Most edge-detection methods rely on calculating gradient derivatives of the potential field, a process that is easily affected by noise and is therefore of low stability. We propose a new edge-detection method named c...Most edge-detection methods rely on calculating gradient derivatives of the potential field, a process that is easily affected by noise and is therefore of low stability. We propose a new edge-detection method named correlation coefficient of multidirectional standard deviations(CCMS) that is solely based on statistics. First, we prove the reliability of the proposed method using a single model and then a combination of models. The proposed method is evaluated by comparing the results with those obtained by other edge-detection methods. The CCMS method offers outstanding recognition, retains the sharpness of details, and has low sensitivity to noise. We also applied the CCMS method to Bouguer anomaly data of a potash deposit in Laos. The applicability of the CCMS method is shown by comparing the inferred tectonic framework to that inferred from remote sensing(RS) data.展开更多
Real-life data introduce noise,uncertainty,and imprecision to statistical projects;it is advantageous to consider strategies to overcome these information expressions and processing problems.Neutrosophic(indeterminate...Real-life data introduce noise,uncertainty,and imprecision to statistical projects;it is advantageous to consider strategies to overcome these information expressions and processing problems.Neutrosophic(indeterminate)numbers can flexibly and conveniently represent the hybrid information of the partial determinacy and partial indeterminacy in an indeterminate setting,while a fuzzy multiset is a vital mathematical tool in the expression and processing of multi-valued fuzzy information with different and/or same fuzzy values.If neutrosophic numbers are introduced into fuzzy sequences in a fuzzy multiset,the introduced neutrosophic number sequences can be constructed as the neutrosophic number multiset or indeterminate fuzzy multiset.Motivated based on the idea,this study first proposes an indeterminate fuzzy multiset,where each element in a universe set can be repeated more than once with the different and/or identical indeterminate membership values.Then,we propose the parameterized correlation coefficients of indeterminate fuzzy multisets based on the de-neutrosophication of transforming indeterminate fuzzy multisets into the parameterized fuzzy multisets by a parameter(the parameterized de-neutrosophication method).Since indeterminate decision-making issues need to be handled by an indeterminate decision-making method,a group decision-making method using the weighted parameterized correlation coefficients of indeterminate fuzzy multisets is developed along with decision makers’different decision risks(small,moderate,and large risks)so as to handle multicriteria group decision-making problems in indeterminate fuzzy multiset setting.Finally,the developed group decision-making approach is used in an example on a selection problem of slope design schemes for an open-pit mine to demonstrate its usability and flexibility in the indeterminate group decision-making problem with indeterminate fuzzy multisets.展开更多
Partition coefficients of Urokinase(UK)were measured in aqueous two-phase systems con-taining polyethylene glycol and potassium phosphate at 273.2K.Based on the Diamond-Hsu model,a modified expression was obtained for...Partition coefficients of Urokinase(UK)were measured in aqueous two-phase systems con-taining polyethylene glycol and potassium phosphate at 273.2K.Based on the Diamond-Hsu model,a modified expression was obtained for the correlation of enzyme partitioning in theabove-mentioned systems.Utilizing a modified form,the partitioning data of UK and heteroproteinwere correlated.The results show that the modified model is simple gives good precision.and will fa-cilitate engineering scale-up of aqueous two-phase systems for certain proteins purification.展开更多
A theoretical model to correlate and predict the liquid diffusion coefficients in binary sys-tems has been developed.Based on this mode1 the diffusion coefficient of 73 binary systems have beencorrelated,the overall a...A theoretical model to correlate and predict the liquid diffusion coefficients in binary sys-tems has been developed.Based on this mode1 the diffusion coefficient of 73 binary systems have beencorrelated,the overall average deviation of the correlation for diffusion coefficients is 0.009.Forbinary systems the diffusion coefficients have been predicted from vapor liquid phase equilibrium(VLE)and vice versa.展开更多
Sensory properties and physico-chemical parameters of 10 most popular brands of commercial set-type Turkish yoghurts were evaluated and correlation coefficients between the two indices were investigated. The results i...Sensory properties and physico-chemical parameters of 10 most popular brands of commercial set-type Turkish yoghurts were evaluated and correlation coefficients between the two indices were investigated. The results indicated that increases in volatile compounds (acetaldehyde, 2-butanone, 2-nanonane, ethyl acetate), titratable acidity, ash and fat contents inversely correlated with the overall acceptability score of the yoghurt. However, diacetyl, C4 to C12 free fatty acids, pH, whiteness index and texture positively correlated with overall acceptability of the yoghurt products. It was concluded that the acceptability of the Turkish set-type yoghurts is mainly governed by the fifteen volatile compounds as well as the physico-chemical properties determined. Thus, the overall acceptability of the yoghurts was not influenced by a single characteristic, but rather by complex in nature.展开更多
This note derives the relationship between the Pearson product-moment coefficient of correlation and the Spearman rank-based coefficient of correlation for the bivariate normal distribution. This new derivation shows ...This note derives the relationship between the Pearson product-moment coefficient of correlation and the Spearman rank-based coefficient of correlation for the bivariate normal distribution. This new derivation shows the relationship between the two correlation coefficients through an infinite cosine series. A computationally efficient algorithm is also provided to estimate the relationship between the Pearson product-moment coefficient of correlation and the Spearman rank-based coefficient of correlation. The algorithm can be implemented with relative ease using current modern mathematical or statistical software programming languages e.g. R, SAS, Mathematica, Fortran, et al. The algorithm is also available from the author of this article.展开更多
Coutsourides (1980) derives an ad hoc nuisance parameter removal test for testing the equality of two multiple correlation coefficients of two independent p variate normal populations, under the assumption that a samp...Coutsourides (1980) derives an ad hoc nuisance parameter removal test for testing the equality of two multiple correlation coefficients of two independent p variate normal populations, under the assumption that a sample of size n is available from each population. He also extends his ad hoc nuisance parameter removal test to the testing of the equality of two multiple correlation matrices. This paper presents likelihood ratio tests for testing the equality of k multiple correlation coefficients, and also k partial correlation coefficients.展开更多
In this paper, we study local influence analysis for Zhang's generalized correlation coefficients and Hotelling's generalized correlation coefficient by using approach. of local influence analysis suggested by...In this paper, we study local influence analysis for Zhang's generalized correlation coefficients and Hotelling's generalized correlation coefficient by using approach. of local influence analysis suggested by Shi (1991), i.e., generalized influence function (GIF) and generalized Cook distance (GCD). An example is given to illustrate our results.展开更多
The diffusion coefficients of aqueous L-threonine solutions were determined from 298.15 K to 328.15 K by the metallic diaphragm cell method with accuracy, promptness and convenience. Meanwhile, the densities and visco...The diffusion coefficients of aqueous L-threonine solutions were determined from 298.15 K to 328.15 K by the metallic diaphragm cell method with accuracy, promptness and convenience. Meanwhile, the densities and viscosities of the solutions were also determined and correlated. Based on a semi-empirical model for correlating the diffusion coefficients of some amino acids in their aqueous solutions, a new semi-empirical model for correlating the diffusion coefficients involving temperature was provided, which is more comprehensive and less experiment dependent compared to the previous model. The fitting results are satisfactory. Compared to a former model for correlating the diffusion coefficients of solid organic salts in their aqueous solutions, this model provides significant improvement in correlation of diffusion coefficients with different temperatures avoiding arduous work.展开更多
The partition coefficients of baicalin were measured in ethylene oxide and propylene oxide (EOPO)/salt aqueous two-phase systems at 298.15K. It was found that most of baicalin partitioned into EOPO-rich phase. The par...The partition coefficients of baicalin were measured in ethylene oxide and propylene oxide (EOPO)/salt aqueous two-phase systems at 298.15K. It was found that most of baicalin partitioned into EOPO-rich phase. The partition coefficients of baicalin varied from 10 to 120. The effect of various factors, including tie-line length, salt composition, molecular weight of EOPO, and solution pH, on the partition behavior was investigated in EOPO/salt systems. Furthermore the partition coefficients of baicalin were correlated using the modified Diamond-Hsu model. Good agreement with experimental data is obtained. The average relative deviations are less than 5.0%.展开更多
On the basis of the free volume theory and activation energy concept,a fundamental equation whichtakes into account the effects of temperature and pressure has been developed.By introducing differentexpressions for th...On the basis of the free volume theory and activation energy concept,a fundamental equation whichtakes into account the effects of temperature and pressure has been developed.By introducing differentexpressions for the free volume and activation energy,several equations for fluid diffusion coefficients were derivedaccordingly.With the van der Waals free volume and intermal energy formula,a three-parameter model for fluiddiffusion coeffficients at moderate pressure was obtained.The grand average absolute deviation percent of 345data points (44 systems)for self-and infinite dilute inter-diffusivities is 2.32,against the results of the model ofCohen and Turnbull,4.13.In particular,by means of the modified Carnahan-Starling free volume equation,afour-parameter model with average abosolute deviation percent 2.64(30 systems,644 data points)for theestimation of dense fluid inter-and self-diffusivities at high pressures and in supercritical conditions was derived.The derived model is superior to the method of展开更多
A shake-flask method was used to determine 1-octanol/water partition coefficients of ofloxacin, norfloxacin, lomefloxacin, ciprofloxacin, pefloxacin and pipemidic acid from 293.15 K to 323.15 K. The results show that ...A shake-flask method was used to determine 1-octanol/water partition coefficients of ofloxacin, norfloxacin, lomefloxacin, ciprofloxacin, pefloxacin and pipemidic acid from 293.15 K to 323.15 K. The results show that 1-octanol/water partition coefficient of each quinolone increased with the increase of temperature. Based on the fluid phase equilibrium theory, the thermodynamic relationship of 1-octanol/water partition coefficient depending on the temperature was proposed, and the changes of enthalpy, entropy, and Gibbs free energy for quinolones partitioning in 1-octanol/water were determined, respectively. Quinolones molecules partitioning in 1-octanol/water was mainly an entropy driving process, during which the order degree of system decreased. The temperature effects of 1-octanol/water partition coefficient were investigated. The results show that its magnitude is the same as the values in the literature.展开更多
In this simulation study, five correlation coefficients, namely, Pearson, Spearman, Kendal Tau, Permutation-based, and Winsorized were compared in terms of Type I error rate and power under different scenarios where t...In this simulation study, five correlation coefficients, namely, Pearson, Spearman, Kendal Tau, Permutation-based, and Winsorized were compared in terms of Type I error rate and power under different scenarios where the underlying distributions of the variables of interest, sample sizes and correlation patterns were varied. Simulation results showed that the Type I error rate and power of Pearson correlation coefficient were negatively affected by the distribution shapes especially for small sample sizes, which was much more pronounced for Spearman Rank and Kendal Tau correlation coefficients especially when sample sizes were small. In general, Permutation-based and Winsorized correlation coefficients are more robust to distribution shapes and correlation patterns, regardless of sample size. In conclusion, when assumptions of Pearson correlation coefficient are not satisfied, Permutation-based and Winsorized correlation coefficients seem to be better alternatives.展开更多
Low Earth Orbit(LEO)multibeam satellites will be widely used in the next generation of satellite communication systems,whose inter-beam interference will inevitably limit the performance of the whole system.Nonlinear ...Low Earth Orbit(LEO)multibeam satellites will be widely used in the next generation of satellite communication systems,whose inter-beam interference will inevitably limit the performance of the whole system.Nonlinear precoding such as Tomlinson-Harashima precoding(THP)algorithm has been proved to be a promising technology to solve this problem,which has smaller noise amplification effect compared with linear precoding.However,the similarity of different user channels(defined as channel correlation)will degrade the performance of THP algorithm.In this paper,we qualitatively analyze the inter-beam interference in the whole process of LEO satellite over a specific coverage area,and the impact of channel correlation on Signal-to-Noise Ratio(SNR)of receivers when THP is applied.One user grouping algorithm is proposed based on the analysis of channel correlation,which could decrease the number of users with high channel correlation in each precoding group,thus improve the performance of THP.Furthermore,our algorithm is designed under the premise of co-frequency deployment and orthogonal frequency division multiplexing(OFDM),which leads to more users under severe inter-beam interference compared to the existing research on geostationary orbit satellites broadcasting systems.Simulation results show that the proposed user grouping algorithm possesses higher channel capacity and better bit error rate(BER)performance in high SNR conditions relative to existing works.展开更多
With the improvement of equipment reliability,human factors have become the most uncertain part in the system.The standardized Plant Analysis of Risk-Human Reliability Analysis(SPAR-H)method is a reliable method in th...With the improvement of equipment reliability,human factors have become the most uncertain part in the system.The standardized Plant Analysis of Risk-Human Reliability Analysis(SPAR-H)method is a reliable method in the field of human reliability analysis(HRA)to evaluate human reliability and assess risk in large complex systems.However,the classical SPAR-H method does not consider the dependencies among performance shaping factors(PSFs),whichmay cause overestimation or underestimation of the risk of the actual situation.To address this issue,this paper proposes a new method to deal with the dependencies among PSFs in SPAR-H based on the Pearson correlation coefficient.First,the dependence between every two PSFs is measured by the Pearson correlation coefficient.Second,the weights of the PSFs are obtained by considering the total dependence degree.Finally,PSFs’multipliers are modified based on the weights of corresponding PSFs,and then used in the calculating of human error probability(HEP).A case study is used to illustrate the procedure and effectiveness of the proposed method.展开更多
Multi-locus sequence typing( MLST) was a newly defined genotyping method used for determining the sequences of nucleic acid. It was used to analyze the sequences of several housekeeping genes and helped to fix the f...Multi-locus sequence typing( MLST) was a newly defined genotyping method used for determining the sequences of nucleic acid. It was used to analyze the sequences of several housekeeping genes and helped to fix the final sequence types. The review was aimed to summarize the advantages and application of MLST in Streptococus agalactiae,S. dysgalactiae subspecies equisimilis,S. pneumonia,S. pyogenes and S. suis,including the amount of housekeeping genes,primer sequences and the size of PCR products.展开更多
The district cooling system (DCS) with ice storage can reduce the peak electricity demand of the business district buildings it serves, improve system efficiency, and lower operational costs. This study utilizes a mon...The district cooling system (DCS) with ice storage can reduce the peak electricity demand of the business district buildings it serves, improve system efficiency, and lower operational costs. This study utilizes a monitoring and control platform for DCS with ice storage to analyze historical parameter values related to system operation and executed operations. We assess the distribution of cooling loads among various devices within the DCS, identify operational characteristics of the system through correlation analysis and principal component analysis (PCA), and subsequently determine key parameters affecting changes in cooling loads. Accurate forecasting of cooling loads is crucial for determining optimal control strategies. The research process can be summarized briefly as follows: data preprocessing, parameter analysis, parameter selection, and validation of load forecasting performance. The study reveals that while individual devices in the system perform well, there is considerable room for improving overall system efficiency. Six principal components have been identified as input parameters for the cold load forecasting model, with each of these components having eigenvalues greater than 1 and contributing to an accumulated variance of 87.26%, and during the dimensionality reduction process, we obtained a confidence ellipse with a 95% confidence interval. Regarding cooling load forecasting, the Relative Absolute Error (RAE) value of the light gradient boosting machine (lightGBM) algorithm is 3.62%, Relative Root Mean Square Error (RRMSE) is 42.75%, and R-squared value (R<sup>2</sup>) is 92.96%, indicating superior forecasting performance compared to other commonly used cooling load forecasting algorithms. This research provides valuable insights and auxiliary guidance for data analysis and optimizing operations in practical engineering applications. .展开更多
Adaptive fractional polynomial modeling of general correlated outcomes is formulated to address nonlinearity in means, variances/dispersions, and correlations. Means and variances/dispersions are modeled using general...Adaptive fractional polynomial modeling of general correlated outcomes is formulated to address nonlinearity in means, variances/dispersions, and correlations. Means and variances/dispersions are modeled using generalized linear models in fixed effects/coefficients. Correlations are modeled using random effects/coefficients. Nonlinearity is addressed using power transforms of primary (untransformed) predictors. Parameter estimation is based on extended linear mixed modeling generalizing both generalized estimating equations and linear mixed modeling. Models are evaluated using likelihood cross-validation (LCV) scores and are generated adaptively using a heuristic search controlled by LCV scores. Cases covered include linear, Poisson, logistic, exponential, and discrete regression of correlated continuous, count/rate, dichotomous, positive continuous, and discrete numeric outcomes treated as normally, Poisson, Bernoulli, exponentially, and discrete numerically distributed, respectively. Example analyses are also generated for these five cases to compare adaptive random effects/coefficients modeling of correlated outcomes to previously developed adaptive modeling based on directly specified covariance structures. Adaptive random effects/coefficients modeling substantially outperforms direct covariance modeling in the linear, exponential, and discrete regression example analyses. It generates equivalent results in the logistic regression example analyses and it is substantially outperformed in the Poisson regression case. Random effects/coefficients modeling of correlated outcomes can provide substantial improvements in model selection compared to directly specified covariance modeling. However, directly specified covariance modeling can generate competitive or substantially better results in some cases while usually requiring less computation time.展开更多
Flaxseed lignan macromolecules(FLM)are a class of important secondary metabolites in fl axseed,which have been widely concerned due to their biological and pharmacological properties,especially for their antioxidative...Flaxseed lignan macromolecules(FLM)are a class of important secondary metabolites in fl axseed,which have been widely concerned due to their biological and pharmacological properties,especially for their antioxidative activity.For the composition and structure of FLM,our results confirmed that ferulic acid glycoside(FerAG)was directly ester-linked with herbacetin diglucoside(HDG)or pinoresinol diglucoside(PDG),which might determine the beginning of FLM biosynthesis.Additionally,p-coumaric acid glycoside(CouAG)might determine the end of chain extension during FLM synthesis in fl axseed.FLM exhibited higher antioxidative activity in polar systems,as shown by its superior 1,1-diphenyl-2-picrylhydrazyl(DPPH)free radical scavenging capacity compared to the 2,2’-azinobis(3-ehtylbenzothiazolin-6-sulfnic acid)(ABTS)cation free radical scavenging capacity in non-polar systems.Moreover,the antioxidative activity of FLM was found to be highly dependent on its composition and structure.In particular,it was positively correlated with the number of phenolic hydroxyl groups(longer FLM chains)and inversely related to the steric hindrance at the ends(lower levels of FerAG and CouAG).These fi ndings verifi ed the potential application of FLM in nonpolar systems,particularly in functional food emulsions。展开更多
The first results of investigation of the turbulence structure using Doppler backscattering(DBS)on the Globus-M2 tokamak are presented.A one-channel DBS system with a variable probing frequency within the 18–26 GHz r...The first results of investigation of the turbulence structure using Doppler backscattering(DBS)on the Globus-M2 tokamak are presented.A one-channel DBS system with a variable probing frequency within the 18–26 GHz range was installed to investigate the edge plasma at normalized minor radiiρ=0.9–1.1.Radial correlation Doppler reflectometry was used to study the changes in turbulence eddies after the LH transition.Correlation analysis was applied to the phase derivative of complex in-phase and quadrature(IQ)signals of the DBS diagnostic as it contains information about the poloidal plasma rotation velocity.In L-mode,the radial correlation length L_(r)is estimated to be 3 cm and after transition to H-mode reduces to approximately 2 cm.Gyrokinetic modelling in a linear local approximation using code GENE indicates that the instability with positive growth rate at the normalized minor radiusρ=0.75 in L-mode and H-mode on Globus-M2 was the ion temperature gradient(ITG)mode.展开更多
基金supported by the National Hi-Tech Research and Development Program of China(863 Program)(No.2006AA06Z107)the National Natural Science Foundation of China(No.40930314)
文摘Most edge-detection methods rely on calculating gradient derivatives of the potential field, a process that is easily affected by noise and is therefore of low stability. We propose a new edge-detection method named correlation coefficient of multidirectional standard deviations(CCMS) that is solely based on statistics. First, we prove the reliability of the proposed method using a single model and then a combination of models. The proposed method is evaluated by comparing the results with those obtained by other edge-detection methods. The CCMS method offers outstanding recognition, retains the sharpness of details, and has low sensitivity to noise. We also applied the CCMS method to Bouguer anomaly data of a potash deposit in Laos. The applicability of the CCMS method is shown by comparing the inferred tectonic framework to that inferred from remote sensing(RS) data.
文摘Real-life data introduce noise,uncertainty,and imprecision to statistical projects;it is advantageous to consider strategies to overcome these information expressions and processing problems.Neutrosophic(indeterminate)numbers can flexibly and conveniently represent the hybrid information of the partial determinacy and partial indeterminacy in an indeterminate setting,while a fuzzy multiset is a vital mathematical tool in the expression and processing of multi-valued fuzzy information with different and/or same fuzzy values.If neutrosophic numbers are introduced into fuzzy sequences in a fuzzy multiset,the introduced neutrosophic number sequences can be constructed as the neutrosophic number multiset or indeterminate fuzzy multiset.Motivated based on the idea,this study first proposes an indeterminate fuzzy multiset,where each element in a universe set can be repeated more than once with the different and/or identical indeterminate membership values.Then,we propose the parameterized correlation coefficients of indeterminate fuzzy multisets based on the de-neutrosophication of transforming indeterminate fuzzy multisets into the parameterized fuzzy multisets by a parameter(the parameterized de-neutrosophication method).Since indeterminate decision-making issues need to be handled by an indeterminate decision-making method,a group decision-making method using the weighted parameterized correlation coefficients of indeterminate fuzzy multisets is developed along with decision makers’different decision risks(small,moderate,and large risks)so as to handle multicriteria group decision-making problems in indeterminate fuzzy multiset setting.Finally,the developed group decision-making approach is used in an example on a selection problem of slope design schemes for an open-pit mine to demonstrate its usability and flexibility in the indeterminate group decision-making problem with indeterminate fuzzy multisets.
基金Supported by National Natural Science Foundation of China
文摘Partition coefficients of Urokinase(UK)were measured in aqueous two-phase systems con-taining polyethylene glycol and potassium phosphate at 273.2K.Based on the Diamond-Hsu model,a modified expression was obtained for the correlation of enzyme partitioning in theabove-mentioned systems.Utilizing a modified form,the partitioning data of UK and heteroproteinwere correlated.The results show that the modified model is simple gives good precision.and will fa-cilitate engineering scale-up of aqueous two-phase systems for certain proteins purification.
文摘A theoretical model to correlate and predict the liquid diffusion coefficients in binary sys-tems has been developed.Based on this mode1 the diffusion coefficient of 73 binary systems have beencorrelated,the overall average deviation of the correlation for diffusion coefficients is 0.009.Forbinary systems the diffusion coefficients have been predicted from vapor liquid phase equilibrium(VLE)and vice versa.
文摘Sensory properties and physico-chemical parameters of 10 most popular brands of commercial set-type Turkish yoghurts were evaluated and correlation coefficients between the two indices were investigated. The results indicated that increases in volatile compounds (acetaldehyde, 2-butanone, 2-nanonane, ethyl acetate), titratable acidity, ash and fat contents inversely correlated with the overall acceptability score of the yoghurt. However, diacetyl, C4 to C12 free fatty acids, pH, whiteness index and texture positively correlated with overall acceptability of the yoghurt products. It was concluded that the acceptability of the Turkish set-type yoghurts is mainly governed by the fifteen volatile compounds as well as the physico-chemical properties determined. Thus, the overall acceptability of the yoghurts was not influenced by a single characteristic, but rather by complex in nature.
文摘This note derives the relationship between the Pearson product-moment coefficient of correlation and the Spearman rank-based coefficient of correlation for the bivariate normal distribution. This new derivation shows the relationship between the two correlation coefficients through an infinite cosine series. A computationally efficient algorithm is also provided to estimate the relationship between the Pearson product-moment coefficient of correlation and the Spearman rank-based coefficient of correlation. The algorithm can be implemented with relative ease using current modern mathematical or statistical software programming languages e.g. R, SAS, Mathematica, Fortran, et al. The algorithm is also available from the author of this article.
文摘Coutsourides (1980) derives an ad hoc nuisance parameter removal test for testing the equality of two multiple correlation coefficients of two independent p variate normal populations, under the assumption that a sample of size n is available from each population. He also extends his ad hoc nuisance parameter removal test to the testing of the equality of two multiple correlation matrices. This paper presents likelihood ratio tests for testing the equality of k multiple correlation coefficients, and also k partial correlation coefficients.
文摘In this paper, we study local influence analysis for Zhang's generalized correlation coefficients and Hotelling's generalized correlation coefficient by using approach. of local influence analysis suggested by Shi (1991), i.e., generalized influence function (GIF) and generalized Cook distance (GCD). An example is given to illustrate our results.
基金Supported by the Educational Ministry Doctor Foundation of China (No. 2000005608).
文摘The diffusion coefficients of aqueous L-threonine solutions were determined from 298.15 K to 328.15 K by the metallic diaphragm cell method with accuracy, promptness and convenience. Meanwhile, the densities and viscosities of the solutions were also determined and correlated. Based on a semi-empirical model for correlating the diffusion coefficients of some amino acids in their aqueous solutions, a new semi-empirical model for correlating the diffusion coefficients involving temperature was provided, which is more comprehensive and less experiment dependent compared to the previous model. The fitting results are satisfactory. Compared to a former model for correlating the diffusion coefficients of solid organic salts in their aqueous solutions, this model provides significant improvement in correlation of diffusion coefficients with different temperatures avoiding arduous work.
基金Supported by the National Natural Science Foundation of China (No. 29736180).
文摘The partition coefficients of baicalin were measured in ethylene oxide and propylene oxide (EOPO)/salt aqueous two-phase systems at 298.15K. It was found that most of baicalin partitioned into EOPO-rich phase. The partition coefficients of baicalin varied from 10 to 120. The effect of various factors, including tie-line length, salt composition, molecular weight of EOPO, and solution pH, on the partition behavior was investigated in EOPO/salt systems. Furthermore the partition coefficients of baicalin were correlated using the modified Diamond-Hsu model. Good agreement with experimental data is obtained. The average relative deviations are less than 5.0%.
文摘On the basis of the free volume theory and activation energy concept,a fundamental equation whichtakes into account the effects of temperature and pressure has been developed.By introducing differentexpressions for the free volume and activation energy,several equations for fluid diffusion coefficients were derivedaccordingly.With the van der Waals free volume and intermal energy formula,a three-parameter model for fluiddiffusion coeffficients at moderate pressure was obtained.The grand average absolute deviation percent of 345data points (44 systems)for self-and infinite dilute inter-diffusivities is 2.32,against the results of the model ofCohen and Turnbull,4.13.In particular,by means of the modified Carnahan-Starling free volume equation,afour-parameter model with average abosolute deviation percent 2.64(30 systems,644 data points)for theestimation of dense fluid inter-and self-diffusivities at high pressures and in supercritical conditions was derived.The derived model is superior to the method of
基金Supported by the Natural Science Foundation of Henan Province,China(No.0611033400)
文摘A shake-flask method was used to determine 1-octanol/water partition coefficients of ofloxacin, norfloxacin, lomefloxacin, ciprofloxacin, pefloxacin and pipemidic acid from 293.15 K to 323.15 K. The results show that 1-octanol/water partition coefficient of each quinolone increased with the increase of temperature. Based on the fluid phase equilibrium theory, the thermodynamic relationship of 1-octanol/water partition coefficient depending on the temperature was proposed, and the changes of enthalpy, entropy, and Gibbs free energy for quinolones partitioning in 1-octanol/water were determined, respectively. Quinolones molecules partitioning in 1-octanol/water was mainly an entropy driving process, during which the order degree of system decreased. The temperature effects of 1-octanol/water partition coefficient were investigated. The results show that its magnitude is the same as the values in the literature.
文摘In this simulation study, five correlation coefficients, namely, Pearson, Spearman, Kendal Tau, Permutation-based, and Winsorized were compared in terms of Type I error rate and power under different scenarios where the underlying distributions of the variables of interest, sample sizes and correlation patterns were varied. Simulation results showed that the Type I error rate and power of Pearson correlation coefficient were negatively affected by the distribution shapes especially for small sample sizes, which was much more pronounced for Spearman Rank and Kendal Tau correlation coefficients especially when sample sizes were small. In general, Permutation-based and Winsorized correlation coefficients are more robust to distribution shapes and correlation patterns, regardless of sample size. In conclusion, when assumptions of Pearson correlation coefficient are not satisfied, Permutation-based and Winsorized correlation coefficients seem to be better alternatives.
基金supported by the Key R&D Project of the Ministry of Science and Technology of China(2020YFB1808005)。
文摘Low Earth Orbit(LEO)multibeam satellites will be widely used in the next generation of satellite communication systems,whose inter-beam interference will inevitably limit the performance of the whole system.Nonlinear precoding such as Tomlinson-Harashima precoding(THP)algorithm has been proved to be a promising technology to solve this problem,which has smaller noise amplification effect compared with linear precoding.However,the similarity of different user channels(defined as channel correlation)will degrade the performance of THP algorithm.In this paper,we qualitatively analyze the inter-beam interference in the whole process of LEO satellite over a specific coverage area,and the impact of channel correlation on Signal-to-Noise Ratio(SNR)of receivers when THP is applied.One user grouping algorithm is proposed based on the analysis of channel correlation,which could decrease the number of users with high channel correlation in each precoding group,thus improve the performance of THP.Furthermore,our algorithm is designed under the premise of co-frequency deployment and orthogonal frequency division multiplexing(OFDM),which leads to more users under severe inter-beam interference compared to the existing research on geostationary orbit satellites broadcasting systems.Simulation results show that the proposed user grouping algorithm possesses higher channel capacity and better bit error rate(BER)performance in high SNR conditions relative to existing works.
基金Shanghai Rising-Star Program(Grant No.21QA1403400)Shanghai Sailing Program(Grant No.20YF1414800)Shanghai Key Laboratory of Power Station Automation Technology(Grant No.13DZ2273800).
文摘With the improvement of equipment reliability,human factors have become the most uncertain part in the system.The standardized Plant Analysis of Risk-Human Reliability Analysis(SPAR-H)method is a reliable method in the field of human reliability analysis(HRA)to evaluate human reliability and assess risk in large complex systems.However,the classical SPAR-H method does not consider the dependencies among performance shaping factors(PSFs),whichmay cause overestimation or underestimation of the risk of the actual situation.To address this issue,this paper proposes a new method to deal with the dependencies among PSFs in SPAR-H based on the Pearson correlation coefficient.First,the dependence between every two PSFs is measured by the Pearson correlation coefficient.Second,the weights of the PSFs are obtained by considering the total dependence degree.Finally,PSFs’multipliers are modified based on the weights of corresponding PSFs,and then used in the calculating of human error probability(HEP).A case study is used to illustrate the procedure and effectiveness of the proposed method.
文摘Multi-locus sequence typing( MLST) was a newly defined genotyping method used for determining the sequences of nucleic acid. It was used to analyze the sequences of several housekeeping genes and helped to fix the final sequence types. The review was aimed to summarize the advantages and application of MLST in Streptococus agalactiae,S. dysgalactiae subspecies equisimilis,S. pneumonia,S. pyogenes and S. suis,including the amount of housekeeping genes,primer sequences and the size of PCR products.
文摘The district cooling system (DCS) with ice storage can reduce the peak electricity demand of the business district buildings it serves, improve system efficiency, and lower operational costs. This study utilizes a monitoring and control platform for DCS with ice storage to analyze historical parameter values related to system operation and executed operations. We assess the distribution of cooling loads among various devices within the DCS, identify operational characteristics of the system through correlation analysis and principal component analysis (PCA), and subsequently determine key parameters affecting changes in cooling loads. Accurate forecasting of cooling loads is crucial for determining optimal control strategies. The research process can be summarized briefly as follows: data preprocessing, parameter analysis, parameter selection, and validation of load forecasting performance. The study reveals that while individual devices in the system perform well, there is considerable room for improving overall system efficiency. Six principal components have been identified as input parameters for the cold load forecasting model, with each of these components having eigenvalues greater than 1 and contributing to an accumulated variance of 87.26%, and during the dimensionality reduction process, we obtained a confidence ellipse with a 95% confidence interval. Regarding cooling load forecasting, the Relative Absolute Error (RAE) value of the light gradient boosting machine (lightGBM) algorithm is 3.62%, Relative Root Mean Square Error (RRMSE) is 42.75%, and R-squared value (R<sup>2</sup>) is 92.96%, indicating superior forecasting performance compared to other commonly used cooling load forecasting algorithms. This research provides valuable insights and auxiliary guidance for data analysis and optimizing operations in practical engineering applications. .
文摘Adaptive fractional polynomial modeling of general correlated outcomes is formulated to address nonlinearity in means, variances/dispersions, and correlations. Means and variances/dispersions are modeled using generalized linear models in fixed effects/coefficients. Correlations are modeled using random effects/coefficients. Nonlinearity is addressed using power transforms of primary (untransformed) predictors. Parameter estimation is based on extended linear mixed modeling generalizing both generalized estimating equations and linear mixed modeling. Models are evaluated using likelihood cross-validation (LCV) scores and are generated adaptively using a heuristic search controlled by LCV scores. Cases covered include linear, Poisson, logistic, exponential, and discrete regression of correlated continuous, count/rate, dichotomous, positive continuous, and discrete numeric outcomes treated as normally, Poisson, Bernoulli, exponentially, and discrete numerically distributed, respectively. Example analyses are also generated for these five cases to compare adaptive random effects/coefficients modeling of correlated outcomes to previously developed adaptive modeling based on directly specified covariance structures. Adaptive random effects/coefficients modeling substantially outperforms direct covariance modeling in the linear, exponential, and discrete regression example analyses. It generates equivalent results in the logistic regression example analyses and it is substantially outperformed in the Poisson regression case. Random effects/coefficients modeling of correlated outcomes can provide substantial improvements in model selection compared to directly specified covariance modeling. However, directly specified covariance modeling can generate competitive or substantially better results in some cases while usually requiring less computation time.
基金support from National Natural Science Foundation of China(32072267)supported by China Agriculture Research System of CRAS-14.
文摘Flaxseed lignan macromolecules(FLM)are a class of important secondary metabolites in fl axseed,which have been widely concerned due to their biological and pharmacological properties,especially for their antioxidative activity.For the composition and structure of FLM,our results confirmed that ferulic acid glycoside(FerAG)was directly ester-linked with herbacetin diglucoside(HDG)or pinoresinol diglucoside(PDG),which might determine the beginning of FLM biosynthesis.Additionally,p-coumaric acid glycoside(CouAG)might determine the end of chain extension during FLM synthesis in fl axseed.FLM exhibited higher antioxidative activity in polar systems,as shown by its superior 1,1-diphenyl-2-picrylhydrazyl(DPPH)free radical scavenging capacity compared to the 2,2’-azinobis(3-ehtylbenzothiazolin-6-sulfnic acid)(ABTS)cation free radical scavenging capacity in non-polar systems.Moreover,the antioxidative activity of FLM was found to be highly dependent on its composition and structure.In particular,it was positively correlated with the number of phenolic hydroxyl groups(longer FLM chains)and inversely related to the steric hindrance at the ends(lower levels of FerAG and CouAG).These fi ndings verifi ed the potential application of FLM in nonpolar systems,particularly in functional food emulsions。
基金the financial support of the Ministry of Science and Higher Education of the Russian Federation in the framework of the State Contract in the Field of Science(No.FSEG-2024-0005)。
文摘The first results of investigation of the turbulence structure using Doppler backscattering(DBS)on the Globus-M2 tokamak are presented.A one-channel DBS system with a variable probing frequency within the 18–26 GHz range was installed to investigate the edge plasma at normalized minor radiiρ=0.9–1.1.Radial correlation Doppler reflectometry was used to study the changes in turbulence eddies after the LH transition.Correlation analysis was applied to the phase derivative of complex in-phase and quadrature(IQ)signals of the DBS diagnostic as it contains information about the poloidal plasma rotation velocity.In L-mode,the radial correlation length L_(r)is estimated to be 3 cm and after transition to H-mode reduces to approximately 2 cm.Gyrokinetic modelling in a linear local approximation using code GENE indicates that the instability with positive growth rate at the normalized minor radiusρ=0.75 in L-mode and H-mode on Globus-M2 was the ion temperature gradient(ITG)mode.