The self-focusing phenomenon of partially coherent beams(PCBs)was simulated using the complex screen method combined with the split-step Fourier method to solve the nonlinear Schrödinger equation.Considering the ...The self-focusing phenomenon of partially coherent beams(PCBs)was simulated using the complex screen method combined with the split-step Fourier method to solve the nonlinear Schrödinger equation.Considering the propagation of Gaussian Schell-model beams in a nonlinear medium as an example,the suppression effects of intensity,propagation distance,and spatial coherence on small-scale self-focusing were demonstrated.Simulations of overall and small-scale self-focusing using this method were compared with the existing literature to demonstrate the validity of the method.This method can numerically analyze the degree of self-focusing in PCBs and advance the study of their nonlinearity.展开更多
The coordination compounds of PdII, PtII, RhIII and IrIII metal ions with a Schiff base ligand (L) i.e. 2,6- diacetylpyridine bis(thiosemicarbazone) have been synthesized and characterized by elemental analyses, molar...The coordination compounds of PdII, PtII, RhIII and IrIII metal ions with a Schiff base ligand (L) i.e. 2,6- diacetylpyridine bis(thiosemicarbazone) have been synthesized and characterized by elemental analyses, molar conductance, magnetic susceptibility measurements, IR, NMR and electronic spectral studies. On the basis of molar conductance and elemental analyses the complexes were found to have composition [M(L)]Cl2 and [M’(L)Cl]Cl2, where M = Pd(II), Pt(II) and M’ = Rh(III), Ir(III). The spectral studies reveal that the complexes possess monomeric composition. Complexes of PdII and PtII were found to have four coordinated square planar geometry whereas the complexes of RhIII and IrIII posses six coordinated octahedral geometry. The ligand field parameters were calculated using various energy level diagrams. In vitro synthesized compounds and metal salts have been tested against some species of plant pathogenic fungi and bacteria in order to assess their antimicrobial properties.展开更多
基金supported by the Strategic Priority Research Program of the Chinese Academy of Sciences(Nos.XDA25020203 and 25020301)the Innovation Fund of the Key Laboratory of the Chinese Academy of Sciences(No.CXJJ-21S015)。
文摘The self-focusing phenomenon of partially coherent beams(PCBs)was simulated using the complex screen method combined with the split-step Fourier method to solve the nonlinear Schrödinger equation.Considering the propagation of Gaussian Schell-model beams in a nonlinear medium as an example,the suppression effects of intensity,propagation distance,and spatial coherence on small-scale self-focusing were demonstrated.Simulations of overall and small-scale self-focusing using this method were compared with the existing literature to demonstrate the validity of the method.This method can numerically analyze the degree of self-focusing in PCBs and advance the study of their nonlinearity.
文摘The coordination compounds of PdII, PtII, RhIII and IrIII metal ions with a Schiff base ligand (L) i.e. 2,6- diacetylpyridine bis(thiosemicarbazone) have been synthesized and characterized by elemental analyses, molar conductance, magnetic susceptibility measurements, IR, NMR and electronic spectral studies. On the basis of molar conductance and elemental analyses the complexes were found to have composition [M(L)]Cl2 and [M’(L)Cl]Cl2, where M = Pd(II), Pt(II) and M’ = Rh(III), Ir(III). The spectral studies reveal that the complexes possess monomeric composition. Complexes of PdII and PtII were found to have four coordinated square planar geometry whereas the complexes of RhIII and IrIII posses six coordinated octahedral geometry. The ligand field parameters were calculated using various energy level diagrams. In vitro synthesized compounds and metal salts have been tested against some species of plant pathogenic fungi and bacteria in order to assess their antimicrobial properties.