In the pursuit of stable,high performance Ni-based oxygen evolution reaction(OER)electrocatalysts,modifying the local chemical compositions or fabricating hybrid nanostructures to generate abundant interfaces for impr...In the pursuit of stable,high performance Ni-based oxygen evolution reaction(OER)electrocatalysts,modifying the local chemical compositions or fabricating hybrid nanostructures to generate abundant interfaces for improving the water oxidation activity of electrocatalysts has emerged as an effective strategy.Herein,we report the facile development of a Ni_(3)S_(2)-CeO_(2)hybrid nanostructure via an electrodeposition method.Benefiting from the strong interfacial interaction between Ni_(3)S_(2)and CeO_(2),the electron transfer is notably improved and the water oxidation activity of Ni_(3)S_(2)nanosheets is significantly enhanced.In 1.0 M KOH,the Ni_(3)S_(2)-CeO_(2)electrocatalyst achieves a current density of 20 mA cm-2 at a low overpotential of 264 mV,which is 92 mV lower than that of Ni_(3)S_(2).Moreover,Ni_(3)S_(2)-CeO_(2)exhibits superior electrochemical stability.Density functional theory calculations demonstrate that the enhanced OER electrocatalytic performance of Ni_(3)S_(2)-CeO_(2)can be ascribed to an increase in the binding strength of the reaction intermediates at the Ni_(3)S_(2)-CeO_(2)interface.展开更多
Free vibration of elastically constrained rectangular single-layered M0S_(2)is investigated by using a nonlocal Kirchhoff plate model with an initial stress.The variationally consistent elastically constrained boundar...Free vibration of elastically constrained rectangular single-layered M0S_(2)is investigated by using a nonlocal Kirchhoff plate model with an initial stress.The variationally consistent elastically constrained boundary conditions are obtained by using the weighted residual method,while the governing equations of the nonlocal Kirchhoff plate model are known.A modified Fourier series method is applied to study the vibrational behaviors of elastically constrained nonlocal Kirchhoff plate models.The convergence and reliability of the modified Fourier series method is verified via comparison with the finite element method.A comprehensive parametric study is performed to show the influences of the boundary elastic constant,nonlocal parameter and initial stress on the vibrational behaviors of single-layered M0S2.The results should be good for the design of nanoresonators.展开更多
文摘In the pursuit of stable,high performance Ni-based oxygen evolution reaction(OER)electrocatalysts,modifying the local chemical compositions or fabricating hybrid nanostructures to generate abundant interfaces for improving the water oxidation activity of electrocatalysts has emerged as an effective strategy.Herein,we report the facile development of a Ni_(3)S_(2)-CeO_(2)hybrid nanostructure via an electrodeposition method.Benefiting from the strong interfacial interaction between Ni_(3)S_(2)and CeO_(2),the electron transfer is notably improved and the water oxidation activity of Ni_(3)S_(2)nanosheets is significantly enhanced.In 1.0 M KOH,the Ni_(3)S_(2)-CeO_(2)electrocatalyst achieves a current density of 20 mA cm-2 at a low overpotential of 264 mV,which is 92 mV lower than that of Ni_(3)S_(2).Moreover,Ni_(3)S_(2)-CeO_(2)exhibits superior electrochemical stability.Density functional theory calculations demonstrate that the enhanced OER electrocatalytic performance of Ni_(3)S_(2)-CeO_(2)can be ascribed to an increase in the binding strength of the reaction intermediates at the Ni_(3)S_(2)-CeO_(2)interface.
基金We gratefully acknowledge the support from the Natural Science Foundation of Chongqing(cstc2020jcyj-msxmX0037)State Key Laboratory of Mechanics and Control of Mechanical Structures(Nanjing University of Aeronautics and astronautics)under Grants MCMS-E-0120G01National Natural Science Foundation of China under Grants Nos.11925205 and 51921003,and the Fundamental Research Funds for the Central Universities of China.
文摘Free vibration of elastically constrained rectangular single-layered M0S_(2)is investigated by using a nonlocal Kirchhoff plate model with an initial stress.The variationally consistent elastically constrained boundary conditions are obtained by using the weighted residual method,while the governing equations of the nonlocal Kirchhoff plate model are known.A modified Fourier series method is applied to study the vibrational behaviors of elastically constrained nonlocal Kirchhoff plate models.The convergence and reliability of the modified Fourier series method is verified via comparison with the finite element method.A comprehensive parametric study is performed to show the influences of the boundary elastic constant,nonlocal parameter and initial stress on the vibrational behaviors of single-layered M0S2.The results should be good for the design of nanoresonators.
