as well as poor diesel blendstocks such as FCC diesel and coker diesel should be hydrotreated before being blended into finished diesel. Developing highly efficient HDC and HDT catalysts and corresponding processes is the key to CNPC economically producing more and cleaner diesel.
文摘Abstract： This article introduces the development and application of the medium-pressure hydro-upgrading （MHUG） tech- nology developed by the Research Institute of Petroleum Processing （RIPP）. The MHUG technology based on the chemistry of diesel hydro-upgrading reactions has the advantages of flexible product slate and excellent product quality that can in- crease the cetane rating of diesel fuel up to more than 15 units. The hydrotreating and hydro-upgrading catalysts associated with the MHUG technology have outstanding performance to meet the demand of MHUG technology for hydro-saturation and selective ring-opening of aromatic rings. New MHUG process flow scheme can further increase the yield and selectivity of target products. Commercial application of multiple MHUG units has revealed that the MHUG technology designated for clean diesel production features good feedstock adaptability and operating stability.
基金Funded by National Natural Science Foundation of China(No2001AA643020)
文摘The catalytic performance of perovskite composite oxide catalyst La0.9 K0.1 CoO3 coated on catalyst supports by traditional solid state reaction method and sol-gel method were investigated by a series of experiments. The restdt shows that the catalytic performance of the La0.9 K0.1 CoO3 perovskite composite oxide catalyst synthesized by sol-gel method is superior to that synthesized by solid state reaction method, having lower ignition temperature of the diesel soot particulates, lower start temperature of NOx treatment, and lower concentration of byproduct CO.
文摘柴油车是城市氮氧化物和颗粒物污染的主要来源之一。以一种新型的发动机前端空气净化技术(warp air clean,WAC)为研究对象,研究其对7辆柴油货车在怠速和自由加速阶段的减排效果。结果表明:WAC对柴油货车一氧化碳(CO)、氮氧化物(NO_(x))、碳氢化合物(HC)和颗粒物数量(particulate number,PN)的平均减排率分别为12.2%、2.9%、3.9%和11.3%;不同排放标准下,WAC对国Ⅲ车辆的净化效果更佳。同一排放标准下,轻型柴油车的减排效果要优于重型柴油车;怠速(空挡)阶段,WAC对使用年限长、排放标准低的车辆净化效果更佳;自由加速阶段,WAC对CO、NO_(x)和HC的净化作用主要表现为降低车辆加速过程中气体污染物排放的峰值,最高分别可达70.6%、50.0%和38.6%。
文摘Ultra-Clean Micronized Coal Water Slurry (UCMCWS ) as a form or coal-based fuel can be used in place of oil in diesel engine, gas turbine and clean combustion. In laboratory UCMCWS has been made from ultra-clean coal with ash less than 0. 8%, with concentration of UCMCWS less than 55%, and with viscosity less than 600 mPa. s. A test rig of atomization with diesel oil nozzle has been made. A preliminary conclusion is that UCMCWS can be atomized as good as diesel oil in the working condition of diesel engine.
文摘Urban smog issue has become more and more heated topic in China in recent years.Vehicle pollution is one of the main reasons for smog and haze in most large and medium-sized cities in the country.Maybe it is not surprising now that the nation drives 95 million cars,second only to the United States with 240 million.Therefore,China has released a series of policies to alleviate the increasingly severe urban smog issues and accelerate upgrading of oil products quality.
