Engineering of geometrical configurations in dual-atom catalysts for electrocatalytic applications

Geometrical configurations play a crucial role in dual-atom catalysts(DACs)for electrocatalytic applications.Significant progress has been made to design DACs electrocatalysts with various geometri-cal configurations,but in-depth understanding the relationship between geometrical configurations and metal-metal interaction mechanisms for designing targeted DACs is still required.In this review,the recent progress in engineering of geometrical configurations of DACs is systematically summarized.Based on the polarity of geometrical configuration,DACs can be classified into two different types that are homonuclear and heteronuclear DACs.Furthermore,with regard to the geometrical configurations of the active sites,homonuclear DACs are identified into adjacent and bridged configurations,and heteronuclear DACs can be classified into adjacent,bridged,and separated configurations.Subsequently,metal-metal interactions in DACs with different geometrical configurations are introduced.Additionally,the applications of DACs in different electrocatalytic reactions are discussed,including the oxygen reduction reaction(ORR),oxygen evolution reaction(OER),hydrogen evolution reaction(HER),and other catalysis.Finally,the future challenges and perspectives for advancements in DACs are high-lighted.This review aims to provide inspiration for the design of highly effcient DACs towards energy relatedapplications.

Integrated Experimental and Simulation Investigation of Breakdown Voltage Characteristics Across Electrode Configurations in SF_(6) Circuit Breakers

This study investigates the breakdown voltage characteristics in sulfur hexafluoride(SF6)circuit breakers,employing a novel approach that integrates both experimental investigations and finite element simulations.Utilizing a sphere-sphere electrode configuration,we meticulously measured the relationship between breakdown voltage and electrode gap distances ranging from 1 cm to 4.5 cm.Subsequent simulations,conducted using COMSOL Multiphysics,mirrored the experimental setup to validate the model’s accuracy through a comparison of the breakdown voltage-electrode gap distance curves.The simulation results not only aligned closely with the experimental data but also allowed the extraction of detailed electric field strength,electric potential contours,and electric current flow curves at the breakdown voltage for gap distances extending from 1 to 4.5 cm.Extending the analysis,the study explored the electric field and potential distribution at a constant voltage of 72.5 kV for gap distances between 1 to 10 cm,identifying the maximum electric field strength.A comprehensive comparison of five different electrode configurations(sphere-sphere,sphere-rod,sphere-plane,rod-plane,rod-rod)at 72.5 kV and a gap distance of 1.84 cm underscored the significant influence of electrode geometry on the breakdown process.Moreover,the research contrasts the breakdown voltage in SF6 with that in air,emphasizing SF6’s superior insulating properties.This investigation not only elucidates the intricate dynamics of electrical breakdown in SF6 circuit breakers but also contributes valuable insights into the optimal electrode configurations and the potential for alternative insulating gases,steering future advancements in high-voltage circuit breaker technology.

Sliding and damming properties of granular debris with different geometric configurations and grain size distributions

Granular debris plays a significant role in determining damming deposit characteristics. An indepth understanding of how variations in grain size distribution(GSD) and geometric configurations impact the behavior of granular debris during the occurrence of granular debris is essential for precise assessment and effective mitigation of landslide hazards in mountainous terrains. This research aims to investigate the impact of GSD and geometric configurations on sliding and damming properties through laboratory experiments. The geometric configurations were categorized into three categories based on the spatial distribution of maximum volume: located at the front(Type Ⅰ), middle(Type Ⅱ), and rear(Type Ⅲ) of the granular debris. Our experimental findings highlight that the sliding and damming processes primarily depend on the interaction among the geometric configuration, grain size, and GSD in granular debris. Different sliding and damming mechanisms across various geometric configurations induce variability in motion parameters and deposition patterns. For Type Ⅰ configurations, the front debris functions as the critical and primary driving component, with energy dissipation primarily occurring through inter-grain interactions. In contrast, Type Ⅱ configurations feature the middle debris as the dominant driving component, experiencing hindrance from the front debris and propulsion from the rear, leading to complex alterations in sliding motion. Here, energy dissipation arises from a combination of inter-grain and grain-substrate interactions. Lastly, in Type Ⅲ configurations, both the middle and rear debris serve as the main driving components, with the rear sliding debris impeded by the front. In this case, energy dissipation predominantly results from grainsubstrate interaction. Moreover, we have quantitatively demonstrated that the inverse grading in damming deposits, where coarse grain moves upward and fine grain moves downward, is primarily caused by grain sorting due to collisions among the grains and between the grain and the base. The impact of grain on the horizontal channel further aids grain sorting and contributes to inverse grading. The proposed classification of three geometric configurations in our study enhances the understanding of damming properties from the view of mechanism, which provides valuable insights for related study about damming granular debris.

Environmental Analysis Using Integrated GIS and Spatial Configurations in Israel

The scope for environmental analysis constitutes a critical factor in recent times, yet demanding importance due to the concerns of environmental sustainability. The study aims at analysing the prospects of implementing an integrated GIS and spatial configuration for environment analysis in Israel. The study adopts an empirical study design to consider the multi-dimensional utilisation of an integrated GIS and spatial configuration for environment analysis. The study considers the materials and methods of the GIS system modelling as well, consisting of satellite imagery, GPS-based location identification, Esri ArcGIS, CyberGIS, and BIM integration to present a comprehensive system for the environmental analysis of Israel. The results of the study indicate that the threats of natural disasters and climate change can be identified based on the synergy of spatial data within an integrated GIS modelling. In many cases, it is also used in collaboration with a BIM to ensure that planning and decision-making processes are sustainable, economically beneficial and environmentally considered. Thus, it is concluded that environmental analysis through the projection of visually represented satellite imagery within an integrated GIS with spatial configurations in Israel can minimise the conflicts between the infrastructural designs, human activities, and environmental sustainability.

A rescaling algorithm for multi-relaxation-time lattice Boltzmann method towards turbulent flows with complex configurations

Understanding and modeling flows over porous layers are of great industrial significance.To accurately solve the turbulent multi-scale flows on complex configurations,a rescaling algorithm designed for turbulent flows with the Chapman-Enskog analysis is proposed.The mesh layout and the detailed rescaling procedure are also introduced.Direct numerical simulations(DNSs)for a turbulent channel flow and a porous walled turbulent channel flow are performed with the three-dimensional nineteen-velocity(D3Q19)multiple-relaxation-time(MRT)lattice Boltzmann method(LBM)to validate the accuracy,adaptability,and computational performance of the present rescaling algorithm.The results,which are consistent with the previous DNS studies based on the finite difference method and the LBM,demonstrate that the present method can maintain the continuity of the macro values across the grid interface and is able to adapt to complex geometries.The reasonable time consumption of the rescaling procedure shows that the present method can accurately calculate various turbulent flows with multi-scale and complex configurations while maintaining high computational efficiency.

Experimental Analysis to Extract the Maximum Output of Serial and Parallel PV Module Configurations under Partial Shadow Conditions: A Case Study for Bambey, Senegal

Using an experimental setup, the series configurations (SC) and the parallel configurations (PC) of the PV cell connection are studied to compare their performance under the condition of partial shading s. The performance of the configurations is evaluated by comparing the open-circuit voltage, the short-circuit current, the maximum power point (MPP), the voltage and current corresponding to MPP, and the Fill Factor (FF). The variations of the series resistance and the shunt resistance of a PV module under different irradiance levels are also determined by considering the effect of thermal voltage. Finally, a comparison between the performance losses in the different configurations is presented. The results of this study show that the parallel configuration has the best performance under the conditions of partial shade in the context of this work.

Collective Flows of 16O＋16O Collisions with α-Clustering Configurations

The main purpose of the present work is to discuss whether or not the collective flows in heavy-ion collision at the Fermi energy can be taken as a tool to investigate the cluster configuration in light nuclei. In practice, within an extended quantum molecular dynamics model, four a-clustering （linear chain, kite, square and tetrahedron） configurations of 16O are employed in the initialization, 16O＋16O around the Fermi energy （40-60 MeV/nucleon） with impact parameter 1-3fro are simulated, and the directed and elliptic flows are analyzed. It is found that collective flows are influenced by the different a-clustering configurations, and the directed flow of free protons is more sensitive to the initial cluster configuration than the elliptic flow. Nuclear reaction at the Fermi energy can be taken as a useful way to study cluster configuration in light nuclei.

Comparisons and applications of numerical simulation methods for predicting aerodynamic heating around complex configurations

Numerical simulation methods of aerodynamic heating were compared by considering the inuence of numerical schemes and turbulence models,and attempting to investigate the applicability of numerical simulation methods on predicting heat flux in engineering applications. For some typical cases provided with detailed experimental data,four spatial schemes and four turbulence models were adopted to calculate surface heat flux. By analyzing and comparing,some inuencing regularities of numerical schemes and turbulence models on calculating heat flux had been acquired. It is clear that AUSM＋-up scheme with rapid compressibilitymodified high Reynolds number k鈥撓？model should be appropriate for calculating heat flux. The numerical methods selected as preference above were applied to calculate the heat flux of a 3-D complex geometry in high speed turbulent flows. The results indicated that numerical simulation can capture the complex flow phenomena and reveal the mechanism of aerodynamic heating. Especially,the numerical result of the heat flux at the stagnation point of the wedge was well in agreement with the prediction of Kemp鈥揜iddel formula,and the surface heat flux distribution was consistent with experiment results,which implied that numerical simulation can be introduced to predict heat flux in engineering applications.

Monte-Carlo Simulation of Response Functions for Natural Gamma-Rays in LaBr_3 Detector System with Complex Borehole Configurations

Usually, there are several methods, e.g. experiment, interpolation experiment-based, analytic function, and Monte-Carlo simulation, to calculate the response functions in LaBr3（Ce） detectors. In logging applications, the experiment-based methods cannot be adopted because of their limitations. Analytic function has the advantage of fast calculating speed, but it is very difficult to take into account many effects that occur in practical applications. On the contrary, Monte-Carlo simulation can deal with physical and geometric configurations very tactfully. It has a distinct advantage for calculating the functions with complex configurations in borehole. A new application of LaBr3（Ce） detector is in natural gamma-rays borehole spectrometer for uranium well logging. Calculation of response functions must consider a series of physical and geometric factors under complex logging conditions, including earth formations and its relevant parameters, different energies, material and thickness of the casings, the fluid between the two tubes, and relative position of the LaBr3（Ce） crystal to steel ingot at the front of logging tube. The present work establishes Monte-Carlo simulation models for the above-mentioned situations, and then performs calculations for main gamma-rays from natural radio-elements series. The response functions can offer experimental directions for the design of borehole detection system, and provide technique basis and basic data for spectral analysis of natural gamma-rays, and for sonrceless calibration in uranium quantitative interpretation.

Lattice configurations in spin-1 Bose–Einstein condensates with the SU(3) spin–orbit coupling

We consider the SU(3) spin–orbit coupled spin-1 Bose–Einstein condensates in a two-dimensional harmonic trap. The competition between the SU(3) spin–orbit coupling and the spin-exchange interaction results in a rich variety of lattice configurations. The ground-state phase diagram spanned by the isotropic SU(3) spin–orbit coupling and the spin–spin interaction is presented. Five ground-state phases can be identified on the phase diagram, including the plane wave phase, the stripe phase, the kagome lattice phase, the stripe-honeycomb lattice phase, and the honeycomb hexagonal lattice phase. The system undergoes a sequence of phase transitions from the rectangular lattice phase to the honeycomb hexagonal lattice phase, and to the triangular lattice phase in spin-1 Bose–Einstein condensates with anisotrpic SU(3) spin–orbit coupling.

Tunable Optical Filters Based on Different Configurations with Cholesteric Liquid Crystals

Optical filters with different configurations based on cholesteric liquid crystals （CLCs） are designed. The central wavelength from CLCs can be tuned by the electric field or temperature. For the electric field tuning, the ITO is designed with circular patterns, which can make the tunable range 18 nm. For the temperature tuning, two-layer- CLC configurations are used. The experimental results indicate that a deepened or broadened bandgap from the CLC can be achieved by different handedness or concentrations of chiral dopants. The spectrum study is carried out.

STUDIES ON CHIRAL THIOPHOSPHORIC ACIDS AND THEIR DERIVATIVES 11.——THE RESOLUTION OF O-METHYL O-PHENYL THIOPHOSPHORIC ACID AND ABSOLUTE CONFIGURATIONS OF ITS OPTICAL ISOMERS

Racemic O-methyl O-pheayl thiophosphoric acid 1 has been successfully resolved through its quinine and brucine salts in methanol solution by fractional crystallization. The absolute configurations of the optically active 1 have been established as (+)-R-1 and (-)-S-1 by chemical correlation.

Relative Irradiance Measurement and Bonding Configurations of Amorphous Fluorinated Carbon Films Deposited by Electron Cyclotron Resonance Plasma

a-C:F films are deposited by microwave electron cyclotron resonance (ECR)plasma chemical vapor deposition (CVD) using trifluoromethane (CHF3) and benzene (C6H6) as source gases at different microwave powers. The radicals in plasma originating from source gases dissociation are analyzed by relative irradiance measurement. The bonding configurations and binding state of a-C:F films are measured with Fourier-transformed infrared spectrometer (FTIR) and x-ray photoelectron spectroscopy (XPS). The results show that a-C:F films are mainly composed of CF radical at lower powers but of CF2 radical at higher powers. The deposition of films is related to the radicals generated in plasma and the main bonding configurations are dependent on the ratio of CF to CF2 radicals in films.

Configurations of the Penrose Tiling beyond Nearest Neighbors

Starting from the eight vertex types in the Penrose tiling, we investigate the configurations beyond the nearest neighbors. The detailed structure of configurations and their concentrations in the whole pattern are obtained. It is found that the number of configuration types increases greatly when the observed clusters are becoming larger, which indicates that it is difficult to generate a perfect Penrose tiling according to the local matching rules.

Self-Similar Transformation and Vertex Configurations of the Octagonal Ammann-Beenker Tiling

Based on the matching rules for squares and rhombuses,we study the self-similar transformation and the vertex configurations of the Ammann-Beenker tiling.The structural properties of the configurations and their relations during the self-similar transformation are obtained.Our results reveal the distribution correlations of the configurations,which provide an intuitive understanding of the octagonal quasi-periodic structure and also give implications for growing perfect quasi-periodic tiling according to the local rules.

Examining the Relationship Between Spatial Configurations of Urban Impervious Surfaces and Land Surface Temperature

The urban heat island(UHI) effect has significant effects on the quality of life and public health. Numerous studies have addressed the relationship between UHI and the increase in urban impervious surface area(ISA), but few of them have considered the impact of the spatial configuration of ISA on UHI. Land surface temperature(LST) may be affected not only by urban land cover, but also by neighboring land cover. The aim of this research was to investigate the effects of the abundance and spatial association of ISAs on LST. Taking Harbin City, China as an example, the impact of ISA spatial association on LST measurements was examined. The abundance of ISAs and the LST measurements were derived from Landsat Thematic Mapper(TM) imagery of 2000 and 2010, and the spatial association patterns of ISAs were calculated using the local Moran’s I index. The impacts of ISA abundance and spatial association on LST were examined using correlation analysis. The results suggested that LST has significant positive associations with both ISA abundance and the Moran’s I index of ISAs, indicating that both the abundance and spatial clustering of ISAs contribute to elevated values of LST. It was also found that LST is positively associated with clustering of high-ISA-percentage areas(i.e.,>50%) and negatively associated with clustering of low-ISA-percentage areas(i.e.,<25%). The results suggest that, in addition to the abundance of ISAs,their spatial association has a significant effect on UHIs.

Simulation of drop breakage in liquid–liquid system by coupling of CFD and PBM: Comparison of breakage kernels and effects of agitator configurations

This work focuses on drop breakage for liquid-liquid system with an adoption of numerical simulation by using computational fluid dynamics and population balance model (PBM) coupled with two-fluid model (TFM). Two different breakage kernels based on identical breakage mechanism but different descriptions of breaking time are take n into account in this work. Eight cases corresp on ding to distinct configurations of agitator are carried out to validate numerical predictions, namely agitators with different porosity and hole diameters, respectively implemented in Cases 1 to 5 and Cases 6 to 8. The results are compared with experimental data for testing the applicability of both kernels. Simulations are implemented, in this work, with an approach of class method for the solution of population balance model by the special-purpose computational fluid dynamics solver Fluent 16.1 based on finite volume method, and the grids used for meshing the solution domain are accomplished in a commercial software Gambit 2.4.6. The effects of configurations of agitator corresponding to different parameters mentioned above on final Sauter mean diameter are equally concentrated in this work. Analysis of both kernels and comparisons with experimental results reveal that, the second kernel has more decent agreement with experiments, and the results of investigations on effects of agitator configurations show that the in fluences of these parameters on Sauter mean diameter are marginal, but appropriate porosity and hole diameter are actually able to decrease Sauter mean diameter. These outcomes allow us to draw general conclusions and help investigate performances of liquid-liquid system.

Statistical and quantum photoionization cross sections in plasmas:Analytical approaches for any configurations including inner shells

Statistical models combined with the local plasma frequency approach applied to the atomic electron density are employed to study the photoionization cross-section for complex atoms.It is demonstrated that the Thomas–Fermi atom provides surprisingly good overall agreement even for complex outer-shell configurations,where quantum mechanical approaches that include electron correlations are exceedingly difficult.Quantum mechanical photoionization calculations are studied with respect to energy and nl quantum number for hydrogen-like and non-hydrogen-like atoms and ions.Ageneralized scaled photoionizationmodel(GSPM)based on the simultaneous introduction of effective charges for non-H-like energies and scaling charges for the reduced energy scale allows the development of analytical formulas for all states nl.Explicit expressions for nl1s,2s,2p,3s,3p,3d,4s,4p,4d,4f,and 5s are obtained.Application to H-like and non-H-like atoms and ions and to neutral atoms demonstrates the universality of the scaled analytical approach including inner-shell photoionization.Likewise,GSPMdescribes the near-threshold behavior and high-energy asymptotes well.Finally,we discuss the various models and the correspondence principle along with experimental data and with respect to a good compromise between generality and precision.The results are also relevant to large-scale integrated light–matter interaction simulations,e.g.,X-ray free-electron laser interactions with matter or photoionization driven by a broadband radiation field such as Planckian radiation.

Singular Assembly Configurations and Configuration Bifurcation Characteristics of the Semi-regular Hexagons 6-6 Gough-Stewart Manipulator

It is well known that singular configurations are inherent to parallel manipulators and have serious influences on their properties. Therefore, these singular configurations should be avoided in the design and application of mechanisms. The researches on the singularity identification and distribution have revealed the relations among the six configuration parameters at singular points. Few works have dealt with the relation between the singularity and the input parameters, as wcll as the properties of the manipulator nearby the singularity. In this paper, taking the semi-regular hexagons 6-6 Gough-Stewart manipulator （SRHGSMP） as an example, the configuration bifurcation characteristics going with the input parameters, the assembly configurations at singular points, and the reasons to cause the singularity are analyzed. The research reveals that the number and the combination of the input parameters have great influences on the complexity of the singularity and the curvature radiuses of the configuration curves. Under different number of input parameters, the dimensional-utmost singularity, line vectors correlation singularity and Jacobian matrix correlation singularity can occur individually or jointly. Choosing the adjacent input parameters, the simple singularity and the large singularity-free input parameters zones can be obtained. And selecting multiple input parameters, the self-motion regions and the singularity avoidance errors can be reduced. These new discoveries are valuable and of significance for the trajectory design, the singularity avoidance, and the self-motion control of the parallel manipulator.

STABILITY OF STEADY MULTI-WAVE CONFIGURATIONS FOR THE FULL EULER EQUATIONS OF COMPRESSIBLE FLUID FLOW

We are concerned with the stability of steady multi-wave configurations for the full Euler equations of compressible fluid flow. In this paper, we focus on the stability of steady four-wave configurations that are the solutions of the Riemann problem in the flow direction, consisting of two shocks, one vortex sheet, and one entropy wave, which is one of the core multi-wave configurations for the two-dimensional Euler equations. It is proved that such steady four-wave configurations in supersonic flow are stable in structure globally, even under the BV perturbation of the incoming flow in the flow direction. In order to achieve this, we first formulate the problem as the Cauchy problem （initial value problem） in the flow direction, and then develop a modified Glimm difference scheme and identify a Glimm-type functional to obtain the required BV estimates by tracing the interactions not only between the strong shocks and weak waves, but also between the strong vortex sheet/entropy wave and weak waves. The key feature of the Euler equations is that the reflection coefficient is always less than 1, when a weak wave of different family interacts with the strong vortex sheet/entropy wave or the shock wave, which is crucial to guarantee that the Glimm functional is decreasing. Then these estimates are employed to establish the convergence of the approximate solutions to a global entropy solution, close to the background solution of steady four-wave configuration.