Forming adsorbents FFA-R,FFA-A and FFA-B were prepared from different particle size coal fly ashes FA-R,FA-A and FA-B,their average particle sizes(d_(50)) were 15.75,3.61 and 1.73 μm respectively.The structure an...Forming adsorbents FFA-R,FFA-A and FFA-B were prepared from different particle size coal fly ashes FA-R,FA-A and FA-B,their average particle sizes(d_(50)) were 15.75,3.61 and 1.73 μm respectively.The structure and adsorption properties for Cr^(6+) of forming adsorbents from aqueous solution were studied.The results show that forming adsorbent prepared from the coal fly ash with smaller particle size exhibits higher specific surface area,higher pore volume and better adsorption properties for Cr^(6+).The adsorption kinetics of Cr^(6+) on FFA-R,FFA-A and FFA-B fitts the second order kinetic model and the second adsorption rate constants are 7.523,3.197 and 2.187 mg·g^(-1)·min^(-1/2),respectively.The adsorption of Cr^(6+) on FFA-R,FFA-A and FFA-B can be described in terms of Langmuir isotherms better,and the adsorption processes are spontaneous and exothermic.展开更多
选取黑褐新糠虾为实验动物,采用半静态暴露法开展研究了As^(3+)、Cr^(6+)、Ni^(2+)毒性效应。急性毒性实验结果表明,As^(3+)、Cr^(6+)、Ni^(2+)对黑褐新糠虾的96 h LC50分别为92.04μg/L、233.20μg/L、537.10μg/L;相关抗氧化酶系统研...选取黑褐新糠虾为实验动物,采用半静态暴露法开展研究了As^(3+)、Cr^(6+)、Ni^(2+)毒性效应。急性毒性实验结果表明,As^(3+)、Cr^(6+)、Ni^(2+)对黑褐新糠虾的96 h LC50分别为92.04μg/L、233.20μg/L、537.10μg/L;相关抗氧化酶系统研究结果显示,SOD和CAT两种酶对三种重金属的暴露均呈现先诱导后抑制趋势。暴露结果显示,各处理组MDA水平显著高于对照组。综合3种重金属离子对黑褐新糠虾毒性数据,3种重金属离子毒性依次为As^(3+)>Cr^(6+)>Ni2,且氧化压力损伤被认为是其主要致毒机制之一。展开更多
Aculon Inc.公司已经开发了一种磷酸盐单层自组装专有技术配方(Self—Assembled Monolayer of Phosphate,SAMP),该技术可以替代用于底层和转化涂层的Cr^6+技术,从而提高涂料对表面的粘附力。在以Cr^6+为喷雾底漆的基础上,这种...Aculon Inc.公司已经开发了一种磷酸盐单层自组装专有技术配方(Self—Assembled Monolayer of Phosphate,SAMP),该技术可以替代用于底层和转化涂层的Cr^6+技术,从而提高涂料对表面的粘附力。在以Cr^6+为喷雾底漆的基础上,这种新的SAMP配方能够迅速地为工业服务,应用在高尔夫球棒、电路板和饮料罐等需要涂料粘附的任何地方,并且该配方在不锈钢、钛和铝金属的表面经久耐用。展开更多
基金Funded by the National Natural Science Foundation of China(No.51278418)the Natural Science Basic Research Plan in Shaanxi Province of China(No.2013K11-10)the Key Laboratory of Environmental Protection&Pollution and Remediation of Water and Soil of Shaanxi Province(Chang’an University)
文摘Forming adsorbents FFA-R,FFA-A and FFA-B were prepared from different particle size coal fly ashes FA-R,FA-A and FA-B,their average particle sizes(d_(50)) were 15.75,3.61 and 1.73 μm respectively.The structure and adsorption properties for Cr^(6+) of forming adsorbents from aqueous solution were studied.The results show that forming adsorbent prepared from the coal fly ash with smaller particle size exhibits higher specific surface area,higher pore volume and better adsorption properties for Cr^(6+).The adsorption kinetics of Cr^(6+) on FFA-R,FFA-A and FFA-B fitts the second order kinetic model and the second adsorption rate constants are 7.523,3.197 and 2.187 mg·g^(-1)·min^(-1/2),respectively.The adsorption of Cr^(6+) on FFA-R,FFA-A and FFA-B can be described in terms of Langmuir isotherms better,and the adsorption processes are spontaneous and exothermic.
文摘选取黑褐新糠虾为实验动物,采用半静态暴露法开展研究了As^(3+)、Cr^(6+)、Ni^(2+)毒性效应。急性毒性实验结果表明,As^(3+)、Cr^(6+)、Ni^(2+)对黑褐新糠虾的96 h LC50分别为92.04μg/L、233.20μg/L、537.10μg/L;相关抗氧化酶系统研究结果显示,SOD和CAT两种酶对三种重金属的暴露均呈现先诱导后抑制趋势。暴露结果显示,各处理组MDA水平显著高于对照组。综合3种重金属离子对黑褐新糠虾毒性数据,3种重金属离子毒性依次为As^(3+)>Cr^(6+)>Ni2,且氧化压力损伤被认为是其主要致毒机制之一。
文摘Aculon Inc.公司已经开发了一种磷酸盐单层自组装专有技术配方(Self—Assembled Monolayer of Phosphate,SAMP),该技术可以替代用于底层和转化涂层的Cr^6+技术,从而提高涂料对表面的粘附力。在以Cr^6+为喷雾底漆的基础上,这种新的SAMP配方能够迅速地为工业服务,应用在高尔夫球棒、电路板和饮料罐等需要涂料粘附的任何地方,并且该配方在不锈钢、钛和铝金属的表面经久耐用。