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On the time-varying correlations between oil-,gold-,and stock markets:The heterogeneous roles of policy uncertainty in the US and China 被引量:1
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作者 Wen Zhao Yu-Dong Wang 《Petroleum Science》 SCIE CAS CSCD 2022年第3期1420-1432,共13页
This paper investigates the effects of economic policy uncertainty(EPU)and monetary policy uncertainty(MPU)in the US and China on oil-stock and gold-stock correlations.A quantile regression approach is employed to ana... This paper investigates the effects of economic policy uncertainty(EPU)and monetary policy uncertainty(MPU)in the US and China on oil-stock and gold-stock correlations.A quantile regression approach is employed to analyze the heterogeneous impacts under different market correlation regimes.Our findings suggest that the“US impact”prevails across all market correlations in the sample,while“China impact”is found for oil-stock correlations.Furthermore,the impacts of EPU and MPU on correlations of different asset pairs exhibit heterogeneity in direction and in different correlation regimes.EPU and MPU have homogenously negative effects on gold-stock correlations across various correlation regimes.Differently,in terms of oil-stock correlations,they exhibit more significant and stronger positive impacts in the medium and high correlation regime than in the low correlation regime.Gold can provide a better diversification for stock market risks than crude oil during the period of high level of economic uncertainty. 展开更多
关键词 Policy uncertainty Crude oil GOLD Cross-asset correlations Quantile regression
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Origin of condensate oil and natural gas in Bozhong 19-6 gas field,Bohai Bay Basin
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作者 Jianyong Xu Wei Li 《Energy Geoscience》 EI 2024年第1期54-62,共9页
The discovery of the Bozhong 19-6 gas field has opened a new frontier for deep gas exploration in the Bohai Bay Basin,with a great potential for further gas exploration.However,poor understanding of oil and gas origin... The discovery of the Bozhong 19-6 gas field has opened a new frontier for deep gas exploration in the Bohai Bay Basin,with a great potential for further gas exploration.However,poor understanding of oil and gas origin has been limiting the exploration progress in this area.To clarify the origin of condensate oil and gas in Bozhong 19-6 gas field,this study adequately utilized the organic geochemical analysis data to investigate the composition and geochemical characteristics of condensate oil and natural gas,and analyzed the relationship between condensate oil and the three sets of source rocks in the nearby subsags.Results show that the lighter components dominate the condensate oil,with a forward type predominance.The parent material of crude oil was primarily deposited in a shallow,clay-rich,low-salinity,weakly reducing aquatic environment.The condensate and natural gas have similar parent source characteristics and maturity,with Ro ranging from 1.4%to 1.6%.Both are products of high maturity stage,indicating that they are hydrocarbon compounds produced by the same group of source rocks in the same stage.Oil-sources correlation shows that condensate oil and gas mainly originate from the source rocks of the third member of Shahejie Formation in the nearby subsags of the Bozhong 19-6 structural belt. 展开更多
关键词 Bozhong Sag Natural gas Condensate oil Light hydrocarbon Gas-source correlation oil-source correlation
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Oil-source rock correlation and quantitative assessment of Ordovician mixed oils in the Tazhong Uplift, Tarim Basin 被引量:11
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作者 Li Sumei Pang Xiongqi +2 位作者 Zhang Baoshou Xiao Zhongyao Gu Qiaoyuan 《Petroleum Science》 SCIE CAS CSCD 2010年第2期179-191,共13页
The origin of the marine oils in the Tarim Basin has long been a disputed topic. A total of 58 DST (drill stem test) crude oil and 8 rock samples were investigated using a comprehensive geochemical method to charact... The origin of the marine oils in the Tarim Basin has long been a disputed topic. A total of 58 DST (drill stem test) crude oil and 8 rock samples were investigated using a comprehensive geochemical method to characterize and identify the origin of the Ordovician oils in the Tazhong Uplift, Tarim Basin, northwest China. Detailed oil–oil and oil–source rock correlations show that the majority of the oils have typical biomarker characteristics of the Middle-Upper Ordovician (O2+3) source rock and the related crude oil. These characteristics include a distinct "V-shaped" relative abundance of C27, C28 and C29 regular steranes, low abundance of dinosterane, 24-norcholestanes, triaromatic dinosteroids and gammacerane. Only a few oils display typical biomarker characteristics indicating the Cambrian–Lower Ordovician (∈-O1) genetic affinity, such as linear or anti "L" shape distribution of C27, C28 and C29 regular sterane, with relatively high concentrations of dinosterane, 24-norcholestanes, triaromatic dinosteroids and gammacerane. It appears that most of the Ordovician oils in the Tazhong Uplift were derived from the O2+3 intervals, as suggested by previous studies. However, the compound specific n-alkane stable carbon isotope data indicate that the Ordovician oils are mixtures from both the ∈-O1 and O2+3 source rocks rather than from the O2+3 strata alone. It was calculated that the proportion of the∈-O1 genetic affinity oils mixed is about 10.8%-74.1%, with an increasing trend with increasing burial depth. This new oil-mixing model is critical for understanding hydrocarbon generation and accumulation mechanisms in the region, and may have important implications for further hydrocarbon exploration in the Tarim Basin. 展开更多
关键词 BIOMARKER compound specific isotope oil–source rock correlation mixed oil
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Measurement and Correlation of the Solubility of Ligusticum Chuanxiong oil in Supercritical CO_2 被引量:7
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作者 孙永跃 李淑芬 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2005年第6期796-799,共4页
Extraction of the Ligusticum Chuanxiong oil with supercritical CO2 (SC-CO2) was investigated at the temperatures ranging from 55℃ to 70℃ and pressure from 25 MPa to 35 MPa. The mass of Ligusticum Chuanxiong oil ex... Extraction of the Ligusticum Chuanxiong oil with supercritical CO2 (SC-CO2) was investigated at the temperatures ranging from 55℃ to 70℃ and pressure from 25 MPa to 35 MPa. The mass of Ligusticum Chuanxiong oil extracted increased with pressure at constant temperature. The initial slope of the extraction was considered as the solubility of oil in SC-CO2. Chrastil equation was used to correlate the solubility data of Ligusticum Chuanxiong oil. An improved Chrastil equation was also presented and was employed to correlate the solubility data, The correlation results show that the values of the average absolute relative deviation are 5.94% and 3.33% respectively, indicating the improved version has better correlation accuracy than that of Chrastil equation. 展开更多
关键词 supercritical CO2 extraction SOLUBILITY Ligusticum Chuanxiong oil correlation
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Effective source rock selection and oil–source correlation in the Western Slope of the northern Songliao Basin,China 被引量:2
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作者 He Bi Peng Li +2 位作者 Yun Jiang Jing-Jing Fan Xiao-Yue Chen 《Petroleum Science》 SCIE CAS CSCD 2021年第2期398-415,共18页
This study considers the Upper Cretaceous Qingshankou Formation,Yaojia Formation,and the first member of the Nenjiang Formation in the Western Slope of the northern Songliao Basin.Dark mudstone with high abundances of... This study considers the Upper Cretaceous Qingshankou Formation,Yaojia Formation,and the first member of the Nenjiang Formation in the Western Slope of the northern Songliao Basin.Dark mudstone with high abundances of organic matter of Gulong and Qijia sags are considered to be significant source rocks in the study area.To evaluate their development characteristics,differences and effectiveness,geochemical parameters are analyzed.One-dimensional basin modeling and hydrocarbon evolution are also applied to discuss the effectiveness of source rocks.Through the biomarker characteristics,the source–source,oil–oil,and oil–source correlations are assessed and the sources of crude oils in different rock units are determined.Based on the results,Gulong and Qijia source rocks have different organic matter primarily detrived from mixed sources and plankton,respectively.Gulong source rock has higher thermal evolution degree than Qijia source rock.The biomarker parameters of the source rocks are compared with 31 crude oil samples.The studied crude oils can be divided into two groups.The oil–source correlations show that group I oils from Qing II–III,Yao I,and Yao II–III members were probably derived from Gulong source rock and that only group II oils from Nen I member were derived from Qijia source rock. 展开更多
关键词 Songliao basin Western slope Source rock distinction Crude oils BIOMARKER oil-source correlation
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Distribution and isotopic signature of 2-alkyl-1,3,4-trimethylbenzenes in the Lower Paleozoic source rocks and oils of Tarim Basin:Implications for the oil-source correlation 被引量:1
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作者 Tao-Hua He Wen-Hao Li +7 位作者 Shuang-Fang Lu Er-Qiang Yang Tao-Tao Jing Jun-Feng Ying Peng-Fei Zhu Xiu-Zhe Wang Wen-Qing Pan Zhong-Hong Chen 《Petroleum Science》 SCIE CAS CSCD 2022年第6期2572-2582,共11页
Series of 2-alkyl-1,3,4-trimethylbenzenes(ATMBs)were detected in most of crude oils and source rocks collected from various strata and locations of the Tarim Basin.They appeared to have heavy carbon isotopic signatur... Series of 2-alkyl-1,3,4-trimethylbenzenes(ATMBs)were detected in most of crude oils and source rocks collected from various strata and locations of the Tarim Basin.They appeared to have heavy carbon isotopic signatures(δ13C,up to~-16‰)compared to those hydrocarbons from oxygenic phototrophic organisms,indicating that the unequivocal source of green sulfur bacteria(GSB)and photic zone euxinia(PZE)existed in the original environment.Considering the high paleoproductivity,the PZE may have enhanced the preservation of organic matter,which triggered the formation of extremely organic-rich source rocks with TOC up to 29.8%for the Lower Cambrian Yuertus Formation(€1y).The coexistence of ATMBs and the diagnostic products from secondary alterations(e.g.,abundant 25-norhopanes,thiadiamondoids,and diamondoids)indicated a stronger ability of anti-second-alterations.Combined with the results of quantitatively de-convoluting mixed oil,the oil-source correlation based on ATMBs from a large number of Lower Paleozoic samples of the Tarim Basin suggested that the abundant deep crude oil resources co ntained a dominant contribution(>50%)from the€1y source rocks.Therefore,the ATMBs,as diagnostic biomarkers indicating unequivocal precursors under special habitat conditions,might provide important insights for the exploration of deep Lower Paleozoic crude oils in the Tarim Basin. 展开更多
关键词 2-alkyl-1 3 4-trimethylbenzenes Carbon isotopes Deep lower paleozoic crude oils Thiadiamondoid oil-source correlation Tarim Basin
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The Occurrence of Oleananes in the Beibuwan Basin and Its Application to the Study of Maturity and Oil-Source Rock Correlation 被引量:9
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作者 LI Meijun WANG Tieguan +4 位作者 LIU Ju ZHANG Meizhu LU Hong MA Qinglin GAO Lihui 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2008年第3期585-595,共11页
The oleanane parameter, i.e., OP (oleananes/(oleananes+C30hopanes)) in the two sedimentary columns of the Beibuwan Basin, South China Sea, can be used to delimit the top of oil generation window, with Ro (/%) o... The oleanane parameter, i.e., OP (oleananes/(oleananes+C30hopanes)) in the two sedimentary columns of the Beibuwan Basin, South China Sea, can be used to delimit the top of oil generation window, with Ro (/%) of 0.53 in Well M1 and 0.55 in Wells H1/Hd1/Hd2, respectively. Comparing with vitrinite reflectance (Ro/%), the OP features a dynamic range and can indicate the oil generation window more precisely. By using OP and other geochemical indices, the oil-source correlation is also conducted. It suggests that the oils in wells M1 and M2 are derived from the source rocks in situ. The mudstone in Huachang uplift is not the main source rocks for oils in this area, The OP is also a useful oil-source correlation parameter in some Tertiary lacustrine basins. 展开更多
关键词 oleanane parameter (OP) BIOMARKER MATURITY oil-source correlation Fushan Depression
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Dibenzofuran Series in Terrestrial Source Rocks and Crude Oils and Applications to Oil-Source Rock Correlations in the Kuche Depression of Tarim Basin, NW China 被引量:9
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作者 李景贵 李梅 王兆云 《Chinese Journal Of Geochemistry》 EI CAS 2004年第2期113-123,共11页
Ten series of aromatic hydrocarbon compounds (biphenyl, naphthalene, phenanthrene, anthracene, retene, chrysene, benzoanthracene, dibenzofuran, fluorene, dibenzothiophene) isolated from seven Triassic and Jurassic lac... Ten series of aromatic hydrocarbon compounds (biphenyl, naphthalene, phenanthrene, anthracene, retene, chrysene, benzoanthracene, dibenzofuran, fluorene, dibenzothiophene) isolated from seven Triassic and Jurassic lacustrine mudstone samples and three swamp coal samples, as well as five crude oil samples collected in the Kuche depression of the Tarim Basin, NW China, have been analysed by GC-MS techniques. It is found that the relative abundances of dibenzofuran series are higher in the three swamp coal samples than those in the lacustrine mudstone samples. Based on the similar relative abundances of dibenzofuran series, especially dibenzofuran compound, in the TICs of aromatic hydrocarbons, crude oils from wells SA3 (K), YTK5 (E, K) and QL1 (E) are thought to have been derived predominantly from the coals of the Lower Jurassic Yangxia Formation or Middle Jurassic Kezilenuer Formation, whereas those from wells YM7 (O) and YH1 (E) were derived mainly from Triassic and Jurassic lacustrine mudstones in the Kuche depression. This is the first report about how to distinguish coal-generated oils from lacustrine mudstone-generated oils in the Kuche depression in terms of the dibenzofuran series. The present paper has enlightening and directive significance for further oil-source rock correlations and oil and/or gas exploration in the Kuche depression of the Tarim Basin. 展开更多
关键词 氧芴 芳烃 三叠纪 侏罗纪 泥岩 油源
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Ruthenium-ion-catalyzed oxidation of asphaltenes and oil-source correlation of heavy oils from the Lunnan and Tahe oilfields in the Tarim Basin, NW China 被引量:1
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作者 马安来 张水昌 +3 位作者 张大江 金之钧 马晓娟 陈清棠 《Chinese Journal Of Geochemistry》 EI CAS 2005年第1期28-36,共9页
The identification of marine source rocks in the Tarim Basin is debated vigorously. The intention of this paper is to investigate the asphaltenes in heavy oils from the Lunnan and Tahe oilfields and Well TD2 with ruth... The identification of marine source rocks in the Tarim Basin is debated vigorously. The intention of this paper is to investigate the asphaltenes in heavy oils from the Lunnan and Tahe oilfields and Well TD2 with ruthenium-ions-catalyzed oxidation technique (RICO), in order to explore its role in oil-oil and oil-source correlations. The RICO products included n-alkanoic acids, α, ω-di-n-alkanoic acids, branched alkanoic acids, tricyclic terpanoic acids, hopanoic acids, gammacerane carboxylic acid , regular sterane carboxylic acids and 4-methylsterane carboxylic acids. The n-alkyl chains and biomarkers bounded on the asphaltenes were of unsusceptibility to biodegradation. The distribution and absolute concentrations of n-alkanoic acids in the RICO products of heavy oils from the Lunnan and Tahe oilfields are different from those of Well TD2. The biomarkers bounded on the asphaltenes, especially steranes, have a distribution trend similar to that of the counterparts in saturates. The sterane carboxylic acids and 4-methylsterane carboxylic acids in the RICO products of heavy oils from the Lunnan and Tahe oilfields, dominated by C-{30} sterane and C-{31} 4-methylsterane carboxylic acids, respectively, are significantly different from those of the heavy oils of Well TD2, whose dominating sterane and 4|methylsterane carboxylic acids are C-{28} sterane and C-{29} 4-methylsterane acids, respectively. The RICO products of the asphaltenes further indicate that the Middle-Upper Ordovician may be the main source rocks for heavy oils from the Lunnan and Tahe oilfields. 展开更多
关键词 钌-离子催化氧化 沥青 重油 塔里木盆地 油源作用
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The geochemical characteristics and oil-source rock correlation of oilshow from the Majiashan profile, Chaoxian County, South of Anhui Province 被引量:4
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作者 TANG Youjun WEN Zhigang ZAN Ling 《Chinese Journal Of Geochemistry》 EI CAS 2008年第1期53-57,共5页
In the future time the exploration of marine oil and gas will be one of the significant domains in China. In this paper the biomarker assemblage characteristics of oilshow in the Nanlinghu Formation of the Majiashan p... In the future time the exploration of marine oil and gas will be one of the significant domains in China. In this paper the biomarker assemblage characteristics of oilshow in the Nanlinghu Formation of the Majiashan pro- file, which is located in Chaoxian County, south of Anhui Province, are described in the light of gas chromatogra- phy/mass spectrometric (GCMS) analysis on the qualitative and quantitative basis. Based on the investigation of the biomarker assemblage characteristics of possible source rocks developed in the area studied, a conclusion is drawn that the oilshow was generated from the Nanlinghu Formation source rocks (abbreviated as T1n), instead of the Qixia Formation source rocks (abbreviated as P1q). It is pointed out that the T1n is of strong potential for future oil explora- tion, and therefore much attention should be paid to it. 展开更多
关键词 地理特征 岩石 油-水系统 安徽省
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Oil-source correlation of the pre-Tertiary in the Huanghua Depression:Insights from stable carbon isotopes and molecular markers 被引量:1
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作者 YANG Yongcai ZHANG Zhihuan +4 位作者 LI Wei QIN Liming FANG Chaohe LIN Yuxiang LIU Hua 《Chinese Journal Of Geochemistry》 EI CAS 2008年第3期265-275,共11页
Stable carbon isotopes were used together with molecular markers to constrain genetic relationships between sandstone extracts and potential source rocks in the pre-Tertiary in the Huanghua Depression,North China.Comp... Stable carbon isotopes were used together with molecular markers to constrain genetic relationships between sandstone extracts and potential source rocks in the pre-Tertiary in the Huanghua Depression,North China.Comparison of the extracts from Permo-Carboniferous terrigenous mudstones and Ordovician marine carbonates indicated that their prominent differences are in stable carbon isotopes,molecular markers and thermal maturity.Although the extracts of the Mesozoic and Lower Permian Xiashihezi Formation sandstones have some similar iso-topic characteristics,molecular markers data provide a good correlation between the Upper Jurassic-Lower Cretaceous oils and the Upper Carboniferous Taiyuan Formation mudstones,and between the Lower Permian Xiashihezi Formation oils and the Lower Permian mudstones.The results showed that the Upper Jurassic-Lower Cretaceous sandstone oils were derived chiefly from the Upper Carboniferous Taiyuan Formation terrigenous mudstones and that the Lower Permian Xiashihezi Formation oils were sourced from the Lower Permian Shanxi Formation and Xiashihezi Formation terrigenous mudstones. 展开更多
关键词 石油资源 中生代 洼地 奥淘纪
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An improved correlation to determine minimum miscibility pressure of CO2–oil system
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作者 Guangying Chen Hongxia Gao +3 位作者 Kaiyun Fu Haiyan Zhang Zhiwu Liang Paitoon Tontiwachwuthikul 《Green Energy & Environment》 CSCD 2020年第1期97-104,共8页
An accurate and reliable estimation of minimum miscibility pressure(MMP) of CO2-oil system is a critical task for the design and implementation of CO2 miscible displacement process.In this study,an improved CO2-oil MM... An accurate and reliable estimation of minimum miscibility pressure(MMP) of CO2-oil system is a critical task for the design and implementation of CO2 miscible displacement process.In this study,an improved CO2-oil MMP correlation was developed to predict the MMP values for both pure and impure CO2 injection cases based on ten influential factors,i.e.reservoir temperature(TR),molecular weight of C7+oil components(MWC7+),mole fraction of volatile oil components(xvol),mole fraction of C2-C4 oil components(xC2-C4),mole fraction of C5-C6 oil components(xCs-5-C6),and the gas stream mole fractions of CO2(yCO2),H2S(yH2S),C1(yC1),hydrocarbons(yHC)and N2(yN2).The accuracy of the improved correlation was evaluated against experimental data reported in literature concurrently with those estimated by several renowned correlations.It was found that the improved correlation provided higher prediction accuracy and consistency with literature experimental data than other literature correlations.In addition,the predictive capability of the improved correlation was further validated by predicting an experimentally measured CO2-Oil MMP data,and it showed an accurate result with the absolute deviation of 4.15%.Besides,the differential analysis of the improved correlation was analyzed to estimate the impact of parameters uncertainty in the original MMP data on the calculated results.Also,sensitivity analysis was performed to analyze the influence of each parameter on MMP qualitatively and quantitatively.The results revealed that the increase of xC2-C4,xC5-C6 and yH2 S lead to the decrease of MMP,while the increase of TR,MWC7+,xvol,yCO2,YC1,yHC and yN2 tend to increase the MMP.Overall,the relevance of each parameter with MMP follows the order of TR> xC5-C6> MWC7+> xvol> yH2 S> yHC> yCO2>yC1>yN2>xC2-C4. 展开更多
关键词 Minimum miscibility pressure correlation CO2 miscible flooding Enhanced oil recovery
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Improved Correlations for Prediction of Viscosity of Iranian Crude Oils
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作者 Majid Taghizadeh Mehdi Eftekhari 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2014年第3期346-354,共9页
Empirical equations for predicting the viscosity of Iranian crude oils above, at and below the bub-ble-point pressure were developed based on pressure-volume-temperature(PVT) data of 57 bottom hole samples collected f... Empirical equations for predicting the viscosity of Iranian crude oils above, at and below the bub-ble-point pressure were developed based on pressure-volume-temperature(PVT) data of 57 bottom hole samples collected from central, southern and offshore oil fields of Iran. Both statistical and graphical techniques were employed to evaluate these equations compared with other empirical correlations. The results show that the developed correlations present better accuracy and performance for predicting the viscosity of Iranian crude oils than those correlations in literature. 展开更多
关键词 viscosity correlations pressure-volume-temperature (PVT) data viscosity prediction Iranian crude oils
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Genesis and distribution of oils in Mahu Sag,Junggar Basin,NW China 被引量:1
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作者 DANG Wenlong GAO Gang +5 位作者 YOU Xincai WU Jun LIU Shiju YAN Qi HE Wenjun GUO Liulinbo 《Petroleum Exploration and Development》 SCIE 2023年第4期840-850,共11页
Based on the geological and geochemical analysis of potential source rocks in different formations and the classification of crude oil types,combined with the hydrocarbon generation thermal simulation experiments,the ... Based on the geological and geochemical analysis of potential source rocks in different formations and the classification of crude oil types,combined with the hydrocarbon generation thermal simulation experiments,the source,genesis,and distribution of different types of oils in the Mahu large oil province of the Junggar Basin are investigated.Four sets of potential source rocks are developed in the Mahu Sag.Specifically,the source rocks of the Permian Fengcheng Formation have the highest hydrocarbon generation potential and contain mainly TypesⅡandⅠorganic matters,with a high oil generation capacity.In contrast,the source rocks in other formations exhibit lower hydrocarbon generation potential and contain mainly TypeⅢorganic matter,with dominant gas generation.Oils in the Mahu Sag can be classified as three types:A,B and C,which display ascending,mountainous and descending C_(20)-C_(21)-C_(23)tricyclic terpenes abundance patterns in sequence,and gradually increasing relative content of tricyclic terpenes and sterane isomerization parameters,indicating an increasing oil maturity.Different types of oils are distributed spatially in an obviously orderly manner:Type A oil is close to the edge of the sag,Type C oil is concentrated in the center of the sag,and Type B oil lies in the slope area between Type A and Type C.The results of oil-source correlation and thermal simulation experiments show that the three types of oils come from the source rocks of the Fengcheng Formation at different thermal evolution stages.This new understanding of the differential genesis of oils in the Mahu Sag reasonably explains the source,distribution,and genetic mechanism of the three types of oils.The study results are of important guidance for the comprehensive and three-dimensional oil exploration,the identification of oil distribution in the total petroleum system,and the prediction of favorable exploration areas in the Mahu Sag. 展开更多
关键词 source rock organic matter hydrocarbon generation potential hydrocarbon generation thermal simulation oil type oil-source correlation Permian Fengcheng Formation Mahu Sag Junggar Basin
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Oil-source correlation of Lower-Triassic oil seepages in Ni'erguan village, Southern Guizhou Depression, China
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作者 Fang Yuan Yuhong Liao +1 位作者 Yunxin Fang Ansong Geng 《Acta Geochimica》 EI CAS CSCD 2016年第1期50-63,共14页
There are abundant bitumens and oil seepages stored in vugs in a Lower-Triassic Daye formation(T_1d)marlite in Ni'erguan village in the Southern Guizhou Depression. However, the source of those oil seepages has no... There are abundant bitumens and oil seepages stored in vugs in a Lower-Triassic Daye formation(T_1d)marlite in Ni'erguan village in the Southern Guizhou Depression. However, the source of those oil seepages has not been determined to date. Multiple suites of source rocks of different ages exist in the depression. Both the oil seepages and potential source rocks have undergone complicated secondary alterations, which have added to the difficulty of an oil-source correlation. For example, the main source rock, a Lower-Cambrian Niutitang Formation"(∈_1n) mudstone, is over mature, and other potential source rocks, both from the Permian and the Triassic, are still in the oil window. In addition, the T_1d oil seepages underwent a large amount of biodegradation. To minimize the influence of biodegradation and thermal maturation, special methods were employed in this oil-source correlation study. These methods included catalytic hydropyrolysis, to release covalently bound biomarkers from the over mature"kerogen of ∈_1n mudstone, sequential extraction, to obtain chloroform bitumen A and chloroform bitumen C from the T_1d marlite, and anhydrous pyrolysis, to release pyrolysates from the kerogen of T_1d marlite. Using the methods above, the biomarkers and n-alkanes releasedfrom the oil samples and source rocks were analysed by GC–MS and GC-C-IRMS. The oil-source correlation indicated that the T_1d oil seepage primarily originated from"the ∈_1n mudstone and was partially mixed with oil generated from the T_1d marlite. Furthermore, the seepage also demonstrated that the above methods were effective for the complicated oil-source correlation in the Southern Guizhou Depression. 展开更多
关键词 oil seepage Biomarker Carbon isotopic composition Catalytic hydropyrolysis oil-source correlation
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Reclassification and distribution patterns of discovered oils in theDongying Depression, Bohai Bay Basin, China
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作者 Bing You Jian-Fa Chen Zhi-Yong Ni 《Petroleum Science》 SCIE EI CAS CSCD 2023年第1期114-127,共14页
The Dongying Depression is an important petrolifeous province,with diverse source rocks and complex petroleum distribution patterns.A total of 32 crude oils were analyzed by the gas chromatographyemass spectrometry an... The Dongying Depression is an important petrolifeous province,with diverse source rocks and complex petroleum distribution patterns.A total of 32 crude oils were analyzed by the gas chromatographyemass spectrometry and isotopic compositions to better understanding the petroleum systems in the study area.Three oil types were classified by hierarchical cluster analyses.Type I and II oils have closely correlation with the discovered source rocks,which have been confirmed to be mainly derived from the lower third and upper forth member of the Eocene Shahejie Formation source rocks(Es3^(L) and Es4^(U)),respectively.Obviously,type III oils contain abundant gammacerane,tricyclic terpanes and C_(29) steranes and have lower values of δ13C than type I and II oils,indicating a completely different source rock and biological origins.Until recently,type III oils fail to match any of the discovered source rock,which contains main contribution of aquatic organism or/and bacteria inputs.In addition,the spacial distribution of these three oil types were discussed.Type I oils mainly distributed in the Es3 and Es4 reservoirs that closed to the generative kitchens.Type II oils occurred in the Es4 reservoirs in the sourthern slope of the depression,which probably caused by lateral migration along the horizontal fractures and sandstone layers within the Es4 interval.Differently,type III oils in the sourthern slope of the depression were mainly discovered in the Eocene Kongdian or Ordocician reservoirs,which suggests great exploration potential of deep underlying strata. 展开更多
关键词 Molecular biomarker oil-oil correlation oil distribution Kongdian Formation Dongying Depression
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Controlling factors on the charging process of oil and gas in the eastern main sub-sag of the Baiyun Sag,Zhujiang River(Pearl River)Mouth Basin
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作者 Cong Chen Xiangtao Zhang +5 位作者 Guangrong Peng Zulie Long Baojun Liu Xudong Wang Puqiang Zhai Bo Zhang 《Acta Oceanologica Sinica》 SCIE CAS CSCD 2023年第3期189-200,共12页
The eastern main sub-sag(E-MSS)of the Baiyun Sag was the main zone for gas exploration in the deep-water area of the Zhujiang River(Pearl River)Mouth Basin at its early exploration stage,but the main goal of searching... The eastern main sub-sag(E-MSS)of the Baiyun Sag was the main zone for gas exploration in the deep-water area of the Zhujiang River(Pearl River)Mouth Basin at its early exploration stage,but the main goal of searching gas in this area was broken through by the successful exploration of the W3-2 and H34B volatile oil reservoirs,which provides a new insight for exploration of the Paleogene oil reservoirs in the E-MSS.Nevertheless,it is not clear on the distribution of“gas accumulated in the upper layer,oil accumulated in the lower layer”(Gas_(upper)-Oil_(lower))under the high heat flow,different source-rock beds,multi-stages of oil and gas charge,and multi-fluid phases,and not yet a definite understanding of the genetic relationship and formation mechanism among volatile oil,light oil and condensate gas reservoirs,and the migration and sequential charge model of oil and gas.These puzzles directly lead to the lack of a clear direction for oil exploration and drilling zone in this area.In this work,the PVT fluid phase,the origin of crude oil and condensate,the secondary alteration of oil and gas reservoirs,the evolution sequence of oil and gas formation,the phase state of oil and gas migration,and the configuration of fault activity were analyzed,which established the migration and accumulation model of Gas_(upper)-Oil_(lower)cocontrolled by source and heat,and fractionation controlled by facies in the E-MSS.Meanwhile,the fractionation evolution model among common black reservoirs,volatile reservoirs,condensate reservoirs and gas reservoirs is discussed,which proposed that the distribution pattern of Gas_(upper)-Oil_(lower)in the E-MSS is controlled by the generation attribute of oil and gas from source rocks,the difference of thermal evolution,and the fractionation controlled by phases after mixing the oil and gas.Overall,we suggest that residual oil reservoirs should be found in the lower strata of the discovered gas reservoirs in the oil-source fault and diapir-developed areas,while volatile oil reservoirs should be found in the deeper strata near the sag with no oil-source fault area. 展开更多
关键词 volatile oil oil-oil correlation phase-controlled fractionation sequential charge model Baiyun Sag
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渤海湾盆地南堡凹陷2号构造带油气地球化学特征与来源 被引量:1
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作者 刘华 魏鑫 +4 位作者 欧阳冠宇 刘景东 陈蕾 刘海青 孟祥雨 《中国海上油气》 CAS CSCD 北大核心 2024年第1期26-36,共11页
渤海湾盆地南堡凹陷2号构造带具有多洼、多层系供烃的特征。为了揭示其复杂的油气来源,开展色谱-质谱等地化测试,分析原油地化特征,将原油分为3类,并确定每类原油的来源。结果表明:(1)Ⅰ类原油主要分布于西构造带沙三段储层中,原油中C27... 渤海湾盆地南堡凹陷2号构造带具有多洼、多层系供烃的特征。为了揭示其复杂的油气来源,开展色谱-质谱等地化测试,分析原油地化特征,将原油分为3类,并确定每类原油的来源。结果表明:(1)Ⅰ类原油主要分布于西构造带沙三段储层中,原油中C27与C29规则甾烷相对含量接近,孕甾烷参数((孕甾烷+升孕甾烷)/规则甾烷)和甾烷异构化参数(C29甾烷20S/(20R+20S)、C29甾烷ββ/(αα+ββ))较高,具有水生生物和高等植物共同输入特征,原油成熟度高,来源于沙三段烃源岩;(2)Ⅱ类原油主要分布于西构造带东二段储层中,原油中C29规则甾烷含量具明显优势,孕甾烷参数和甾烷异构化参数均低,原油母质中高等植物具有明显优势,原油成熟度整体偏低,来源于沙一段—东三段烃源岩;(3)Ⅲ类原油主要分布于东构造带东三段和西构造带东一段和明化镇组储层中,原油中C29规则甾烷具有一定优势,孕甾烷参数较低,甾烷异构化参数较高,以高等植物输入为主,原油成熟度较高,为3套烃源岩的混合来源;(4)原油4-/1-MDBT和Ts/Tm指数具有沿断层向浅部层系减小的趋势,且原油甲基菲换算的镜质体反射率与下覆烃源岩镜质体反射率一致,表明研究区原油具有原地供烃的特点。本研究成果为研究区的浅层精细勘探及深层勘探提供理论指导。 展开更多
关键词 渤海湾盆地 南堡凹陷 2号构造带 原油类型 地化特征 生物标志化合物 油源对比 原地供烃
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准噶尔盆地玛湖凹陷艾湖油田原油地球化学特征与油源对比
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作者 朱涛 李娜 +6 位作者 邹阳 刘国良 赵毅 周作铭 王然 刘新龙 绳智健 《地球学报》 CAS CSCD 北大核心 2024年第6期1013-1022,共10页
玛湖凹陷作为准噶尔盆地重要富油气凹陷之一,油气藏主要分布在二叠系、三叠系和侏罗系,油气性质复杂。本次研究在前人工作基础上,以玛湖凹陷风城组(P1f)、夏子街组(P2x)、下乌尔禾组(P2w)和克拉玛依组(T2k)的烃源岩样品以及艾湖油田百... 玛湖凹陷作为准噶尔盆地重要富油气凹陷之一,油气藏主要分布在二叠系、三叠系和侏罗系,油气性质复杂。本次研究在前人工作基础上,以玛湖凹陷风城组(P1f)、夏子街组(P2x)、下乌尔禾组(P2w)和克拉玛依组(T2k)的烃源岩样品以及艾湖油田百口泉组(T1b)的原油样品为主要研究对象。通过TOC分析、岩石热解、碳同位素、饱和烃色谱、饱和烃色谱-质谱和单井埋藏史-热史的分析,明确玛湖凹陷百口泉组的原油来源问题。研究表明,玛湖凹陷风城组烃源岩有机质丰度明显优于下乌尔禾组烃源岩,且有机质丰度高,有机质类型以Ⅱ型干酪根为主,具有较高的生油潜力。百口泉组原油已达到成熟阶段,主要来源于弱氧化-弱还原的沉积环境。通过油源对比发现,玛湖凹陷原油与风城组烃源岩的生物标志物具有良好的可比性,反映了该地区原油主要来源于风城组烃源岩的贡献。且百口泉组油藏主要存在两期原油充注,分别为侏罗纪早期和白垩纪早期的原油充注,同风城组烃源岩生、排烃具有很好的耦合性。进一步佐证百口泉组原油来自风城组烃源岩这一观点。 展开更多
关键词 玛湖凹陷 艾湖油田 烃源岩 生物标志化合物 地球化学 油源对比
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6种植物油料油脂的品质及氧化稳定性研究
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作者 王亚萍 姚小华 +4 位作者 曹永庆 常君 任华东 张成才 王开良 《中国油脂》 CAS CSCD 北大核心 2024年第9期50-58,65,共10页
为拓宽我国植物油料的开发利用途径,测定了薄壳山核桃、油茶、香榧、核桃、花生、油菜等6种植物种子的含油率及其油脂的总酚、生育酚含量和脂肪酸组成,并采用加速氧化试验对其油脂的氧化稳定性进行评价,探究了各项品质指标与氧化稳定性... 为拓宽我国植物油料的开发利用途径,测定了薄壳山核桃、油茶、香榧、核桃、花生、油菜等6种植物种子的含油率及其油脂的总酚、生育酚含量和脂肪酸组成,并采用加速氧化试验对其油脂的氧化稳定性进行评价,探究了各项品质指标与氧化稳定性指标的相关性。结果表明:薄壳山核桃仁的含油率最高(73.07%),且其油脂的总酚含量最高(12.6 mg/kg),香榧籽油的生育酚总量最高(114.90 mg/100 g);6种植物油中有5种共同脂肪酸,分别为棕榈酸、硬脂酸、油酸、亚油酸和花生烯酸;6种植物油中,薄壳山核桃油的氧化稳定性最强,其酸值、过氧化值、共轭二烯值、共轭三烯值、羰基值的变化幅度均较小,氧化诱导时间(OSI值)处于最高水平,核桃油的变化幅度较大;加速氧化过程中6种植物油的油酸、亚油酸、不饱和脂肪酸、饱和脂肪酸含量均无明显变化;油脂的OSI值与油酸、生育酚、总酚含量呈显著正相关,与亚油酸、亚麻酸含量呈显著负相关。综上,薄壳山核桃含油率高,薄壳山核桃油含有较高的总酚含量和较好的氧化稳定性,是一种优质的食用油,可作为营养保健油开发利用。 展开更多
关键词 木本植物油 品质指标 加速氧化试验 氧化稳定性 相关性分析
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