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Chemical etching process of copper electrode for bioelectrical impedance technology 被引量:2
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作者 周伟 宋嵘 +4 位作者 蒋乐伦 许文平 梁国开 程德才 刘灵蛟 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2012年第6期1501-1506,共6页
In order to obtain bioelectrical impedance electrodes with high stability, the chemical etching process was used to fabricate the copper electrode with a series of surface microstructures. By changing the etching proc... In order to obtain bioelectrical impedance electrodes with high stability, the chemical etching process was used to fabricate the copper electrode with a series of surface microstructures. By changing the etching processing parameters, some comparison experiments were performed to reveal the influence of etching time, etching temperature, etching liquid concentration, and sample sizes on the etching rate and surface microstructures of copper electrode. The result shows that the etching rate is decreased with increasing etching time, and is increased with increasing etching temperature. Moreover, it is found that the sample size has little influence on the etching rate. After choosing the reasonable etching liquid composition (formulation 3), the copper electrode with many surface microstructures can be obtained by chemical etching process at room temperature for 20 rain. In addition, using the alternating current impedance test of electrode-electrode for 24 h, the copper electrode with a series of surface microstructures fabricated by the etching process presents a more stable impedance value compared with the electrocardiograph (ECG) electrode, resulting from the reliable surface contact of copper electrode-electrode. 展开更多
关键词 bioelectrical impedance copper electrode chemical etching surface microstructures processing parameters
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Preparation of B_(2)O_(3)-ZnO-SiO_(2)Glass and Sintering Densification of Copper Terminal Electrode Applied in Multilayer Ceramic Capacitors
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作者 YUE Yi LI Hong +6 位作者 CAO Xiuhua ZHANG Xuehui HUANG Jun HUANG Xuye ZHANG Yongqiang XU Ruipeng XIONG Dehua 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2023年第5期960-968,共9页
B_(2)O_(3)-Zn O-SiO_(2)(BZS)glass containing Cu O with excellent acid resistance,wetting properties,and high-temperature sintering density was prepared by high temperature melting method and then applied in copper ter... B_(2)O_(3)-Zn O-SiO_(2)(BZS)glass containing Cu O with excellent acid resistance,wetting properties,and high-temperature sintering density was prepared by high temperature melting method and then applied in copper terminal electrode for multilayer ceramic capacitors(MLCC)applications.The structure and property characterization of B_(2)O_(3)-Zn O-SiO_(2)glass,including X-ray diffraction,FTIR,scanning electron microscopy,high-temperature microscopy,and differential scanning calorimetry,indicated that the addition of CuO improved the glass’s acid resistance and glass-forming ability.The wettability and acid resistance of this glass were found to be excellent when CuO content was 1.50 wt%.Compared to BZS glass,the CuO-added glass exhibited excellent wettability to copper powder and corrosion resistance to the plating solution.The sintered copper electrode films prepared using the glass with CuO addition had better densification and lower sintering temperature of 750℃.Further analysis of the sintering mechanism reveals that the flowability and wettability of the glass significantly impact the sintering densification of the copper terminal electrodes. 展开更多
关键词 B_(2)O_(3)-ZnO-SiO_(2)(BZS) low melting glass MLCC DENSIFICATION copper terminal electrode
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Electrochemical reduction characteristics and the mechanism of chlorinated hydrocarbons at the copper electrode 被引量:1
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作者 XU Wenying GAO Tingyao +1 位作者 ZHOU Rongfeng MA Lumin 《Frontiers of Environmental Science & Engineering》 SCIE EI CSCD 2007年第2期207-212,共6页
The electrochemical reduction characteristics of chlorinated hydrocarbons were investigated by cyclic voltam-metry technique.The reduction mechanism and activity of the chlorinated hydrocarbons at the copper electrode... The electrochemical reduction characteristics of chlorinated hydrocarbons were investigated by cyclic voltam-metry technique.The reduction mechanism and activity of the chlorinated hydrocarbons at the copper electrode were explored.The relationship between the structure of chlori-nated hydrocarbons and their reductive activity were dis-cussed.The experimental results showed that chlorinated alkanes and a portion of chlorinated aromatic hydrocarbons could be reduced directly at the copper electrode.However,chlorinated aromatic hydrocarbons were not easy to reduce at the copper electrode.The results provided a theoretical basis for the catalyzed iron inner electrolysis method. 展开更多
关键词 chlorinated hydrocarbons cyclic voltammetry electrochemical reduction copper electrode
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Copper modified platinum electrode for amperometric detection of spectinomycin sulfate by anion-exchange chromatography 被引量:1
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作者 Ling Ling Xi Pei Min Zhang Yan Zhu 《Chinese Chemical Letters》 SCIE CAS CSCD 2009年第10期1245-1247,共3页
A La^3+-Cu/Pt modified electrode was fabricated by electrodepositing process in CuS04 solution by adding a small amount of lanthium compound, and it was employed for direct current (DC) amperometric detection of sp... A La^3+-Cu/Pt modified electrode was fabricated by electrodepositing process in CuS04 solution by adding a small amount of lanthium compound, and it was employed for direct current (DC) amperometric detection of spectinomycin by anion-exchange chromatography. Without derivatization, this method can simultaneously determine the main component and impurities in spectinomycin pharmaceutical raw material. Ease of preparation, being applied in DC detection mode and good catalytic stability confirmed the interests of this modified electrode as amperometric sensor for the determination of spectinomycin. 展开更多
关键词 copper/platinum chemically modified electrode High performance anion-exchange chromatography Direct current amperometricdetection SPECTINOMYCIN
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Novel Screen-Printed All-Solid-State Copper(II)-Selective Electrode for Mobile Environmental Analysis 被引量:1
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作者 Johannes Schwarz Kathrin Trommer Michael Mertig 《American Journal of Analytical Chemistry》 2016年第7期525-532,共9页
Based on poly(vinyl chloride) membranes, a novel miniaturized screen-printed all-solid-state copper(II)-selective electrode has been developed for applications in environmental monitoring. Performance and applicabilit... Based on poly(vinyl chloride) membranes, a novel miniaturized screen-printed all-solid-state copper(II)-selective electrode has been developed for applications in environmental monitoring. Performance and applicability of the ion-selective electrode (ISE) have been proved by potentiometric investigations. Conducting polymers were used as intermediate layers and as solid contacts between the ion-selective membrane and the graphite transducer. The ion-complexing reagent 2-mercapto-benzoxazole was incorporated into poly(vinyl chloride) membranes. In the concentration range 10<sup>-6</sup> - 10<sup>-2</sup> mol/L, the ISE exhibited a linear Nernstian potential response to copper(II) with an average slope value of 28 mV/decade. The detection limit was 3 × 10<sup>-7</sup> mol/L. The electrode exhibits a short response time (<10 s) and can be used in the range of pH = 3 - 7. Selectivity coefficents against certain interfering ions are investigated. The life time of the electrode under laboratory conditions was approximately 12-month. The electrode was applied in the investigation of different aqueous environmental samples and the electrode characteristics were described. The copper(II) ASS electrode has also successfully been used in potentiometric, complexometric titrations with ethylenediaminetetraacetic acid. 展开更多
关键词 All-Solid-State copper(II)-Selective electrode Conducting Polymers Potentiometric Titration Environmental Samples
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Laser Erasing and Rewriting of Flexible Copper Circuits 被引量:1
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作者 Xingwen Zhou Wei Guo Peng Peng 《Nano-Micro Letters》 SCIE EI CAS CSCD 2021年第11期409-420,共12页
Integrating construction and reconstruction of highly conductive structures into one process is of great interest in developing and manufacturing of electronics,but it is quite challenging because these two involve co... Integrating construction and reconstruction of highly conductive structures into one process is of great interest in developing and manufacturing of electronics,but it is quite challenging because these two involve contradictive additive and subtractive processes.In this work,we report an all-laser mask-less processing technology that integrates manufacturing,modifying,and restoring of highly conductive Cu structures.By traveling a focused laser,the Cu patterns can be fabricated on the flexible substrate,while these as-written patterns can be selectively erased by changing the laser to a defocused state.Subsequently,the fresh patterns with identical conductivity and stability can be rewritten by repeating the writing step.Further,this erasing–rewriting process is also capable of repairing failure patterns,such as oxidation and cracking.Owing to the high controllability of this writing–erasing–rewriting process and its excellent reproducibility for conductive structures,it opens a new avenue for rapid healing and prototyping of electronics. 展开更多
关键词 Laser writing Laser erasing copper electrodes Electronic repairing Flexible electronics
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Free cupric ions in contaminated agricultural soils around a copper mine in eastern Nanjing City, China 被引量:4
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作者 LUO Xiao-san ZHOU Dong-mei WANG Yu-jun 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2006年第5期927-931,共5页
To determine the environmental free metal ion activity was a recent hot issue. A method to measure low-level free cupric ion activity in soil solution extracted with 0.01 mol/L KNO3 was developed by using cupric ion-s... To determine the environmental free metal ion activity was a recent hot issue. A method to measure low-level free cupric ion activity in soil solution extracted with 0.01 mol/L KNO3 was developed by using cupric ion-selective electrode (ISE) and calibrating with Cu-buffer solution. Three copper buffers including iminodiacetic acid (IDA), ethylenediamine (EN), and glycine (Gly) were compared for calibrating the Cu-ISE curves in the range of free cupric ions (pCu^2+) 7-13. The Cu-EN buffer showed the best electrode response and thus was applied as the calibration buffer. The pCu^2+ of 39 contaminated agricultural soils around a copper mine was measured, ranging from 5.03 to 9.20. Most Cu in the soil solutions was found to be complexed with dissolved soil organic matters, averaging 98.1%. The proportion of free Cu^2+ ions in the soil solutions decreased with the increasing of solution pH. Soluble Cu and free Cu^2+ ions concentrations were analyzed by multiple linear regressions to evaluate the effects of soil properties on metal levels and speciation. The results showed that soil solution pH was the most significant factor influencing pCu^2+ (with R^2 value of 0.76), while not important for the soluble Cu concentration. 展开更多
关键词 copper ion selective electrode (Cu-ISE) free metal ion activity soil solution metal speciation BIOAVAILABILITY
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Electrochemical oxidation of polyethylene glycol in electroplating solution using paraffin composite copper hexacyanoferrate modified (PCCHM) anode
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作者 Rajesh S. Bejankiwar Abir Basu Max Cementi 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2004年第5期851-855,共5页
Electrochemical oxidation of polyethylene glycol(PEG) in an acidic(pH 0.18 to 0.42) and high ionic strength electroplating solution was investigated. The electroplating solution is a major source of wastewater in the ... Electrochemical oxidation of polyethylene glycol(PEG) in an acidic(pH 0.18 to 0.42) and high ionic strength electroplating solution was investigated. The electroplating solution is a major source of wastewater in the printing wiring board industry. A paraffin composite copper hexacyanoferrate modified(PCCHM) electrode was used as the anode and a bare graphite electrode was used as the cathode. The changes in PEG and total organic carbon(TOC) concentrations during the course of the reaction were monitored. The efficiency of the PCCHM anode was compared with bare graphite anode and it was found that the former showed significant electrocatalytic property for PEG and TOC removal. Chlorides present in the solution were found to contribute significantly in the overall organic removal process. Short chain organic compounds like acetic acid, oxalic acid, formic acid and ethylene glycol formed during electrolysis were identified by HPLC method. Anode surface area and applied current density were found to influence the electro-oxidation process, in which the former was found to be dominating. Investigations of the kinetics for the present electrochemical reaction suggested that the two stage first-order kinetic model provides a much better representation of the overall mechanism of the process if compared to the generalized kinetic model. 展开更多
关键词 polyethylene glycol(PEG) paraffin composite copper hexacyanoferrate modified(PCCHM) electrode electroplating solution two stage first-order kinetic model generalized kinetic model
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Enhancing ammonia production rates from electrochemical nitrogen reduction by engineering three-phase boundary with phosphorus-activated Cu catalysts
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作者 Jeehye Kim Cho Hee Lee +5 位作者 Yong Hyun Moon Min Hee Lee Eun Hyup Kim Sun Hee Choi Youn Jeong Jang Jae Sung Lee 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2023年第9期394-401,共8页
Electrochemical N_(2) reduction reaction(eNRR) over Cu-based catalysts suffers from an intrinsically low activity of Cu for activation of stable N_(2) molecules and the limited supply of N_(2) to the catalyst due to i... Electrochemical N_(2) reduction reaction(eNRR) over Cu-based catalysts suffers from an intrinsically low activity of Cu for activation of stable N_(2) molecules and the limited supply of N_(2) to the catalyst due to its low solubility in aqueous electrolytes.Herein,we propose phosphorus-activated Cu electrocatalysts to generate electron-deficient Cu sites on the catalyst surface to promote the adsorption of N_(2) molecules.The eNRR system is further modified using a gas diffusion electrode(GDE) coated with polytetrafluoroethylene(PTFE) to form an effective three-phase boundary of liquid water-gas N_(2)-solid catalyst to facilitate easy access of N_(2) to the catalytic sites.As a result,the new catalyst in the flow-type cell records a Faradaic efficiency of 13.15% and an NH_(3) production rate of 7.69 μg h^(-1) cm^(-2) at-0.2 V_(RHE),which represent 3.56 and 59.2 times increases from those obtained with a pristine Cu electrode in a typical electrolytic cell.This work represents a successful demonstration of dual modification strategies;catalyst modification and N_(2) supplying system engineering,and the results would provide a useful platform for further developments of electrocatalysts and reaction systems. 展开更多
关键词 Electrochemical nitrogen reduction reaction Ammonia production Phosphorous modified copper electrodes Gas diffusion electrodes Three-phase boundary PTFE coating
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Thermal Spray Coating of Tungsten for Tokamak Device 被引量:1
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作者 蒋显亮 F. GITZHOFER M.I. BOULOS 《Plasma Science and Technology》 SCIE EI CAS CSCD 2006年第2期164-167,共4页
Thermal spray, such as direct current (d.c.) plasma spray or radio frequency induced plasma spray, was used to deposit tungsten coatings on the copper electrodes of a tokamak device. The tungsten coating on the oute... Thermal spray, such as direct current (d.c.) plasma spray or radio frequency induced plasma spray, was used to deposit tungsten coatings on the copper electrodes of a tokamak device. The tungsten coating on the outer surface of one copper electrode was formed directly through d.c. plasma spraying of fine tungsten powder. The tungsten coating/lining on the inner surface of another copper electrode could be formed indirectly through induced plasma spraying of coarse tungsten powder. Scanning electron microscopy (SEM) was used to examine the cross section and the interface of the tungsten coating. Energy Dispersive Analysis of X-ray (EDAX) was used to analyze the metallic elements attached to a separated interface. The influence of the particle size of the tungsten powder on the density, cracking behavior and adhesion of the coating is discussed. It is found that the coarse tungsten powder with the particle size of 45-75μm can be melted and the coating can be formed only by using induced plasma. The coating deposited from the coarse powder has much higher cohesive strength, adhesive strength and crack resistance than the coating made from the fine powder with a particle size of 5μm. 展开更多
关键词 tokamak device copper electrode thermal spray tungsten coating tungsten/copper interface
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Steering CO_(2)electrolysis selectivity by modulating the local reaction environment:An online DEMS approach for Cu electrodes 被引量:2
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作者 Ke Ye Guiru Zhang +6 位作者 Baoxin Ni Liang Guo Chengwei Deng Xiaodong Zhuang Changying Zhao Wen-Bin Cai Kun Jiang 《eScience》 2023年第4期89-98,共10页
Electrochemical CO_(2)reduction is a typical surface-mediated reaction,with its reaction kinetics and product distributions largely dependent on the dynamic evolution of reactive species at the cathode–catholyte inte... Electrochemical CO_(2)reduction is a typical surface-mediated reaction,with its reaction kinetics and product distributions largely dependent on the dynamic evolution of reactive species at the cathode–catholyte interface and on the resultant mass transport within the hydrodynamic boundary layer in the vicinity of the cathode.To resolve the complex local reaction environment of branching CO_(2)reduction pathways,we here present a dif-ferential electrochemical mass spectroscopic(DEMS)approach for Cu electrodes to investigate CO_(2)mass trans-port,the local concentration gradients of buffering anions,and the Cu surface topology effects on CO_(2)electrolysis selectivity at a temporal resolution of~400 ms.As a proof of concept,these tuning knobs were validated on an anion exchange membrane electrolyzer,which delivered a Faradaic efficiency of up to 40.4%and a partial current density of 121 mA cm^(-2)for CO_(2)-to-C_(2)H_(4)valorization.This methodology,which bridges the study of fundamental surface electrochemistry and the upgrading of practical electrolyzer performance,could be of general interest in helping to achieve a sustainable circular carbon economy. 展开更多
关键词 SPECTROELECTROCHEMISTRY CO_(2)reduction reaction copper electrode Differential electrochemical mass spectroscopy Local reaction environment
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Regulated CO adsorption by the electrode with OH^(-) repulsive property for enhancing C–C coupling
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作者 Qixing Zhang Dan Ren +8 位作者 Jing Gao Zhongke Wang Juan Wang Sanjiang Pan Manjing Wang Jingshan Luo Ying Zhao Michael Gratzel Xiaodan Zhang 《Green Chemical Engineering》 EI CSCD 2023年第3期331-337,共7页
Electrochemical CO_(2) reduction driven by renewable electricity is one of the promising strategies to store sus-tainable energy as fuels.However,the selectivity of value-added multi-carbon products remains poor for f... Electrochemical CO_(2) reduction driven by renewable electricity is one of the promising strategies to store sus-tainable energy as fuels.However,the selectivity of value-added multi-carbon products remains poor for further application of this process.Here,we regulate CO adsorption by forming a Nafion layer on the copper(Cu)electrode that is repulsive to OH^(-),contributing to enhanced selectivity of CO_(2) reduction to C_(2) products with the suppression of C 1 products.The operando Raman spectroscopy indicates that the local OH^(-)would adsorb on part of active sites and decrease the adsorption of CO.Therefore,the electrode with repulsive to OH^(-)can adjust the concentration of OH^(-),leading to the increased adsorption of CO and enhanced C–C coupling.This work shows that electrode design could be an effective strategy for improving the selectivity of CO_(2) reduction to multi-carbon products. 展开更多
关键词 CO_(2)reduction Polymer modified copper electrode Repulsive to OH^(-) Regulated CO adsorption Enhancing C-C coupling
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Low-cost and high safe manganese-based aqueous battery for grid energy storage and conversion 被引量:5
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作者 Jianhang Huang Zhaowei Guo +3 位作者 Xiaoli Dong Duan Bin Yonggang Wang Yongyao Xia 《Science Bulletin》 SCIE EI CAS CSCD 2019年第23期1780-1787,共8页
As an effective energy storage technology, rechargeable batteries have long been considered as a promising solution for grid integration of intermittent renewables(such as solar and wind energy). However,their wide ap... As an effective energy storage technology, rechargeable batteries have long been considered as a promising solution for grid integration of intermittent renewables(such as solar and wind energy). However,their wide application is still limited by safety issue and high cost. Herein, a new battery chemistry is proposed to satisfy the requirements of grid energy storage. We report a simple Cu-Mn battery, which is composed of two separated current collectors in an H2SO4-CuSO4-MnSO4 electrolyte without using any membrane. The Cu-Mn battery shows an energy density of 40.8 Wh L-1, a super-long life of 10,000 cycles(without obvious capacity decay) and negligible self-discharge. And the capital cost of US$ 11.9 kWh-1 based on electrolyte is lower than any previous batteries. More importantly, the battery can still work smoothly during thermal abuse test and drill-through test, showing high safe nature. Furthermore, a combination system integrating the Cu-Mn battery and hydrogen evolution is also proposed, which is able to avoid the generation of explosive H2/O2 mixture, and presents an efficient approach for grid energy storage and conversion. 展开更多
关键词 Manganese dioxide copper electrode Aqueous battery Decoupled hydrogen evolution Water splitting Large-scale energy storage
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