Effect and Mechanism of Rare Earth Hydrotalcite Inhibiting Coal Spontaneous Combustion

A hydrotalcite(layered double hydroxide, LDH) inhibitor which is suitable for the whole process of coal spontaneous combustion and a LDH inhibitor containing rare earth lanthanum elements were prepared. The inhibition effect and mechanism were analyzed by scanning electron microscopy(SEM),X-ray diffraction(XRD), thermal performance analysis, in-situ diffuse reflectance infrared spectroscopy and temperature-programmed experiment. The results have shown that the inhibitor containing lanthanum can play a good inhibitory role in every stage of coal oxidation. During the slow oxidation of coal samples, the inhibitor containing lanthanum ions can slow down the oxidation process of coal and increase the initial temperature of coal spontaneous combustion. At the same time, because the hydroxyl groups in LDHs are connected with-COO-groups on the coal surface through hydrogen bonds, the stability of coal is improved. With the increase of temperature, LDHs can remove interlayer water molecules and reduce the surface temperature of coal. CO release rate of coal samples decreases significantly after adding inhibitor containing lanthanum element, and the maximum inhibition rate of the inhibitor is 58.1%.

Disasters of gas-coal spontaneous combustion in goaf of steeply inclined extra-thick coal seams

In light of the escalating global energy imperatives,mining of challenging-to-access resources,such as steeply inclined extra-thick coal seams(SIEC),has emerged as one of the future trends within the domain of energy advancement.However,there is a risk of gas and coal spontaneous combustion coupling disasters(GCC)within the goaf of SIEC due to the complex goaf structure engendered by the unique mining methodologies of SIEC.To ensure that SIEC is mined safely and efficiently,this study conducts research on the GCC within the goaf of SIEC using field observation,theoretical analysis,and numerical modeling.The results demonstrate that the dip angle,the structural dimensions in terms of width-to-length ratio,and compressive strength of the overlying rock are the key factors contributing to the goaf instability of SIEC.The gangue was asymmetrically filled,primarily accumulating within the central and lower portions of the goaf,and the filling height increased proportionally with the advancing caving height,the expansion coefficient,and the thickness of the surrounding rock formation.The GCC occurs in the goaf of SIEC,with an air-return side range of 41 m and an air-intake side range of 14 m,at the intersection area of the“<”-shaped oxygen concentration distribution(coal spontaneous combustion)and the“>”-shaped gas concentration distribution(gas explosion).The optimal nitrogen flow rate is 1000 m3/h with an injection port situated 25 m away from the working face for the highest nitrogen diffusion efficacy and lowest risk of gas explosion,coal spontaneous combustion,and GCC.It has significant engineering applications for ensuring the safe mining of SIEC threatened by the GCC.

Role of iron-based catalysts in reducing NO_(x) emissions from coal combustion

Nitrogen oxide(NO_(x))pollutants emitted from coal combustion are attracting growing public concern.While the traditional technologies of reducing NO_(x) were mainly focused on terminal treatment,and the research on source treatment is limited.This paper proposes a new coal combustion strategy that significantly reduces NO_(x) emissions during coal combustion.This strategy has two important advantages in reducing NO_(x) emissions.First,by introducing iron-based catalyst at the source,which will catalyze the conversion of coke nitrogen to volatile nitrogen during the pyrolysis process,thereby greatly reducing the coke nitrogen content.The second is de-NO_(x) process by a redox reaction between NO_(x) and reducing agents(coke,HCN,NH_(3),etc.)that occurred during coke combustion.Compared to direct combustion of coal,coke prepared by adding iron-based catalyst has 46.1% reduction in NO_(x) emissions.To determine the effect of iron-based additives on de-NO_(x) performance,demineralized coal(de-coal)was prepared to eliminate the effect of iron-based minerals in coal ash.The effects of iron compounds,additive dosages,and combustion temperatures on de-NO_(x) efficiency are systematically studied.The results revealed that the NO_(x) emission of the coke generated by pyrolysis of de-coal loaded with 3%(mass)Fe_(2)O_(3) decreases to 27.3% at combustion temperature of 900℃.Two main reasons for lower NO_(x) emissions were deduced:(1)During the catalytic coal pyrolysis stage,the nitrogen content in the coke decreases with the release of volatile nitrogen.(2)Part of the NO_(x) emitted during the coke combustion was converted into N_(2) for the catalytic effect of the Fe-based catalysts.It is of great practical value and scientific significance to the comprehensive treatment and the clean utilization process of coal.

Time-shift effect of spontaneous combustion characteristics and microstructure difference of dry-soaked coal

The physical and chemical properties of the air-dried residual coal after soaking in the goaf will change,resulting in an increase in its spontaneous combustion tendency.This study aimed to look into the features and mechanism of soaked-dried coal's spontaneous combustion.Five samples of coal were dried to various degrees,and the weight loss features during thermal processing were examined.Based on this,the pore structure and chemical structure characteristics of the coal samples with the highest tendency to spontaneous combustion were quantitatively examined,and the mechanism by which soaking-drying afected the spontaneous combustion heating process of the remaining coal in goaf was investigated in turn.The results show that T1 decreases with the increase of drying time,T2–T6 shows a fuctuating change,and the ignition activation energy of 36-S-Coal is smaller than that of other coal samples.The pore type of 36-S-Coal changes from a oneend closed impermeable pore to an open pore,and the pore group area is large.During the 36 h drying process,the internal channels of the coal were dredged,and a large number of gravels and minerals were precipitated from the pores with the air fow.A large number of gravels were around the pores to form a surface structure that was easy to adsorb various gases.Furthermore,infrared spectroscopy was used to analyze the two coal samples.It was found that soaking and drying did not change the functional group types of coal samples,but the fatty chain degree of 36-S-Coal was reduced to 1.56.It shows that the aliphatic chain structure of coal is changed after 36 h of drying after 30 days of soaking,which leads to the continuous shedding of aliphatic chain branches of residual coal,and the skeleton of coal is looser,which makes the low-temperature oxidation reaction of 36-S-Coal easier.Based on the above results,the coal-oxygen composite mechanism of water-immerseddried coal is obtained,and it is considered that the key to the spontaneous combustion oxidation process of coal is to provide oxygen atoms and accelerate the formation of peroxides.

Effect of Bio-Based Organic‒Inorganic Hybrid Hydrogels on Fire Prevention of Spontaneous Combustion of Coals

To solve the fire accidents caused by coal combustion,this work prepared four hybrid hydrogel materials using bio-based polymers,flame retardants,and inorganic materials.Compared to pure water and 3.5 wt%MgCl_(2)solution,the as-prepared hydrogel presents good fire prevention performance.In addition,it is found that CO and CO_(2)are not produced by coal when the pyrolysis temperature is lower than 200℃.During low-temperature pyrolysis,CO is more likely to be produced than CO_(2),indicating inadequate pyrolysis behavior.At the same time,the addition of fire-preventing hydrogel can not only decrease the maximum CO_(2)concentration before the critical temperature but also prolong the corresponding time.In addition,based on the cone calorimeter test,the inhibition effects of pure water,magnesium chloride solution,and four hybrid hydrogels on heat release behavior are evaluated.It is demonstrated that different dosages of different hydrogels affected the fire prevention effect.Phosphorous-modified cellulose/silica and carrageenan/DMMP/vermiculite composite hydrogels have the weakest fire prevention effect at 20 g,which is weaker than that of water.However,the fire prevention effect of carrageenan/DMMP/vermiculite composite hydrogels exceeded that of water at 40 and 60 g.Additionally,the fire prevention effect of the sodium alginate/sepiolite/ammonium polyphosphate composite hydrogel is most significant in common tests,attributed to the intumescent flame retardant system.

Effects of pyrite on the spontaneous combustion of coal

Abstract Pyrite has a significant effect on the spontaneous combustion of coal. The presence of pyrite can change the propensity of coal towards spontaneous combustion. The influences of various pyrite contents on the parameters of spontaneous combustion, such as index gases, temperature and released heat etc., were investigated in this study, Coal samples with different pyrite contents （0 %, 3 %, 5 %, 7 % and 9 %） were made by mixing coal and pyrite. The oxidation experiments under temperature-programmed condition were carried out to test the release rate of gaseous oxidation products at different temperatures. Differential scanning calorimeter （DSC） was employed to measure the intensity of heat release during coal oxidation for various pyrite contents. The results indicate that pyrite can nonlinearly accelerate the process of spontaneous combustion. The coal sample with a pyrite content of 5 % has the largest CO release rate and oxygen adsorption as well. However, the coal sample with a pyrite content of ？ % has the largest rate of heat flow according to the results from the DSC tests. Pyrite contents of 5 %-7 % in coal has the most significant effects on spontaneous combustion within the range of this study. The conclusions are conducive to the evaluation and control for the spontaneous combustion of coal.

The Cellular Toxicity of PM_(2.5) Emitted from Coal Combustion in Human Umbilical Vein Endothelial Cells

Objective To explore the relationship between different components of fine particulate matter（PM2.5） emitted from coal combustion and their cytotoxic effect in the vascular endothelial cells. Methods Coal-fired PM2.5 was sampled using a fixed-source dilution channel and flow sampler. The sample components were analyzed by ion chromatography and inductively coupled plasma atomic emission spectroscopy（ICP-AES）. The PM2.5 suspension was extracted using an ultrasonic water-bath method and then human umbilical vein endothelial cells（EA.hy926） were treated with various concentrations of the PM2.5 suspension. Cell proliferation, oxidative DNA damage, and global DNA methylation levels were used to measure the cellular toxicity of PM2.5 emitted from coal combustion. Results Compared to other types of coal-fired PM2.5 preparations, the PM2.5 suspension from Yinchuan coal had the highest cytotoxicity. PM2.5 suspension from Datong coal had the highest toxic effect while that from Yinchuan coal had the lowest. Exposure to coal-fired PM2.5 from Jingxi coal resulted in lower 8-hydroxy-2’-deoxyguanosine（8-OHd G） levels. At the same dose, PM2.5 emitted from coal combustion could produce more severe DNA impairment compared to that produced by carbon black. Cell survival rate was negatively correlated with chloride and potassium ions content. The 5-methylcytosine（5-m C） level was positively correlated with Mn and negatively correlated with Zn levels. The 8-OHd G% level was positively correlated with both Mn and Fe. Conclusion PM2.5 emitted from coal combustion can decrease cell viability, increase global DNA methylation, and cause oxidative DNA damage in EA.hy926 cells. Metal components may be important factors that influence cellular toxicity.

Spontaneous coal combustion producing carbon dioxide and water

Gas products from the process of coal oxidization and spontaneous combustion have been studied at different temperatures with FTI spectroscopic tests. With temperatures rising to about 30~100 ℃, water and carbon dioxide gas were formed and from about 105~150 ℃, carbon monoxide was produced. Using the DFT B3LYP method with a 6-311G basis set, the reaction system, where spontaneous combustion between coal and oxygen occurs and produces water and monoxide, has been studied, with the geometric configuration for all stagnation points on the potential reaction energy surface optimized. With a frequency analysis and an IRC method, transient formations were tested. Our results indicate that in the reaction of coal oxidization and spontaneous com-bustion producing carbon dioxide and water, oxygen molecules attack carbon atoms of the terminal of the propyl alcohol group on the lateral chain of benzene rings, which causes this propyl alcohol group to produce the acid (-CH2-CH2-COOH) group and water. This acid group continues its break up into carbon dioxide and the (-CH2-CH3) ethyl group. We have come to the conclusion that this water-and-carbon dioxide-production reaction is spontaneous, based on the observation of the energy released by the reaction.

The Production and Release of CFCs from Coal Combustion

The destruction of the ozone layer in the atmosphere caused by industriallysynthesized CFCs has aroused greatest concerns from the international society, but the CFCs formedfrom burning of coal containing fluorine have not been recognized by the world yet. In the presentstudy, we condensed the gas through cold traps and used the GC-MS to measure the gas composition,and found that the content of CFC-12 in the smog from coal combustion was significantly higher thanthe background value of the local atmosphere. This proves that CFC- 12 is formed in the process ofcoal combustion. This paper discusses a new source of non-synthesized CFCs.

A review on nitrogen transformation and conversion during coal pyrolysis and combustion based on quantum chemical calculation and experimental study

The emission of NOx during coal combustion contributes to the formation of acid rain and photochemical smog,which would seriously affect the quality of atmospheric environment.Therefore,the decrease of NOx is of great importance for improving the efficient utilization of coal.The present review comprehensively summarized the influence factors and mechanisms of migration and transformation of nitrogen during the coal pyrolysis and combustion based on experimental study and quantum chemical calculation.Firstly,in the process of pyrolysis:the occurrence state and transformation of nitrogen were concluded.The influence of temperature,atmosphere,heating rate and catalyst on formation of NOx precursor and nitrogen migration path at the molecular level were summarized;Secondly,during the process of combustion:the influence of temperature,ambient oxygen concentration,physical structure of coal char,catalyst on heterogeneous oxidation of char(N)were summarized;The effects of char surface properties,catalyst and ambient atmosphere on heterogeneous reduction of NOx were also concluded.Based on the quantum chemical calculation,the reaction path of heterogeneous oxidation of char-N and heterogeneous reduction of NOx were described in detail.Current studies focus more on the generation of HCN and NH3,but in order to reduce the pollution of NOx from the source,it is necessary to further improve the process conditions and the optimal formula of producing more N2 during pyrolysis,as well as clarify the path of the generation of N2.Experiments study and quantum chemistry calculation should be combined to complete the research of directional nitrogen reduction during pyrolysis and denitration during combustion.

Analysis and key control technologies to prevent spontaneous coal combustion occurring at a fully mechanized caving face with large obliquity in deep mines

In order to prevent spontaneous coal combustion occurring at a fully mechanized caving face with large obliquity in deep mines in China, we have analyzed the characteristics of spontaneous coal combustion and explain theoretically the factors affecting spontaneous coal combustion, such as rock bursts, high temperatures, high ventilation resistance, slow advancing speed and large obliquity mining. Key technologies to prevent spontaneous combustion occurring in sharply inclined seams in deep mines are pro- posed; these include pouring water, stopping leakage in upper and lower comers of the working face, choking off the goaf and cov- eting the coal. CO concentrations were controlled within two years to less than 15×10^-6 at the upper comer by applying these tech- nologies at the 1410 working face of the Huafeng coal mine. Our method has significant theoretical value and is of practical impor- tance in controlling spontaneous coal combustion occurring at a fully mechanized caving face with large obliquity in deep mines.

Radiant Image Simulation of Pulverized Coal Combustion in Blast Furnace Raceway

The relationship between two-dimensional radiant image and three-dimensional radiant energy in blast furnace raceway was studied by numerical simulation of combustion process. Taking radiant image as radiant boundary for numerical simulation of combustion process, the uneven radiation parameter can be calculated. A method to examine three-dimensional temperature distribution in blast furnace raceway was put forward by radiant image processing. The numeral temperature field matching the real combustion can be obtained by proposed numeric image processing technique.

Flame radiant image numeralization for pulverized coal combustion in BF raceway

In order to establish correlativity between pulverized coal combustion in a blast furnace raceway and its radiant image, we investigated the relationships between two dimensional radiant images and three dimensional radiant energy in a blast furnace raceway, focusing on the correlativity of the numerical simulation of combustion processes with the connection of radiant images information and space temperature distribution. We calculated the uneven radiate characteristic parameterby taking radiant images as a kind of radiative boundary for numerical simulation of combustion processes, and put fonward a method to examine three-dimensional temperatures distribution in blast furnace raceway by radiant image processing. The numeral temperature fields matching the real combustion can be got by the numeric image processing technique.

Presenting an engineering classification system for coal spontaneous combustion potential

The phenomenon of coal spontaneous combustion is one of the common hazards in coal mines and also one of the important reasons for the loss of coal in piles and mines. Based on previous researches, different types of coals have different spontaneous combustion characteristics. For coal loss prevention, a measure is necessary for prediction of coal spontaneous combustion. In this study, a new engineering classification system called ＂Coal Spontaneous Combustion Potential Index （CSCPI）＂ is presented based on the Fuzzy Delphi Analytic Hierarchy Process （FDAHP） approach. CSCPI classifies coals based on their spontaneous combustion capability. After recognition of the roles of the effective parameters influencing the initiation of a spontaneous combustion, a series of intrinsic, geological, and mining characteristics of coal seams are investigated. Then, the main stages of the implementation of the FDAHP method are studied and the weight of each parameter involved is calculated. A classification list of each parameter is formed, the CSCPI system is described, and the engineering classifying system is subsequently presented. In the CSCPI system, each coal seam can be rated by a number from 0 to 100; a higher number implies a greater ease for the coal spontaneous combustion capability. Based on the CSCPI system, the propensity of spontaneous combustion of coal can be classified into three potential levels： low, medium, and high. Finally, using the events of coal spontaneous combustion occurring in one of the Iranian coal mines, Eastern Alborz Coal Mines, an initial validation of the mentioned systematic approach is conducted. Comparison of the results obtained in this study illustrate a relatively good agreement.

Study on partition of spontaneous combustion danger zone and prediction of self-ignition in coalmine based on numeric simulation

By solving steady model of air flow diffusion and chemical reaction in loose coal, distribution of oxygen concentration and flow velocity magnitude were obtained. Compared the simulating results with critic value as well as duration of spontaneous combustion from large-scale spontaneous combustion experiment, 'three zones' of spontaneous combustion were partitioned and mining conditions to avoid spontaneous combustion were obtained. The above method was employed to partition 'three zones' in gob of fully mechanized top-coal caving long wall face and got fairly good result. Calculation of the above method is much smaller than simulating the whole process of coal spontaneous combustion, but the prediction precision can satisfy the demand of predicting and extinguishing spontaneous combustion in mining.

Thermogravimetric study of the effect of a PVA oxygen-insulating barrier on the spontaneous combustion of coal

Coal samples in the air for three months were characterized by Thermogravimetric Analysis (TGA). The effect of a PVA oxygen-insulating barrier on the spontaneous combustion of coal was examined. The moisture loss activation energy, oxidation activation energy and combustion activation energy were calculated by an integral method using the Coats-Redfen formula. The results show that the tendency for spontaneous combustion of three coal samples (judged by the activation energy) falls in the order: CYW>YJL>SW. The oxidation activation energy and combustion activation energy of coal protected by the PVA oxygen-insulating barrier increased. A significant increase in the combustion activation energy was noted, especially for the CYW coal where the in-crease was 28.53 kJ/mol. Hence, oxidation of the protected coal samples was more difficult. The PVA oxygen-insulating barrier helps to prevent spontaneous combustion of the coal.

Emissions of volatile organic compounds and carbonyl compounds from residential coal combustion in China

Emissions of volatile organic compounds （VOCs） and carbonyls from residential coal combustion of five coals with different maturities were studied in a simulated room.The coals were burned in form of honeycomb briquettes in a domestic coal stove,one of the most common fuel/stove combinations in China.Through a dilution system,VOCs and carbonyls samples were collected by canisters and silica-gel cartridges and analyzed by gas chromatography and mass spectrum （GC/MS） and high performance liquid chromatography/ultraviolet （HPLC/UV）,respectively.The results show that the bituminous coals with medium volatile matter content produce the highest emissions while the anthracite yields the lowest.Among the identified carbonyls from the coal smoke,the aromatic compounds （benzaldehyde,2,5-dimethylbenzaldehyde and p-tolualdehyde,m/o-tolualdehyde,benzene,m,p-xylene and trimethyl-benzene） were relatively abundant,which might be due to the molecular structure of the coal.For formaldehyde,aromatic carbonyls and aliphatic alkanes,their concentrations increase up to the maximum values and then decrease with increasing coal maturity.The total carbonyls and VOCs have the same tendency,which was observed for the emission factors of organic carbon （OC）,elemental carbon （EC）,particulate matter （PM） and polycyclic aromatic hydrocarbons （PAHs） detected in the series study.

Numerical comparison of coal spontaneous combustion danger influenced by different methane drainage patterns in gob area

The influence of gas drainage on float coal spontaneous combustion in the work face with ＂U＂ style ventilation was studied. Numerical simulation was used to compare the mutative law of steady flow and density field in the gob area under different drainage conditions by solving the equation set, including mass, momentum, and component transition. Consequently, the sequence of drainage effect and safety was obtained. The result manifests that the more effective the drainage pattern is, the easier float coal spontaneous combustion is caused due to air being guided into the depth of the gob area when the drainage position is arranged in the gas accumulation area. If the widened scope of oxidation zone exceeds the upper limit of the work face advancing speed, nitrogen injection should be applied to decrease the probability of spontaneous combustion. Then, the pipe laying drainage in the upper angle is most economical and safe compared with other drainage patterns when only the situation of gas accumulation is controlled in the upper angle. Finally, drainage pressure must not be too great. Otherwise the drainage density will decrease even if hazard is caused by back flow possibly happening in the return outlet when the drainage position is arranged near the work face.

Critical Value of CO of Forecasting Coal Spontaneous Combustion

CO has been used widely in the production process of colliery as an index gas to predict spontaneous combustion of coal. But in some collieries there are CO gas in the upper corner of the face all the times, sometime CO gas even exceeds the regulated critical index. This phenomenon is much more obvious in the fully-mechanized longwall face and fully-mechanized longwall and top-coal caving face. Although many measures of fire-proof and fire-extinguishing have been adopted, the flowing amount of CO gas can be only decreasd, but can not be eliminated completely. Using the different kinds of coal, the experiment of coal oxidation was made at the low temperature. The experiment indicates that some kinds of coal can produce CO under the condition of normal temperature oxidation, sometime the CO consistency is very high, and the intension of CO can be decreased with oxidation time prolonging. Selecting rational critical value of CO is the kev to predicting spontaneous combustion of coal correctly and reliably. The problem of selecting retional critical value of CO was studied. Finally, the amount of CO gas released by different kinds of coal was obtained under normal temperature condition.

Experimental study on performance that carbon dioxide inhibits coal oxidation and spontaneous combustion

Adopting oil-bath temperature programming experiment and gas chromatography, CO2＇s inhibitory performance on spontaneous combustion of Tingnan Coal Mine sample was analyzed. Through temperature rise rate test experiment, the accuracy, stability and reliability of the improved oil-bath temperature programming system applied in this experiment was proved to be superior to the traditional system. Spontaneous combustion characters parameters test of coal sample in pure air was carried out with this system and offered comparison standard for research in next stage. Temperature programming to coal sample was further conducted in oil-bath with different concentration of CO2. Testing results are compared with parameters of concentration of CO, O2, temperature, CO generation rate and O2 consumption rate tested and calculated in previous experiment in pure air. Methods of proportioning between concentration of CO and O2, CO concentration and temperature, CO generation rate and O2 consumption rate were applied to eliminate obstructions from certain external factors such as inlet of CO2; meanwhile influences of CO2 of different concentrations to coal oxidation and spontaneous combustion were investigated. Also CO2 inhibition technique was used in spontaneous combustion prevention in workface No. 106 of Tingnan Coal Mine, data collected from which indicate that CO2 performs well in inhibiting coal oxidation and spontaneous combustion.