In this paper, a facile synthesis of 100 nm commercial colloid silica coated with nano-ceria core-shell composite particles by the precipitation method using ammonium cerium nitrate and urea as a precipitator with pol...In this paper, a facile synthesis of 100 nm commercial colloid silica coated with nano-ceria core-shell composite particles by the precipitation method using ammonium cerium nitrate and urea as a precipitator with polyvinylpyrrolidone (PVP) as an assistant was briefly introduced. The results showed that the colloid silica was surrounded by nano-ceria uniformly forming the core-shell composite particles. The synthesis process was further discussed and optimized. It was found that the type and quantity of surfactant played a key role in the process. PVP connected the surface of colloid silica and that of the ceria precursor.展开更多
Non-spherical colloidal silica nanoparticle was prepared by a simple new method, and its particle size distribution and shape morphology were characterized by dynamic light scattering(DLS) and the Focus Ion Beam(FIB) ...Non-spherical colloidal silica nanoparticle was prepared by a simple new method, and its particle size distribution and shape morphology were characterized by dynamic light scattering(DLS) and the Focus Ion Beam(FIB) system. This kind of novel colloidal silica particles can be well used in chemical mechanical polishing(CMP) of sapphire wafer surface. And the polishing test proves that non-spherical colloidal silica slurry shows much higher material removal rate(MRR) with higher coefficient of friction(COF) when compared to traditional large spherical colloidal silica slurry with particle size 80 nm by DLS. Besides, sapphire wafer polished by non-spherical abrasive also has a good surface roughness of 0.460 6 nm. Therefore, non-spherical colloidal silica has shown great potential in the CMP field because of its higher MRR and better surface roughness.展开更多
A method for preparation of particle crystal film constructed trom monodisperse silica colloidal partices in diameter of about 300 nm is reported. The films were prepared from an ethanol suspension by vertical deposit...A method for preparation of particle crystal film constructed trom monodisperse silica colloidal partices in diameter of about 300 nm is reported. The films were prepared from an ethanol suspension by vertical deposition that relies on capillary forces to assemble colloidal crystal particles on a vertical substrate. The 3D ordered films were characterized by transmission spectra and scanning electric microscope (SEM). The effect of evaporation temperature, particle concentration and sintered temperature on the quality of colloidal particle crystal film was investigated.展开更多
This paper mainly focuses on the influence of colloidal silica polishing on the damage performance of fused silica optics. In this paper, nanometer sized colloidal silica and micron sized ceria are used to polish fuse...This paper mainly focuses on the influence of colloidal silica polishing on the damage performance of fused silica optics. In this paper, nanometer sized colloidal silica and micron sized ceria are used to polish fused silica optics. The colloidal silica polished samples and ceria polished samples exhibit that the root-mean-squared (RMS) average surface roughness values are 0.7 nm and 1.0 rim, respectively. The subsurface defects and damage performance of the polished optics are analyzed and discussed. It is revealed that colloidal silica polishing will introduce much fewer absorptive con- taminant elements and subsurface damages especially no trailing indentation fracture. The 355-nm laser damage test reveals that each of the fused silica samples polished with colloidal silica has a much higher damage threshold and lower damage density than ceria polished samples. Colloidal silica polishing is potential in manufacturing high power laser optics.展开更多
Colloidal silica can be prepared by various methods and starting materials including ion exchange of aqueous silicates, hydrolysis and condensation of silicon compounds, direct oxidation of silicon, and milling and pe...Colloidal silica can be prepared by various methods and starting materials including ion exchange of aqueous silicates, hydrolysis and condensation of silicon compounds, direct oxidation of silicon, and milling and peptization of silica powder. Various silica sols having particle sizes of 10-60 nm prepared by these methods and the preparation methods have been compared on the basis of their shape, size uniformity, sphericity, stability against pH variation, cation concentration, and price, etc. Silica sol prepared from tetraethoxysilane affords uniform size control and growth, and high purity, despite the relatively high costs. Silica sol prepared from liquid silicates affords relatively easy size and shape control;however, it is difficult to lower the alkali content to a level that is appropriate for carrying out semiconductor chemical mechanical polishing processes;in addition, the waste water treatment carried out for recovering the ion exchange resin gives rise environmental consideration. The properties of colloidal silica prepared from fumed silica powder by milling and dispersion depend on the starting silica source and it is relatively difficult to obtain monodispersed particles using this method. Colloidal silica prepared from silicon by direct oxidation has a monodispersed spherical shape and purity control with reasonable prices. It generates less waste water because it can be directly produced in relatively high concentrations. The cation fraction located in the particle relative to the free cation in the fluid is relatively lower in the silica sol prepared by the direct oxidation than others. A careful comparison of colloidal silica and the preparation methods may help in choosing the proper colloidal silica that is the most appropriate for the application being considered.展开更多
A new industrial method has been developed to produce polydisperse spherical colloidal silica particles with a very broad particle size,ranging from 20-95 nm.The process uses a reactor in which the original seed solut...A new industrial method has been developed to produce polydisperse spherical colloidal silica particles with a very broad particle size,ranging from 20-95 nm.The process uses a reactor in which the original seed solution is heated to 100 ℃,and then active silicic acid and the seed solution are titrated to the reactor continuously with a constant rate.The original seeds and the titrated seeds in the reactor will go through different particle growth cycles to form different particle sizes.Both the particles' size distribution and morphology have been characterized by dynamic light scattering(DLS)and the focus ion beam(FIB) system.In addition,the as-prepared polydisperse colloidal silica particle in the application of sapphire wafer's chemical mechanical polishing(CMP) process has been tested.The material removal rate(MRR) of this kind of abrasive has been tested and verified to be much faster than traditional monodisperse silica particles.Finally,the mechanism of sapphire CMP process by this kind of polydisperse silica particles has been investigated to explore the reasons for the high polishing rate.展开更多
Nanomaterials have been widely used in the past few decades due to their proven capacity to enhance the mechanical properties of materials. While many studies have sought to improve the understanding of how nanomateri...Nanomaterials have been widely used in the past few decades due to their proven capacity to enhance the mechanical properties of materials. While many studies have sought to improve the understanding of how nanomaterials affect the behavior of concrete, additional research is needed in order to achieve the full potential of the material, especially in the presence of supplementary cementitious materials. This study aims to investigate the mechanical properties of cement mortars incorporating both nano-silica (NS) and class F fly ash (FA). Furthermore, mercury intrusion porosimetry (MIP) was performed to study its effect on pore characteristics, and thermogravimetric analysis (TGA) was performed to measure the calcium hydroxide Ca(OH)2 content in the mixtures. It was found that using nano-silica enhances the compressive strength, reduces the total porosity and accelerates the pozzolanic reaction.展开更多
The effect of inhomogeneity of particles on the band-gap of silica colloidal crystals(SCCs) fabricated by vertical deposition method was studied.The optical properties of the crystals were examined.The SEM images and ...The effect of inhomogeneity of particles on the band-gap of silica colloidal crystals(SCCs) fabricated by vertical deposition method was studied.The optical properties of the crystals were examined.The SEM images and transmission spectrum of the crystals showed that the inhomogeneity of particles not only affected the ordering,but also their mid-gap position.When the volume ratio of S particles(VS) to L particles(VL) in suspension was 1:1,the band-gap of silica colloidal crystals changed with the growth of particles.When the ratio was 2:1,the quality of SCCs on substrate was obviously improved simultaneously with the number decreasing of L particles.Especially,the quality of SCCs at the bottom of substrate was the best and its mid-gap(634 nm) was very close to that of theoretic value of S particles(636 nm).When the ratio was 3:1,the effect of L particles became smaller with the number decreasing of L particles in suspension.The mid-gap position(638 nm) of whole SCCs on substrate were all close to that of theoretic value of S particles(636 nm).展开更多
Poly(St-co-BuA)/silica nanocomposite latexes were synthesized via conventional emulsion polymerization in the presence of 3-(trimethoxysilyl)propyl methacrylate modified colloidal nano-silica. The effects of surfa...Poly(St-co-BuA)/silica nanocomposite latexes were synthesized via conventional emulsion polymerization in the presence of 3-(trimethoxysilyl)propyl methacrylate modified colloidal nano-silica. The effects of surface property, particle size and content of colloidal nano-silica as well as the concentrations of monomer and surfactant on the morphology of nanocomposite latex particles were investigated by transmission electron microscope (TEM) and scanning electron microscope (SEM) in detail. Various interesting morphologies such as grape-like, Chinese gooseberry-like, pomegranate-like and normal core-shell structures were observed. Droplet nucleation mechanism competing with micelle nucleation mechanism was proposed to explain the morphological evolution of the nanocomposite particles.展开更多
The paper is based on the development of a wood preservative without metal salts to be used in use classes 3 and 4 (EN 335), eco-friendly and harmless to humans and animals. Boric acid was used as a biocide, due to it...The paper is based on the development of a wood preservative without metal salts to be used in use classes 3 and 4 (EN 335), eco-friendly and harmless to humans and animals. Boric acid was used as a biocide, due to its effectiveness against fungi and insects. It is also known to be easily leached from wood exposed to weather action. Colloidal silica was therefore added in the formulations to guarantee the fixation of boric acid to wood. The different formulations were tested for the protective efficacy against decay fungi through laboratory tests (EN 113) and field trials (EN 252). The results were promising, especially those concerning boron fixation and efficacy against decay fungi through laboratory tests, where some formulations and retentions gave a durability class 1 (very durable) according to EN 350-1. The fourth evaluation, after 50 months of field trials showed only a slight difference between the treated samples and controls.展开更多
The effect of water content on the electrorheological effect (ERE) behaviour of silica dispersions has been investigated. The types of silica powders were fumed silica, precipitated and acid washed silica and colloida...The effect of water content on the electrorheological effect (ERE) behaviour of silica dispersions has been investigated. The types of silica powders were fumed silica, precipitated and acid washed silica and colloidal silica. Silica dispersions with a water content varying in the range 10% - 30%, and with conducting ions deliberately added, were redispersed in chlorinated hydrocarbon oil and then the ER behaviour studied. Samples were tested on a static yield rig (SYR), an instrument which can measure both the yield stress and the conductivity. The effects of electric field strength and water content on the ERE were studied. The yield stress initially increased with increase in electric field strength and then decreased at high electric fields suggesting a breakdown in structure of the electrorheological fluid samples tested. It was also found that the ERE increased and electric saturation or electric breakdown shifted to lower electric fields as the water content increased. Higher electric fields caused a drop in the ERE.展开更多
Monodispersed silica microspheres with diameter of 353nm were assembled into photonic crystal in ethanol colloidal suspensions of varied silica volume fraction at different temperature and humidity by means of contr...Monodispersed silica microspheres with diameter of 353nm were assembled into photonic crystal in ethanol colloidal suspensions of varied silica volume fraction at different temperature and humidity by means of controllable vertical deposition method. The surface morphology and optical properties were studied by SEM and UV-Vis-NIR. It was found that the high-quality silica colloidal photonic crystals were obtained from ethanol solutions with environment temperature between 45℃ and 55℃, humidity between 66% and 76%, the volume fraction of microspheres is between 0.8% and 1.5%. The ordered close-packed photonic crystal fabricated by controllable vertical deposition method had the two photonic bandgaps in the visible light band and near infrared band.展开更多
Industrially produced sodium water glasses were dried in climates with controlled temperature and humidity to transparent amorphous water containing sodium silicate materials. The water glasses had molar SiO2:Na2O rat...Industrially produced sodium water glasses were dried in climates with controlled temperature and humidity to transparent amorphous water containing sodium silicate materials. The water glasses had molar SiO2:Na2O ratios of 2.2, 3.3 and 3.9 and were dried up to 84 days at temperatures between 40°C and 95°C and water vapour pressures between 5 and 40 kPa. The materials approached final water concentrations which are equilibrium values and are controlled by the water vapour pressure of the atmosphere and the microstructure of the solids. The microstructure of the dried water glasses was characterized by atomic force microscopy. It has a nanosized substructure built up by the silicate colloids of the educts but deformed by capillary forces. In the final drying equilibrium, the water vapour pressure of the atmosphere in the drying cabinet is equal to the reduced vapour pressure of the capillary system built up by the silicate colloids. Their size scale can be explained by the deformation of colloidal aggregates due to capillary forces.展开更多
基金supported by National Integrate Circuit Research Program of China (Nos.2011ZX02704-002,2009ZX02030-001)National Natural Science Foundation of China (No.51205387)Science and Technology Council of Shanghai (Nos.11nm0500300,10QB1403600)
文摘In this paper, a facile synthesis of 100 nm commercial colloid silica coated with nano-ceria core-shell composite particles by the precipitation method using ammonium cerium nitrate and urea as a precipitator with polyvinylpyrrolidone (PVP) as an assistant was briefly introduced. The results showed that the colloid silica was surrounded by nano-ceria uniformly forming the core-shell composite particles. The synthesis process was further discussed and optimized. It was found that the type and quantity of surfactant played a key role in the process. PVP connected the surface of colloid silica and that of the ceria precursor.
基金Funded by the National Major Scientific and Technological Special Project during the Twelfth Five-year Plan Period(No.2009ZX02030-1)the National Natural Science Foundation of China(No.51205387)the Science and Technology Commission of Shanghai(No.11nm0500300),the Science and Technology Commission of Shanghai(No.14XD1425300)
文摘Non-spherical colloidal silica nanoparticle was prepared by a simple new method, and its particle size distribution and shape morphology were characterized by dynamic light scattering(DLS) and the Focus Ion Beam(FIB) system. This kind of novel colloidal silica particles can be well used in chemical mechanical polishing(CMP) of sapphire wafer surface. And the polishing test proves that non-spherical colloidal silica slurry shows much higher material removal rate(MRR) with higher coefficient of friction(COF) when compared to traditional large spherical colloidal silica slurry with particle size 80 nm by DLS. Besides, sapphire wafer polished by non-spherical abrasive also has a good surface roughness of 0.460 6 nm. Therefore, non-spherical colloidal silica has shown great potential in the CMP field because of its higher MRR and better surface roughness.
基金Supported by the Chinese National Key Basic Research Special Fund (No.2001CB6104) and the National Natural Science Foundation of China(No.20076027)
文摘A method for preparation of particle crystal film constructed trom monodisperse silica colloidal partices in diameter of about 300 nm is reported. The films were prepared from an ethanol suspension by vertical deposition that relies on capillary forces to assemble colloidal crystal particles on a vertical substrate. The 3D ordered films were characterized by transmission spectra and scanning electric microscope (SEM). The effect of evaporation temperature, particle concentration and sintered temperature on the quality of colloidal particle crystal film was investigated.
文摘This paper mainly focuses on the influence of colloidal silica polishing on the damage performance of fused silica optics. In this paper, nanometer sized colloidal silica and micron sized ceria are used to polish fused silica optics. The colloidal silica polished samples and ceria polished samples exhibit that the root-mean-squared (RMS) average surface roughness values are 0.7 nm and 1.0 rim, respectively. The subsurface defects and damage performance of the polished optics are analyzed and discussed. It is revealed that colloidal silica polishing will introduce much fewer absorptive con- taminant elements and subsurface damages especially no trailing indentation fracture. The 355-nm laser damage test reveals that each of the fused silica samples polished with colloidal silica has a much higher damage threshold and lower damage density than ceria polished samples. Colloidal silica polishing is potential in manufacturing high power laser optics.
文摘Colloidal silica can be prepared by various methods and starting materials including ion exchange of aqueous silicates, hydrolysis and condensation of silicon compounds, direct oxidation of silicon, and milling and peptization of silica powder. Various silica sols having particle sizes of 10-60 nm prepared by these methods and the preparation methods have been compared on the basis of their shape, size uniformity, sphericity, stability against pH variation, cation concentration, and price, etc. Silica sol prepared from tetraethoxysilane affords uniform size control and growth, and high purity, despite the relatively high costs. Silica sol prepared from liquid silicates affords relatively easy size and shape control;however, it is difficult to lower the alkali content to a level that is appropriate for carrying out semiconductor chemical mechanical polishing processes;in addition, the waste water treatment carried out for recovering the ion exchange resin gives rise environmental consideration. The properties of colloidal silica prepared from fumed silica powder by milling and dispersion depend on the starting silica source and it is relatively difficult to obtain monodispersed particles using this method. Colloidal silica prepared from silicon by direct oxidation has a monodispersed spherical shape and purity control with reasonable prices. It generates less waste water because it can be directly produced in relatively high concentrations. The cation fraction located in the particle relative to the free cation in the fluid is relatively lower in the silica sol prepared by the direct oxidation than others. A careful comparison of colloidal silica and the preparation methods may help in choosing the proper colloidal silica that is the most appropriate for the application being considered.
基金Project supported by the National Major Scientific and Technological Special Project during the Twelfth Five-year Plan Period of China(Grant No.2009ZX02030-1)the National Natural Science Foundation of China(Grant No.51205387)the Science and Technology Commission of Shanghai,China(Grant No. 11nm0500300),and the Science and Technology Commission of Shanghai,China(Grant No. 14XD1425300)
文摘A new industrial method has been developed to produce polydisperse spherical colloidal silica particles with a very broad particle size,ranging from 20-95 nm.The process uses a reactor in which the original seed solution is heated to 100 ℃,and then active silicic acid and the seed solution are titrated to the reactor continuously with a constant rate.The original seeds and the titrated seeds in the reactor will go through different particle growth cycles to form different particle sizes.Both the particles' size distribution and morphology have been characterized by dynamic light scattering(DLS)and the focus ion beam(FIB) system.In addition,the as-prepared polydisperse colloidal silica particle in the application of sapphire wafer's chemical mechanical polishing(CMP) process has been tested.The material removal rate(MRR) of this kind of abrasive has been tested and verified to be much faster than traditional monodisperse silica particles.Finally,the mechanism of sapphire CMP process by this kind of polydisperse silica particles has been investigated to explore the reasons for the high polishing rate.
文摘Nanomaterials have been widely used in the past few decades due to their proven capacity to enhance the mechanical properties of materials. While many studies have sought to improve the understanding of how nanomaterials affect the behavior of concrete, additional research is needed in order to achieve the full potential of the material, especially in the presence of supplementary cementitious materials. This study aims to investigate the mechanical properties of cement mortars incorporating both nano-silica (NS) and class F fly ash (FA). Furthermore, mercury intrusion porosimetry (MIP) was performed to study its effect on pore characteristics, and thermogravimetric analysis (TGA) was performed to measure the calcium hydroxide Ca(OH)2 content in the mixtures. It was found that using nano-silica enhances the compressive strength, reduces the total porosity and accelerates the pozzolanic reaction.
基金Supported by National Key Basic Research Special Fund (No. 2006CB932606)National Natural Science Foundation of China (No. 50702077)
文摘The effect of inhomogeneity of particles on the band-gap of silica colloidal crystals(SCCs) fabricated by vertical deposition method was studied.The optical properties of the crystals were examined.The SEM images and transmission spectrum of the crystals showed that the inhomogeneity of particles not only affected the ordering,but also their mid-gap position.When the volume ratio of S particles(VS) to L particles(VL) in suspension was 1:1,the band-gap of silica colloidal crystals changed with the growth of particles.When the ratio was 2:1,the quality of SCCs on substrate was obviously improved simultaneously with the number decreasing of L particles.Especially,the quality of SCCs at the bottom of substrate was the best and its mid-gap(634 nm) was very close to that of theoretic value of S particles(636 nm).When the ratio was 3:1,the effect of L particles became smaller with the number decreasing of L particles in suspension.The mid-gap position(638 nm) of whole SCCs on substrate were all close to that of theoretic value of S particles(636 nm).
基金This research was financially supported by the Key Project of China Educational Ministry (No. 103064)the Doctoral Foundation of University (No. 20020246031)
文摘Poly(St-co-BuA)/silica nanocomposite latexes were synthesized via conventional emulsion polymerization in the presence of 3-(trimethoxysilyl)propyl methacrylate modified colloidal nano-silica. The effects of surface property, particle size and content of colloidal nano-silica as well as the concentrations of monomer and surfactant on the morphology of nanocomposite latex particles were investigated by transmission electron microscope (TEM) and scanning electron microscope (SEM) in detail. Various interesting morphologies such as grape-like, Chinese gooseberry-like, pomegranate-like and normal core-shell structures were observed. Droplet nucleation mechanism competing with micelle nucleation mechanism was proposed to explain the morphological evolution of the nanocomposite particles.
文摘The paper is based on the development of a wood preservative without metal salts to be used in use classes 3 and 4 (EN 335), eco-friendly and harmless to humans and animals. Boric acid was used as a biocide, due to its effectiveness against fungi and insects. It is also known to be easily leached from wood exposed to weather action. Colloidal silica was therefore added in the formulations to guarantee the fixation of boric acid to wood. The different formulations were tested for the protective efficacy against decay fungi through laboratory tests (EN 113) and field trials (EN 252). The results were promising, especially those concerning boron fixation and efficacy against decay fungi through laboratory tests, where some formulations and retentions gave a durability class 1 (very durable) according to EN 350-1. The fourth evaluation, after 50 months of field trials showed only a slight difference between the treated samples and controls.
文摘The effect of water content on the electrorheological effect (ERE) behaviour of silica dispersions has been investigated. The types of silica powders were fumed silica, precipitated and acid washed silica and colloidal silica. Silica dispersions with a water content varying in the range 10% - 30%, and with conducting ions deliberately added, were redispersed in chlorinated hydrocarbon oil and then the ER behaviour studied. Samples were tested on a static yield rig (SYR), an instrument which can measure both the yield stress and the conductivity. The effects of electric field strength and water content on the ERE were studied. The yield stress initially increased with increase in electric field strength and then decreased at high electric fields suggesting a breakdown in structure of the electrorheological fluid samples tested. It was also found that the ERE increased and electric saturation or electric breakdown shifted to lower electric fields as the water content increased. Higher electric fields caused a drop in the ERE.
基金Aeronautic Science Foundation Programof China( 05G53038)
文摘Monodispersed silica microspheres with diameter of 353nm were assembled into photonic crystal in ethanol colloidal suspensions of varied silica volume fraction at different temperature and humidity by means of controllable vertical deposition method. The surface morphology and optical properties were studied by SEM and UV-Vis-NIR. It was found that the high-quality silica colloidal photonic crystals were obtained from ethanol solutions with environment temperature between 45℃ and 55℃, humidity between 66% and 76%, the volume fraction of microspheres is between 0.8% and 1.5%. The ordered close-packed photonic crystal fabricated by controllable vertical deposition method had the two photonic bandgaps in the visible light band and near infrared band.
文摘Industrially produced sodium water glasses were dried in climates with controlled temperature and humidity to transparent amorphous water containing sodium silicate materials. The water glasses had molar SiO2:Na2O ratios of 2.2, 3.3 and 3.9 and were dried up to 84 days at temperatures between 40°C and 95°C and water vapour pressures between 5 and 40 kPa. The materials approached final water concentrations which are equilibrium values and are controlled by the water vapour pressure of the atmosphere and the microstructure of the solids. The microstructure of the dried water glasses was characterized by atomic force microscopy. It has a nanosized substructure built up by the silicate colloids of the educts but deformed by capillary forces. In the final drying equilibrium, the water vapour pressure of the atmosphere in the drying cabinet is equal to the reduced vapour pressure of the capillary system built up by the silicate colloids. Their size scale can be explained by the deformation of colloidal aggregates due to capillary forces.