Analysis of combustion characteristics and chemical properties for biocoke fuel

Analyses of the characteristics and properties of biocoke fuel from several biomass wastes were carried out to determine the energy potential of the fuel.Biocoke production in this research uses heating and pressure methods simultaneously under constant conditions.Experimental results using thermogravimetric analysis show that biocoke empty-fruit-bunches(EFB)have a higher energy potential of 26.57 MJ/kg.Meanwhile,mangrove biocoke recorded the lowest ash content at 1.81%compared to EFB at 5.09%.The carbon content of mangrove biocoke is 58.02%,slightly higher than that of EFB,56.70%,but EFB is higher than that of other biomass.Overall,the energy content recorded in biocoke increased significantly compared to raw biomass.

Comparison of Combustion Characteristics of Tars Produced with Tobacco Stem Biomass Gasification

In order to study the combustion characteristics of tar in biomass gasifier inner wall and gasification gas,“tobacco stem semi-tar inside furnace”,“tobacco stem tar inside furnace”and“tobacco stem tar out-of-furnace”were subjected to thermogravimetric experiments,and the combustion characteristics and kinetic characteristics were analyzed.The result shows that“tobacco stem semi-tar inside furnace”has the highest value and“tobacco stem tar out-of-furnace”is has the lowest value on ignition characteristics,combustion characteristics and combustible stability;“tobacco stem semi-tar inside furnace”has the lowest value and“tobacco stem tar outside furnace”has the highest value on burnout characteristics;“tobacco stem tar outside furnace”has the highest value and“tobacco stem tar inside furnace”has the lowest value on integrated combustion characteristics.

The Effect of Ignition Parameters on the Combustion Characteristics of an Aviation Piston Engine

A cylinder combustion simulation model was established for a two-stroke aviation piston engine used in a small unmanned aerial vehicle. The influence of different ignition system parameters on the combustion process of aviation kerosene was studied using this model. The research results showed that under the working conditions of 5500 r/min and 50% throttle opening, as the ignition energy increased, the peak values of average cylinder pressure and average temperature increased, and the combustion duration shortened, The advance of the combustion center of gravity increases the tendency of the engine to knock. Under the same operating conditions, as the ignition timing advances, the peak values of average pressure and average temperature in the cylinder increase, gradually approaching the top dead center, and the tendency of engine detonation increases more significantly.

Combustion characteristics of Daqing oil shale and oil shale semi-cokes

Thermo-gravimetric-analysis(TGA) was used to analyze the combustion characteristics of an oil shale and semi-cokes prepared from it.The effect of prior pyrolysis and TGA heating rate on the combustion process was studied.Prior pyrolysis affects the initial temperature of mass loss and the ignition temperature.The ignition temperature increases as the volatile content of the sample decreases.TG/DTG curves obtained at different heating rates show that heating rate has little effect on ignition temperature.But the peak of combustion shifts to higher temperatures as the heating rate is increased.The Coats-Redfern integration method was employed to find the combustion-reaction kinetic parameters for the burning of oil shale and oil shale semi-coke.

Combustion characteristics of semicokes derived from pyrolysis of low rank bituminous coal

Various semicokes were obtained from medium-low temperature pyrolysis of Dongrong long flame coal.The proximate analysis,calorific value and Hardgrove grindability index(HGI) of semicokes were determined,and the ignition temperature,burnout temperature,ignition index,burnout index,burnout ratio,combustion characteristic index of semicokes were measured and analyzed using thermogravimetry analysis(TGA).The effects of pyrolysis temperature,heating rate,and pyrolysis time on yield,composition and calorific value of long flame coal derived semicokes were investigated,especially the influence of pyrolysis temperature on combustion characteristics and grindability of the semicokes was studied combined with X-ray diffraction(XRD) analysis of semicokes.The results show that the volatile content,ash content and calorific value of semicokes pyrolyzed at all process parameters studied meet the technical specifications of the pulverized coal-fired furnaces(PCFF) referring to China Standards GB/T 7562-1998.The pyrolysis temperature is the most influential factor among pyrolysis process parameters.As pyrolysis temperature increases,the yield,ignition index,combustion reactivity and burnout index of semicokes show a decreasing tend,but the ash content increases.In the range of 400 and 450 °C,the grindability of semicokes is rational,especially the grindability of semicokes pyrolyzed at 450 °C is suitable.Except for the decrease of volatile content and increase of ash content,the decrease of combustion performance of semicokes pyrolyzed at higher temperature should be attributed to the improvement of the degree of structural ordering and the increase of aromaticity and average crystallite size of char.It is concluded that the semicokes pyrolyzed at the temperature of 450 °C is the proper fuel for PCFF.

Experimental determination and research on combustion characteristics domain of gas appliance

This manuscript developed an adjustability test system of gas appliances,and proposed determination methods of adjustability domain and technical approach of performance testing of gas appliance,in order to develop experimental determination,quantify the product performance,design quality and combustion characteristics of gas appliances,and provide test foundation and platform for product design,performance test,quality assessment and technology upgrading for gas appliance industry aiming to multi-gas resources in China.The flexible range of gas appliances to different gases and the interchangeability domain of city gases were determined experimentally,together with the equation of combustion characteristics limit curves of gas appliances.The results showed that the second gas appliance has the biggest capability for the change of gas quality,which permits an 11.2% fluctuation in the Wobbe Index of gas;while the third gas appliance has the least capability for the change of gas quality,which only permits a 1.9% fluctuation in the Wobbe Index of gas.The paper also provides the common adjustability domain of the three gas appliances.

Experimental Study on Combustion Characteristics of Pulverized Coal under Enriched-oxygen Condition by Entrained Flow Reactor

Four different pulverized coals have been used to study the effects of oxygen concentration on combustion characteristics under different enriched-oxygen conditions by entrained flow reactor experiments. The results show that: with the increase of oxygen concentration, the ignition temperature of four coals greatly decreases and the low volatile coals decrease faster; with the increase of oxygen concentration, the ignition mode of pulverized coal has an obviously transformation from homogeneous ignition to heterogeneous ignition, and the corresponding oxygen concentrations are about 40% and 50%-60% respectively for bituminous coal and lignite, and both about 30% for lean coal and anthracite; with the increase of oxygen concentration, the optimal pulverized coal concentrations of bituminous coal and lignite increase firstly and then decrease, but for lean coal and anthracite, the optimal pulverized coal concentrations decrease slowly with the increase of oxygen concentration.

Combustion characteristics of Methanol-base fuel （MBF） made by coal

Profound experimental research was made on Methanol-base fuel （MBF） mainly consisting of methanol, and the results were compared with that of diesel oil. Their respective combustion characteristics of caloric value, combustion efficiency and components of smoke were synthetically analyzed by employing the electronic weighing devices, the rotor flow-meter, intelligent flue gas analyzer, advanced bomb calorimeter, etc., referring to the feasibility of taking it as a fuel for general use. Experiment results show that Methanol-base fuel not only has superiorities on combustion characteristics but also bears energy saving and environmental protection advantages.

Combustion characteristics and kinetics of anthracite with added chlorine

The combustion process of Yangquan anthracite（YQ） with the addition of 0.045wt%, 0.211wt%, 1.026wt%, and 2.982wt% chlorine was investigated using a thermogravimetric method from an ambient temperature to 1173 K in an air atmosphere. Results show that the YQ combustion characteristics are not significantly affected by an increase in chlorine content. Data acquired for combustion conversion are then further processed for kinetic analysis. Average apparent activation energies determined using the model-free method（specifically the KAS method） are 103.025, 110.250, 99.906, and 110.641 k J/mol, respectively, and the optimal kinetic model for describing the combustion process of chlorine-containing YQ is the nucleation kinetic model, as determined by the z（α） master plot method. The mechanism function of the nucleation kinetic model is then employed to estimate the pre-exponential factor, by making use of the compensation effect. The kinetic models to describe chlorine-containing YQ combustion are thus obtained through advanced determination of the optimal mechanism function, average apparent activation energy, and the pre-exponential factor.

Effect of the microporous structure of ammonium perchlorate on thermal behaviour and combustion characteristics

Ammonium perchlorate(AP)is the component with the highest content in composite propellants,and it plays a crucial role in propellant performance.In view of the effects of low-temperature AP thermal decomposition on thermal safety and combustion characteristics,porous ammonium perchlorate(PAP)samples with different mass losses were first prepared by thermal convection heating,and the structures were characterized and analysed.Second,the effects of decomposition degree on the thermal decomposition characteristics of PAP were studied by DSC-TG.Finally,the combustion characteristics of AP/Al binary mixtures were tested with high-speed photography and in a sealed bomb.The results showed that low-temperature decomposition of AP resulted in formation of porous structures for AP particles.The pores first appeared near the surfaces of the particles and began from multiple points at the same time.The pores increased in size to approximately 5 mm and then expanded,and finally,the AP particles were full of pores.After partial decomposition,the crystal structure of AP remained unchanged,but the low and high decomposition temperatures decreased obviously.The decomposition rate accelerated.Due to the porous structure of PAP,the combustion rate of the AP/Al system increased obviously with increasing decomposition of AP.The relationship between the combustion rate and the mass loss was approximately linear under open conditions,and it was exponential for a high-pressure environment.A computational model of the combustion process for the AP/Al binary system was established to explain the effects of pore structure and pressure on the combustion process.

Experimental study on combustion characteristics of municipal solid waste

As incineration provides a relatively safe means of disposal, significant reduction of weight and volume, and energy recovery from the waste, it was adopted by many countries. For the experimental investigation on the combustion characteristics of municipal solid waste(MSW), a lab scale fluidized bed facility was constructed. Many kinds of combustion runs were conducted in this fluidized bed combustion facility. The examined parameters were bed temperature(773 to 1143K), form of fuels (scrap or whole), moisture of fuels and so on. Concentration of CO 2,CO,SO 2, O 2 and NOx in the flue gas were monitored and recorded every 5 seconds. The temperatures along the reactor are recorded every 10 seconds. Experimental results were given and analyzed.

Effect of Moisture on Combustion Characteristics of High⁃Moisture⁃Content Coal Slime

The effects of moisture content on the combustion characteristics and pore structure change of coal slime are studied in this paper.The effect of moisture content on the bed temperature change,combustion efficiency,and NO_(x)and SO_(2)emission were obtained in a bench⁃scale fluidized bed reactor,revealing that the lowest bed temperature decreases with the increase in moisture content,but the effect on the highest bed temperature is not the same.Moreover,with the increase in moisture content,the observed degree of blackening of the flue gas increased,and more CO was produced,which in turn leads to a lower combustion efficiency of the coal slime.However,the presence of moisture plays a positive role in the reduction of NO_(x)and SO_(2).With the increase in moisture content,the amount of NO_(x)and SO_(2)produced tends to decrease.The effect of water on the combustion process of slime is mostly the impact of the severe vaporization process in the early stage to form a large water vapor channel,which is beneficial to the evaporation and loss of water,conducive to the reaction of water and coal combustion products,such as the formation of CO,reduction of NO_(x),SO_(2),etc.The large holes formed by the impact of water vapor decreased with the decrease of moisture content,and the nanoscale pores are mostly caused by the combustion process of volatilization and coke formation after the end of vaporization,and increase with the decrease of moisture content.

Optimization of Combustion Characteristics and Fuel Injection Timing of a New Type Dual-Pit Combustor Rotary Engine

In order to improve the performance of the rotary engine,this paper has designed a new type of dual-pit rotary engine combustion chamber structure,and compares the combustion and emission characteristics with the rotary engine with a traditional combustion chamber.The existence of the dual-pit combustion chamber strengthens the overall vortex intensity in the cylinder,effectively promotes the mixing process of fuel and air in the cylinder,the maximum combustion pressure in the cylinder increased by 8.6%,significantly increases the diffusion combustion speed,and significantly improves the dynamic performance of the rotary engine.On this basis,the effects of fuel injection timing parameters on fuel distribution,combustion and emission characteristics were studied.Fuel distribution is more even and dispersed during injection in the later stage of compression.When the fuel injection timing was 105°BTDC in the middle of the compression phase,the matching effect of fuel distribution law and ignition scheme was the best.When the injection timing was 75°BTDC and 85°BTDC in the late compression stage,the mass fraction of NOx remained at a low level.The correlation between soot generation and the change of fuel injection timing was weak.When the injection time was 85°BTDC,the soot generation remained at a relatively high level.

Time Series of Combustion Characteristics and Particulate Emission during Combustion of Thai Lignite in a Fixed Bed

The combustion characteristics and particulate emission during combustion of Thai lignite with 30% of secondary air to total air （SA：TA） in a fixed bed combustor have been investigated in real-time. The results have shown that particle formation is governed by competing reaction between the formation of the nucleated sized-particles （Dp 〈 0.1μm） and the coagulated particle （Dp 0.1-1 μm）. Temperature and burning rate are the highest priority factors to control the emission of particulate. Furthermore, the co-firing of coal/rice husks at 60：40% mass fraction with 10%SA：TA could be the alternative options to further reduction of particulate and to be recommended.

Combustion Characteristics of a Single Cylinder Spark Ignition Engine Fueled with Coal Mine Methane

An experimental investigation was conducted on combustion characteristics of a single cylinder spark ignition engine fueled with coal-mine methane （CMM）.The CMM was simulated by the compressed nature gas （CNG）/nitrogen blend fuels.The cylinder pressure was measured.The maximum heat release ratio,the flame development duration and the main combustion duration were analyzed with the nitrogen volume fraction in the blends changing from 0% to 35%.The results indicate that the maximum cylinder pressure,the maximum rate of pressure,the flame development duration and the main combustion duration increase and the maximum rate of heat release decreases with increasing nitrogen fraction.When the level of nitrogen volume fraction in coalmine methane is lower than 20%,the combustion process of engine is stable.But with the level of nitrogen volume fraction over 30%,the cycle to cycle combustion variation is large,especially under low load condition.

The experimental study on combustion characteristics and emissions of a CMM fueled engine

In this paper, an experimental study on combustion characteristics and emissions of a single cylinder spark ignition engine fueled with coal-mine methane （CMM） is investigated under various loads. CMM is simulated by the compressed nature gas（ CNG）/nitrogen blend fuels. Based on experiment results, it is shown that under 0% - 35% nitrogen volume fraction in CNG/nitrogen blends, the maximum cylinder pressure, the maximum rate of pressure rise and the rate of heat release decrease, the flame propagation period increases, the center of heat release curve is closed to the top dead centre （TDC）markedly with the increase of nitrogen volume fraction. Meanwhile, the hydrocarbon （HC）, CO emissions increase, the NOx emission decreases apparently with the increase of nitrogen volume fraction.

Experimental study on combustion characteristics of supersonic combustor based on alternating-wedge strut

Acetone Planar Lase-Induced Fluorescence(PLIF)and OH-PLIF were employed to capture the fuel distribution and OH distribution downstream for the supersonic combustor based on the alternating-wedge strut.The combustion establishment process and combustion mode in the combustor under different fuel injection methods and different equivalence ratios were analyzed.Combined with the kerosene-PLIF and OH-PLIF results in the cavity combustor,a comparative analysis was conducted to understand the combustion characteristics and combustion modes between the alternating-wedge strut-based combustor and the cavity-based combustor.The results show that the combustor is in weak combustion mode in the case of low equivalence ratio,and the combustor is in intensive combustion mode in the case of high equivalence ratio.The lower limit of the equivalence ratio of the combustor to maintain the intensive combustion mode varies based on different fuel injection methods.The OH distribution under reacting condition has a strong correlation with the fuel distribution under non-reacting condition.The OH fluorescence signal near the injector is weaker when the fuel distribution is more concentrated.The injector position located at the base of the strut rear has better mixing performance,enabling the combustor to be in intensive combustion mode at a lower equivalence ratio.The combustion reaction in the alternating-wedge strut-based combustor is not necessarily dominated by mass transfer due to the mixing enhancement and premixed zone downstream of strut,while the combustion reaction process in the cavity-based combustor is mainly influenced by mass transfer.

Influence of Mixture Gas Conditions on the Laminar Combustion Characteristics of Natural Gas

Natural gas is a promising alternative fuel for the internal combustion engine,and natural gas engine has become an efficient and feasible measure to deal with the energy shortage and climate change.Since the laminar flame characteristics are the foundation of the turbulent flame,the laminar flame characteristics of natural gas have a significant impact on the combustion status and efficiency of the engine.A visual constant volume bomb was used to study the influence of the gas components,different excess air coefficient(λ),and initial conditions on the laminar combustion characteristics of natural gas.The experimental results showed that when the initial pressure and temperature were 0.1 MPa and 300 K respectively,compared to propane,ethane had a remarkable influence on the equivalent-combustion laminar-combustion-speed,with an average increase of approximately 5.1%for every 2.5%increase in the ethane proportion.The laminar combustion velocity of the natural gas under different excess air coefficients had a maximum value at aboutλ=1.0,and the Markstein length of the flame decreased with the increase of theλ.The increase in the initial pressure of the mixture resulted in a decrease in the equivalent-combustion laminar-combustion-speed of the flame,a significant decrease in the Markstein length.The increase of the initial temperature of the mixture led to a rapid increase of the equivalent-combustion laminar-combustion-speed,but the effect on the flame Markstein length was not dominant.

Effects of Interaction between Axial and Radial Secondary Air and Reductive Intensity in Reduction Region on Combustion Characteristics and NO_(x) Emission of Coal Preheated by a Self-Preheating Burner

The study focused on the effects of the interaction between axial and radial secondary air and the reductive intensity in reduction region on combustion characteristics and NO_(x) emission in a 30 kW preheating combustion system.The results revealed that the interaction and reductive intensity influenced the combustion in the down-fired combustor(DFC) and NO_(x) emission greatly.For the temperature distribution,the interaction caused the position of the main combustion region to shift down as R_(2-12)(ratio of axial secondary air flow to radial secondary air flow) decreased or λ_(2)(total secondary air ratio) increased,and there was the interplay between both of their effects.As R_(3-12)(ratio of first-staged tertiary air flow to second-staged tertiary air flow)increased,the decrease in the reductive intensity also caused the above phenomenon,and the peak temperature increased in this region.For the NO_(x) emission,the interaction affected the NO_(x) reduction adversely when λ_(2) or R_(2-12) was higher,and the range of this effect was larger,so that the NO_x emission increased obviously as they increased.The decrease in the reductive intensity caused the NO_(x) emission increased under the homogeneous reduction mechanism,while was unchanged at a high level under the heterogeneous reduction mechanism.For the combustion efficiency,the interaction improved the combustion efficiency as λ_(2) increased when R_(2-12) was lower,while reduced it as λ_(2) increased excessively when R_(2-12) was higher.The proper decrease in the reductive intensity caused the combustion efficiency increased obviously,while was hardly improved further when the intensity decreased excessively.In this study,the lowest NO_(x) emission was only 41.75 mg/m^(3) without sacrificing the combustion efficiency by optimizing the interaction and reductive intensity.

Experimental investigation on combustion and unregulated emission characteristics of butanol-isomer/gasoline blends

Effects of butanol isomers on characteristics of combustion and emission were studied on PFI SI engine. Experiments were operated under the condition of 3 and 5 bar brake mean effective pressure (BMEP) engine loads and different equivalence ratios (φ=0.83-1.25) with engine speed of 1200 r/min using blends made of 70 vol.% gasoline and 30 vol.% butanol isomers (N30, S30, I30 and T30). The results indicated that compared with gasoline, all butanol isomer blends have higher cylinder pressure. N30 has the highest and most advanced peak pressure, and T30 shows a higher brake specific fuel consumption (BSFC) and lower brake thermal efficiency (BTE). N30 presents a lower UHC emissions and I30 has slightly higher CO emissions than other blends. For unregulated emissions, compared with gasoline, butanol isomer blends have higher acetaldehyde, and N30 produces a higher emission of 1,3-butadiene than other blends. A reduction in benzene, toluene, ethylbenzene and xylene (BTEX) has been found with butanol isomer blends.