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High-chromium vanadium-titanium magnetite all-pellet integrated burden optimization and softening-melting behavior based on flux pellets
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作者 Bojian Chen Tao Jiang +4 位作者 Jing Wen Guangdong Yang Tangxia Yu Fengxiang Zhu Peng Hu 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2024年第3期498-507,共10页
High-chromium vanadium-titanium magnetite(HVTM)is a crucial polymetallic-associated resource to be developed.The allpellet operation is a blast furnace trend that aims to reduce carbon dioxide emissions in the future.... High-chromium vanadium-titanium magnetite(HVTM)is a crucial polymetallic-associated resource to be developed.The allpellet operation is a blast furnace trend that aims to reduce carbon dioxide emissions in the future.By referencing the production data of vanadium-titanium magnetite blast furnaces,this study explored the softening-melting behavior of high-chromium vanadium-titanium magnetite and obtained the optimal integrated burden based on flux pellets.The results show that the burden with a composition of 70wt%flux pellets and 30wt%acid pellets exhibits the best softening-melting properties.In comparison to that of the single burden,the softening-melting characteristic temperature of this burden composition was higher.The melting interval first increased from 307 to 362℃and then decreased to 282℃.The maximum pressure drop(ΔPmax)decreased from 26.76 to 19.01 kPa.The permeability index(S)dropped from 4643.5 to 2446.8 kPa·℃.The softening-melting properties of the integrated burden were apparently improved.The acid pellets played a role in withstanding load during the softening process.The flux pellets in the integrated burden exhibited a higher slag melting point,which increased the melting temperature during the melting process.The slag homogeneity and the TiC produced by over-reduction led to the gas permeability deterioration of the single burden.The segregation of the flux and acid pellets in the HVTM proportion and basicity mainly led to the better softening-melting properties of the integrated burden. 展开更多
关键词 high-chromium vanadium-titanium magnetite softening-melting properties all pellets integrated burden flux pellets
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Production and Characterization of Green Biosorbent Based on Modified Corn Cob Decorated Magnetite Nanoparticles
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作者 N’guadi Blaise Allou N’goran Sévérin Eroi +2 位作者 Mougo André Tigori Patrick Atheba Albert Trokourey 《Journal of Materials Science and Chemical Engineering》 CAS 2023年第2期1-12,共12页
In most developing countries, particularly in the countries of sub-Saharan Africa, corn cobs are considered as waste polluting the environment during the harvest period of this cereal. In order to valorize this agricu... In most developing countries, particularly in the countries of sub-Saharan Africa, corn cobs are considered as waste polluting the environment during the harvest period of this cereal. In order to valorize this agricultural waste, high-performance, inexpensive and low-energy consumption magnetic bioadsorbents were prepared from corn cobs. The chemically activated raw corn cob was magnetized by coating the surface with magnetite nanoparticles. The prepared biosorbents were characterized by FT-IR, XRD, FE-SEM associated with EDX, HR-TEM, TG analysis, BET surface area analysis and XPS. The maximum specific surface area of 35.22 m<sup>2</sup>/g was reached. An attempt to use of these magnetic biosorbents for the removal of heavy metal like Cr(VI) from aqueous solution was envisaged. 展开更多
关键词 Green Biosorbent Corn Cob magnetite Nanoparticles Surface Chemistry NaOH Activation
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Exsolutions of Diopside and Magnetite in Olivine from Mantle Dunite,Luobusa Ophiolite,Tibet,China 被引量:8
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作者 REN Yufeng CHEN Fangyuan YANG Jingsui GAO Yuanhong 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2008年第2期377-384,共8页
The exsolutious of diopside and magnetite occur as intergrowth and orient within olivine from the mantle dunite, Luobusa ophiolite, Tibet. The dunite is very fresh with a mineral assemblage of olivine (〉95%) + chr... The exsolutious of diopside and magnetite occur as intergrowth and orient within olivine from the mantle dunite, Luobusa ophiolite, Tibet. The dunite is very fresh with a mineral assemblage of olivine (〉95%) + chromite (1%-4%) + diopside (〈1%). Two types of olivine are found in thin sections: one (Fo = 94) is coarse-grained, elongated with development of kink bands, wavy extinction and irregular margins; and the other (Fo = 96) is fine-grained and poly-angied. Some of the olivine grains contain minor Ca, Cr and Ni. Besides the exsolutions in olivine, three micron-size inclusions are also discovered. Analyzed through energy dispersive system (EDS) with unitary analytical method, the average compositions of the inclusions are: Na20, 3.12%-3.84%; MgO, 19.51%-23.79%; Al2O3, 9.33%-11.31%; SiO2, 44.89%-46.29%; CaO, 11.46%-12.90%; Cr2O3, 0.74%-2.29%; FeO, 4.26%- 5.27%, which is quite similar to those of amphibole. Diopside is anhedral f'dling between olivines, or as micro-inclusions oriented in olivines. Chromite appears euhedral distributed between olivines, sometimes with apparent compositional zone. From core to rim of the chromite, Fe content increases and Cr decreases; and A! and Mg drop greatly on the rim. There is always incomplete magnetite zone around the chromite. Compared with the nodular chromite in the same section, the euhedral chromite has higher Fe3O4 and lower MgCr2O4 and MgAI2O4 end member contents, which means it formed under higher oxygen fugacity environment. With a geothermometer estimation, the equilibrium crystalline temperature is 820℃-960℃ for olivine and nodular chromite, 630℃-770℃ for olivine and euhedral chromite, and 350℃-550℃ for olivine and exsoluted magnetite, showing that the exsolutions occurred late at low temperature. Thus we propose that previously depleted mantle harzburgite reacted with the melt containing Na, Al and Ca, and produced an olivine solid solution added with Na^+, Al^3+, Ca^2+, Fe^3+, Cr^3+. With temperature decreasing, the olivine solid solution decomposed; and Fe^3+, Cr^3+ diffused into magnetite and Ca^2+ and Na^+ into clinopyroxene, both of which formed intergrowth textures. A few Fe^3+ and Cr^3+ entered interstitial chromite. Through later tectonism, the peridotite recrystallized and formed deformational coarse grained olivine, fine grained and poly-angled olivine, and euhedral grained chromite. Due to the fast cooling rate of the rock or rapid tectonic emplacement, the exsolution textures in olivine and compositional zones of chromite are preserved. 展开更多
关键词 DIOPSIDE magnetite exsolution OLIVINE DUNITE OPHIOLITE Luobusa TIBET
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Effect of MgO content in sinter on the softening–melting behavior of mixed burden made from chromium-bearing vanadium–titanium magnetite 被引量:13
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作者 Zheng-gen Liu Man-sheng Chu +2 位作者 Hong-tao Wang Wei Zhao Xiang-xin Xue 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2016年第1期25-32,共8页
The effect of sinter with different MgO contents on the softening-melting behavior of mixed burden made from chro- mium-bearing vanadium-titanium magnetite was investigated. The results show that with increasing MgO c... The effect of sinter with different MgO contents on the softening-melting behavior of mixed burden made from chro- mium-bearing vanadium-titanium magnetite was investigated. The results show that with increasing MgO content in the sinter, the softening interval and melting interval increased and the location of the cohesive zone shifted downward slightly and became moderately thicker. The softening-melting characteristic value was less pronounced when the MgO content in the sinter was 2.98wt%-3.40wt%. Increasing MgO content in the sinter reduced the content and recovery of V and Cr in the dripped iron. In addition, greater MgO contents in the sinter resulted in the generation of greater amounts of high-melting-point components, which adversely affected the permeability of the mixed burden. When the softening-melting behavior of the mixed burden and the recovery of valuable elements were taken into account, proper MgO con- tents in the sinter and slag ranged from 2.98wt% to 3.40wt% and from 11.46wt% to 12.72wt%, respectively, for the smelting of burden made from chromium-bearing vanadium-titanium magnetite in a blast furnace. 展开更多
关键词 IRONMAKING magnetite MAGNESIA SOFTENING melting behavior SINTER blast furnace practice
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Some basic properties of granules from ore blends consisting of ultrafine magnetite and hematite ores 被引量:9
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作者 Cong-cong Yang De-qing Zhu +1 位作者 Jian Pan Yue Shi 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2019年第8期953-962,共10页
Some basic properties of granules,including the granule size distribution,packed-bed permeability,and chemical composition of the adhering layer,were investigated in this study for four iron ore blends consisting of 5... Some basic properties of granules,including the granule size distribution,packed-bed permeability,and chemical composition of the adhering layer,were investigated in this study for four iron ore blends consisting of 5wt%,25wt%,and 45wt%ultrafine magnetite and 25wt%ultrafine hematite concentrates.The effects of varying the sinter basicity(CaO/SiO2 mass ratio=1.4 to 2.2)and adding ultrafine concentrates on the variation of the adhering-layer composition and granule microstructure were studied.Moreover,the effect of adhering-layer compositional changes on sintering reactions was discussed in combination with pot sintering results of ore blends.Increasing sinter basicity led to an increase in the basicities of both the adhering layer and the fine part of the sinter mix,which were higher than the overall sinter basicity.When the sinter chemistry was fixed and fine Si-bearing materials(e.g.,quartz sand)were used,increasing the amount of ultrafine ores in the ore blends tended to reduce the adhering-layer basicity and increase the SiO2 content in both the adhering layer and the fine part of the sinter mix,which will induce the formation of low-strength bonding phases and the deterioration of sinter strength.The adhering-layer composition in granules can be estimated in advance from the compositions of the-1 mm fractions of the raw materials. 展开更多
关键词 iron ORE GRANULE adhering layer magnetite concentrate SINTER BASICITY
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Mineralogy and carbothermal reduction behaviour of vanadium-bearing titaniferous magnetite ore in Eastern India 被引量:9
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作者 Saikat Samanta Manik Chandra Goswami +2 位作者 Tapan Kumar Baidya Siddhartha Mukherjee Rajib Dey 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2013年第10期917-924,共8页
Vanadium-beaxing titaniferous magnetite bands hosted by Precambrian gabbro-norite-anorthositic rocks or their metamorphic equivalents were discovered in some parts of Eastern Indian Shield, containing 48%-49% Fe (to... Vanadium-beaxing titaniferous magnetite bands hosted by Precambrian gabbro-norite-anorthositic rocks or their metamorphic equivalents were discovered in some parts of Eastern Indian Shield, containing 48%-49% Fe (total), 10%-25% TiO2, and 0.3%-2.20% V2O5 by mass. Mineralogical and petrological study, composition, and characterization of the vanadium-bearing titaniferous magnetite ore were carried out by scanning electron microscopy-energy dispersive X-ray (SEM-EDX), wave length X-ray florescence (WDXRF), inductively coupled plasma-atomic emission spectroscopy (ICP-AES), X-ray diffraction (XRD), etc. Chemical beneficiation for valuable metals, such as Fe, Ti, andV, was performed by reduction roasting. The direct and indirect reduction were investigated by mixing the lump ore with solid activated charcoal in a closed reactor and purging the reducing gas mixture in standard reducibility index apparatus at different temperatures and time intervals. The reduction roasting parameters were optimized. Finally, the reduced samples were crushed and upgraded by magnetic separation. The results show that, the maximum mass fractions of magnetic and nonmagnetic parts achieved axe 69.36% and 30.64%, respectively, which contain 10.6% TiO2 and 0.84% V205 in the magnetic part and 36.5% TiO2 and 0.22% V205 in the nonmagnetic part. 展开更多
关键词 magnetite MINERALOGY carbothermal reduction BENEFICIATION VANADIUM
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Metalizing reduction and magnetic separation of vanadium titano-magnetite based on hot briquetting 被引量:10
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作者 Shuang-yin Chen Man-sheng Chu 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2014年第3期225-233,共9页
To achieve high efficiency utilization of Panzhihua vanadium titano-magnetite, a new process of metalizing reduction and magnetic separation based on hot briquetting is proposed, and factors that affect the cold stren... To achieve high efficiency utilization of Panzhihua vanadium titano-magnetite, a new process of metalizing reduction and magnetic separation based on hot briquetting is proposed, and factors that affect the cold strength of the hot-briquetting products and the efficiency of reduction and magnetic separation are successively investigated through laboratory experiments. The relevant mechanisms are elucidated on the basis of microstructural observations. Experimental results show that the optimal process parameters for hot briquetting include a hot briquetting temperature of 475°C, a carbon ratio of 1.2, ore and coal particle sizes of less than 74 μm. Additionally, with respect to metalizing reduction and magnetic separation, the rational parameters include a magnetic field intensity of 50 mT, a reduction temperature of 1350°C, a reduction time of 60 min, and a carbon ratio of 1.2. Under these above conditions, the crushing strength of the hot-briquetting agglomerates is 1480 N, and the recovery ratios of iron, vanadium, and titanium are as high as 91.19%, 61.82%, and 85.31%, respectively. The new process of metalizing reduction and magnetic separation based on hot briquetting demonstrates the evident technological advantages of high efficiency separation of iron from other valuable elements in the vanadium titano-magnetite. 展开更多
关键词 magnetite hot briquetting ore reduction magnetic separation
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Sintering behaviors and consolidation mechanism of high-chromium vanadium and titanium magnetite fines 被引量:6
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作者 Mi Zhou Tao Jiang +1 位作者 Song-tao Yang Xiang-xin Xue 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2015年第9期917-925,共9页
To achieve high efficiency utilization of high-chromium vanadium-titanium magnetite (V-Ti-Cr) fines, an investigation of V Ti42r fines was conducted using a sinter pot. The chemical composition, particle parameters,... To achieve high efficiency utilization of high-chromium vanadium-titanium magnetite (V-Ti-Cr) fines, an investigation of V Ti42r fines was conducted using a sinter pot. The chemical composition, particle parameters, and granulation of V-Ti-Cr mixtures were analyzed, and the effects of sintering parameters on the sintering behaviors were investigated. The results indicated that the optimum quicklime dosage, mixture moisture, wetting time, and granulation time for V-Ti-Cr fines are 5wt%, 7.5wt%, 10 min, and 5-8 min, respectively. Meanwhile, the vertical sintering speed, yield, tumbler strength, and productivity gains were shown to be 21.28 mm/min, 60.50wt% , 58.26wt%, and 1.36 t·m^-2·h^-1, respectively. Furthermore, the consolidation mechanism of V-Ti-Cr fines was clarified, revealing that the consolidation of a V-Ti-Cr sinter requires an approximately 14vo1% calcium ferrite liquid-state, an approximately 15vo1% silicate liq- uid-state, a solid-state reaction, and the recrystallization of magnetite. Compared to an ordinary sinter, calcium ferrite content in a V-Ti-Cr sinter is lower, while the perovskite content is higher, possibly resulting in unsatisfactory sinter outcomes. 展开更多
关键词 magnetite CHROMIUM VANADIUM titanium ore sintering CONSOLIDATION mineralogy
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Oxidation behavior of artificial magnetite pellets 被引量:5
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作者 Han-quan Zhang Jin-tao Fu 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2017年第6期603-610,共8页
The oxidation behavior of artificial magnetite pellets was investigated through measurements of the oxidation degree and mineralogical analysis. The results show that artificial magnetite pellets are much easier to ox... The oxidation behavior of artificial magnetite pellets was investigated through measurements of the oxidation degree and mineralogical analysis. The results show that artificial magnetite pellets are much easier to oxidize than natural magnetite. The oxidation is controlled through two different reaction mechanisms. The oxidation of artificial magnetite is dominated by internal diffusion, with an activation energy of 8.40 kJ/mol, at temperatures less than 800°C, whereas it is controlled by chemical reaction, with a reaction activation energy of 67.79 kJ/mol, at temperatures greater than 800°C. In addition, factors such as the oxygen volume fraction and the pellet diameter strongly influence the oxidation of artificial magnetite: a larger oxygen volume fraction and a smaller pellet diameter result in a much faster oxidation process. 展开更多
关键词 artificial magnetite PELLETS OXIDATION REACTION MECHANISMS
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Optimized use of MgO flux in the agglomeration of high-chromium vanadium–titanium magnetite 被引量:4
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作者 Jue Tang Man-sheng Chu Xiang-xin Xue 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2015年第4期371-380,共10页
The optimized use of MgO flux in the agglomeration of high-chromium vanadium-titanium magnetite was investigated system- atically through sinter and pellet experiments. MgO was added in the form of magnesite. When the... The optimized use of MgO flux in the agglomeration of high-chromium vanadium-titanium magnetite was investigated system- atically through sinter and pellet experiments. MgO was added in the form of magnesite. When the content of MgO in the sinter was in- creased from 1.95wt% to 2.63wt%, the low-temperature reduction degradation index increased from 80.57% to 82.71%. When the content of MgO in the pellet was increased from 1.14wt% to 2.40wt%, the reduction swelling index decreased from 15.2% to 8.6%; however, the com- pressive strength of the oxidized pellet decreased dramatically and it was 1985 N with an MgO content of 1.14wt%. This compressive strength does not satisfy the requirements for blast-furnace production. When all of the aforementioned results were taken into account, the sinter with a high MgO content (2.63wt%) matching the pellet with a low MgO content (less than 1.14wt%) was the rational burden structure for smelting high-chromium vanadium-titanium magnetite in blast furnaces. 展开更多
关键词 magnetite ore pellets MAGNESIA AGGLOMERATION BURDEN sintering
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Influence of basicity and temperature on bonding phase strength,microstructure,and mineralogy of high-chromium vanadium–titanium magnetite 被引量:4
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作者 Wei-dong Tang Xiang-xin Xue +2 位作者 Song-tao Yang Li-heng Zhang Zhuang Huang 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2018年第8期871-880,共10页
To develop a smelting process for the comprehensive utilization of high-chromium vanadium-titanium magnetite(HCVTM),the micro-sinter test was applied to investigate the influence of basicity and temperature on the HCV... To develop a smelting process for the comprehensive utilization of high-chromium vanadium-titanium magnetite(HCVTM),the micro-sinter test was applied to investigate the influence of basicity and temperature on the HCVTM sinters.The bonding phase strength(BS) was tested via an electronic universal testing machine.The phase transformations of the HCVTM sinters were detected via X-ray diffraction(XRD),whereas the structure and mineralogy of the HCVTM sinters under different temperatures and basicities were detected via scanning electron microscopy in combination with energy-dispersive spectroscopy(SEM–EDS).Our results demonstrate that the BS of the HCVTM sinters exhibits a slightly increasing tendency with an increase in temperature when the basicity is 2.4 and within the range of 2.8–4.0.Many cracks,small size crystals,and dependent phase structures are generated by increasing the sinter basicity.The BS is lower than 4000 N when the basicity is 2.2 and 2.8.When the temperature is in the range of 1280–1300?C,the BS exceeds 4000 N with the basicity of 2.0,2.4,and 3.4–4.0.The pore size of the HCVTM sinters increases with the increase of the temperature.The perovskite decreases,whereas the silicate phase increases with basicity higher than 3.2.This study provides theoretical and technical foundations for the effective production of HCVTM sinters. 展开更多
关键词 IRONMAKING magnetite sintering BONDING PHASE STRENGTH
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Platinum-group Element Geochemistry of Magnetite from Porphyry-Cu-Mo Deposits and their Host Rocks(Siberia,Russia) 被引量:5
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作者 Anita BERZINA 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2012年第1期106-117,共12页
The concentrations of platinum-group elements (PGE) have been analyzed in primary magmatic magnetite samples from the Zhireken, Shakhtama and Aksug porphyry Cu-Mo deposits (Siberia, Russia) by laser ablation-induc... The concentrations of platinum-group elements (PGE) have been analyzed in primary magmatic magnetite samples from the Zhireken, Shakhtama and Aksug porphyry Cu-Mo deposits (Siberia, Russia) by laser ablation-inductively coupled plasma mass spectrometry to determine the range of PGE contents in magnetites and to check whether magnetite from two main rock suites (barren plutonic suite and mineralized porphyry suite) has distinct PGE composition. The results presented here indicate that magnetites are enriched in PGE relative to whole-rocks. Comparison of ore-related porphyry and barren plutonic suites shows that magnetite exhibit relatively similar PGE distribution patterns in both suites. Variations in Rh and Ru contents were controlled by the oxygen fugacity during magma crystallization. 展开更多
关键词 magnetite platinum-group elements porphyry Zhireken Shakhtama Aksug Siberia Russia
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Application of Modified Silica Coated Magnetite Nanoparticles for Removal of Iodine from Water Samples 被引量:6
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作者 Tayyebeh Madrakian Abbas Afkhami +2 位作者 Mohammad Ali Zolfigol Mazaher Ahmadi Nadia Koukabi 《Nano-Micro Letters》 SCIE EI CAS 2012年第1期57-63,共7页
The adsorption of iodine onto silica coated magnetite nanoparticles(im-SCMNPs) that modified with imidazole was investigated for removal of high concentrations of iodine from wastewater. Modified silica magnetite nano... The adsorption of iodine onto silica coated magnetite nanoparticles(im-SCMNPs) that modified with imidazole was investigated for removal of high concentrations of iodine from wastewater. Modified silica magnetite nanoparticles showed high efficiency in removing iodine from wastewater samples. The optimum pH for iodine removal was 7.0-8.0. The adsorption capacity was evaluated using both the Langmuir and Freundlich adsorption isotherm models. The size of the produced magnetite nanoparticles was determined by X-ray diffraction analysis and scanning electron microscopy. Synthesized magnetite nanoparticles showed the high adsorption capacity and would be a good method to increase adsorption efficiency for the removal of iodine in a wastewater treatment process. The Langmuir adsorption capacity(qmax) was found to be 140.84 mg/g of the adsorbent. 展开更多
关键词 Modified silica magnetite nanoparticles IODINE IMIDAZOLE Water samples
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Shear behavior of ultrafine magnetite tailings subjected to freeze-thaw cycles 被引量:4
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作者 Chong Wei Derek B.Apel Yunhai Zhang 《International Journal of Mining Science and Technology》 SCIE EI CSCD 2019年第4期609-616,共8页
To study the shear behavior of the ultrafine magnetite tailings subjected to freeze-thaw cycles,unconsolidated-undrained shear tests were conducted on ultrafine-grained tailings that were subjected to 1-11 cycles of f... To study the shear behavior of the ultrafine magnetite tailings subjected to freeze-thaw cycles,unconsolidated-undrained shear tests were conducted on ultrafine-grained tailings that were subjected to 1-11 cycles of freeze-thaw and defined as a type of clayey silt under confining pressures of 100,200,and 300 kPa.Taking the number of freeze-thaw cycles,cooling temperature,initial dry density,and moisture content as the four main influencing factors of shear behavior of the tailings samples,the shear stress-strain curve,compression modulus,failure strength,cohesion,and internal friction angle were measured.The results show that the freeze-thaw cycle has an obvious weakening effect on the shear behavior of the tailings material,and the shear mechanical parameters are affected by a combination of confining pressure,freeze-thaw cycle condition,and initial physical-mechanical properties of the tailings samples.Through the microstructural analysis of the tailings samples subjected to freeze-thaw cycles,it shows that the freeze-thaw cycle mainly affects the porosity,bound water,and arrangement of the tailings particles.Subsequently,the macroscopic changes in shear strength indexes emerge,and then the stability of the tailings dam will decrease. 展开更多
关键词 ULTRAFINE magnetite tailings(UMT) FREEZE-THAW cycle SHEAR behavior TRIAXIAL SHEAR test
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Effect of diboron trioxide on the crushing strength and smelting mechanism of high-chromium vanadium–titanium magnetite pellets 被引量:3
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作者 Gong-jin Cheng Zi-xian Gao +1 位作者 He Yang Xiang-xin Xue 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2017年第11期1228-1240,共13页
The effect of diboron trioxide(B_2O_3) on the crushing strength and smelting mechanism of high-chromium vanadium–titanium magnetite pellets was investigated in this work. The main characterization methods were X-ray ... The effect of diboron trioxide(B_2O_3) on the crushing strength and smelting mechanism of high-chromium vanadium–titanium magnetite pellets was investigated in this work. The main characterization methods were X-ray fluorescence, inductively coupled plasma–atomic emission spectroscopy, mercury injection porosimetry, X-ray diffraction, metallographic microscopy, and scanning electron microscopy–energy-dispersive X-ray spectroscopy. The results showed that the crushing strength increased greatly with increasing B_2O_3 content and that the increase in crushing strength was strongly correlated with a decrease in porosity, the formation of liquid phases, and the growth and recrystallization consolidation of hematite crystalline grains. The smelting properties were measured under simulated blast furnace conditions; the results showed that the smelting properties within a certain B_2O_3 content range were improved and optimized except in the softening stage. The valuable element B was easily transformed to the slag, and this phenomenon became increasingly evident with increasing B_2O_3 content. The formation of Ti(C,N) was mostly avoided, and the slag and melted iron were separated well during smelting with the addition of B_2O_3. The size increase of the melted iron was consistent with the gradual optimization of the dripping characteristics with increasing B_2O_3 content. 展开更多
关键词 high-chromium vanadium–titanium magnetite PELLETS diboron TRIOXIDE crushing strength SMELTING mechanism
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Major and Trace Elements of Magnetite from the Qimantag Metallogenic Belt: Insights into Evolution of Ore–forming Fluids 被引量:3
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作者 YI Liwen GU Xiangping +6 位作者 LU Anhuai LIU Jianping LEI Hao WANG Zhiling CUI Yu ZUO Hongyan SHEN Can 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2015年第4期1226-1243,共18页
Magnetite, as a genetic indicator of ores, has been studied in various deposits in the world. In this paper, we present textural and compositional data of magnetite from the Qimantag metallogenic belt of the Kunlun Or... Magnetite, as a genetic indicator of ores, has been studied in various deposits in the world. In this paper, we present textural and compositional data of magnetite from the Qimantag metallogenic belt of the Kunlun Orogenic Belt in China, to provide a better understanding of the formation mechanism and genesis of the metallogenic belt and to shed light on analytical protocols for the in situ chemical analysis of magnetite. Magnetite samples from various occurrences, including the ore-related granitoid pluton, mineralised endoskarn and vein-type iron ores hosted in marine carbonate intruded by the pluton, were examined using scanning electron microscopy and analysed for major and trace elements using electron microprobe and laser ablation-inductively coupled plasma-mass spectrometry. The field and microscope observation reveals that early-stage magnetite from the Hutouya and Kendekeke deposits occurs as massive or banded assemblages, whereas late- stage magnetite is disseminated or scattered in the ores. Early-stage magnetite contains high contents of Ti, V, Ga, AI and low in Mg and Mn. In contrast, late-stage magnetite is high in Mg, Mn and low in Ti, V, Ga, AI. Most magnetite grains from the Qimantag metallogenic belt deposits except the Kendekeke deposit plot in the " Skarn " field in the Ca+AI+Mn vs Ti+V diagram, far from typical magmatic Fe deposits such as the Damiao and Panzhihua deposits. According to the (MgO+MnO)- TiO^-AI203 diagram, magnetite grains from the Kaerqueka and Galingge deposits and the No.7 ore body of the Hutouya deposit show typical characteristics of skarn magnetite, whereas magnetite grains from the Kendekeke deposit and the No.2 ore body of the Hutouya deposit show continuous elemental variation from magmatic type to skarn type. This compositional contrast indicates that chemical composition of magnetite is largely controlled by the compositions of magmatic fluids and host rocks of the ores that have reacted with the fluids. Moreover, a combination of petrography and magnetite geochemistry indicates that the formation of those ore deposits in the Qimantag metallogenic belt involved a magmatic-hydrothermal process. 展开更多
关键词 magnetite trace element LA-ICP-MS ore genesis Qimantag metallogenic belt
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Spatial Variations in Particle Size and Magnetite Concentration on Cedar Beach:Implications for Grain-Sorting Processes,Western Lake Erie,Canada 被引量:3
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作者 ZHANG Shuwei Maria T. CIOPPA ZHANG Shihong 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2010年第6期1520-1532,共13页
This study examined spatial variations in the concentration,grain size and heavy mineral assemblages on Cedar Beach(Lake Erie,Canada).Magnetic studies of heavy mineral-enriched,dark-reddish sands present on the beac... This study examined spatial variations in the concentration,grain size and heavy mineral assemblages on Cedar Beach(Lake Erie,Canada).Magnetic studies of heavy mineral-enriched,dark-reddish sands present on the beach showed that magnetite(~150μm) is the dominant magnetic mineral.Surficial magnetic susceptibility values defined three zones:a lakeward region close to the water line(Zone 1),the upper swash zone(Zone 2) and the region landwards of the upper swash zone (Zone 3).Zone 2 showed the highest bulk and mass susceptibility(κ,χ) and the highest mass percentage of smaller grain-size(250μm) fractions in the bulk sand sample.Susceptibility(i.e.κandχ) values decreased and grain size coarsened from Zone 2 lakewards(into Zone 1) and landwards (into Zone 3),and correlated with the distribution of the heavy mineral assemblage,most probably reflecting preferential separation of large,less dense particles by waves and currents both along and across the beach.The eroded western section of Cedar Beach showed much higher concentrations of heavy minerals including magnetite,and finer sand grain sizes than the accreting eastern section, suggesting that magnetic techniques could be used as a rapid,cost-effective way of examining erosion along sensitive coastline areas. 展开更多
关键词 magnetic susceptibility magnetite concentration grain size grain-sorting processes Cedar Beach Lake Erie
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Germanium in Magnetite:A Preliminary Review 被引量:2
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作者 MENG Yumiao HU Ruizhong +1 位作者 HUANG Xiaowen GAO Jianfeng 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2017年第2期711-726,共16页
Magnetite is a very common mineral in various types of iron deposits and some sulfide deposits. Recent studies have focused on the use of trace elements in magnetite to discriminate ore types or trace ore-forming proc... Magnetite is a very common mineral in various types of iron deposits and some sulfide deposits. Recent studies have focused on the use of trace elements in magnetite to discriminate ore types or trace ore-forming process. Germanium is a disperse element in the crust, but sometimes is not rare in magnetite. Germanium in magnetite can be determined by laser ablation ICP-MS due to its low detection limit(0.0X ppm). In this study, we summary the Ge data of magnetite from magmatic deposits, iron formations, skarn deposits, iron oxide copper-gold deposits, and igneous derived hydrothermal deposits. Magnetite from iron formations contains relatively high Ge(up to ~250 ppm), whereas those from all other deposits mostly contains Ge less than 10 ppm, indicating that iron formations can be discriminated from other Fe deposits by Ge contents. Germanium in magmatic/hydrothermal magnetite is controlled by a few factors. Primary magma/fluid composition may be the major control of Ge in magnetite. Higher oxygen fugacity may be beneficial to Ge partition into magnetite. Sulfur fugacity and temperature may have little effect on Ge in magnetite. The enrichment mechanism of Ge in magnetite from iron formations remains unknown due to the complex ore genesis. Germanium along with other elements(Mn, Ni, Ga) and element ratios(Ge/Ga and Ge/Si raios) can distinguish different types of deposits, indicating that Ge can be used as a discriminate factor like Ti and V. Because of the availability of in situ analytical technique like laser ablation ICP-MS, in situ Ge/Si ratio of magnetite can serve as a geochemical tracer and may provide new constraints on the genesis of banded iron formations. 展开更多
关键词 GERMANIUM magnetite controlling factor iron deposits discriminate factor
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Biomimetic Preparation of Magnetite/Chitosan Nanocomposite via In Situ Composite Method ——Potential Use in Magnetic Tissue Repair Domain 被引量:2
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作者 HU Qiao-ling WU Jia CHEN Fu-ping SHEN Jia-cong 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 2006年第6期792-796,共5页
This study focused on the preparation of magnetic chitusan nanocompesite that has a potential application to bone repair and regeneration using an in situ composite method where chitosan membrane was used as the templ... This study focused on the preparation of magnetic chitusan nanocompesite that has a potential application to bone repair and regeneration using an in situ composite method where chitosan membrane was used as the template and NaOH was used as the precipitant. X-ray diffraction analysis results show the formation of magnetite in the chitosan matrix. From the magnetic measurement, it could be concluded that the magnetic chitosan rods were superparamagnetic,and that this is the unique property of nanomagnetite. Macroscopical layer structure of the magnetic chitosan rods was observed from the photographs after mechanical test, and the microlayer structure of the rods was observed from the images of scanning electron microscopy. The mechanism for preparing the rods was discussed in detail. Transmission electron microscope was used to investigate the magnetite particles in the chitosan matrix and from the images it was concluded that the magnetite particles dispersed well in chitosan matrix with particle size of about 10 nm. The mechanical properties of the magnetic chitosan rods were measured and the blending strength was found to be 98. 8 MPa. The mechanical properties did not decline when compared with those of the pure chitosan materials. 展开更多
关键词 CHITOSAN magnetite In situ compositing Red
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The thermo-electric effect of magnetite and the mechanism of geo-electric abnormalities during earthquakes 被引量:2
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作者 Junfeng Shen Xuhui Shen +1 位作者 Qian Liu Na Ying 《Geoscience Frontiers》 SCIE CAS 2010年第1期99-104,共6页
The thermo-electric coefficients of twenty-six magnetite samples, formed either by magmatism or metamorphism, were tested by the thermo-electric instrument BHET -06. Results showed that the coef- ficient is of a const... The thermo-electric coefficients of twenty-six magnetite samples, formed either by magmatism or metamorphism, were tested by the thermo-electric instrument BHET -06. Results showed that the coef- ficient is of a constant value of about -0.05 mV/℃. It is emphasized that because every magnetite grain was tested randomly, the coefficient is independent of the crystallographic direction. This fact means the thermal voltage generated from a single magnetite crystal can be accumulated, and as a result a new thermo-electric field can arise when a gradient thermal field exists and is active within the earth's crust. Because magnetite is widespread in the earth's crust (generally appearing more in the middle-lower crust), there is more-thanrandom probability that the additional thermo-electric field can be generated when certain thermal conditions are fulfilled. We, therefore, used the thermo-electric effect of magnetite to study the mechanism responsible for the presence of abnormal geo-electric fields during earthquake formation and occurrence, because gradient thermal fields always exist before earthquakes. The possible presence of additional thermo-electric fields was calculated under theoretical seismological conditions, using the following calculation formula:E= - 0.159(σ×△T×Ф×ρ2×[[(h^2 - 2x^2)cos α + 3hxsin α]/ρ1 (h^2 +x^2)^5/2). In the above formula, σ is thermo-electric coefficient of magnetite, △T is the temperature difference acting on it, Ф is a sectional area on a block of magnetite vertically perpendicular to the direction of the thermal current, ρ1 and ρ2 are the respective resistivities of magnetite and the crust, and h, α, and x, respectively, h is the depth of embedded magnetite block. α means the angle created by the horizontal line and ligature of the two poles of magnetite block, and x is the distance from observation point to projective center point of the magnetite block on earth surface. According to simulations calculated with this formula, additional thermo-electric field intensity may reach as high as n to n × 10^2 mV/km. This field is strong enough to cause obvious anomalies in the background geo-electric field, and can be easy probed by earthquake monitoring equipment. Therefore, we hypothesize that geo-electric abnormalities which occur during earthquakes may be caused by the thermo-electric effect of magnetite. 展开更多
关键词 magnetite Thermo-electric Earthquake Abnormal geo-electricity
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