Suppression of Co(Ⅱ)ion deposition and hazards:Regulation of SEI film composition and structure

Despite the presence of Li F components in the solid electrolyte interphase(SEI)formed on the graphite anode surface by conventional electrolyte,these Li F components primarily exist in an amorphous state,rendering them incapable of effectively inhibiting the exchange reaction between lithium ions and transition metal ions in the electrolyte.Consequently,nearly all lithium ions within the SEI film are replaced by transition metal ions,resulting in an increase in interphacial impedance and a decrease in stability.Herein,we demonstrate that the SEI film,constructed by fluoroethylene carbonate(FEC)additive rich in crystalline Li F,effectively inhibits the undesired Li^(+)/Co^(2+)ion exchange reaction,thereby suppressing the deposition of cobalt compounds and metallic cobalt.Furthermore,the deposited cobalt compounds exhibit enhanced structural stability and reduced catalytic activity with minimal impact on the interphacial stability of the graphite anode.Our findings reveal the crucial influence of SEI film composition and structure on the deposition and hazards associated with transition metal ions,providing valuable guidance for designing next-generation electrolytes.

Floristic Composition, Structure and Soil Properties of Mixed Deciduous Forest and Deciduous Dipterocarp Forest: Case Study in Madan Watershed, Myanmar

Patterns of woody regeneration in terms of species composition and diversity were studied in mixed deciduous forest (MDF) and deciduous dipterocarp forest (DDF) in Minbyin reserved forest of Lewe Township. A total of 57 plant species of MDF belonging to 28 families and 342 individuals and 25 plant species of DDF consist of 15 families and 285 individuals were identified. Plant species diversity was quantitatively higher in the MDF (H' = 3.68) compared to the DDF (H' = 2.39). Tectona grandis showed the highest density (30), dominance (4.40 m2) and IVI (27.01) of MDF and Dipterocarpus tuberculatus also composed the highest density (109), dominance (9.02 m2) and IVI (81.87) in DDF. The smallest diameter class (10 - 20 cm) comprised with 29 species, 103 individuals in MDF and 18 species, 85 individuals in DDF. The size class distribution displayed a reverse J-shaped pattern. The largest numbers of species were concentrated in the smallest height class in both investigated forests because of height and diameter distribution is closely related. The total densities of seedlings and saplings were 1219 and 531 ha-1 in MDF and 988 and 444 ha-1 in DDF respectively. Although soil texture of (40 - 50 cm) and (90 - 100 cm) were sandy clay loam in mixed deciduous forest, the other layers of both investigated forests were sandy loam.

DEVELOPING A NEW GENERATION OF HIGH PERFORMANCE COMPOSITE CEMENT

This paper proposed a new generation of high performance composite cement which is designed according to the optimization of composition and structure of cement paste and is manufactured by blending the differ ent components with special composite techniques. Each of these components has its different special property, and should be compatible with each other and match each other, and the properties of them are complementary mutually. At present, such kind of high performance composite cement can be manufactured with high reactivity cement clinker, ground granulated blast - furnace slag, high grade fly ash, silica fume etc..

Social engineering in cybersecurity:a domain ontology and knowledge graph application examples

Social engineering has posed a serious threat to cyberspace security.To protect against social engineering attacks,a fundamental work is to know what constitutes social engineering.This paper first develops a domain ontology of social engineering in cybersecurity and conducts ontology evaluation by its knowledge graph application.The domain ontology defines 11 concepts of core entities that significantly constitute or affect social engineering domain,together with 22 kinds of relations describing how these entities related to each other.It provides a formal and explicit knowledge schema to understand,analyze,reuse and share domain knowledge of social engineering.Furthermore,this paper builds a knowledge graph based on 15 social engineering attack incidents and scenarios.7 knowledge graph application examples(in 6 analysis patterns)demonstrate that the ontology together with knowledge graph is useful to 1)understand and analyze social engineering attack scenario and incident,2)find the top ranked social engineering threat elements(e.g.the most exploited human vulnerabilities and most used attack mediums),3)find potential social engineering threats to victims,4)find potential targets for social engineering attackers,5)find potential attack paths from specific attacker to specific target,and 6)analyze the same origin attacks.

Return to the Moon:New perspectives on lunar exploration

Lunar exploration is deemed crucial for uncovering the origins of the Earth-Moon system and is the first step for advancing humanity’s exploration of deep space.Over the past decade,the Chinese Lunar Exploration Program(CLEP),also known as the Chang’e(CE)Project,has achieved remarkable milestones.It has successfully developed and demonstrated the engineering capability required to reach and return from the lunar surface.Notably,the CE Project has made historic firsts with the landing and on-site exploration of the far side of the Moon,along with the collection of the youngest volcanic samples from the Procellarum KREEP Terrane.These achievements have significantly enhanced our understanding of lunar evolution.Building on this success,China has proposed an ambitious crewed lunar exploration strategy,aiming to return to the Moon for scientific exploration and utilization.This plan encompasses two primary phases:the first crewed lunar landing and exploration,followed by a thousand-kilometer scale scientific expedition to construct a geological cross-section across the lunar surface.Recognizing the limitations of current lunar exploration efforts and China’s engineering and technical capabilities,this paper explores the benefits of crewed lunar exploration while leveraging synergies with robotic exploration.The study refines fundamental lunar scientific questions that could lead to significant breakthroughs,considering the respective engineering and technological requirements.This research lays a crucial foundation for defining the objectives of future lunar exploration,emphasizing the importance of crewed missions and offering insights into potential advancements in lunar science.