BACKGROUND Phosphoglyceride crystal deposition disease(PCDD)is a rare acquired disease in which phospholipid crystals deposit in bone and soft tissue long after surgery,trauma,or repeated injections.CASE SUMMARY A 60-...BACKGROUND Phosphoglyceride crystal deposition disease(PCDD)is a rare acquired disease in which phospholipid crystals deposit in bone and soft tissue long after surgery,trauma,or repeated injections.CASE SUMMARY A 60-year-old-woman was referred to our department because of multiple abdominal masses after open splenectomy for idiopathic thrombocytopenic purpura 29 years earlier.All the masses showed marked fluorodeoxyglucose(FDG)uptake on ^(18)F-fluorodeoxyglucose positron emission tomography(^(18)F-FDGPET)and were strongly suspected to be malignant tumors.Surgical biopsies were performed,and the abdominal masses were found to be aligned vertically,three in a row,along the tissue layers cut in the patient’s previous surgery.Pathological finding of the specimens showed foreign body granuloma consisting of histiocytes and multinucleated giant cells accumulating around needle-like crystals.The crystals were confirmed as phosphoglyceride by Raman spectroscopy,and PCDD was diagnosed.To our knowledge,this is the first report of PCDD diagnosed by Raman spectroscopy.CONCLUSION We made a definitive diagnosis of PCDD in a patient with multiple tumors showing marked FDG uptake on ^(18)F-FDG-PET by incisional biopsy and composition analysis using Raman spectroscopy,a method that has not previously been reported for the diagnosis of PCDD.展开更多
Depositional growth of ice crystal is one of the major processes for development of precipitation systems and can be represented by depositional growth of cloud ice from cloud water(P_(IDW)) and depositional growth of...Depositional growth of ice crystal is one of the major processes for development of precipitation systems and can be represented by depositional growth of cloud ice from cloud water(P_(IDW)) and depositional growth of snow from cloud ice(P_(SFI)) in cloud-resolving model. Four parameterization schemes are analyzed in the cloud-resolving model simulations of four rainfall cases over the tropics and midlatitudes. The comparison of time and model domain mean data shows that Shen's scheme produces the closest rainfall simulation to the observation. Compared to Zeng's scheme,Shen's scheme improves the mean rain-rate simulation significantly through the dramatic decrease in depositional growth of cloud ice from cloud water. Compared to other schemes, Shen's scheme produces the better rainfall simulation via the reduction in the mean rain rate associated with the enhanced gain of cloud water and ice.展开更多
The effect of inhomogeneity of particles on the band-gap of silica colloidal crystals(SCCs) fabricated by vertical deposition method was studied.The optical properties of the crystals were examined.The SEM images and ...The effect of inhomogeneity of particles on the band-gap of silica colloidal crystals(SCCs) fabricated by vertical deposition method was studied.The optical properties of the crystals were examined.The SEM images and transmission spectrum of the crystals showed that the inhomogeneity of particles not only affected the ordering,but also their mid-gap position.When the volume ratio of S particles(VS) to L particles(VL) in suspension was 1:1,the band-gap of silica colloidal crystals changed with the growth of particles.When the ratio was 2:1,the quality of SCCs on substrate was obviously improved simultaneously with the number decreasing of L particles.Especially,the quality of SCCs at the bottom of substrate was the best and its mid-gap(634 nm) was very close to that of theoretic value of S particles(636 nm).When the ratio was 3:1,the effect of L particles became smaller with the number decreasing of L particles in suspension.The mid-gap position(638 nm) of whole SCCs on substrate were all close to that of theoretic value of S particles(636 nm).展开更多
The crystallization of NiTi shape memory alloy sputter deposition film in the course of sputtering deposition and that after heat treated were studied. The relationship between the process factors, such as substrate t...The crystallization of NiTi shape memory alloy sputter deposition film in the course of sputtering deposition and that after heat treated were studied. The relationship between the process factors, such as substrate type, temperature, as well as the crystallization when heat treated after plating was investigated. The results show that a new phase precipitates during heat treatment after sputtering deposition and the degree of crystallization among different layers and the stress in grains are obviously different.展开更多
The Baiyunpu deposit lies in the southwest plunging Dachengshan anticline in central Hunan, which is a large Pb-Zn polymetallic deposit. The orebodies were surrounded by the Qiziqiao Formation limestone in the Middle ...The Baiyunpu deposit lies in the southwest plunging Dachengshan anticline in central Hunan, which is a large Pb-Zn polymetallic deposit. The orebodies were surrounded by the Qiziqiao Formation limestone in the Middle Devonian, and its geological occurrence is consistent with the wall rocks. A large number of spheroidal pyrite aggregates are found unevenly distributed in the ores. The spheroidal aggregates are made up of kernels and concentric rings. The kernels are composed of approximately epigranular pyrite nanocrystals, while the rings are composed of accumulated pyrite microcrystals growing along the radial direction. The spheroidal pyrite aggregate and its outer zones can be divided into five areas(A–E). The results of electron probe micro analysis(EPMA) show that from the zone A1 to B, Co/Ni 〈1, the sum of Co and Ni is 0.08%–0.26%, S/Fe increases from 2.06 to 2.15. While from the zone C to E, Ni cannot be detected and S/Fe decreases from 2.22 to 2.08. Powder X-ray diffraction(XRD) analysis in the micro zone shows obvious crystalline characteristics in the aggregates. Moving from the inside outwards, the maximum diffraction peak intensity of the(111) and(220) crystal planes of pyrite increases, and the crystallinity improves. The degree of change in the(111) plane is the most prominent. Considering the theory of crystal growth along with the geologic features of the depositional environment where the spheroidal pyrite aggregates developed, we confirm that the spheroidal aggregates are the result of nano-micro crystalline gathering and growth occurring by the following sequence of processes:nano-crystalline nucleation and growth, gathering into a ball, oriented growth of microcrystals, continuous accumulation, and adjustment of grain boundaries. The formation of the spheroidal pyrite aggregates in the late Qiziqiao Formation of the Middle Devonian occurred in a neutral to weak alkaline and reductive sedimentary environment in the normal oxygen-rich shallowwater carbonate platform edge. The variations in the S/Fe ratio and crystallisation characteristics indicate that during pyrite crystal growth, the sulphur fugacity was high locally and rose constantly, the degree of supersaturation decreased locally and the growth environment was stable relatively.展开更多
Monodispersed silica microspheres with diameter of 353nm were assembled into photonic crystal in ethanol colloidal suspensions of varied silica volume fraction at different temperature and humidity by means of contr...Monodispersed silica microspheres with diameter of 353nm were assembled into photonic crystal in ethanol colloidal suspensions of varied silica volume fraction at different temperature and humidity by means of controllable vertical deposition method. The surface morphology and optical properties were studied by SEM and UV-Vis-NIR. It was found that the high-quality silica colloidal photonic crystals were obtained from ethanol solutions with environment temperature between 45℃ and 55℃, humidity between 66% and 76%, the volume fraction of microspheres is between 0.8% and 1.5%. The ordered close-packed photonic crystal fabricated by controllable vertical deposition method had the two photonic bandgaps in the visible light band and near infrared band.展开更多
A dichlorosilane gas and a trichlorosilane gas in ambient hydrogen were evaluated to show their different gas flow motions in a slim vertical cold wall chemical vapor deposition reactor for the Minimal Fab system. Thi...A dichlorosilane gas and a trichlorosilane gas in ambient hydrogen were evaluated to show their different gas flow motions in a slim vertical cold wall chemical vapor deposition reactor for the Minimal Fab system. This evaluation was performed for improving and controlling the film qualities and the productivities, using two quartz crystal microbalances (QCM) installed at the </span><span style="font-family:Verdana;">inlet and exhaust of the chamber by taking into account that the QCM frequency corresponds to the real time changes in the gas properties.</span><span style="font-family:Verdana;"> Typically, the time period approaching from the inlet to the exhaust was shorter for the trichlorosilane gas than that for the dichlorosilane gas. The trichlorosilane gas was shown to move like plug flow, while the dichlorosilane gas seemed to be well mixed in the entire chamber.展开更多
MoS2 coatings were prepared using an unbalanced bipolar pulsed DC (direct current) magnetron sputtering apparatus under different targets, cathode current densities, power modes and bias voltages. The morphology, st...MoS2 coatings were prepared using an unbalanced bipolar pulsed DC (direct current) magnetron sputtering apparatus under different targets, cathode current densities, power modes and bias voltages. The morphology, structure and growth characteristics of MoS2 coatings were observed and identified respectively by scanning electron microscopy, X-ray diffractometry and mass spectrometry. The results show that MoS2 coatings evolve with the (002) basal plane parallel to the surface by using cold pressed target with lower density, lower cathodic current density, bipolar pulse DC power and minus bias voltage, whereas the coatings deposited under hot pressed target, higher cathodic current density, simple DC power and positive bias voltage have the (002) basal plane perpendicular to the surface. The influence of deposition conditions on the crystal structure of MoS2 coating is implemented by altering its growth rate and the energy of sputtering-deposition particles.展开更多
Orthogonal experiments of Ga Sb films growth on Ga As(001) substrates have been designed and performed by using a low-pressure metal–organic chemical vapor deposition(LP-MOCVD) system. The crystallinities and mic...Orthogonal experiments of Ga Sb films growth on Ga As(001) substrates have been designed and performed by using a low-pressure metal–organic chemical vapor deposition(LP-MOCVD) system. The crystallinities and microstructures of the produced films were comparatively analyzed to achieve the optimum growth parameters. It was demonstrated that the optimized Ga Sb thin film has a narrow full width at half maximum(358 arc sec) of the(004) ω-rocking curve, and a smooth surface with a low root-mean-square roughness of about 6 nm, which is typical in the case of the heteroepitaxial single-crystal films. In addition, we studied the effects of layer thickness of Ga Sb thin film on the density of dislocations by Raman spectra. It is believed that our research can provide valuable information for the fabrication of high-crystalline Ga Sb films and can promote the integration probability of mid-infrared devices fabricated on mainstream performance electronic devices.展开更多
Using the langasite crystal microbalance (LCM), the trends in film thickness produced by means of the chemical vapor deposition using trichlorosilane gas, monomethylsilane gas and their mixed gas were observed at 600?...Using the langasite crystal microbalance (LCM), the trends in film thickness produced by means of the chemical vapor deposition using trichlorosilane gas, monomethylsilane gas and their mixed gas were observed at 600?C and evaluated by comparison with the information from a transmission electron microscope (TEM). The crystalline silicon film thickness from trichlorosilane gas was comparable to that of an amorphous silicon carbide film from monomethylsilane gas. The film obtained from the gas mixture was amorphous and was the thinnest in this study. Because the thickness trend obtained by the LCM agreed with that by the TEM, the LCM is shown to be a convenient evaluation tool for the behavior of various film deposition.展开更多
Cu-phthalocyanine is widely studied as a hole-transport layer in organic electronic devices. Since Cu-phthalocyanine is a molecular solid, the crystal structure depends on a circumstance to a great extent. Vacuum depo...Cu-phthalocyanine is widely studied as a hole-transport layer in organic electronic devices. Since Cu-phthalocyanine is a molecular solid, the crystal structure depends on a circumstance to a great extent. Vacuum deposited layers were known to consist of two consecutive layers. In this article, Cu-phthalocyanine was deposited on the glass substrate inclined at several angles. The thickness of the first layer was found to be dependent on the substrate angle.展开更多
Erdaohezi lead-zinc deposit belongs to the Derbugan metallogenic belt lying on the northwestern Hailaer-Genhe Mesozoic volcanic basin,located on the western slope of the Da Hinggan Mountains. The deposit is considered...Erdaohezi lead-zinc deposit belongs to the Derbugan metallogenic belt lying on the northwestern Hailaer-Genhe Mesozoic volcanic basin,located on the western slope of the Da Hinggan Mountains. The deposit is considered as one of the hypabyssal low-temprature hydrothermal lead-zinc deposits associated with volcanism. In order to lay the foundation on studying its diagenesis and mineralization ages,the detailed studies were carried out by dating the host rocks( i. e. rhyolitic lithic-crystal tuffs) using zircon LA-ICP-MS U-Pb method.The dating results show three groups of ages. The first group is the captured zircons( the weighted mean ^(206)Pb /^(238) U age as 175. 6 ± 2. 3 Ma,MSWD = 0. 70,n = 3). The second group can be regarded as the rockforming age( the weighted mean ^(206)Pb /^(238) U age as 165. 3 ± 1. 9 Ma,MSWD = 2. 40,n = 14). The third group should represent the late stage of the magmatic evolution( the weighted mean ^(206)Pb /^(238) U age as 161. 0 ± 3. 1Ma,MSWD = 0. 86,n = 4). According to the ages and the crystal form or CL image characteristics of zircons,it is determined that the diagenesis occurred in the late Middle Jurassic. Based on the regional geology and geochronological research,the acidic pyroclastic rocks are space accompaniment and time connection with the Tamulangou Formation intermediate-mafic volcanic rocks. Both of them constitute the host rocks of the deposit together. The rock combination also provides favorable conditions for large-scale silver,lead and zinc mineralization in this area.展开更多
文摘BACKGROUND Phosphoglyceride crystal deposition disease(PCDD)is a rare acquired disease in which phospholipid crystals deposit in bone and soft tissue long after surgery,trauma,or repeated injections.CASE SUMMARY A 60-year-old-woman was referred to our department because of multiple abdominal masses after open splenectomy for idiopathic thrombocytopenic purpura 29 years earlier.All the masses showed marked fluorodeoxyglucose(FDG)uptake on ^(18)F-fluorodeoxyglucose positron emission tomography(^(18)F-FDGPET)and were strongly suspected to be malignant tumors.Surgical biopsies were performed,and the abdominal masses were found to be aligned vertically,three in a row,along the tissue layers cut in the patient’s previous surgery.Pathological finding of the specimens showed foreign body granuloma consisting of histiocytes and multinucleated giant cells accumulating around needle-like crystals.The crystals were confirmed as phosphoglyceride by Raman spectroscopy,and PCDD was diagnosed.To our knowledge,this is the first report of PCDD diagnosed by Raman spectroscopy.CONCLUSION We made a definitive diagnosis of PCDD in a patient with multiple tumors showing marked FDG uptake on ^(18)F-FDG-PET by incisional biopsy and composition analysis using Raman spectroscopy,a method that has not previously been reported for the diagnosis of PCDD.
基金National Natural Science Foundation of China(41475039)National Key Basic Research and Development Project of China(2015CB953601)
文摘Depositional growth of ice crystal is one of the major processes for development of precipitation systems and can be represented by depositional growth of cloud ice from cloud water(P_(IDW)) and depositional growth of snow from cloud ice(P_(SFI)) in cloud-resolving model. Four parameterization schemes are analyzed in the cloud-resolving model simulations of four rainfall cases over the tropics and midlatitudes. The comparison of time and model domain mean data shows that Shen's scheme produces the closest rainfall simulation to the observation. Compared to Zeng's scheme,Shen's scheme improves the mean rain-rate simulation significantly through the dramatic decrease in depositional growth of cloud ice from cloud water. Compared to other schemes, Shen's scheme produces the better rainfall simulation via the reduction in the mean rain rate associated with the enhanced gain of cloud water and ice.
基金Supported by National Key Basic Research Special Fund (No. 2006CB932606)National Natural Science Foundation of China (No. 50702077)
文摘The effect of inhomogeneity of particles on the band-gap of silica colloidal crystals(SCCs) fabricated by vertical deposition method was studied.The optical properties of the crystals were examined.The SEM images and transmission spectrum of the crystals showed that the inhomogeneity of particles not only affected the ordering,but also their mid-gap position.When the volume ratio of S particles(VS) to L particles(VL) in suspension was 1:1,the band-gap of silica colloidal crystals changed with the growth of particles.When the ratio was 2:1,the quality of SCCs on substrate was obviously improved simultaneously with the number decreasing of L particles.Especially,the quality of SCCs at the bottom of substrate was the best and its mid-gap(634 nm) was very close to that of theoretic value of S particles(636 nm).When the ratio was 3:1,the effect of L particles became smaller with the number decreasing of L particles in suspension.The mid-gap position(638 nm) of whole SCCs on substrate were all close to that of theoretic value of S particles(636 nm).
文摘The crystallization of NiTi shape memory alloy sputter deposition film in the course of sputtering deposition and that after heat treated were studied. The relationship between the process factors, such as substrate type, temperature, as well as the crystallization when heat treated after plating was investigated. The results show that a new phase precipitates during heat treatment after sputtering deposition and the degree of crystallization among different layers and the stress in grains are obviously different.
基金granted by the National Natural Science Foundation of China (Grant No. 41172047, 41272062)the Open Fund of the State Key Laboratory of Ore Deposit Geochemistry (Institute of Geochemistry, Chinese Academy of Sciences, Guiyang) (Grant No. 201308)
文摘The Baiyunpu deposit lies in the southwest plunging Dachengshan anticline in central Hunan, which is a large Pb-Zn polymetallic deposit. The orebodies were surrounded by the Qiziqiao Formation limestone in the Middle Devonian, and its geological occurrence is consistent with the wall rocks. A large number of spheroidal pyrite aggregates are found unevenly distributed in the ores. The spheroidal aggregates are made up of kernels and concentric rings. The kernels are composed of approximately epigranular pyrite nanocrystals, while the rings are composed of accumulated pyrite microcrystals growing along the radial direction. The spheroidal pyrite aggregate and its outer zones can be divided into five areas(A–E). The results of electron probe micro analysis(EPMA) show that from the zone A1 to B, Co/Ni 〈1, the sum of Co and Ni is 0.08%–0.26%, S/Fe increases from 2.06 to 2.15. While from the zone C to E, Ni cannot be detected and S/Fe decreases from 2.22 to 2.08. Powder X-ray diffraction(XRD) analysis in the micro zone shows obvious crystalline characteristics in the aggregates. Moving from the inside outwards, the maximum diffraction peak intensity of the(111) and(220) crystal planes of pyrite increases, and the crystallinity improves. The degree of change in the(111) plane is the most prominent. Considering the theory of crystal growth along with the geologic features of the depositional environment where the spheroidal pyrite aggregates developed, we confirm that the spheroidal aggregates are the result of nano-micro crystalline gathering and growth occurring by the following sequence of processes:nano-crystalline nucleation and growth, gathering into a ball, oriented growth of microcrystals, continuous accumulation, and adjustment of grain boundaries. The formation of the spheroidal pyrite aggregates in the late Qiziqiao Formation of the Middle Devonian occurred in a neutral to weak alkaline and reductive sedimentary environment in the normal oxygen-rich shallowwater carbonate platform edge. The variations in the S/Fe ratio and crystallisation characteristics indicate that during pyrite crystal growth, the sulphur fugacity was high locally and rose constantly, the degree of supersaturation decreased locally and the growth environment was stable relatively.
基金Aeronautic Science Foundation Programof China( 05G53038)
文摘Monodispersed silica microspheres with diameter of 353nm were assembled into photonic crystal in ethanol colloidal suspensions of varied silica volume fraction at different temperature and humidity by means of controllable vertical deposition method. The surface morphology and optical properties were studied by SEM and UV-Vis-NIR. It was found that the high-quality silica colloidal photonic crystals were obtained from ethanol solutions with environment temperature between 45℃ and 55℃, humidity between 66% and 76%, the volume fraction of microspheres is between 0.8% and 1.5%. The ordered close-packed photonic crystal fabricated by controllable vertical deposition method had the two photonic bandgaps in the visible light band and near infrared band.
文摘A dichlorosilane gas and a trichlorosilane gas in ambient hydrogen were evaluated to show their different gas flow motions in a slim vertical cold wall chemical vapor deposition reactor for the Minimal Fab system. This evaluation was performed for improving and controlling the film qualities and the productivities, using two quartz crystal microbalances (QCM) installed at the </span><span style="font-family:Verdana;">inlet and exhaust of the chamber by taking into account that the QCM frequency corresponds to the real time changes in the gas properties.</span><span style="font-family:Verdana;"> Typically, the time period approaching from the inlet to the exhaust was shorter for the trichlorosilane gas than that for the dichlorosilane gas. The trichlorosilane gas was shown to move like plug flow, while the dichlorosilane gas seemed to be well mixed in the entire chamber.
文摘MoS2 coatings were prepared using an unbalanced bipolar pulsed DC (direct current) magnetron sputtering apparatus under different targets, cathode current densities, power modes and bias voltages. The morphology, structure and growth characteristics of MoS2 coatings were observed and identified respectively by scanning electron microscopy, X-ray diffractometry and mass spectrometry. The results show that MoS2 coatings evolve with the (002) basal plane parallel to the surface by using cold pressed target with lower density, lower cathodic current density, bipolar pulse DC power and minus bias voltage, whereas the coatings deposited under hot pressed target, higher cathodic current density, simple DC power and positive bias voltage have the (002) basal plane perpendicular to the surface. The influence of deposition conditions on the crystal structure of MoS2 coating is implemented by altering its growth rate and the energy of sputtering-deposition particles.
基金Project supported by the National Natural Science Foundation of China(Grant No.61076010)the International Science and Technology Cooperation Program of Science and Technology Bureau of Changchun,China(Grant No.12ZX68)
文摘Orthogonal experiments of Ga Sb films growth on Ga As(001) substrates have been designed and performed by using a low-pressure metal–organic chemical vapor deposition(LP-MOCVD) system. The crystallinities and microstructures of the produced films were comparatively analyzed to achieve the optimum growth parameters. It was demonstrated that the optimized Ga Sb thin film has a narrow full width at half maximum(358 arc sec) of the(004) ω-rocking curve, and a smooth surface with a low root-mean-square roughness of about 6 nm, which is typical in the case of the heteroepitaxial single-crystal films. In addition, we studied the effects of layer thickness of Ga Sb thin film on the density of dislocations by Raman spectra. It is believed that our research can provide valuable information for the fabrication of high-crystalline Ga Sb films and can promote the integration probability of mid-infrared devices fabricated on mainstream performance electronic devices.
文摘Using the langasite crystal microbalance (LCM), the trends in film thickness produced by means of the chemical vapor deposition using trichlorosilane gas, monomethylsilane gas and their mixed gas were observed at 600?C and evaluated by comparison with the information from a transmission electron microscope (TEM). The crystalline silicon film thickness from trichlorosilane gas was comparable to that of an amorphous silicon carbide film from monomethylsilane gas. The film obtained from the gas mixture was amorphous and was the thinnest in this study. Because the thickness trend obtained by the LCM agreed with that by the TEM, the LCM is shown to be a convenient evaluation tool for the behavior of various film deposition.
文摘Cu-phthalocyanine is widely studied as a hole-transport layer in organic electronic devices. Since Cu-phthalocyanine is a molecular solid, the crystal structure depends on a circumstance to a great extent. Vacuum deposited layers were known to consist of two consecutive layers. In this article, Cu-phthalocyanine was deposited on the glass substrate inclined at several angles. The thickness of the first layer was found to be dependent on the substrate angle.
基金Supported by National Natural Science Foundation of China(No.41390444)
文摘Erdaohezi lead-zinc deposit belongs to the Derbugan metallogenic belt lying on the northwestern Hailaer-Genhe Mesozoic volcanic basin,located on the western slope of the Da Hinggan Mountains. The deposit is considered as one of the hypabyssal low-temprature hydrothermal lead-zinc deposits associated with volcanism. In order to lay the foundation on studying its diagenesis and mineralization ages,the detailed studies were carried out by dating the host rocks( i. e. rhyolitic lithic-crystal tuffs) using zircon LA-ICP-MS U-Pb method.The dating results show three groups of ages. The first group is the captured zircons( the weighted mean ^(206)Pb /^(238) U age as 175. 6 ± 2. 3 Ma,MSWD = 0. 70,n = 3). The second group can be regarded as the rockforming age( the weighted mean ^(206)Pb /^(238) U age as 165. 3 ± 1. 9 Ma,MSWD = 2. 40,n = 14). The third group should represent the late stage of the magmatic evolution( the weighted mean ^(206)Pb /^(238) U age as 161. 0 ± 3. 1Ma,MSWD = 0. 86,n = 4). According to the ages and the crystal form or CL image characteristics of zircons,it is determined that the diagenesis occurred in the late Middle Jurassic. Based on the regional geology and geochronological research,the acidic pyroclastic rocks are space accompaniment and time connection with the Tamulangou Formation intermediate-mafic volcanic rocks. Both of them constitute the host rocks of the deposit together. The rock combination also provides favorable conditions for large-scale silver,lead and zinc mineralization in this area.