Types, Metallogenic Environments and Characteristics of Temporal and Spatial Distribution of Copper Deposits in China

Based upon a comprehensive study of 123 copper deposits in China. this paper reaches the following conclusions: 1. The crust in China was solidified pretty late; with the accretion of the plate, the copper mineralization moved towards its margin in space and became successively younger in age. 2. The major copper ore types ever found in the world have mostly been discovered in China, in which the porphyry type seems to be the most important and the massive sulfide type in the transitional bed between marine clastic and carbonate rocks is clearly defined. 3. Carbonate strata are widespread in China and their deposition lasted for a long geological period, so the proportion of copper deposits occurring in them is large as compared with other parts of the world. 4. Seven metallogenic epochs can be recognized, in which the Mesozoic one plays the leading role and the middle(late) Palaeozoic and Cenozoic ones are next in importance. Mineralization was comparatively simple in the early geological period. and became diversified later on. In the early epochs copper deposits related to basaltic magmatism and metamorphosed marine sediments predominated, whereas in the later epochs those related to granitic magmatism and continental sedimentation were dominant. 5. There exist in China thirteen metallogenic provinces, of which the Lower Yangtze downwarping belt, Sanjiang fold system, Jiangnan axis and Xikang-Yunnan axis are of greater significance. 6. The crustal mobility in China was rather pronounced, the polycyclic evolution of the crust has resulted in such obvious phenomena as the inheritance of mineralization, the coexistence of various types and the superposition of different genetic types.

Exogenous Nitric Oxide Involved in Subcellular Distribution and Chemical Forms of Cu^(2+) Under Copper Stress in Tomato Seedlings

Nitric oxide（NO）,a bioactive signaling molecule,serves as an antioxidant and anti-stress agent under abiotic stress.A hydroponics experiment was conducted to investigate the effects of sodium nitroprusside（SNP）,a NO donor,on tomato seedlings exposed to 50 μmol L-1CuCl 2.The results show that copper is primarily stored in the soluble cell sap fraction in the roots,especially after treatment with Cu＋SNP treatment,which accounted for 66.2% of the total copper content.The copper concentration gradually decreased from the roots to the leaves.In the leaves,exogenous NO induces the storage of excess copper in the cell walls.Copper stress decreases the proportion of copper integrated with pectates and proteins,but exogenous NO remarkably reverses this trend.The alleviating effect of NO is blocked by hemoglobin.Thus,exogenous NO is likely involved in the regulation of the subcellular copper concentrations and its chemical forms under copper stress.Although exogenous NO inhibited the absorption and transport of excess copper to some extent,the copper accumulation in tomato seedlings significantly increased under copper stress.The use of exogenous NO to enhance copper tolerance in some plants is a promising method for copper remediation.