This paper investigated the continuous measurement of a refractive index(RI)sensor based on macrobending microoptical plastic fiber(m-POF).The sensing properties of the RI sensor depend on the structure parameter,whic...This paper investigated the continuous measurement of a refractive index(RI)sensor based on macrobending microoptical plastic fiber(m-POF).The sensing properties of the RI sensor depend on the structure parameter,which is the ratio of macrobending radius of m-POF to the radius of fiber itself.The ratio changes with the measurement time increasing because of the water absorption,which introduces an maximum measurement deviation of 7.3×10^(-5) RIU when the immersion time exceeds 40 h.This work indicates that for the sensors based on POF,the measurement time must be taken into consideration for continuous measurement.展开更多
We present an experimental demonstration of the rotation measurement using a compact cold atom gyroscope. Atom interference fringes are observed in the stationary frame and the rotating frame, respectively. The phase ...We present an experimental demonstration of the rotation measurement using a compact cold atom gyroscope. Atom interference fringes are observed in the stationary frame and the rotating frame, respectively. The phase shift and contrast of the interference fringe are experimentally investigated. The results show that the contrast of the interference fringe is well held when the platform is rotated, and the phase shift of the interference fringe is linearly proportional to the rotation rate of the platform. The long-term stability, which is evaluated by the overlapped Allan deviation, is 8.5 × 10^-6 rad/s over the integrating time of 1000s.展开更多
In this paper we give a sufficient and necessary condition under which a continuous measure (whose values belong to, the extended half-line (0,+∞) defined on a class of sets closed under the formation of intersection...In this paper we give a sufficient and necessary condition under which a continuous measure (whose values belong to, the extended half-line (0,+∞) defined on a class of sets closed under the formation of intersection can be extended to a smallest monotone class containing this class, and we also give a condition under which there exists a unique extension. In addition, we give a method by means of which a continuous measure on a monotone class can be extended again.展开更多
In this study,the micro-failure process and failure mechanism of a typical brittle rock under uniaxial compression are investigated via continuous real-time measurement of wave velocities.The experimental results indi...In this study,the micro-failure process and failure mechanism of a typical brittle rock under uniaxial compression are investigated via continuous real-time measurement of wave velocities.The experimental results indicate that the evolutions of wave velocities became progressively anisotropic under uniaxial loading due to the direction-dependent development of micro-damage.A wave velocity model considering the inner anisotropic crack evolution is proposed to accurately describe the variations of wave velocities during uniaxial compression testing.Based on which,the effective elastic parameters are inferred by a transverse isotropic constitutive model,and the evolutions of the crack density are inversed using a self-consistent damage model.It is found that the propagation of axial cracks dominates the failure process of brittle rock under uniaxial loading and oblique shear cracks develop with the appearance of macrocrack.展开更多
This study proposed a measurement platform for continuous blood pressure estimation based on dual photoplethysmography(PPG)sensors and a deep learning(DL)that can be used for continuous and rapid measurement of blood ...This study proposed a measurement platform for continuous blood pressure estimation based on dual photoplethysmography(PPG)sensors and a deep learning(DL)that can be used for continuous and rapid measurement of blood pressure and analysis of cardiovascular-related indicators.The proposed platform measured the signal changes in PPG and converted them into physiological indicators,such as pulse transit time(PTT),pulse wave velocity(PWV),perfusion index(PI)and heart rate(HR);these indicators were then fed into the DL to calculate blood pressure.The hardware of the experiment comprised 2 PPG components(i.e.,Raspberry Pi 3 Model B and analog-todigital converter[MCP3008]),which were connected using a serial peripheral interface.The DL algorithm converted the stable dual PPG signals acquired from the strictly standardized experimental process into various physiological indicators as input parameters and finally obtained the systolic blood pressure(SBP),diastolic blood pressure(DBP)and mean arterial pressure(MAP).To increase the robustness of the DL model,this study input data of 100 Asian participants into the training database,including those with and without cardiovascular disease,each with a proportion of approximately 50%.The experimental results revealed that the mean absolute error and standard deviation of SBP was 0.17±0.46 mmHg.The mean absolute error and standard deviation of DBP was 0.27±0.52 mmHg.The mean absolute error and standard deviation of MAP was 0.16±0.40 mmHg.展开更多
The detection of a particle in electromagnetic plus gravitational fields is investigated. We obtain a set of quantum nondemolition variables. The continuous measurements of these nondemolition parameters are analyzed ...The detection of a particle in electromagnetic plus gravitational fields is investigated. We obtain a set of quantum nondemolition variables. The continuous measurements of these nondemolition parameters are analyzed in the framework of restricted path integral formalism. We manipulate the corresponding propagators, and deduce the probabilities associated with the possible measurement outputs.展开更多
In holes, the measurement of the velocity of detonation(VOD) helps in comparing and evaluating relative performance of explosives. In this paper a blast performance assessment was conducted based on the results obta...In holes, the measurement of the velocity of detonation(VOD) helps in comparing and evaluating relative performance of explosives. In this paper a blast performance assessment was conducted based on the results obtained from the steady state VOD measurement of emulsion explosives HEF100 and degree of blast fragmentation conducted on an open pit blast. The aim of this study was to compare the steady state VOD measured in the field and the published VOD of HEF100 under ideal laboratory conditions and ascertain its efficacy. In the trial, a resistance wire continuous VOD measurement system connected to a SpeedVOD was employed to measure and record the steady state VOD values from five different blast holes. Furthermore, a post fragmentation analysis was conducted using the existing fragmentation models and an image processing software. The steady state VOD values recorded from the field ranged between 4981 m/s to 5387 m/s consistent with the published VOD subjected to ideal laboratory conditions and the analyzed fragmentation size distribution indicates that 90% of the blasted muck pile was within the allowable and optimal 700 mm passing size.展开更多
Rail irregularities, in particular for urban rail- way infrastructures, are one of the main causes for the generation of noise and vibrations. In addition, repetitive loading may also lead to decay of the structural e...Rail irregularities, in particular for urban rail- way infrastructures, are one of the main causes for the generation of noise and vibrations. In addition, repetitive loading may also lead to decay of the structural elements of the rolling stock. This further causes an increase in main- tenance costs and reduction of service life. Monitoring these defects on a periodic basis enables the network rail managers to apply proactive measures to limit further damage. This paper discusses the measurement methods for rail corrugation with particular regard to the analysis tools for evaluating the thresholds of acceptability in re- lation to the tramway Italian transport system. Further- more, a method of analysis has been proposed: an application of the methodology used for treating road profiles has been also utilized for the data processing of rail profilometric data.展开更多
Based on the continuous strain data recorded in Xinjiang since 1985, we discuss the mechanisms of Tianshan' s uplift and Tarim basin' s clockwise rotation. The results indicate : 1 ) The principal - compression di...Based on the continuous strain data recorded in Xinjiang since 1985, we discuss the mechanisms of Tianshan' s uplift and Tarim basin' s clockwise rotation. The results indicate : 1 ) The principal - compression directions in Tianshan are nearly NS, and their intersection angles with regional structures and mountains are nearly perpendicular, which is in accordance with Tianshan' s uplift and crustal shortening. 2)The principal compressions around Tarim basin tend to facilitate the regional faults' left-lateral strike-slip movements and the basin' s clockwise rotation. These phenomena of uplift/shortening and rotation are fundamentally the re- suits of India plate' s northward push on Euro-Asia plate, and the associated Pamir arc ' s rapid northward movement and regional blocks' interaction.展开更多
In this paper,some conditions which assure the compactly supported refinable distributions supported on a self-affine tile to be Lebesgue-Stieltjes measures or absolutely continuous measures with respect to Lebesgue-S...In this paper,some conditions which assure the compactly supported refinable distributions supported on a self-affine tile to be Lebesgue-Stieltjes measures or absolutely continuous measures with respect to Lebesgue-Stieltjes measures are given.展开更多
In order to know the distribution of magnetic field in a novel flow control of mold (NFC Mold) and to provide the experimental data for the electromagnetic structure design and the analysis of flow control in continuo...In order to know the distribution of magnetic field in a novel flow control of mold (NFC Mold) and to provide the experimental data for the electromagnetic structure design and the analysis of flow control in continuous casting mold, the magnetic field in a NFC Mold were measured by Tesla meter of Model CT-3. The method of vector synthesis was adopted in the measurement of magnetic fields. The results showed that the magnetic field in the NFC Mold was composed of two main magnetic areas that were symmetrical. Although there was leaking magnetic flux between the lower surface of the upper pole and the upper surface of the lower pole on the sides, it was restrained by the main magnetic fields effectively. Therefore the NFC Mold was more preferably satisfied to be used in controlling the molten steel flow in continuous casting mold.展开更多
Altai polymetallic mineralization belt is famous copper-polymetallic mineralization belt in the world. There are a lot of gold deposits in the Altai ore belt in Xinjiang, China. These gold deposits belong to two genet...Altai polymetallic mineralization belt is famous copper-polymetallic mineralization belt in the world. There are a lot of gold deposits in the Altai ore belt in Xinjiang, China. These gold deposits belong to two genetic types: volcanogene late-stage hydrothermal type and fractured altered rock type. The authors discuss mainly the geological and mineralized features of fractured altered rock type of gold deposits in Altai gold ore belt. Base on this study, the metallogenic law is summarized and the deep metallogenic prognosis has been done in Duolanasayi and Tuokuzibayi gold deposits, and some mineralized anomalys have been discovered.展开更多
Bridge is an important part of modem transportation systems and deformation is a key index for bridge's safety evaluation. To achieve the long span bridge curve measurement rapidly and timely and accurately locate th...Bridge is an important part of modem transportation systems and deformation is a key index for bridge's safety evaluation. To achieve the long span bridge curve measurement rapidly and timely and accurately locate the bridge maximum deformation, the continuous deformation measurement system (CDMS) based on inertial platform is presented and validated in this paper. Firstly, based on various bridge deformation measurement methods, the method of deformation measurement based on the fiber optic gyro (FOG) is introduced. Secondly, the basic measurement principle based on FOG is presented and the continuous curve trajectory is derived by the formula. Then the measurement accuracy is analyzed in theory and the relevant factors are presented to ensure the measurement accuracy. Finally, the deformation measurement experiments are conducted on a bridge across the Yangtze River. Experimental results show that the presented deformation measurement method is feasible, practical, and reliable; the system can accurately and quickly locate the maximum deformation and has extensive and broad application prospects.展开更多
Beijing is one of the most polluted cities in the world.In this study,the long-term and continuous measurements of volatile organic compounds (VOCs) in the urban area of Beijing,specifically at Beijing 325 m Meteoro...Beijing is one of the most polluted cities in the world.In this study,the long-term and continuous measurements of volatile organic compounds (VOCs) in the urban area of Beijing,specifically at Beijing 325 m Meteorological Tower,were conducted from 2000 to 2007.The annual record of VOC trends exhibited in two different phases was separated in 2003.Records show that VOC concentrations increased from 2000 to 2003 due to the abrupt increase in vehicle number.Contrarily,since 2003,there had been a decrease in VOCs concentrations as the policy on gasoline and air pollution was implemented.Toluene,benzene,and i-pentane are the chemicals that abound in and are directly related to vehicle activity,such as in vehicle exhaust and gasoline evaporation.Furthermore,records indicate that there had been seasonal variation in VOCs levels in that VOCs level in summer is higher than that in winter.As such,temperature is considered to significantly contribute to VOCs in Beijing.Records also show that VOCs level was high in the morning and during rush hours in the evening.In contrast,VOCs level was low during midday due to photochemical destruction with OH radical and dilution effect.In this study,a particular benzene to toluene ratio range (0.4–1.0) was used as the indicator of air propelled by vehicular exhaust.We also applied the correlation coefficients between BTEX and i-pentane to evaluate evaporation influence to ambient BTEX in the Beijing urban area.展开更多
This paper presents a comprehensive review of the wave-flmction approach for derivation of the number- resolved Master equations, used for description of transport and measurement in mesoseopie systems. The review con...This paper presents a comprehensive review of the wave-flmction approach for derivation of the number- resolved Master equations, used for description of transport and measurement in mesoseopie systems. The review contains important amendments, clarifying subtle points in derivation of the Master equa- tions and their validity. This completes the earlier works on the subject. It is demonstrated that the derivation does not assume weak coupling with the environment and reservoirs, but needs only high bias condition. This condition is very essential for validity of the Markovian Master equations, widely used for a phenomenological description of different physical processes.展开更多
Nitro MAC(French acronym for continuous atmospheric measurements of nitrogenous compounds) is an instrument which has been developed for the semi-continuous measurement of atmospheric nitrous acid(HONO). This inst...Nitro MAC(French acronym for continuous atmospheric measurements of nitrogenous compounds) is an instrument which has been developed for the semi-continuous measurement of atmospheric nitrous acid(HONO). This instrument relies on wet chemical sampling and detection using high performance liquid chromatography(HPLC)-visible absorption at540 nm. Sampling proceeds by dissolution of gaseous HONO in a phosphate buffer solution followed by derivatization with sulfanilamide/N-(1-naphthyl)-ethylenediamine. The performance of this instrument was found to be as follows: a detection limit of around 3 ppt with measurement uncertainty of 10% over an analysis time of 10 min. Intercomparison was made between the instrument and a long-path absorption photometer(LOPAP) during two experiments in different environments. First, air was sampled in a smog chamber with concentrations up to 18 ppb of nitrous acid. Nitro MAC and LOPAP measurements showed very good agreement. Then, in a second experiment, ambient air with HONO concentrations below250 ppt was sampled. While Nitro MAC showed its capability of measuring HONO in moderate and highly polluted environments, the intercomparison results in ambient air highlighted that corrections must be made for minor interferences when low concentrations are measured.展开更多
基金National Natural Science Foundation of China(No.61405127)Key Program for International S&T Cooperation Projects of China(No.2013DFR10150)
文摘This paper investigated the continuous measurement of a refractive index(RI)sensor based on macrobending microoptical plastic fiber(m-POF).The sensing properties of the RI sensor depend on the structure parameter,which is the ratio of macrobending radius of m-POF to the radius of fiber itself.The ratio changes with the measurement time increasing because of the water absorption,which introduces an maximum measurement deviation of 7.3×10^(-5) RIU when the immersion time exceeds 40 h.This work indicates that for the sensors based on POF,the measurement time must be taken into consideration for continuous measurement.
基金Supported by the National Natural Science Foundation of China under Grant Nos 11227083 and 91536221
文摘We present an experimental demonstration of the rotation measurement using a compact cold atom gyroscope. Atom interference fringes are observed in the stationary frame and the rotating frame, respectively. The phase shift and contrast of the interference fringe are experimentally investigated. The results show that the contrast of the interference fringe is well held when the platform is rotated, and the phase shift of the interference fringe is linearly proportional to the rotation rate of the platform. The long-term stability, which is evaluated by the overlapped Allan deviation, is 8.5 × 10^-6 rad/s over the integrating time of 1000s.
文摘In this paper we give a sufficient and necessary condition under which a continuous measure (whose values belong to, the extended half-line (0,+∞) defined on a class of sets closed under the formation of intersection can be extended to a smallest monotone class containing this class, and we also give a condition under which there exists a unique extension. In addition, we give a method by means of which a continuous measure on a monotone class can be extended again.
基金Projects(41502283,41772309)supported by the National Natural Science Foundation of ChinaProject(2017YFC1501302)supported by the National Key Research and Development Program of ChinaProject(2017ACA102)supported by the Major Program of Technological Innovation of Hubei Province,China。
文摘In this study,the micro-failure process and failure mechanism of a typical brittle rock under uniaxial compression are investigated via continuous real-time measurement of wave velocities.The experimental results indicate that the evolutions of wave velocities became progressively anisotropic under uniaxial loading due to the direction-dependent development of micro-damage.A wave velocity model considering the inner anisotropic crack evolution is proposed to accurately describe the variations of wave velocities during uniaxial compression testing.Based on which,the effective elastic parameters are inferred by a transverse isotropic constitutive model,and the evolutions of the crack density are inversed using a self-consistent damage model.It is found that the propagation of axial cracks dominates the failure process of brittle rock under uniaxial loading and oblique shear cracks develop with the appearance of macrocrack.
基金This study was supported in part by the Ministry of Science and Technology MOST 108-2221-E-150-022-MY3 and Taiwan Ocean University.
文摘This study proposed a measurement platform for continuous blood pressure estimation based on dual photoplethysmography(PPG)sensors and a deep learning(DL)that can be used for continuous and rapid measurement of blood pressure and analysis of cardiovascular-related indicators.The proposed platform measured the signal changes in PPG and converted them into physiological indicators,such as pulse transit time(PTT),pulse wave velocity(PWV),perfusion index(PI)and heart rate(HR);these indicators were then fed into the DL to calculate blood pressure.The hardware of the experiment comprised 2 PPG components(i.e.,Raspberry Pi 3 Model B and analog-todigital converter[MCP3008]),which were connected using a serial peripheral interface.The DL algorithm converted the stable dual PPG signals acquired from the strictly standardized experimental process into various physiological indicators as input parameters and finally obtained the systolic blood pressure(SBP),diastolic blood pressure(DBP)and mean arterial pressure(MAP).To increase the robustness of the DL model,this study input data of 100 Asian participants into the training database,including those with and without cardiovascular disease,each with a proportion of approximately 50%.The experimental results revealed that the mean absolute error and standard deviation of SBP was 0.17±0.46 mmHg.The mean absolute error and standard deviation of DBP was 0.27±0.52 mmHg.The mean absolute error and standard deviation of MAP was 0.16±0.40 mmHg.
文摘The detection of a particle in electromagnetic plus gravitational fields is investigated. We obtain a set of quantum nondemolition variables. The continuous measurements of these nondemolition parameters are analyzed in the framework of restricted path integral formalism. We manipulate the corresponding propagators, and deduce the probabilities associated with the possible measurement outputs.
文摘In holes, the measurement of the velocity of detonation(VOD) helps in comparing and evaluating relative performance of explosives. In this paper a blast performance assessment was conducted based on the results obtained from the steady state VOD measurement of emulsion explosives HEF100 and degree of blast fragmentation conducted on an open pit blast. The aim of this study was to compare the steady state VOD measured in the field and the published VOD of HEF100 under ideal laboratory conditions and ascertain its efficacy. In the trial, a resistance wire continuous VOD measurement system connected to a SpeedVOD was employed to measure and record the steady state VOD values from five different blast holes. Furthermore, a post fragmentation analysis was conducted using the existing fragmentation models and an image processing software. The steady state VOD values recorded from the field ranged between 4981 m/s to 5387 m/s consistent with the published VOD subjected to ideal laboratory conditions and the analyzed fragmentation size distribution indicates that 90% of the blasted muck pile was within the allowable and optimal 700 mm passing size.
文摘Rail irregularities, in particular for urban rail- way infrastructures, are one of the main causes for the generation of noise and vibrations. In addition, repetitive loading may also lead to decay of the structural elements of the rolling stock. This further causes an increase in main- tenance costs and reduction of service life. Monitoring these defects on a periodic basis enables the network rail managers to apply proactive measures to limit further damage. This paper discusses the measurement methods for rail corrugation with particular regard to the analysis tools for evaluating the thresholds of acceptability in re- lation to the tramway Italian transport system. Further- more, a method of analysis has been proposed: an application of the methodology used for treating road profiles has been also utilized for the data processing of rail profilometric data.
基金supported by the National Natural Science Foundation of China( 40864003,40562001)
文摘Based on the continuous strain data recorded in Xinjiang since 1985, we discuss the mechanisms of Tianshan' s uplift and Tarim basin' s clockwise rotation. The results indicate : 1 ) The principal - compression directions in Tianshan are nearly NS, and their intersection angles with regional structures and mountains are nearly perpendicular, which is in accordance with Tianshan' s uplift and crustal shortening. 2)The principal compressions around Tarim basin tend to facilitate the regional faults' left-lateral strike-slip movements and the basin' s clockwise rotation. These phenomena of uplift/shortening and rotation are fundamentally the re- suits of India plate' s northward push on Euro-Asia plate, and the associated Pamir arc ' s rapid northward movement and regional blocks' interaction.
文摘In this paper,some conditions which assure the compactly supported refinable distributions supported on a self-affine tile to be Lebesgue-Stieltjes measures or absolutely continuous measures with respect to Lebesgue-Stieltjes measures are given.
基金the National Natural Science Foundation of China (Grant No. 59734080), the National Key Basic Research and Development Programme of China (Grant No. G1998061510) and the Project of National High Te
文摘In order to know the distribution of magnetic field in a novel flow control of mold (NFC Mold) and to provide the experimental data for the electromagnetic structure design and the analysis of flow control in continuous casting mold, the magnetic field in a NFC Mold were measured by Tesla meter of Model CT-3. The method of vector synthesis was adopted in the measurement of magnetic fields. The results showed that the magnetic field in the NFC Mold was composed of two main magnetic areas that were symmetrical. Although there was leaking magnetic flux between the lower surface of the upper pole and the upper surface of the lower pole on the sides, it was restrained by the main magnetic fields effectively. Therefore the NFC Mold was more preferably satisfied to be used in controlling the molten steel flow in continuous casting mold.
基金Supported by the National "305" Project(2001BA609A-07-08)Innovative Project of CAS(KZCX1-Y-03-01)
文摘Altai polymetallic mineralization belt is famous copper-polymetallic mineralization belt in the world. There are a lot of gold deposits in the Altai ore belt in Xinjiang, China. These gold deposits belong to two genetic types: volcanogene late-stage hydrothermal type and fractured altered rock type. The authors discuss mainly the geological and mineralized features of fractured altered rock type of gold deposits in Altai gold ore belt. Base on this study, the metallogenic law is summarized and the deep metallogenic prognosis has been done in Duolanasayi and Tuokuzibayi gold deposits, and some mineralized anomalys have been discovered.
基金This work was supported by the National Natural Science Foundation of China (NO. 61402345), National Science and Technology Support Program (2014BAG07B01), and Fundamental Research Funds for the Central Universities Special Fund (WUT: 2014-II-012).
文摘Bridge is an important part of modem transportation systems and deformation is a key index for bridge's safety evaluation. To achieve the long span bridge curve measurement rapidly and timely and accurately locate the bridge maximum deformation, the continuous deformation measurement system (CDMS) based on inertial platform is presented and validated in this paper. Firstly, based on various bridge deformation measurement methods, the method of deformation measurement based on the fiber optic gyro (FOG) is introduced. Secondly, the basic measurement principle based on FOG is presented and the continuous curve trajectory is derived by the formula. Then the measurement accuracy is analyzed in theory and the relevant factors are presented to ensure the measurement accuracy. Finally, the deformation measurement experiments are conducted on a bridge across the Yangtze River. Experimental results show that the presented deformation measurement method is feasible, practical, and reliable; the system can accurately and quickly locate the maximum deformation and has extensive and broad application prospects.
基金supported by the Knowledge Innovation Program of Chinese Academy of Sciences (No.KZCX2-YW-Q02-03)the Chinese Academy of Sciences Strategic Priority Research Program (No. XDA05100100)+1 种基金the Science and Technology Project of Bejing (No.D09040903670902)the National Natural Science Foundation of China (No. 41021004)
文摘Beijing is one of the most polluted cities in the world.In this study,the long-term and continuous measurements of volatile organic compounds (VOCs) in the urban area of Beijing,specifically at Beijing 325 m Meteorological Tower,were conducted from 2000 to 2007.The annual record of VOC trends exhibited in two different phases was separated in 2003.Records show that VOC concentrations increased from 2000 to 2003 due to the abrupt increase in vehicle number.Contrarily,since 2003,there had been a decrease in VOCs concentrations as the policy on gasoline and air pollution was implemented.Toluene,benzene,and i-pentane are the chemicals that abound in and are directly related to vehicle activity,such as in vehicle exhaust and gasoline evaporation.Furthermore,records indicate that there had been seasonal variation in VOCs levels in that VOCs level in summer is higher than that in winter.As such,temperature is considered to significantly contribute to VOCs in Beijing.Records also show that VOCs level was high in the morning and during rush hours in the evening.In contrast,VOCs level was low during midday due to photochemical destruction with OH radical and dilution effect.In this study,a particular benzene to toluene ratio range (0.4–1.0) was used as the indicator of air propelled by vehicular exhaust.We also applied the correlation coefficients between BTEX and i-pentane to evaluate evaporation influence to ambient BTEX in the Beijing urban area.
文摘This paper presents a comprehensive review of the wave-flmction approach for derivation of the number- resolved Master equations, used for description of transport and measurement in mesoseopie systems. The review contains important amendments, clarifying subtle points in derivation of the Master equa- tions and their validity. This completes the earlier works on the subject. It is demonstrated that the derivation does not assume weak coupling with the environment and reservoirs, but needs only high bias condition. This condition is very essential for validity of the Markovian Master equations, widely used for a phenomenological description of different physical processes.
基金supported by EU Sixth Framework Programme (FP6) Eurochamp program (grant number 505968)EU Seventh Framework Programme (FP7) Eurochamp-2 program (grant number 228335)+2 种基金the NeoRad program from the French National Agency for Research (ANR-07-2/21-8908)the PhotoBat project from the Primequal program of the French Ministry of Environment (Primequal-project number 19599)the PhotoPaq LIFE + program (LIFE 08/ENV/F/000487 PHOTOPAQ)
文摘Nitro MAC(French acronym for continuous atmospheric measurements of nitrogenous compounds) is an instrument which has been developed for the semi-continuous measurement of atmospheric nitrous acid(HONO). This instrument relies on wet chemical sampling and detection using high performance liquid chromatography(HPLC)-visible absorption at540 nm. Sampling proceeds by dissolution of gaseous HONO in a phosphate buffer solution followed by derivatization with sulfanilamide/N-(1-naphthyl)-ethylenediamine. The performance of this instrument was found to be as follows: a detection limit of around 3 ppt with measurement uncertainty of 10% over an analysis time of 10 min. Intercomparison was made between the instrument and a long-path absorption photometer(LOPAP) during two experiments in different environments. First, air was sampled in a smog chamber with concentrations up to 18 ppb of nitrous acid. Nitro MAC and LOPAP measurements showed very good agreement. Then, in a second experiment, ambient air with HONO concentrations below250 ppt was sampled. While Nitro MAC showed its capability of measuring HONO in moderate and highly polluted environments, the intercomparison results in ambient air highlighted that corrections must be made for minor interferences when low concentrations are measured.